DE69406166T2 - Water repellent organosilicon compositions - Google Patents
Water repellent organosilicon compositionsInfo
- Publication number
- DE69406166T2 DE69406166T2 DE69406166T DE69406166T DE69406166T2 DE 69406166 T2 DE69406166 T2 DE 69406166T2 DE 69406166 T DE69406166 T DE 69406166T DE 69406166 T DE69406166 T DE 69406166T DE 69406166 T2 DE69406166 T2 DE 69406166T2
- Authority
- DE
- Germany
- Prior art keywords
- water repellent
- organosilicon compositions
- repellent organosilicon
- compositions
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title 1
- 230000002940 repellent Effects 0.000 title 1
- 239000005871 repellent Substances 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/06—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wood
- B05D7/08—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wood using synthetic lacquers or varnishes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/4922—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/495—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
- C04B41/4961—Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/62—Coating or impregnation with organic materials
- C04B41/64—Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/4935—Impregnated naturally solid product [e.g., leather, stone, etc.]
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/035,025 US5300327A (en) | 1993-03-22 | 1993-03-22 | Water repellent organosilicon compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69406166D1 DE69406166D1 (en) | 1997-11-20 |
DE69406166T2 true DE69406166T2 (en) | 1998-04-23 |
Family
ID=21880157
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69406166T Expired - Lifetime DE69406166T2 (en) | 1993-03-22 | 1994-03-15 | Water repellent organosilicon compositions |
Country Status (6)
Country | Link |
---|---|
US (1) | US5300327A (en) |
EP (1) | EP0616990B1 (en) |
JP (1) | JP4008509B2 (en) |
CA (1) | CA2115622C (en) |
DE (1) | DE69406166T2 (en) |
ES (1) | ES2107747T3 (en) |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4330967A1 (en) * | 1993-09-13 | 1995-03-16 | Pfersee Chem Fab | Compositions containing organic silicon compounds for the treatment of fiber materials |
US5421866A (en) * | 1994-05-16 | 1995-06-06 | Dow Corning Corporation | Water repellent compositions |
US6572978B1 (en) * | 1994-05-24 | 2003-06-03 | Brian G. Bagley | Method of making wood composition boards resistant to water permeation |
DE4419257A1 (en) * | 1994-06-01 | 1995-12-07 | Wacker Chemie Gmbh | Process for water-repellent impregnation of gypsum |
DE19744612A1 (en) * | 1997-10-09 | 1999-04-15 | Wacker Chemie Gmbh | Emulsions of organosilicon compounds for the hydrophobization of building materials |
US6294608B1 (en) | 1995-05-11 | 2001-09-25 | Wacker-Chemie Gmbh | Emulsions of organosilicon compounds for imparting water repellency to building materials |
US5650001A (en) * | 1995-12-01 | 1997-07-22 | Howell; Bradley | Compositions and methods for treating compact discs |
GB9605706D0 (en) * | 1996-03-19 | 1996-05-22 | Dow Corning | Method for hydrophobing gypsum |
US5811483A (en) * | 1996-04-01 | 1998-09-22 | Syn-Coat Enterprises, Inc. | Water repellent system |
WO1997036967A1 (en) * | 1996-04-02 | 1997-10-09 | S.C. Johnson & Son, Inc. | A method for imparting hydrophobicity to a surface of a substrate with low concentration organofunctional silanes |
GB9614978D0 (en) * | 1996-07-17 | 1996-09-04 | Dow Corning | Gypsum mixture containing hydrophobic additive and method for hydrophobing gypsum |
US5782962A (en) * | 1996-10-16 | 1998-07-21 | Sara Lee Corporation | Cleaning and polishing composition |
US5695551A (en) * | 1996-12-09 | 1997-12-09 | Dow Corning Corporation | Water repellent composition |
US6114299A (en) * | 1997-12-23 | 2000-09-05 | Wacker Silicones Corporation | Textile treating compositions comprising n-functional organopolysiloxanes and polyisobutylene polymers, and process of using same |
WO1999034933A1 (en) * | 1998-01-02 | 1999-07-15 | Ashland Inc. | Water repellent glass treatment for automotive applications |
US6403163B1 (en) | 2000-06-27 | 2002-06-11 | Chemrex, Inc. | Method of treating surfaces with organosilicon water repellent compositions |
US6323268B1 (en) | 2000-06-27 | 2001-11-27 | Dow Corning Corporation | Organosilicon water repellent compositions |
US6689200B2 (en) | 2001-07-25 | 2004-02-10 | The Sherwin-Williams Company | Film-forming water-based water repellent coating compositions |
EP1441016A4 (en) * | 2001-09-25 | 2005-04-27 | Daikin Ind Ltd | Hydrophilizing wax composition |
EP1388571A1 (en) * | 2002-08-08 | 2004-02-11 | Ciba Spezialitätenchemie Pfersee GmbH | Organopolysiloxane composition comprising quaternized ammonium groups |
WO2006113183A1 (en) * | 2005-04-18 | 2006-10-26 | Dow Corning Corporation | Architectural coating compositions containing silicone resins |
CA2656793C (en) * | 2006-07-07 | 2015-10-06 | Ranka, Seema Ajay | Methods of treating surfaces with ionic organosilicon compositions |
WO2008004243A2 (en) * | 2006-07-07 | 2008-01-10 | Ranka, Seema, Ajay | Ionic organosilicon compounds and compositions thereof |
US7553983B2 (en) | 2006-07-07 | 2009-06-30 | Zydex Industries | Organosilicon compounds |
US8455585B2 (en) * | 2006-11-14 | 2013-06-04 | Wacker Chemical Corporation | Water repellant compositions and coatings |
DK2139963T3 (en) * | 2007-04-26 | 2015-08-24 | Dow Corning | AUXILIARY SILICONE EMULSIONS FOR THE PUBLICITY OF WATERPROOFABILITY |
EP2096151A1 (en) * | 2008-02-27 | 2009-09-02 | Degussa Novara Technology S.p.A. | Composition |
WO2010046370A1 (en) | 2008-10-24 | 2010-04-29 | Dow Corning Corporation | Composition containing a silicon-containing compound |
DE102009047582A1 (en) * | 2009-12-07 | 2011-06-09 | Wacker Chemie Ag | Silicone resin emulsion and its use in the hydrophobing of gypsum |
JP2013515154A (en) | 2009-12-22 | 2013-05-02 | ダウ コーニング コーポレーション | Water dispersible silicone resin |
WO2011087829A1 (en) | 2009-12-22 | 2011-07-21 | Dow Corning Corporation | Aqueous emulsions of alkylalkoxysilanes |
JP5720227B2 (en) * | 2009-12-28 | 2015-05-20 | 日信化学工業株式会社 | Wood processing method |
DE102010031178A1 (en) * | 2010-07-09 | 2012-01-12 | Evonik Degussa Gmbh | Quaternary amino alcohol functional, organosilicon compounds, compositions containing them and their preparation and use |
DE102010031184A1 (en) * | 2010-07-09 | 2012-01-12 | Evonik Degussa Gmbh | Process for the preparation of a dispersion comprising silica particles and cationizing agents |
CN103003333A (en) | 2010-07-22 | 2013-03-27 | 道康宁公司 | Process for making polysiloxane emulsions |
DE102012221170A1 (en) * | 2012-11-20 | 2014-05-22 | Evonik Industries Ag | Process for deep impregnation of mineral substrates and use of organosilanes and / or organosiloxanes for deep impregnation of mineral substrates |
CN108883998A (en) | 2016-04-20 | 2018-11-23 | 美国陶氏有机硅公司 | Alkyl silicic acids lithium composition, coating and preparation method thereof |
US10487242B2 (en) | 2016-08-11 | 2019-11-26 | Gelest Technologies, Inc. | Stabilized solutions of alkylalkoxysilane hydrolysates and flexible films formed thereof |
US11118352B2 (en) | 2017-12-20 | 2021-09-14 | Certainteed Llc | Microbial growth and dust retardant roofing shingles |
JP2021054874A (en) * | 2018-01-30 | 2021-04-08 | マナック株式会社 | Anti-static agent |
US20220017778A1 (en) | 2018-12-31 | 2022-01-20 | Zydex Inc. | Methods of Treating Inorganic Surfaces |
CN116004118B (en) * | 2021-10-22 | 2023-09-29 | 中国石油化工股份有限公司 | Coating treatment fluid and preparation method and application thereof |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB804241A (en) * | 1953-11-26 | 1958-11-12 | Tretol Ltd | Waterproofing compositions and use thereof |
JPS5122757A (en) * | 1974-08-19 | 1976-02-23 | Shinetsu Chemical Co | ORUGANOHORISHIROKISANSOSEIBUTSU |
US3963677A (en) * | 1974-11-21 | 1976-06-15 | Enger Carl C | Impermeable silicone composition |
US4221688A (en) * | 1978-04-28 | 1980-09-09 | Dow Corning Corporation | Silicone emulsion which provides an elastomeric product and methods for preparation |
FR2477563A1 (en) * | 1980-03-04 | 1981-09-11 | Dev Rech Indle | Bill sticking and graffiti prevention compsn. - prepd. from wax. soln. aq. air polymerisable monomer soln., xylene, toluene butyl alcohol, (m)ethanol, castor oil and petroleum fraction |
US4273813A (en) * | 1980-05-19 | 1981-06-16 | Dow Corning Corporation | Method of providing waterproof coating for masonry walls |
JPS6096650A (en) * | 1983-10-31 | 1985-05-30 | Toray Silicone Co Ltd | Production of aqueous silicone emulsion composition |
US5037873A (en) * | 1989-08-08 | 1991-08-06 | Pcr Group, Inc. | Water-repellent silane emulsions comprising copolymers of acrylic acid and alkyl methacrylates |
US5226954A (en) * | 1989-12-22 | 1993-07-13 | Toyo Ink Manufacturing Co., Ltd. | Organosilicon composition |
US5073195A (en) * | 1990-06-25 | 1991-12-17 | Dow Corning Corporation | Aqueous silane water repellent compositions |
US5154759A (en) * | 1991-04-11 | 1992-10-13 | Dow Corning Corporation | Polish containing amine functional siloxane |
US5205860A (en) * | 1992-01-23 | 1993-04-27 | Dow Corning Corporation | Water repellents containing organosilicon compounds |
US5217758A (en) * | 1992-05-15 | 1993-06-08 | Dow Corning Corporation | Silicone containing automotive vinyl protectant |
-
1993
- 1993-03-22 US US08/035,025 patent/US5300327A/en not_active Expired - Lifetime
-
1994
- 1994-02-14 CA CA002115622A patent/CA2115622C/en not_active Expired - Lifetime
- 1994-03-01 JP JP03117394A patent/JP4008509B2/en not_active Expired - Lifetime
- 1994-03-15 EP EP94301828A patent/EP0616990B1/en not_active Expired - Lifetime
- 1994-03-15 DE DE69406166T patent/DE69406166T2/en not_active Expired - Lifetime
- 1994-03-15 ES ES94301828T patent/ES2107747T3/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0616990A1 (en) | 1994-09-28 |
JP4008509B2 (en) | 2007-11-14 |
EP0616990B1 (en) | 1997-10-15 |
ES2107747T3 (en) | 1997-12-01 |
CA2115622C (en) | 2004-11-02 |
DE69406166D1 (en) | 1997-11-20 |
JPH06322319A (en) | 1994-11-22 |
CA2115622A1 (en) | 1994-09-23 |
US5300327A (en) | 1994-04-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |