DE50463C - Method of staining with benzoazurine, azo violet and heliotrope - Google Patents
Method of staining with benzoazurine, azo violet and heliotropeInfo
- Publication number
- DE50463C DE50463C DENDAT50463D DE50463DA DE50463C DE 50463 C DE50463 C DE 50463C DE NDAT50463 D DENDAT50463 D DE NDAT50463D DE 50463D A DE50463D A DE 50463DA DE 50463 C DE50463 C DE 50463C
- Authority
- DE
- Germany
- Prior art keywords
- dyes
- heliotrope
- copper
- violet
- ethers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- NGPGYVQZGRJHFJ-BUHFOSPRSA-N Azo violet Chemical compound OC1=CC(O)=CC=C1\N=N\C1=CC=C([N+]([O-])=O)C=C1 NGPGYVQZGRJHFJ-BUHFOSPRSA-N 0.000 title claims description 3
- 240000007724 Heliotropium arborescens Species 0.000 title description 2
- 238000010186 staining Methods 0.000 title 1
- 239000000975 dye Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 238000004040 coloring Methods 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L Nickel(II) sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- FJCLABNSNOPCBX-VPHRWSHRSA-L disodium;(3E)-3-[[2-methoxy-4-[3-methoxy-4-[(2Z)-2-(1-oxo-4-sulfonatonaphthalen-2-ylidene)hydrazinyl]phenyl]phenyl]hydrazinylidene]-4-oxonaphthalene-1-sulfonate Chemical compound [Na+].[Na+].C\1=C(S([O-])(=O)=O)C2=CC=CC=C2C(=O)C/1=N/NC(C(OC)=C1)=CC=C1C1=CC=C(N\N=C\2C(C3=CC=CC=C3C(=C/2)S([O-])(=O)=O)=O)C(OC)=C1 FJCLABNSNOPCBX-VPHRWSHRSA-L 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical class [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- HFACYLZERDEVSX-UHFFFAOYSA-N Benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 claims 1
- 240000001194 Heliotropium europaeum Species 0.000 claims 1
- NUIURNJTPRWVAP-UHFFFAOYSA-N Tolidine Chemical compound C1=C(N)C(C)=CC(C=2C=C(C)C(N)=CC=2)=C1 NUIURNJTPRWVAP-UHFFFAOYSA-N 0.000 claims 1
- 210000002268 Wool Anatomy 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000002474 experimental method Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Chemical class 0.000 claims 1
- 239000011701 zinc Chemical class 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 150000001879 copper Chemical class 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000012266 salt solution Substances 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-Naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-Naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-Naphthylamine Chemical class C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
- JRBJSXQPQWSCCF-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine Chemical compound C1=C(N)C(OC)=CC(C=2C=C(OC)C(N)=CC=2)=C1 JRBJSXQPQWSCCF-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 229940097275 Indigo Drugs 0.000 description 1
- 240000007871 Indigofera tinctoria Species 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L Zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000009967 direct dyeing Methods 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229940053662 nickel sulfate Drugs 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/02—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes
- D06P1/10—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes containing metal
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
Werden die in den Patentschriften No. 38802, 40247, 43204, 44650, 44775 und 47136 beschriebenen Farbstoffe, welche der Einwirkung von Tetrazodiphenoläthern auf Amine, Phenole und deren Sulfosäuren entstammen, mit Lösungen von Metallsalzen versetzt, so ergiebt nich eine auffallende Verschiedenheit unter den entstehenden Niederschlägen.Are the in patent specifications no. 38802, 40247, 43204, 44650, 44775 and 47136 Dyes, which the effect of tetrazodiphenol ethers on amines, phenols and their sulfonic acids come from, mixed with solutions of metal salts, so it gives not a striking difference among the precipitates produced.
Während die Farbentöne der mit der Mehrzahl der Metallsalze erzeugten Niederschläge stumpf sind und sich von den Farbentönen der directen Farbstoffniederschläge nur wenig unterscheiden, erzeugen speciell Kupfersalze prachtvolle Farblacke, welche aufserordentlich widerstandsfähig gegen Seife sind und somit den Schlüssel dazu liefern, diese Farbstoffe, welche nach dem directen Färben die unangenehme Eigenschaft zeigen, beim Waschen mit Seife abzufärben (»zu bluten«), widerstandsfähiger gegen Seife zu machen.While the hues of the precipitates generated with the majority of the metal salts are dull and differ only slightly from the hues of the direct dye precipitates distinguish, especially copper salts produce splendid colored lacquers, which are extraordinary are resistant to soap and thus provide the key to these dyes, which after direct dyeing show the unpleasant quality of being washed with To stain soap ("to bleed"), to make it more resistant to soap.
Kocht man z. B. einen Baumwollstrang, welcher mit Benzoazurin G des Handels (dem Farbstoff aus Tetrazodiphenoläther und a-Naphtola-monosulfosäure) gefärbt ist, einige Zeit mit einer schwachen Lösung von Kupfervitriol oder einem anderen Kupfersalz, so wird der Lösung das Kupfer entzogen, indem sich auf der Faser eine fcupferverbindung des Farbstoffs bildet, welche nicht nur der Seife besser als der ursprüngliche Farbstoff widersteht, sondern aufserdem eine mehr nach Grün hinneigende blaue Nuance zeigt und daher werthvoller ist.If you cook z. B. a cotton strand, which with Benzoazurin G of the trade (the dye from tetrazodiphenol ether and a-naphtola-monosulfonic acid) is colored, for some time with a weak solution of vitriol or another copper salt, the solution becomes the copper is withdrawn by forming a copper compound of the dye on the fiber, which not only resists the soap better than the original dye, but also shows a blue shade tending more towards green, and is therefore more valuable.
In noch viel höherem Mafse wird dieses Resultat erzielt, wenn man den aus Tetrazodiphenoläther und der sogenannten Cleve'schen α - Naphtolmonosulfosäure dargestellten , im Handel unter dem Namen »Benzoazurin 3 Gi bekannten Farbstoff, nachdem er auf der Faser fixirt ist, mit Kupfersalzlösungen kocht. Hierbei wird das Product derartig vortheilhaft verändert, dafs es kaum als Benzoazurin 3 G wieder zu erkennen ist, indem die blaue Nuance noch bedeutend mehr Grün aufweist.This result is achieved to a much greater extent when one is obtained from that from tetrazodiphenol ether and the so-called Cleve's α-naphthol monosulfonic acid, im Trade under the name »Benzoazurine 3 Gi known dye after being on the fiber is fixed, boils with copper salt solutions. Here the product is changed in such a beneficial way that that it can hardly be recognized as benzoazurine 3 G because the blue shade is still has significantly more green.
In ähnlicher Weise wird das aus Tetrazodiphenoläther, ι Molecül a-Naphtolmonosulfosäure und 1 Molecül α - Naphtylaminmonosulfosäure dargestellte, im Handel unter dem Namen »Azoviolett« bekannte röthlichviolett färbende Product durch Kochen mit Kupfersalzlösungen blau mit nur schwach violettem Schein, ohne beim nachherigen Seifen seine ursprüngliche Farbe (röthlichviolett) wieder anzunehmen. In a similar way, the tetrazodiphenol ether, ι Molecül a-naphthol monosulfonic acid and 1 molecule of α-naphthylamine monosulfonic acid, sold under the Reddish-violet coloring product known as "Azoviolet" by boiling with copper salt solutions blue with only a faint violet glow, without taking on its original color (reddish violet) again during subsequent soaping.
So wird das aus Dianisidin und alkylirter ß-Naphtylaminmonosulfosäure dargestellte violettroth färbende Heliotrop violett, kurz, alle Producte der oben angeführten Patente verändern beim Kochen mit Kupfervitriol ihre Farbe, werden mehr blau und sind bedeutend widerstandsfähiger gegen Seifen.Thus that which is produced from dianisidine and alkylated β-naphthylamine monosulfonic acid becomes violet-red coloring heliotrope violet, in short, all products of the patents cited above their color when cooked with green vitriol, become more blue and are significantly more resistant to soaps.
Wendet man an Stelle von Kupfervitriol andere Metallsalze, z. B. Nickelsulfat oder Zinksulfat an, so wird dadurch zwar auch die Widerstandsfähigkeit gegen Seife erhöht, die Nuance dagegen nicht verändert.If, instead of vitriol, other metal salts are used, e.g. B. nickel sulfate or zinc sulfate on, this also increases the resistance to soap, but does not change the nuance.
Dazu kommt ein weiterer, wesentlich neuer technischer Effect. Die so behandelten Farbstoffe, welche bisher vorschriftsmäfsig nur wenig lichtecht waren, erwiesen sich nach dieser Behandlung als absolut lichtecht und bilden jetzt, soweit sie von blauer Farbe sind, vortreffliche Ersatzmittel für Indigo, welche ihm nicht nurIn addition, there is another, significantly new technical effect. The dyestuffs treated in this way, which hitherto have been prescribed only a little were lightfast, proved to be absolutely lightfast after this treatment and now form as far as they are blue in color, excellent substitutes for indigo, which not only give it
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE50463C true DE50463C (en) |
Family
ID=325309
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT50463D Expired - Lifetime DE50463C (en) | Method of staining with benzoazurine, azo violet and heliotrope |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE50463C (en) |
-
0
- DE DENDAT50463D patent/DE50463C/en not_active Expired - Lifetime
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