DE69203327T2 - METHOD FOR PRODUCING A PURIFIED DERIVATE FROM AN ACRYLAMIDOSULFONIC ACID MONOMER. - Google Patents
METHOD FOR PRODUCING A PURIFIED DERIVATE FROM AN ACRYLAMIDOSULFONIC ACID MONOMER.Info
- Publication number
- DE69203327T2 DE69203327T2 DE69203327T DE69203327T DE69203327T2 DE 69203327 T2 DE69203327 T2 DE 69203327T2 DE 69203327 T DE69203327 T DE 69203327T DE 69203327 T DE69203327 T DE 69203327T DE 69203327 T2 DE69203327 T2 DE 69203327T2
- Authority
- DE
- Germany
- Prior art keywords
- purified
- group
- nitrogens
- derivate
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/42—Separation; Purification; Stabilisation; Use of additives
- C07C303/44—Separation; Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Peptides Or Proteins (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
A process for the preparation of a purified monomer is disclosed which comprises the steps of reacting an impure monomerwherein R1 and R2 are independently hydrogen or alkyl groups containing from 1 to about 6 carbon atoms, with(B) a substantially aqueous solution of an oxide or hydroxide of the structure MO or MOH wherein M is a Group IA or Group IIA metal, or an amine of the structure NR3R4R5 wherein R3, R4 and R5 are independently hydrogen or alkyl, alkanol or alkoxy groups containing from 1 to about 12 carbon atoms,wherein the molar ratio of (A):(B) is from about 1:1-2 for Group IA metals, 2:1-2 for Group IIA metals or ratio of moles of (A) to nitrogens of (B) is from about 1:1-2 nitrogens to form a salt, wherein in order to prevent polymerization of (A), the purified monomer or both or prevent undesired side reactions, the reaction of (A) and (B) occurs at a temperature of between about -20 to 75° C. and at a pH between about 7 to about 12.5, and recovering a purified salt by crystallization in the presence of an oxygen bearing gas stream by subjecting the aqueous solution to changes in temperature and/or pressure and/or concentration.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US70974591A | 1991-06-03 | 1991-06-03 | |
| PCT/US1992/003754 WO1992021652A1 (en) | 1991-06-03 | 1992-05-06 | Process for the preparation of a purified acrylamido sulfonic acid monomer derivative |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69203327D1 DE69203327D1 (en) | 1995-08-10 |
| DE69203327T2 true DE69203327T2 (en) | 1995-11-02 |
Family
ID=24851163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69203327T Expired - Fee Related DE69203327T2 (en) | 1991-06-03 | 1992-05-06 | METHOD FOR PRODUCING A PURIFIED DERIVATE FROM AN ACRYLAMIDOSULFONIC ACID MONOMER. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6331647B1 (en) |
| EP (1) | EP0541770B1 (en) |
| JP (1) | JPH05508869A (en) |
| AT (1) | ATE124682T1 (en) |
| AU (1) | AU1993692A (en) |
| CA (1) | CA2087715A1 (en) |
| DE (1) | DE69203327T2 (en) |
| ES (1) | ES2077421T3 (en) |
| FI (1) | FI930345A (en) |
| MX (1) | MX9202625A (en) |
| NO (1) | NO179323C (en) |
| WO (1) | WO1992021652A1 (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5912387A (en) * | 1997-01-28 | 1999-06-15 | The Dow Chemical Company | Amine heat stable salt neutralization having reduced solids |
| JP2004345994A (en) * | 2003-05-21 | 2004-12-09 | Nippon Shokubai Co Ltd | Method for purifying n-vinyl-2-pyrrolidone |
| US20080221253A1 (en) * | 2004-02-19 | 2008-09-11 | The Lubrizol Corporation | Lipophilic Properties of 2-Acrylamido-2-Methylpropanesulfonic Acid |
| JP5304205B2 (en) * | 2007-12-06 | 2013-10-02 | 東亞合成株式会社 | 2-acrylamido-2-methylpropanesulfonic acid and method for producing the same |
| CN102452965B (en) * | 2010-10-22 | 2013-08-14 | 中国石油化工股份有限公司 | Method for removing polymerization inhibitor in AMPS (2-acrylamide-2-methyl propanesulfonic acid) raw material |
| US9073826B2 (en) | 2011-11-29 | 2015-07-07 | Basf Se | Process for preparing and purifying salts of acrylamido-2-methylpropanesulfonic acid |
| RU2619462C2 (en) * | 2011-11-29 | 2017-05-16 | Басф Се | Method for acrylamide-2-methylpropanesulfonic acid salts production and treatment |
| CN103086930A (en) * | 2013-01-17 | 2013-05-08 | 潍坊泉鑫化工有限公司 | Method for extracting 2-acrylamide-2-methylpropanesulfonic acid from recrystallization filtrate |
| CN103086929B (en) * | 2013-02-04 | 2014-11-05 | 梅龙毅 | Solid acrylamidealkyl sulfonate preparation method |
| CN103254102B (en) * | 2013-06-06 | 2015-09-30 | 梅龙毅 | A kind of method of purifying acrylamide alkyl sulfonic acid |
| FR3041344B1 (en) * | 2015-09-18 | 2019-12-13 | S.P.C.M. Sa | PROCESS FOR OBTAINING 2-ACRYLAMIDO-2-METHYLPROPANESULPHONIC ACID MONOMER AND POLYMER COMPRISING SAID MONOMER |
| WO2017162545A1 (en) | 2016-03-24 | 2017-09-28 | Basf Se | Method for producing atbs and copolymers therefrom |
| FR3064004B1 (en) * | 2017-03-20 | 2019-03-29 | S.P.C.M. Sa | HYDRATED CRYSTALLINE FORM OF 2-ACRYLAMIDO-2-METHYLPROPANE SULFONIC ACID |
| CN110857280B (en) * | 2018-08-22 | 2022-06-03 | 潍坊金石环保科技有限公司 | Preparation method of 2-acrylamide-2-methylpropanesulfonate |
| CN112047863A (en) * | 2020-09-19 | 2020-12-08 | 寿光市荣晟新材料有限公司 | Preparation process of 2-acrylamide-2-methylpropanesulfonic acid sodium salt |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2549840A1 (en) * | 1975-11-06 | 1977-05-12 | Lubrizol Corp | Acrylamido-alkane-sulphonic acid amine and quat. ammonium salts - and their (co)polymers used as lubricant additives and pesticides |
| JPS54106427A (en) * | 1978-02-09 | 1979-08-21 | Nitto Chem Ind Co Ltd | Purification of 2-acrylamide-2-methylpropane sulfonic acid |
| US4650614A (en) * | 1980-02-21 | 1987-03-17 | Medtronic, Inc. | Refining of reaction grade 2-acrylamido-2-methylpropane sulfonic acid |
| JPS58225056A (en) * | 1982-06-24 | 1983-12-27 | Mitsui Toatsu Chem Inc | Preparation of amidoalkanesulfonic acid derivative |
| DE3627455A1 (en) * | 1985-08-15 | 1987-02-19 | Chevron Res | ACRYLAMIDO AND METHACRYLAMIDO-N SUBSTITUTED SULPHONIC ACIDS |
-
1992
- 1992-05-06 AT AT92912157T patent/ATE124682T1/en active
- 1992-05-06 AU AU19936/92A patent/AU1993692A/en not_active Abandoned
- 1992-05-06 EP EP92912157A patent/EP0541770B1/en not_active Expired - Lifetime
- 1992-05-06 WO PCT/US1992/003754 patent/WO1992021652A1/en active IP Right Grant
- 1992-05-06 ES ES92912157T patent/ES2077421T3/en not_active Expired - Lifetime
- 1992-05-06 CA CA002087715A patent/CA2087715A1/en not_active Abandoned
- 1992-05-06 DE DE69203327T patent/DE69203327T2/en not_active Expired - Fee Related
- 1992-05-06 JP JP93500413A patent/JPH05508869A/en active Pending
- 1992-06-02 MX MX9202625A patent/MX9202625A/en not_active IP Right Cessation
-
1993
- 1993-01-27 FI FI930345A patent/FI930345A/en unknown
- 1993-02-02 NO NO930357A patent/NO179323C/en unknown
-
1994
- 1994-12-14 US US08/355,712 patent/US6331647B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US6331647B1 (en) | 2001-12-18 |
| FI930345A0 (en) | 1993-01-27 |
| FI930345A (en) | 1993-01-27 |
| JPH05508869A (en) | 1993-12-09 |
| NO179323C (en) | 1996-09-18 |
| ES2077421T3 (en) | 1995-11-16 |
| ATE124682T1 (en) | 1995-07-15 |
| MX9202625A (en) | 1993-04-01 |
| AU1993692A (en) | 1993-01-08 |
| NO179323B (en) | 1996-06-10 |
| NO930357L (en) | 1993-02-02 |
| EP0541770B1 (en) | 1995-07-05 |
| WO1992021652A1 (en) | 1992-12-10 |
| NO930357D0 (en) | 1993-02-02 |
| DE69203327D1 (en) | 1995-08-10 |
| CA2087715A1 (en) | 1992-12-04 |
| EP0541770A1 (en) | 1993-05-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |