DE597448C - Method for gluing foils made from cellulose hydrate - Google Patents

Method for gluing foils made from cellulose hydrate

Info

Publication number
DE597448C
DE597448C DEW75084D DEW0075084D DE597448C DE 597448 C DE597448 C DE 597448C DE W75084 D DEW75084 D DE W75084D DE W0075084 D DEW0075084 D DE W0075084D DE 597448 C DE597448 C DE 597448C
Authority
DE
Germany
Prior art keywords
adhesive
cellulose hydrate
gluing
foils made
sugar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEW75084D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Produktions und Vertriebs GmbH and Co oHG
Original Assignee
Wolff and Co AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wolff and Co AG filed Critical Wolff and Co AG
Priority to DEW75084D priority Critical patent/DE597448C/en
Application granted granted Critical
Publication of DE597448C publication Critical patent/DE597448C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • C08J5/127Aqueous adhesives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2301/00Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • C08J2301/06Cellulose hydrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Description

Verfahren zum Kleben von Folien aus Cellulosehydrat Verwendet man zum Zusammenkleben von Folien aus Cellulosehydrat die für Papier üblichen wässerigen Lösungen von Leim, Gelatine, Stärke, Gummiarabikum und ähnlichen Stoffen, so tritt beim Auftragen dieser Klebemittel infolge ihres hohen Wassergehaltes ein starkes Quellen der Cellulosehydratschichten durch Wasseraufnahme aus dem Klebemittel auf. Dies hat beim nachberigen Trocknen eine starke Faltenbildung zur Folge, die dem Enderzeugnis ein unschönes Aussehen verleiht.Method for gluing sheets of cellulose hydrate is used For gluing together foils made of cellulose hydrate, the aqueous ones commonly used for paper Solutions of glue, gelatin, starch, gum arabic and similar substances, so occurs when applying these adhesives due to their high water content a strong one Swelling of the cellulose hydrate layers by absorption of water from the adhesive. This leads to strong wrinkles when it is dried afterwards, which leads to the Gives the end product an unsightly appearance.

Erfindungsgemäß hat sich nun gezeigt, daß man diesem Übelstande abhelfen kann, wenn man den osmotischen Druck der als Klebemittel benutzten wässerigen Lösungen erhöht und dadurch das Quellvermögen der Klebemittel entsprechend vermindert. Diese Erhöhung des osmotischen Druckes wird nach der Erfindung dadurch erreicht, daß zu wässerigen Lösungen von Klebestoffen, z. B. von Leim, Gelatine oder Gummiarabikum, ein Zusatz von Zucker oder Sirup in einer solchen Menge zugegeben wird, daß die wässerigen Klebstofflösungen auf die Cellulosehydratfolien praktisch keine quellende Wirkung mehr auszuüben vermögen.According to the invention it has now been shown that this deficiency can be remedied can if one considers the osmotic pressure of the aqueous solutions used as adhesives increased and thereby the swelling capacity of the adhesive correspondingly reduced. These Increasing the osmotic pressure is achieved according to the invention in that to aqueous solutions of adhesives, e.g. B. of glue, gelatine or gum arabic, an addition of sugar or syrup is added in such an amount that the aqueous adhesive solutions on the cellulose hydrate films practically no swelling Be able to exert more effect.

Man hat bereits vorgeschlagen, einem aus Dextrin bestehenden Klebstoff eine geringe Menge Glycerin beizufügen, indem man auf i kg Dextrin 1/41 Wasser und etwa 5o g Glycerin zufügt. Ferner ist zum Überziehen von Papierbahnen mit Cellulosehvdratfolien schon ein Klebstoff verwendet worden, der aus 15 °/o Gelatine, 15 % Glycerin und 70 % Wasser besteht. In diesen beiden Klebstofflösungen kann das Glycerin bei dem vorgesehenen Prozentsatz nur als Weichinachungsmittel wirken, das ein Sprödewerden der Klebnaht verhindert, nicht aber kann es die Quellung einer Cellulosehydratfolie und die dadurch bedingte Schrumpffaltenbildung an der Klebnaht zweier Cellulosehydratfolien vermeiden. Hierzu .wird erfindungsgemäß Zucker und Sirup in wesentlich größeren Mengen verwendet, die so bestimmt sind, daß der Klebstoff auf die Folien keine quellende Wirkung mehr auszuüben vermag. Dieser grundsätzliche Unterschied besteht für das Verfahren der Erfindung auch gegenüber der bekannten Benutzung von Zucker und Sirup als Klebstoff, da auch bei diesem im übrigen wenig gebräuchlichen Kleben mittels Zucker oder Sirup nicht nach dem Gesichtspunkt der Erfindung bestimmte Mengen angewendet werden. Beispiel Zum Zusammenkleben von Viskoseglashäuten hat sich eine Mischung aus 2o g Gelatine, 6oo g Rohrzucker und 5oo ccm Wasser vorteilhaft erwiesen. Diese Klebemittellösung, der zweckmäßig zur Haltbarmachung i g Salicylsäure zugesetzt wird, ergibt glatte und auch sonst einwandfreie Klebenähte.It has already been proposed to add a small amount of glycerin to an adhesive made of dextrin by adding 1/41 of water and about 50 g of glycerin to 1 kg of dextrin. Furthermore, an adhesive has already been used for covering paper webs with cellulose substrate films which consists of 15 % gelatin, 15% glycerol and 70 % water. In these two adhesive solutions, the glycerine can only act as a softening agent in the intended percentage, which prevents the adhesive seam from becoming brittle, but cannot prevent the swelling of a cellulose hydrate film and the resulting shrinkage wrinkles on the adhesive seam of two cellulose hydrate films. For this purpose, sugar and syrup are used according to the invention in much larger quantities, which are determined in such a way that the adhesive is no longer able to exert a swelling effect on the films. This fundamental difference exists for the method of the invention also compared to the known use of sugar and syrup as adhesive, since even with this otherwise little common gluing by means of sugar or syrup, certain amounts are not used according to the aspect of the invention. Example A mixture of 20 g gelatine, 600 g cane sugar and 500 cc water has proven to be advantageous for gluing viscose glass skins together. This adhesive solution, to which salicylic acid is expediently added for preservation, results in smooth and otherwise perfect adhesive seams.

Claims (1)

PATENTANSPRUCH: Verfahren zum Kleben von Folien aus Cellulosehydrat mittels einer wässerigen Lösung von Klebstoffen mit einem Zusatz von wasserbindenden Mitteln, dadurch gekennzeichnet, daß man dem Klebstoff Zucker oder Sirup in solchen Mengen zusetzt, daß die wässerige Lösung des Klebstoffes auf die Folien praktisch keine quellende Wirkung mehr ausübt.PATENT CLAIM: Method for gluing foils made of cellulose hydrate by means of an aqueous solution of adhesives with an addition of water-binding Means, characterized in that the adhesive sugar or syrup in such Adds amounts that the aqueous solution of the adhesive on the films practical no longer has a swelling effect.
DEW75084D 1927-02-17 1927-02-17 Method for gluing foils made from cellulose hydrate Expired DE597448C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEW75084D DE597448C (en) 1927-02-17 1927-02-17 Method for gluing foils made from cellulose hydrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEW75084D DE597448C (en) 1927-02-17 1927-02-17 Method for gluing foils made from cellulose hydrate

Publications (1)

Publication Number Publication Date
DE597448C true DE597448C (en) 1934-05-24

Family

ID=7609806

Family Applications (1)

Application Number Title Priority Date Filing Date
DEW75084D Expired DE597448C (en) 1927-02-17 1927-02-17 Method for gluing foils made from cellulose hydrate

Country Status (1)

Country Link
DE (1) DE597448C (en)

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