DE595106C - Protecting wool, fur, etc. Like. Against attacks by textile pests - Google Patents

Protecting wool, fur, etc. Like. Against attacks by textile pests

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Publication number
DE595106C
DE595106C DEI44947D DEI0044947D DE595106C DE 595106 C DE595106 C DE 595106C DE I44947 D DEI44947 D DE I44947D DE I0044947 D DEI0044947 D DE I0044947D DE 595106 C DE595106 C DE 595106C
Authority
DE
Germany
Prior art keywords
sulfonic acid
fur
against attacks
butoxy
pests
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEI44947D
Other languages
German (de)
Inventor
Dr Theodor Hermann
Dr Walther Retter
Dr Robert Seydel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEI44947D priority Critical patent/DE595106C/en
Application granted granted Critical
Publication of DE595106C publication Critical patent/DE595106C/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/14—Ethers
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

Es wurde gef unden, daß halogensubstituierte Alkoxy- bzw. Aralkoxydi- oder -triarylmethanverbindungen bzw. ihre Sulfosäuren oder sonstigen Substitutionsprodukte in vorzüglicher Weise geeignet sind, Wolle, Pelzwerk u. dgl. gegen die Angriffe von Textilschädlingen zu schützen.It has been found that halogen-substituted alkoxy or aralkoxydi- or triarylmethane compounds or their sulfonic acids or other substitution products are particularly suitable, wool, fur and the like to protect against attacks by textile pests.

Die Anwendung dieser neuen Schutzsto'ffe kann sowohl in wäßriger Lösung wie aus organischen Lösungsmitteln erfolgen. Die angewandte Menge des Schutzstoffes wechselt mit der Wirksamkeit des Mittels. Ebenso können die neuen Produkte als solche oder in Mischung benutzt werden.The use of these new protective substances can be carried out both in aqueous solution and from organic solvents. The applied The amount of protective substance changes with the effectiveness of the agent. Likewise, the new products as such or can be used in a mixture.

Vor den bisher bekannten Verfahren, Textilien, wie Wolle, Pelze, Haare, Federn u. dgl., gegen Fraßschädlinge mit Hilfe von Oxydi- oder -triarylmethanverbindungen zu schützen, besitzt das erfmdungsgemäße Verfahren den Vorzug, daß die hiernach imprägnierten Textilien eine gesteigerte Wasch- und Lichtechtheit aufweisen.Before the previously known methods, textiles such as wool, furs, hair, feathers and the like., to protect against feeding pests with the help of oxydi- or triarylmethane compounds, the method according to the invention has the advantage that the textiles impregnated afterwards have increased wash and lightfastness.

Beispiel 1example 1

100 kg Ware werden nach Art des Färbeprozesses unter Zusatz von Säure mit 3 kg eines Produktes gemäß der Formel100 kg of goods are made according to the type of dyeing process with the addition of acid with 3 kg of a product according to the formula

behandelt, gegebenenfalls unter Zugabe eines Farbstoffes, der geeignet ist, gleichzeitig mit dem Schutzmittel aufzuziehen. Es können auch noch andere geeignete Chemikalien zugesetzt werden. Auf diese Weise wird die behandelte Ware gegen Angriffe von Textil-Schädlingen geschützt.treated, optionally with the addition of a dye which is suitable simultaneously with to pull up the protective agent. Other suitable chemicals can also be added will. In this way, the treated goods are protected against attacks by textile pests protected.

An Stelle des genannten Produktes könnenInstead of the product mentioned, you can

*) Von dem Patentsucher sind als die Erfinder angegeben worden:*) The patent seeker indicated the following as the inventors:

Dr. Theodor Hennann in Frankfurt a. M.-Höchst, Dr. Robert Seydel in Köln-Dellbrück und Dr. Walther Retter in Köln-Deuts.Dr. Theodor Hennann in Frankfurt a. M.-Höchst, Dr. Robert Seydel in Cologne-Dellbrück and Dr. Walther Retter in Cologne-Deuts.

CK: 'Tf CK: 'Tf

auch die Natriumsalze folgender Sulfosäuren verwendet werden:the sodium salts of the following sulfonic acids can also be used:

· 2'-Dimethoxy-3 · 5 · 3' · 5'-tetrachlortriphenylmethan-2"-sulfosäure,
2 ■ 2' - Diäthoxy - 3 · 5 · 3' · 5' - tetrachlortriphenylmethan-2"-sulfosäure,
· 2'-Di-(n- oder iso)-Propyloxy-3 · 5 · 3' · 5'-tetrachlortriphenylmethan-2"-sulfosäure, · 2'-Di-n-butoxy-3 · 5 · 3'"· 5'-tetrachlortriphenylmethan-2"-sulfosäure, · 2'-Dimethoxy-3 · 5 · 3 '· 5'-tetrachlorotriphenylmethane-2 "-sulfonic acid,
2 ■ 2 '- diethoxy - 3 · 5 · 3' · 5 '- tetrachlorotriphenylmethane-2 "-sulfonic acid,
· 2'-di- (n- or iso) -propyloxy-3 · 5 · 3 '· 5'-tetrachlorotriphenylmethane-2 "-sulfonic acid, · 2'-di-n-butoxy-3 · 5 · 3'"5'-tetrachlorotriphenylmethane-2"-sulfonic acid,

· 2'-Diisobutoxy-3 · 5 · 3' · s'-tetrachlortriphenylmethan-2"-sulfosäure,
· 2'-Diisoamyloxy-3 · 5■ · 3' · 5'-tetrachlor triphenylmethan-2"-sulfosäure,
2 · 2'-Diallyloxy-3 · 5 · 3' · 5'-tetrachlortriphenylmethan-2"-sulfosäure,
· 2'-Dicyclohexyloxy-3 · 5 · 3' · 5'-tetrachlortriphenylmethan-2"-sulfosäure,
· 2'-Dimethoxy-3 · 5 · 3' · s'-tetrachlortriphenylmethan-4"-sulfosäure, · 2'-Diisobutoxy-3 · 5 · 3 '· s'-tetrachlorotriphenylmethane-2 "-sulfonic acid,
· 2'-Diisoamyloxy-3 · 5 · 3 '· 5'-tetrachloro triphenylmethane-2 "-sulfonic acid,
2 · 2'-diallyloxy-3 · 5 · 3 '· 5'-tetrachlorotriphenylmethane-2 "-sulfonic acid,
· 2'-Dicyclohexyloxy-3 · 5 · 3 '· 5'-tetrachlorotriphenylmethane-2 "-sulfonic acid,
· 2'-Dimethoxy-3 · 5 · 3 '· s'-tetrachlorotriphenylmethane-4 "-sulfonic acid,

· 2'-Dimethoxy-3 · 3'-dimethyl-5' · 5'-dichlortriphenylmethan-4"-sulfosäure,
· 2'-Diäthoxy-3 · 5 · 3' · 5' · 4"-pentachlortriphenylmethan-6 "-sulf osäure,
2 · 2'-Di-n-butoxy-3 · 5 · 3' · 5' · 4"-pentachlor-· 2'-Dimethoxy-3 · 3'-dimethyl-5 '· 5'-dichlorotriphenylmethane-4 "-sulfonic acid,
· 2'-diethoxy-3 · 5 · 3 '· 5' · 4 "-pentachlorotriphenylmethane-6" -sulfonic acid,
2 x 2'-di-n-butoxy-3 x 5 x 3 'x 5' x 4 "-pentachlor-

triphenylmethan-6"-sulfosäure,
Dicyclohexyloxy-s · 5 · 3' · 5' ■ 4"-pentachlor-triphenylmethane-6 "-sulfonic acid,
Dicyclohexyloxy-s · 5 · 3 '· 5' ■ 4 "-pentachlor-

triphenylmethan-6"-sulfosäure,
Dibenzyloxy-3 · 5 · 3' · 5' · 4"-pentachlortriphenyknethan-6"-sulfosäure, triphenylmethane-6 "-sulfonic acid,
Dibenzyloxy-3 · 5 · 3 '· 5' · 4 "-pentachlorotriphenylnethan-6" -sulfonic acid,

· 2' - Dimethoxy - 3 · 5 · 3' · 5' - tetrachlor-4"-bromtriphenylmethan-6"-sulf osäure,
· 2'-Dimethoxy-3 · 5 · 3' · 5' · 3"-pentachlortriphenylmethan-6"-sulfosäure,
2 · 2'-Di-n-butoxy-3 · 5 · 3' · 5' · 3"-pentachlortriphenyltnethan-6"-sulfosäure,
· 2'-Dimethoxy-5 · 5' · 3"-trichlortriphenylmethan-6"-sulfosäure, · 2 '- Dimethoxy - 3 · 5 · 3' · 5 '- tetrachloro-4 "-bromtriphenylmethane-6" -sulfonic acid,
· 2'-Dimethoxy-3 · 5 · 3 '· 5' · 3 "-pentachlorotriphenylmethane-6" -sulfonic acid,
2 x 2'-di-n-butoxy-3 x 5 x 3 'x 5' x 3 "-pentachlorotriphenyltethane-6" -sulfonic acid,
· 2'-Dimethoxy-5 · 5 '· 3 "-trichlorotriphenylmethane-6" -sulfonic acid,

· 2'-Di-n-butoxy-3 · 3'-dimethjd-5 ■ 5' · 3"-trichlortriphenylmethan-o^sulfosaure, · 2'-Di-n-butoxy-3 · 3'-dimethjd-5 ■ 5 '· 3 "-trichlorotriphenylmethane-o ^ sulfonic acid,

· 3'-Di-n-butoxy-3 · 5 · 2' · 4' · 6'-pentachlortriphenylmethan-4"-sulfosäure. · 3'-Di-n-butoxy-3 · 5 · 2 '· 4' · 6'-pentachlorotriphenylmethane-4 "-sulfonic acid.

Beispiel 2Example 2

Die zu schützende Ware wird in eine Lösung von 2· 2'-Di-n-butoxy-5 «5'-dichlordiphenylmethan The goods to be protected are dissolved in a solution of 2x2'-di-n-butoxy-5 «5'-dichlorodiphenylmethane

OC4K0 H3C4O. sOC 4 K 0 H 3 C 4 O. s

ClCl

CH,CH,

ClCl

in einer Mischung von Cyclohexanon und Benzin eingelegt und nach voller Durchtränkung so weit ausgeschleudert, daß sie nach dem Trocknen 2 bis 3 0/0 des Schutzmittels enthält. Die so behandelte Ware ist mottenecht. placed in a mixture of cyclohexanone and gasoline and, after being fully soaked, thrown out so far that they after contains 2 to 3% of the protective agent after drying. The goods treated in this way are moth-proof.

Statt die Ware in die Lösung des Schutzmittels einzulegen, kann man auch so verfahren, daß man durch Aufspritzen oder eine sonst übliche Weise die Ware mit 2 bis 3 0/0 des Schutzmittels ausrüstet.Instead of immersing the goods in the solution of the protective agent, one can also proceed in this way, that you can spray the goods with 2 to 3 0/0 of the protective agent.

An Stelle des genannten Mittels können auch Produkte folgender Art angewandt werden: The following types of products can also be used in place of the agent mentioned:

2 · 2'-Di-n-butoxy-3 · 5 · 3' · 5' · 4"-pentachlortriphenylmethan, 2 x 2'-di-n-butoxy-3 x 5 x 3 'x 5' x 4 "-pentachlorotriphenylmethane,

2 · 2'-Di-n-butoxy-3 · 5 · 3' ■ 5' · 2" · 4" · 5"-heptachlortriphenylmethan, 2 x 2'-di-n-butoxy-3 x 5 x 3 '■ 5' x 2 "x 4" x 5 "-heptachlorotriphenylmethane,

2 · 2'-Di-n-butoxy-3 · 5 · 5'-trichlordiphenylmethan-3'-sulfosäure. 2x2'-di-n-butoxy-3x5x5'-trichlorodiphenylmethane-3'-sulfonic acid.

Claims (1)

Patentanspruch:Claim: Verwendung von halogensubstituierten Alkoxy- bzw. Aralkoxydi- oder -triarylmethanverbindungen bzw. ihrer Sulfosäuren oder sonstigen Substitutionsprodukte zum Schützen von Wolle, Pelzwerk u. dgl. gegen die Angriffe von Textilschädlingen. Use of halogen-substituted alkoxy or aralkoxydi- or triarylmethane compounds or their sulfonic acids or other substitution products to protect wool, fur and the like against attacks by textile pests.
DEI44947D 1932-07-22 1932-07-23 Protecting wool, fur, etc. Like. Against attacks by textile pests Expired DE595106C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEI44947D DE595106C (en) 1932-07-22 1932-07-23 Protecting wool, fur, etc. Like. Against attacks by textile pests

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE758192X 1932-07-22
DEI44947D DE595106C (en) 1932-07-22 1932-07-23 Protecting wool, fur, etc. Like. Against attacks by textile pests

Publications (1)

Publication Number Publication Date
DE595106C true DE595106C (en) 1934-04-05

Family

ID=25947737

Family Applications (1)

Application Number Title Priority Date Filing Date
DEI44947D Expired DE595106C (en) 1932-07-22 1932-07-23 Protecting wool, fur, etc. Like. Against attacks by textile pests

Country Status (1)

Country Link
DE (1) DE595106C (en)

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