DE586450C - Method of hardening - Google Patents

Method of hardening

Info

Publication number
DE586450C
DE586450C DEM113862D DEM0113862D DE586450C DE 586450 C DE586450 C DE 586450C DE M113862 D DEM113862 D DE M113862D DE M0113862 D DEM0113862 D DE M0113862D DE 586450 C DE586450 C DE 586450C
Authority
DE
Germany
Prior art keywords
hardening
layer
nitriding
workpieces
carburizing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEM113862D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MAN AG
Original Assignee
MAN Maschinenfabrik Augsburg Nuernberg AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MAN Maschinenfabrik Augsburg Nuernberg AG filed Critical MAN Maschinenfabrik Augsburg Nuernberg AG
Priority to DEM113862D priority Critical patent/DE586450C/en
Application granted granted Critical
Publication of DE586450C publication Critical patent/DE586450C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/02Pretreatment of the material to be coated
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)

Description

Verfahren zum Härten Mit der üblichen Kohlenstoffhärtung (Zementieren) von Werkstücken aus Eisen oder Stahl lassen sich im allgemeinen Härten. zwischen 6oo und 7oo Brinelleinheiten erzielen. Eine größere Härte wird demgegenüber durch das bekamite Nitrieren erzielt, welches aus einem oberflächlichen Eindringen von Stickstoff in das Eisen besteht. Die so gebildete Schicht mit einer Härte bis fast r ooo Brinelleinheiten ist außerordentlich verschleißfest. Der große Nachteil dieser hohen Nitrierhärte ist aber die geringe Widerstandsfähigkeit der nitrierten Schicht gegen hohe Flächendrücke, die darin begründet ist, daß diese harte dünne Schicht auf einer verhältnismäßig weichen Unterlage liegt und daher -unter Umständen sehr leichteingedrückt wird.Method of hardening With the usual carbon hardening (cementing) Workpieces made of iron or steel can generally be hardened. between Achieve 6oo and 7oo Brinel units. A greater hardness is on the other hand by obtained nitriding, which results from superficial penetration of Nitrogen is made up of iron. The layer thus formed with a hardness of almost r ooo Brinelle is extremely wear-resistant. The big disadvantage of this high nitriding hardness is the low resistance of the nitrided layer against high surface pressures, which is due to the fact that this hard thin layer is on a relatively soft surface and therefore - under certain circumstances very is slightly pressed.

Das bekannte Zementieren (Aufkohlen) mit seiner größeren Tiefenwirkung ergibt zwar eine bedeutend tragfähigere Härteschicht, doch besitzt diese nur die vorerwähnten Härtegrade von etwa 6oo biss 7oo Brinelleinheiten.The well-known cementing (carburizing) with its greater depth effect Although results in a significantly more stable hardness layer, this only has the the aforementioned degrees of hardness of about 600 to 7oo Brinel units.

Die vorliegende Erfindung besteht nun darin, die glasharte, aber dünne Nitrierschicht auf eine tragfähige, durch Aufkohlen gehärtete Decke zu legen. Neben der so erzielten hohen. Oberflächenhärte ergibt sich der weitere Vorteil, daß die aufgekohlte Schicht einen günstigen Übergang zum weichen Kern aufweist, was für die Haltbarkeit der Werkstücke von großem Wert ist. Das Verfahren wird erfindungsgemäß so ausgeführt, daß man die Werkstücke zuerst aufkohlt, dann die oberste Kohlungsschicht @entkohlt und hierauf nitriert. Die Art der für die Aufkohlung, Entkohlung und Nitrierung verwendeten Verfahren ist hierbei gleichgültig; die Technik kennt bereits zahlreiche Vorschläge dafür.The present invention now consists in the glass hard but thin Lay a nitriding layer on a stable, carburized cover. Next to the high level achieved in this way. Surface hardness results in the further advantage that the carburized layer has a favorable transition to the soft core, what for the durability of the workpieces is of great value. The method is according to the invention designed in such a way that the workpieces are first carburized, then the top layer of carburization @decarburized and then nitrided. The type of used for carburizing, decarburizing and nitriding The method used is irrelevant here; the technology already knows many Suggestions for that.

Es muß erwähnt werden, daß der Gedanke, Nitrieren und Aufkohlen (Zementieren) bei der Behandlung von Werkstücken zu vereinigen, an sich .nicht neu ist. So wurden schon Stahlguß und Grauguß, die sehr viel Kohlenstoff enthalten, vor dem Nitrieren zur Verbesserung des Nitriervorganges oberflächlich entkohlt. Die Erfindung unterscheidet sich hiervon dadurch, daß das Entkohlen bei einem Werkstück aus weichem Eisen oder Stahl angewendet wird, welches durch Härten vergütet werden soll, und insbesondere dadurch, daß die nach dem Aufkohlen wieder entkohlte Schicht ihrer ganzen Ausdehnung nachnitriert wird, so daß die nitrierte Schicht unmittelbar auf einer vorher durch Kohlehärtung gebildeten aufliegt. Weiterhin ist auch schon vorgeschlagen worden, Werkstücke erst durch Aufkohlen zu härten und dann durch Nitrieren noch weiter zu vergüten. Hierbei jedoch folgte der Nitriervorgang unmittelbar auf den Härtungsvorgang, also ohne Zwischenschaltung des Entkohlens. Dabei zeigte es sich, daß die Verbindung der beiden gehärteten Schichten unvollkommen war. Bekannt ist es auch, das Nitrieren und Aufkohlen (Zementieren) gleichzeitig erfolgen zu lassen, indem die Werkstücke in einer geeigneten Mischung von Salzen behandelt wurden, Das erzielte Ergebnis war hierbei aber meistens nicht einwandfrei, da die Tiefen der beiden Härtungsschichten nicht genau kontrolliert und nicht gegeneinander abgestimmt werden konnten.It must be mentioned that the idea of nitriding and carburizing (cementing) to unite in the treatment of workpieces, in itself. is not new. So were already cast steel and gray cast iron, which contain a lot of carbon, before nitriding Surface decarburized to improve the nitriding process. The invention differs from the fact that the decarburization of a workpiece made of soft iron or Steel is used, which is to be tempered by hardening, and in particular in that the layer which has been decarburized again after the carburizing takes place over its entire extent is post-nitrided, so that the nitrided layer immediately on a previously by Coal hardening rests formed. Furthermore, it has also already been suggested To harden workpieces first by carburizing and then to harden them further by nitriding reward. Here, however, the nitriding process immediately followed the hardening process, so without the interposition of decarburization. It turned out that the connection of the two hardened layers was imperfect. It is known also to let nitriding and carburizing (cementing) take place at the same time, by treating the workpieces in a suitable mixture of salts, that The result achieved was mostly not perfect because the depths of the both hardening layers are not precisely controlled and not coordinated with one another could become.

Claims (1)

PATENTANSPRUCH: Verfahren zum Härten. von Werkstükken aus weichem Eisen oder Stahl, dadurch gekennzeichnet; daß die Werkstücke zunächst aufgekohlt werden, dann die aufgekohlte Schicht bis zu bestimmten Tiefen entkohlt und hierauf die entköhlte Schicht bis zur Isohlungszone nitriert wird. PATENT CLAIM: Method of hardening. of work pieces made of soft iron or steel, characterized; that the workpieces are first carburized, then the carburized layer is decarburized to certain depths and then the decarburized layer is nitrided down to the Isohlungszone.
DEM113862D 1931-02-01 1931-02-01 Method of hardening Expired DE586450C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEM113862D DE586450C (en) 1931-02-01 1931-02-01 Method of hardening

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEM113862D DE586450C (en) 1931-02-01 1931-02-01 Method of hardening

Publications (1)

Publication Number Publication Date
DE586450C true DE586450C (en) 1933-10-21

Family

ID=7327903

Family Applications (1)

Application Number Title Priority Date Filing Date
DEM113862D Expired DE586450C (en) 1931-02-01 1931-02-01 Method of hardening

Country Status (1)

Country Link
DE (1) DE586450C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE740414C (en) * 1937-10-14 1943-10-20 Benno Schilde Maschb Ag Surface hardening of iron and steel by means of gases
DE746003C (en) * 1939-01-27 1944-12-13 Bmw Flugmotorenbau Ges M B H Improvement of the nitriding ability of austenitic steels or corrosion-resistant steel alloys
DE767481C (en) * 1936-01-29 1952-08-28 American Gas Furnace Co Process for the continuous carburization and embroidery of work pieces made of iron and iron alloys
DE102019114135B4 (en) 2018-12-11 2024-09-05 Hyundai Motor Company Brake disc having a decarburization layer and a nitride composite layer, and manufacturing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE767481C (en) * 1936-01-29 1952-08-28 American Gas Furnace Co Process for the continuous carburization and embroidery of work pieces made of iron and iron alloys
DE740414C (en) * 1937-10-14 1943-10-20 Benno Schilde Maschb Ag Surface hardening of iron and steel by means of gases
DE746003C (en) * 1939-01-27 1944-12-13 Bmw Flugmotorenbau Ges M B H Improvement of the nitriding ability of austenitic steels or corrosion-resistant steel alloys
DE102019114135B4 (en) 2018-12-11 2024-09-05 Hyundai Motor Company Brake disc having a decarburization layer and a nitride composite layer, and manufacturing method thereof

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