DE577040C - Process for the preparation of polymeric acrylic acid chloride - Google Patents

Process for the preparation of polymeric acrylic acid chloride

Info

Publication number
DE577040C
DE577040C DE1930577040D DE577040DD DE577040C DE 577040 C DE577040 C DE 577040C DE 1930577040 D DE1930577040 D DE 1930577040D DE 577040D D DE577040D D DE 577040DD DE 577040 C DE577040 C DE 577040C
Authority
DE
Germany
Prior art keywords
acrylic acid
acid chloride
preparation
polymeric acrylic
polymeric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE1930577040D
Other languages
German (de)
Inventor
Dr Hans Fikentscher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Application granted granted Critical
Publication of DE577040C publication Critical patent/DE577040C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/04—Acids; Metal salts or ammonium salts thereof
    • C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Hydrogenated Pyridines (AREA)

Description

Verfahren zur Darstellun' von polymerem Acrylsäurechlorid Es ist bekannt, Acrylsäurechlorid unter Einwirkung des Lichts zu polymerisieren. Es wurde nun gefunden, daß man diese Polymerisation außerordentlich beschleunigen kann, wenn man dem Acrylsäurechlorid kleine Mengen organischer basischer Körper, die in der Kälte nicht mit dem Acrylsäurechlorid reagieren, namentlich solcher, die auch als Vulkanisationsbeschleuniger wirksam sind, beispielsweise von Äthylenpolyamingemischen, d. h. Produkten, die durch Einwirkung von Ammoniak auf Dichloräthan erhältlich sind, Bipiperidyl, Aldehyd - Ammoniak - Kondensationsprodukten u. dgl. oder deren Gemischen, zusetzt. Die zur Polymerisation unter Einwirkung des Sonnenlichts erforderliche Zeit wird durch Zusatz derartiger Katalysatoren auf etwa 1/,3 verkürzt; im diffusen Tageslicht tritt unter Umständen überhaupt erst nach Zusatz dieser Stoffe eine Polymerisation ein. Beispiel ioo Teile reines Acrylsäurechlorid werden mit o, 5 Teilen Triäthylentetramin (vgl. B e i 1-stein, Handbuch der org. Chemie, IV. Auflage, Bd. q., S. 2¢9), die in ersterem ungelöst bleiben, versetzt und in einem gut gegen Luftfeuchtigkeit verschlossenen, nicht zu starkwandigen Glasgefäß 6i Stunden lang dem Sonnenlicht ausgesetzt. Ohne den Zusatzstoff benötigt die Polymerisation 18 und mehr Stunden einer Bestrahlung durch Sonnenlicht.Process for the preparation of polymeric acrylic acid chloride It is known Polymerize acrylic acid chloride under the action of light. It has now been found that you can accelerate this polymerization extremely if you use the acrylic acid chloride small amounts of organic basic bodies that do not react with the acrylic acid chloride in the cold react, especially those that are also effective as vulcanization accelerators are, for example, ethylene polyamine mixtures, d. H. Products by exposure from ammonia to dichloroethane are available, bipiperidyl, aldehyde - ammonia - Condensation products and the like or mixtures thereof. The one used for polymerization The time required under the action of sunlight is increased by the addition of such Catalysts shortened to about 1 /, 3; may occur in diffuse daylight Only after these substances have been added does a polymerisation occur. Example ioo parts pure acrylic acid chloride are mixed with 0.5 parts of triethylenetetramine (cf.B e i 1-stein, Org. Chemie, IV. Edition, Vol. Q., P. 2 [9), the first unsolved stay, displaced and in a well sealed against humidity, not Exposed to thick-walled glass vessels to sunlight for 6i hours. Without that The additive requires 18 and more hours of irradiation to polymerize Sunlight.

Man kann auch gewöhnliches Tageslicht oder künstliches Licht verwenden. An Stelle des obenerwähnten Triäthylentetramins kann man auch ein Gemisch von Aminen, wie es bei der Herstellung des vorgenannten Produktes erhalten wird, verwenden.Ordinary daylight or artificial light can also be used. Instead of the above-mentioned triethylenetetramine, you can also use a mixture of amines, as obtained in the manufacture of the aforementioned product, use.

Die Polymerisati3n verläuft auf diese Weise nahezu quantitativ. Das polymere Acrylsäurechlorid stellt eine klare, durchsichtige, zähe, elastische Masse dar, die sich an feuchter Luft oder in Wasser unter Salzsäureabspaltung mit einer weißen Haut überzieht. Es ist eüi wertvolles Zwischenprodukt, das beispielsweise zur Herstellung polymerer Acrylsäure, Acrylsäureester oder Acrylsäureamide Verwendung finden kann.The polymerisation proceeds almost quantitatively in this way. That polymeric acrylic acid chloride is a clear, transparent, tough, elastic mass which are in moist air or in water with elimination of hydrochloric acid with a covered with white skin. It is a valuable intermediate product, for example for the production of polymeric acrylic acid, acrylic acid esters or acrylic acid amides use Can be found.

Claims (1)

PATENTANSPRUCH: Verfahren zur Darstellung von polymerem Acrylsäurechlorid durch Belichtung, dadurch gekennzeichnet, daß man dem monomeren Acrylsäurechlorid geringe Mengen organischer basischer Körper oder Gemische von diesen, die mit Acry1säurechlorid in der Kälte nicht reagieren, zusetzt.PATENT CLAIM: Process for the preparation of polymeric acrylic acid chloride by exposure, characterized in that the monomeric acrylic acid chloride small amounts of organic basic bodies or mixtures of these with acrylic acid chloride do not react in the cold, clogs.
DE1930577040D 1930-01-25 1930-01-25 Process for the preparation of polymeric acrylic acid chloride Expired DE577040C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE577040T 1930-01-25

Publications (1)

Publication Number Publication Date
DE577040C true DE577040C (en) 1933-05-22

Family

ID=6570110

Family Applications (1)

Application Number Title Priority Date Filing Date
DE1930577040D Expired DE577040C (en) 1930-01-25 1930-01-25 Process for the preparation of polymeric acrylic acid chloride

Country Status (1)

Country Link
DE (1) DE577040C (en)

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