DE69232891T2 - Reforming process under low sulfur conditions - Google Patents

Reforming process under low sulfur conditions

Info

Publication number
DE69232891T2
DE69232891T2 DE69232891T DE69232891T DE69232891T2 DE 69232891 T2 DE69232891 T2 DE 69232891T2 DE 69232891 T DE69232891 T DE 69232891T DE 69232891 T DE69232891 T DE 69232891T DE 69232891 T2 DE69232891 T2 DE 69232891T2
Authority
DE
Germany
Prior art keywords
hydrocarbons
reforming
reactor system
reactors
under low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69232891T
Other languages
German (de)
Other versions
DE69232891D1 (en
Inventor
John V Heyse
Robert L Hise
Bernard F Mulaskey
Steven E Trumbull
Robert A Innes
Daniel P Hagewiesche
Gale L Hubred
Steven C Moore
Paul F Bryan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron Phillips Chemical Co LP
Original Assignee
Chevron Phillips Chemical Co LLC
Chevron Phillips Chemical Co LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co LLC, Chevron Phillips Chemical Co LP filed Critical Chevron Phillips Chemical Co LLC
Application granted granted Critical
Publication of DE69232891D1 publication Critical patent/DE69232891D1/en
Publication of DE69232891T2 publication Critical patent/DE69232891T2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • C10G35/06Catalytic reforming characterised by the catalyst used
    • C10G35/095Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves

Abstract

There is disclosed a catalytic reforming method in which hydrocarbons are treated in a reactor system to produce an aromatics enriched product, said reactor system comprising: (a) a series of reactors (10,20,30), containing a catalyst bed comprising a sulfur sensitive zeolite reforming catalyst, and each being associated with (b) a respective furnace (11,21,31) each comprising a plurality of furnace tubes for heating hydrocarbons to an elevated temperature in the range of from 850 to 1025 F suitable for reforming, (c) a heat exchanger (12); and (d) a separator (13) for separating an aromatics enriched product from effluent gas; said method comprising passing hydrocarbons through said reactor system to contact the hydrocarbons with the reforming catalyst in said reactors and separating said aromatics enriched product from said effluent gas; wherein: (i) hydrocarbons are reformed in each of said reactors under low sulfur reforming conditions of less than 50ppb sulfur; and (ii) at least the furnace tubes of the reactor system are protected from carburization and metal dusting. Apparatus for carrying out the process is also described. <IMAGE>
DE69232891T 1991-03-08 1992-03-06 Reforming process under low sulfur conditions Expired - Lifetime DE69232891T2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US66669691A 1991-03-08 1991-03-08
US80321591A 1991-12-06 1991-12-06
US80282191A 1991-12-06 1991-12-06
US80306391A 1991-12-06 1991-12-06

Publications (2)

Publication Number Publication Date
DE69232891D1 DE69232891D1 (en) 2003-02-13
DE69232891T2 true DE69232891T2 (en) 2003-11-06

Family

ID=27505330

Family Applications (3)

Application Number Title Priority Date Filing Date
DE69232891T Expired - Lifetime DE69232891T2 (en) 1991-03-08 1992-03-06 Reforming process under low sulfur conditions
DE69233084T Expired - Lifetime DE69233084T2 (en) 1991-03-08 1992-03-06 Low sulfur reforming process
DE69222633T Expired - Lifetime DE69222633T2 (en) 1991-03-08 1992-03-06 REFORMING PROCEDURE WITH LOW SULFUR CONTENT

Family Applications After (2)

Application Number Title Priority Date Filing Date
DE69233084T Expired - Lifetime DE69233084T2 (en) 1991-03-08 1992-03-06 Low sulfur reforming process
DE69222633T Expired - Lifetime DE69222633T2 (en) 1991-03-08 1992-03-06 REFORMING PROCEDURE WITH LOW SULFUR CONTENT

Country Status (16)

Country Link
EP (3) EP0798363B1 (en)
JP (1) JP3836499B2 (en)
KR (1) KR100230727B1 (en)
CN (1) CN1039720C (en)
AT (1) ATE159040T1 (en)
AU (1) AU665534B2 (en)
BR (1) BR9205738A (en)
DE (3) DE69232891T2 (en)
ES (3) ES2108112T3 (en)
HU (1) HUT75107A (en)
MY (1) MY109992A (en)
NO (1) NO933165D0 (en)
OA (1) OA09910A (en)
SA (1) SA92130085B1 (en)
SG (2) SG72690A1 (en)
WO (1) WO1992015653A1 (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5413700A (en) * 1993-01-04 1995-05-09 Chevron Research And Technology Company Treating oxidized steels in low-sulfur reforming processes
JP3472577B2 (en) * 1993-01-04 2003-12-02 シェブロン ケミカル カンパニー Hydrodealkylation method
US5405525A (en) * 1993-01-04 1995-04-11 Chevron Research And Technology Company Treating and desulfiding sulfided steels in low-sulfur reforming processes
US5658452A (en) * 1994-01-04 1997-08-19 Chevron Chemical Company Increasing production in hydrocarbon conversion processes
US5575902A (en) * 1994-01-04 1996-11-19 Chevron Chemical Company Cracking processes
US5516421A (en) * 1994-08-17 1996-05-14 Brown; Warren E. Sulfur removal
US5565087A (en) * 1995-03-23 1996-10-15 Phillips Petroleum Company Method for providing a tube having coke formation and carbon monoxide inhibiting properties when used for the thermal cracking of hydrocarbons
AU7006596A (en) * 1995-06-07 1997-01-09 Chevron Chemical Company Using hydrocarbon streams to prepare a metallic protective l ayer
CA2229655C (en) * 1995-08-18 2004-11-23 Chevron Chemical Company Diffusion barriers for preventing high temperature hydrogen attack
US6497809B1 (en) * 1995-10-25 2002-12-24 Phillips Petroleum Company Method for prolonging the effectiveness of a pyrolytic cracking tube treated for the inhibition of coke formation during cracking
WO1997028235A1 (en) * 1996-02-02 1997-08-07 Chevron Chemical Company Llc Hydrocarbon processing in equipment having increased halide stress-corrosion cracking resistance
CN1043782C (en) * 1996-03-21 1999-06-23 中国石油化工总公司 Gasoline octane number-raising catalytic conversion method
US5914028A (en) * 1997-01-10 1999-06-22 Chevron Chemical Company Reforming process with catalyst pretreatment
US5879538A (en) * 1997-12-22 1999-03-09 Chevron Chemical Company Zeolite L catalyst in conventional furnace
US6120926A (en) * 1998-11-10 2000-09-19 International Fuel Cells, Llc Inhibition of carbon deposition on fuel gas steam reformer walls
US6258330B1 (en) * 1998-11-10 2001-07-10 International Fuel Cells, Llc Inhibition of carbon deposition on fuel gas steam reformer walls
AU6784601A (en) * 2000-06-28 2002-01-08 Sanyo Electric Co., Ltd. Fuel reforming reactor and method for manufacture thereof
CN1394981A (en) * 2001-07-09 2003-02-05 李兰根 Atmosphere heat treatment adjuvant and its application method
RU2470065C2 (en) * 2007-10-31 2012-12-20 Чайна Петролеум & Кемикал Корпорейшн Method of passivation for continuous reforming plant (versions)
DE202009005950U1 (en) 2009-04-27 2009-08-20 Holland-Letz, Peter Tissue for body cover for the application of medicines
US20120277500A1 (en) * 2011-04-29 2012-11-01 Uop Llc High Temperature Platforming Process
US20120277511A1 (en) * 2011-04-29 2012-11-01 Uop Llc High Temperature Platformer
CN102898265B (en) * 2011-07-29 2014-08-06 中国石油化工股份有限公司 Method for producing olefin
ES2549704B1 (en) * 2014-04-30 2016-09-08 Abengoa Hidrógeno, S.A. Water vapor reforming reactor tube
DK3336055T3 (en) 2016-12-19 2019-08-05 Air Liquide CORROSION PROTECTED REFORMER PIPE WITH INTERNAL HEAT EXCHANGE
CN115463662B (en) * 2022-10-08 2023-06-02 中国矿业大学 Preparation of supported intermetallic compound catalyst and application of supported intermetallic compound catalyst in hydrodeoxygenation of lignin-derived phenolic compounds

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1149163A (en) * 1966-03-22 1969-04-16 Ici Ltd Protection against carburisation
GB1362374A (en) * 1970-06-17 1974-08-07 Wisniewski L Method of and composition for anti-corrosive protection by reduc tion of ionised metals on metal substrate
CH556396A (en) * 1971-11-03 1974-11-29 Buechler Josef Heinrich Forming corrosion-preventing coatings on metals - by thermally decomposing paint contg. metal pigment and binder
US4348271A (en) * 1981-07-14 1982-09-07 Exxon Research & Engineering Co. Catalytic reforming process
US4447316A (en) * 1982-02-01 1984-05-08 Chevron Research Company Composition and a method for its use in dehydrocyclization of alkanes
US4456527A (en) * 1982-10-20 1984-06-26 Chevron Research Company Hydrocarbon conversion process
US4634515A (en) * 1985-10-25 1987-01-06 Exxon Research And Engineering Company Nickel adsorbent for sulfur removal from hydrocarbon feeds
US4692234A (en) * 1986-04-09 1987-09-08 Phillips Petroleum Company Antifoulants for thermal cracking processes
JPS62256946A (en) * 1986-04-30 1987-11-09 Nippon Kokan Kk <Nkk> Cr-mo steel excellent in resistance to creep embrittlement and low-temperature cracking
FR2600668B1 (en) * 1986-06-25 1989-05-19 Inst Francais Du Petrole CATALYTIC REFORMING PROCESS THROUGH AT LEAST TWO CATALYST BEDS

Also Published As

Publication number Publication date
EP0798363B1 (en) 2003-05-28
WO1992015653A1 (en) 1992-09-17
DE69222633T2 (en) 1998-04-23
SA92130085B1 (en) 2006-04-22
ES2108112T3 (en) 1997-12-16
DE69233084T2 (en) 2004-01-29
SG72690A1 (en) 2000-05-23
EP0798363A3 (en) 1998-03-11
KR100230727B1 (en) 1999-11-15
AU1580192A (en) 1992-10-06
EP0845521B1 (en) 2003-01-08
CN1039720C (en) 1998-09-09
HUT75107A (en) 1997-04-28
EP0798363A2 (en) 1997-10-01
ES2201223T3 (en) 2004-03-16
MY109992A (en) 1997-10-31
DE69233084D1 (en) 2003-07-03
AU665534B2 (en) 1996-01-11
NO933165D0 (en) 1993-09-06
JPH06507191A (en) 1994-08-11
JP3836499B2 (en) 2006-10-25
DE69222633D1 (en) 1997-11-13
ATE159040T1 (en) 1997-10-15
SG96561A1 (en) 2003-06-16
BR9205738A (en) 1994-08-23
EP0576571B1 (en) 1997-10-08
EP0576571A1 (en) 1994-01-05
DE69232891D1 (en) 2003-02-13
CN1067258A (en) 1992-12-23
OA09910A (en) 1994-09-15
EP0845521A1 (en) 1998-06-03
EP0576571A4 (en) 1994-03-23
ES2190551T3 (en) 2003-08-01
HU9302543D0 (en) 1993-12-28

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Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: CHEVRON PHILLIPS CHEMICAL CO. LP, HOUSTON, TEX., U

8327 Change in the person/name/address of the patent owner

Owner name: CHEVRON PHILLIPS CHEMICAL CO. LP, THE WOODLANDS, T

8364 No opposition during term of opposition