DE50312354D1 - Process for the preparation of tert-butanol - Google Patents
Process for the preparation of tert-butanolInfo
- Publication number
- DE50312354D1 DE50312354D1 DE50312354T DE50312354T DE50312354D1 DE 50312354 D1 DE50312354 D1 DE 50312354D1 DE 50312354 T DE50312354 T DE 50312354T DE 50312354 T DE50312354 T DE 50312354T DE 50312354 D1 DE50312354 D1 DE 50312354D1
- Authority
- DE
- Germany
- Prior art keywords
- butanol
- tert
- isobutene
- water
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 title abstract 8
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 239000008240 homogeneous mixture Substances 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The invention relates to a process for preparing tert-butanol by reaction of a homogeneous mixture comprising water; tert-butanol and an isobutene-containing hydrocarbon mixture over an acidic ion-exchange resin at from 30 to 120 DEG C, wherein the homogeneous mixture contains, at a proportion by mass of isobutene of above 10%, from 30 to 80% of the maximum amount of water made possible by the solubility of water in the mixture of tert-butanol and the isobutene-containing hydrocarbon mixture.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10259413 | 2002-12-19 | ||
DE10330710A DE10330710A1 (en) | 2002-12-19 | 2003-07-08 | Process for the preparation of tert-butanol |
Publications (1)
Publication Number | Publication Date |
---|---|
DE50312354D1 true DE50312354D1 (en) | 2010-03-11 |
Family
ID=32403935
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE10330710A Withdrawn DE10330710A1 (en) | 2002-12-19 | 2003-07-08 | Process for the preparation of tert-butanol |
DE50312354T Expired - Lifetime DE50312354D1 (en) | 2002-12-19 | 2003-10-22 | Process for the preparation of tert-butanol |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE10330710A Withdrawn DE10330710A1 (en) | 2002-12-19 | 2003-07-08 | Process for the preparation of tert-butanol |
Country Status (3)
Country | Link |
---|---|
AT (1) | ATE455744T1 (en) |
DE (2) | DE10330710A1 (en) |
TW (1) | TW200418769A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10338581A1 (en) | 2003-08-22 | 2005-03-17 | Oxeno Olefinchemie Gmbh | Process for producing tert-butanol |
DE102004030943B4 (en) * | 2004-06-26 | 2013-10-02 | Evonik Oxeno Gmbh | Process for the preparation of tert-butanol from isobutene-containing hydrocarbon mixtures |
DE102011005608A1 (en) | 2011-03-16 | 2012-09-20 | Evonik Oxeno Gmbh | Mixed oxide compositions and processes for the preparation of isoolefins |
-
2003
- 2003-07-08 DE DE10330710A patent/DE10330710A1/en not_active Withdrawn
- 2003-10-22 AT AT03103901T patent/ATE455744T1/en not_active IP Right Cessation
- 2003-10-22 DE DE50312354T patent/DE50312354D1/en not_active Expired - Lifetime
- 2003-12-15 TW TW092135452A patent/TW200418769A/en unknown
Also Published As
Publication number | Publication date |
---|---|
DE10330710A1 (en) | 2004-07-01 |
TW200418769A (en) | 2004-10-01 |
ATE455744T1 (en) | 2010-02-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |