DE553036C - Process for mixing or bubbling gases or vapors through layered powdery substances - Google Patents

Process for mixing or bubbling gases or vapors through layered powdery substances

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Publication number
DE553036C
DE553036C DEV22319D DEV0022319D DE553036C DE 553036 C DE553036 C DE 553036C DE V22319 D DEV22319 D DE V22319D DE V0022319 D DEV0022319 D DE V0022319D DE 553036 C DE553036 C DE 553036C
Authority
DE
Germany
Prior art keywords
vapors
mixing
gases
layered
powdery substances
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEV22319D
Other languages
German (de)
Inventor
Dr Hans Walter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH filed Critical Degussa GmbH
Priority to DEV22319D priority Critical patent/DE553036C/en
Application granted granted Critical
Publication of DE553036C publication Critical patent/DE553036C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B11/00—Oxides or oxyacids of halogens; Salts thereof
    • C01B11/04—Hypochlorous acid
    • C01B11/06—Hypochlorites
    • C01B11/064—Hypochlorites of alkaline-earth metals
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/02—Apparatus specially adapted for manufacture or treatment of sweetmeats or confectionery; Accessories therefor
    • A23G3/0236—Shaping of liquid, paste, powder; Manufacture of moulded articles, e.g. modelling, moulding, calendering
    • A23G3/0294—Moulding or shaping of cellular or expanded articles
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
    • A47J43/00—Implements for preparing or holding food, not provided for in other groups of this subclass
    • A47J43/12—Whipping by introducing a stream of gas
    • A47J43/121—Devices using a static mixing element; Static mixing elements therefor
    • A47J43/122—Devices using a static mixing element; Static mixing elements therefor the mixing element being of considerable length, e.g. labyrinth-type mixing elements
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62C—FIRE-FIGHTING
    • A62C5/00—Making of fire-extinguishing materials immediately before use
    • A62C5/002—Apparatus for mixing extinguishants with water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30—Injector mixers
    • B01F25/31—Injector mixers in conduits or tubes through which the main component flows
    • B01F25/313—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit
    • B01F25/3131—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit with additional mixing means other than injector mixers, e.g. screens, baffles or rotating elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/433—Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
    • B01F25/4331—Mixers with bended, curved, coiled, wounded mixing tubes or comprising elements for bending the flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/433—Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
    • B01F25/4337—Mixers with a diverging-converging cross-section
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/433—Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
    • B01F25/4338—Mixers with a succession of converging-diverging cross-sections, i.e. undulating cross-section
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/45—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/45—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads
    • B01F25/452—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces
    • B01F25/4521—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces the components being pressed through orifices in elements, e.g. flat plates or cylinders, which obstruct the whole diameter of the tube
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/45—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads
    • B01F25/452—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces
    • B01F25/4524—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces the components being pressed through foam-like inserts or through a bed of loose bodies, e.g. balls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/45—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads
    • B01F25/452—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces
    • B01F25/4524—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces the components being pressed through foam-like inserts or through a bed of loose bodies, e.g. balls
    • B01F25/45241—Mixers in which the materials to be mixed are pressed together through orifices or interstitial spaces, e.g. between beads characterised by elements provided with orifices or interstitial spaces the components being pressed through foam-like inserts or through a bed of loose bodies, e.g. balls through a bed of balls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00—Other mixers; Mixing plants; Combinations of mixers
    • B01F33/25—Mixers with loose mixing elements, e.g. loose balls in a receptacle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • B01J8/28—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations the one above the other
    • B01J8/30—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations the one above the other the edge of a lower bed projecting beyond the edge of the superjacent bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19—Details relating to the geometry of the reactor
    • B01J2219/194—Details relating to the geometry of the reactor round
    • B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
    • B01J2219/1942—Details relating to the geometry of the reactor round circular or disk-shaped spherical

Description

Verfahren zum Durchmischen oder Durchperlen von Gasen oder Dämpfen durch geschichtete pulverförmige Stoffe Die Erfindung bezieht sich auf ein Verfahren zum Durchmischen von Gasen oder Dämpfen mit geschichteten pulverförmigen Materialien zwecks Ausführung von chemischen oder physikalischen Prozessen.Process for mixing or bubbling gases or vapors by layered powdery substances The invention relates to a method for mixing gases or vapors with layered powdery materials for the purpose of performing chemical or physical processes.

Es ist bereits versucht worden, Gase oder Dämpfe auf pulverige Stoffe in der Weise physikalisch oder chemisch einwirken zu lassen, daß man die Stoffe mittels eines Rührwerkes verrührt und unter gleichzeitiger Einwirkung von durchströmenden Gasen oder Dämpfen auflockerte. Das neue Kennzeichen der vorliegenden Erfindung besteht hingeben darin, daß man für die Auflockerung der pulverigen 1Ias'se, wie sie durch das Hindurchströmen von Gasen oder Dämpfen erfolgt, einen Mischraum benutzt, der abwechselnd verengten und erweiterten Durchlaßquerschnitt besitzt. Die Dämpfe oder Gase «-erden dabei so durch diesen Mischraum hindurchgeleitet, daß sie durch das geschichtete Material sozusagen wie Luft durch eine Flüssigkeit hindurchperlen.Attempts have already been made to apply gases or vapors to powdery substances to act physically or chemically in such a way that the substances are allowed to act stirred by means of an agitator and with the simultaneous action of flowing through Gases or vapors. The new feature of the present invention consists in indulging in the need for loosening the powdery 1Ias'se, like it takes place through the flow of gases or vapors, uses a mixing room, the alternately narrowed and widened passage cross-section. The fumes or gases «earths passed through this mixing space in such a way that they pass through bubbling the layered material through a liquid, so to speak, like air.

In der Abbildung ist ein derartiger Dlischraum dargestellt; er besteht im wesentlichen in einer in beliebiger Lage aufwärts gerichteten Rühre mit abwechselnd verengten und erweiterten Durchlaßquerschnitten. Werden beispielsweise die unteren Kammern a, ai usw. einer derartigen Röhre mit dem pulverförmigen Stoff c gefüllt und läßt man von unten her einen Gas- oder Luftstrom in die Röhre eindringen, dann perlen oder glucksen Teilchen der Gase oder Dämpfe, wie es in der Abbildung dargestellt ist, durch die pulverige lIasse hindurch, letztere verteilt sich auf die darüberliegenden Kammern 2. 3 usw., indem sie jeweils an den verengten Stellen Schichten bildet, die von den nach oben aufströmenden Gasen oder Dämpfen ständig durchdrungen werden.Such a Dlischraum is shown in the figure; he exists essentially in a stirrer directed upwards in any position with alternating narrowed and widened passage cross-sections. For example, the lower ones Chambers a, ai, etc. of such a tube are filled with the powdery substance c and if a gas or air stream is allowed to enter the tube from below, then Particles of gases or vapors pearl or gurgle, as shown in the picture is, through the powdery passage, the latter is distributed to the one above Chambers 2, 3, etc., by forming layers at the narrowed points, which are constantly penetrated by the gases or vapors flowing upwards.

Während die mit Rührwerk versehenen Apparate sehr umständlich zu handhaben und auch schwer dicht zu halten sind, andererseits die Rührwerke auch einen erheblichen Teil des Innenraumes beanspruchen und dazu noch tote Räume bilden, ergibt sich bei der beanspruchten Einrichtung bei voller Ausnutzung des Innenraumes lediglich nur durch die Einwirkung der durchströmenden Gase und Dämpfe eine bisher unerreichte Mischung. lIan hat es hier=bei ohne weiteres in der Hand, die Gase oder Dämpfe unter beliebiger Verweilzeit unter den Pulverteilchen hindurchzuleiten, so daß sowohl physikalische gis auch chemische Prozesse in höchst -wirksamer ZVeise durchgeführt werden können.While the apparatus provided with a stirrer is very cumbersome to handle and are also difficult to keep tight, on the other hand the agitators also have a significant impact Claiming part of the interior space and also creating dead spaces results in the claimed facility with full utilization of the interior only due to the effects of the gases and vapors flowing through it, an unprecedented level Mixture. lIan has it here = at hand, the gases or vapors underneath to pass any dwell time under the powder particles, so that both physical gis also chemical processes carried out in a highly effective way can be.

Die Einrichtung, wie sie in der Abbildung dargestellt ist, kann eine beliebige Anzahl von erweiterten und verengten Querschnitten besitzen, sie kann beliebig hoch sein und je nach der Zweckv envendung in entsprechenden anderen Apparaturen angeordnet werden. Was die Gestaltung der Rohre anbelangt, so kommt es natürlich im wesentlichen nur auf die inneren Querschnittsveränderungen an, so daß die Apparatur im übrigen beliebige äußere Gestaltung haben kann.The device as shown in the figure can be a any number of widened and narrowed cross-sections own, it can be of any size and, depending on the intended use, in corresponding others Apparatus are arranged. As for the design of the tubes, so come of course, it essentially only depends on the changes in the internal cross-section, so that the apparatus can otherwise have any external design.

als physikalische oder chemische Prozesse kommen in Betracht z. B. die Absorption oder Trennung von Gasen und Dämpfen oder Dampfgemischen von festen pulverigen Stoffen, ferner Reaktionen. wie sie bei der Aktivierüng oder Reaktivierung kohlenstoffhaltiger Substanzen, ferner aktivierter Kieselsäure usw. vorgenommen werden, die gegebenenfalls auch mit einer Veränderung der festen pulverigen Substanz verbunden sein können.as physical or chemical processes come into consideration z. B. the absorption or separation of gases and vapors or vapor mixtures from solids powdery substances, furthermore reactions. as in the case of activation or reactivation carbon-containing substances, also activated silica, etc. made be that possibly also with a change in the solid powdery substance can be connected.

Selbstredend kann das Verfahren auch dazu benutzt -werden', katalytische Prozesse durchzuführen, bei welchen die pulverige Substanz eine aktivierte oder aktivierende sein kann. um chemische Veränderungen oder Umsetzungen zu bewirken.Of course, the process can also be used for catalytic purposes Perform processes in which the powdery substance is an activated or can be activating. to cause chemical changes or conversions.

So kann beispielsweise mittels eines Katalysators, den man dadurch herstellt, daß man Nickelhydrat mit Tonerdehydrat durch Soda ausfällte. danach wusch, reduzierte und fein pulverisierte, oder daß man eine 1Lischung von Natron-Wasserglas-Lösung und atriumaluminat durch eine Mischung von Nickelnitratlösung und Salpetersäure koagulierte, ebenfalls auswusch, trocknete, reduzierte und pulverte, danach fein gesiebt über die gasdurchlässige Wand o. dgl. brachte und unter Erhitzung auf 25o° ein Gasgemisch von Kohlenoxyd und überschüssigem Wasserstoff hindurchleitete, Methan gewonnen werden. 31s Beweis für die innige -Mischung ist hervorzuheben, daß bei Versuchen dieser Art in der Regel keine Spur von hohl: noxyd nachzuweisen ist.So, for example, by means of a catalyst, which one thereby produces that one precipitated nickel hydrate with alumina hydrate by soda. afterwards washed, reduced and finely pulverized, or a mixture of soda-waterglass solution and atrium aluminate by a mixture of nickel nitrate solution and nitric acid coagulated, also washed out, dried, reduced and powdered, then fine sifted over the gas-permeable wall or the like and brought with heating to 25o ° a gas mixture of carbon monoxide and excess hydrogen passed through, methane be won. 31s proof of the intimate mixture is to be emphasized that with Attempts of this kind as a rule do not show any trace of hollow: noxyd.

Eine in den Apparat gebrachte, fein gepulverte aktive Kieselsäure ergab, nachdem in der beschriebenen --"eise ein acetonhaltiger Luftstrom hindurchgeschickt war, Restgase, die praktisch frei waren von Aceton.A finely powdered active silica placed in the apparatus revealed after a stream of air containing acetone was sent through in the described - "ice was, residual gases that were practically free of acetone.

In derselben Weise lassen sich auch Reaktionen ausführen, die mit einem Verbrauch der festen Stoffe verbunden sind, wie z. B. die Wassergasbildung aus Kohlenstaub und Wasserdampf oder die Aktivierung oder Reaktivierung von kohlenstoffhaltigen Substanzen, ferner die Wiedergerinnung von durch Absorptionsstoffe aufgenommenen Gasen oder Dämpfen, ebenso aber auch die Regenerierung von Katalysatoren usw.In the same way, reactions can also be carried out with a consumption of solid substances are associated, such as. B. the formation of water gas from coal dust and water vapor or the activation or reactivation of carbonaceous Substances, as well as the coagulation of those absorbed by absorption substances Gases or vapors, but also the regeneration of catalysts, etc.

Claims (1)

PATENTANSPRUCH: Verfahren zum Durchmischen oder Durchperlen von Gasen oder Dämpfen durch geschichtete pulverförmige Stoffe zwecks Ausführung von chemischen oder physikalischen Prozessen, gekennzeichnet durch die Verwendung von Mischräumen mit übereinander abwechselnd verengten und erweiterten Durchgangsquerschnitten.PATENT CLAIM: Process for mixing or bubbling gases or steaming through layered powdery substances for the purpose of chemical execution or physical processes, characterized by the use of mixing rooms with alternately narrowed and enlarged passage cross-sections.
DEV22319D 1927-03-25 1927-03-25 Process for mixing or bubbling gases or vapors through layered powdery substances Expired DE553036C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEV22319D DE553036C (en) 1927-03-25 1927-03-25 Process for mixing or bubbling gases or vapors through layered powdery substances

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DEV22319D DE553036C (en) 1927-03-25 1927-03-25 Process for mixing or bubbling gases or vapors through layered powdery substances

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DE553036C true DE553036C (en) 1932-06-21

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1041475B (en) * 1954-02-12 1958-10-23 Dr Rudolf E C Pflock Process for the continuous implementation of mixing and reaction processes
DE1059888B (en) * 1957-11-30 1959-06-25 Degussa Method and device for carrying out an exchange of substance and / or heat between gaseous and / or liquid media
DE10007565B4 (en) * 1999-02-19 2006-12-21 Sanyo Electric Co., Ltd., Moriguchi A CO remover, which has a simple structure and performs a selective reaction of CO at high CO selectivity

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1041475B (en) * 1954-02-12 1958-10-23 Dr Rudolf E C Pflock Process for the continuous implementation of mixing and reaction processes
DE1059888B (en) * 1957-11-30 1959-06-25 Degussa Method and device for carrying out an exchange of substance and / or heat between gaseous and / or liquid media
DE10007565B4 (en) * 1999-02-19 2006-12-21 Sanyo Electric Co., Ltd., Moriguchi A CO remover, which has a simple structure and performs a selective reaction of CO at high CO selectivity

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