DE476998C - Process for the preparation of rubber or for the production of objects from rubber, as well as the vulcanized and unvulcanized objects produced by this process - Google Patents
Process for the preparation of rubber or for the production of objects from rubber, as well as the vulcanized and unvulcanized objects produced by this processInfo
- Publication number
- DE476998C DE476998C DEM89378D DEM0089378D DE476998C DE 476998 C DE476998 C DE 476998C DE M89378 D DEM89378 D DE M89378D DE M0089378 D DEM0089378 D DE M0089378D DE 476998 C DE476998 C DE 476998C
- Authority
- DE
- Germany
- Prior art keywords
- rubber
- objects
- vulcanized
- production
- well
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001971 elastomer Polymers 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 15
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000007788 liquid Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000004073 vulcanization Methods 0.000 description 4
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000011265 semifinished product Substances 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- NGDNCZPCIZNCQS-UHFFFAOYSA-N ctk3j8699 Chemical compound Cl=S NGDNCZPCIZNCQS-UHFFFAOYSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007511 glassblowing Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/005—Shaping by stretching, e.g. drawing through a die; Apparatus therefor characterised by the choice of materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
- B29B15/02—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of crude rubber, gutta-percha, or similar substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/18—Cold vulcanisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/0005—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor characterised by the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D22/00—Producing hollow articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2791/00—Shaping characteristics in general
- B29C2791/004—Shaping under special conditions
- B29C2791/006—Using vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2007/00—Use of natural rubber as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2023/00—Tubular articles
- B29L2023/24—Endless tubes, e.g. inner tubes for pneumatic tyres
- B29L2023/245—Inner tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2030/00—Pneumatic or solid tyres or parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/54—Balls
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Description
Verfahren zur Aufbereitung von Kautschuk oder zur#.Herstellungvon Gegenständen aus Kautschuk, sowie die nach""diesem Verfahren hergestellten vulkanisierten und unvulkanisierten Gegenstände Die Erfindung betrifft ein Verfahren zur Aufbereitung von Kautschuk und zur Herstellung von Gegenständen aus Kautschuk sowie die nach diesem Verfahren hergestellten vulkanisierten und unvulkanisierten Gegenstände.Process for the processing of rubber or for the # .production of Articles made of rubber, as well as vulcanized articles made by "" this process and unvulcanized articles The invention relates to a method for processing of rubber and for the manufacture of articles from rubber as well as the after vulcanized and unvulcanized articles produced by this process.
Das neue Verfahren ist auf der Erkenntnis gegründet, daß, falls frisch koagulierter Rohkautschuk, beispielsweise koagulierter Latex von Hevea Brasiliensis, hier »Koagulum« genannt, in dünner Schicht der Luft oder einem ähnlichen Medium ausgesetzt wird, sich nach kurzer Zeit verfestigt.The new method is based on the knowledge that, if fresh coagulated raw rubber, for example coagulated latex from Hevea Brasiliensis, here called "coagulum", in a thin layer of air or a similar medium is exposed, solidifies after a short time.
Hierdurch ist es möglich, auf Koagulum ein Verfahren anzuwenden, das dem Glasblasen ähnlich ist, wobei die Erstarrungsstrecke durch eine Verfestigungsstrecke (durch Einwirkung der Luft, wobei deren trocknende Wirkung hauptsächlich ins Gewicht fällt) ersetzt gedacht werden muß.This makes it possible to apply a method to coagulum that is similar to glass blowing, with the solidification path being a solidification path (by the action of the air, the drying effect of which is mainly due to the weight falls) must be thought of as a replacement.
Nach der Erfindung verfährt man grundsätzlich so, daß aus Koagulum zuerst ein Hohlkörper gebildet wird, dessen Wände mit Hilfe eines gasförmigen, flüssigen oder festen Druckmittels ausgedehnt werden. Wird der Druck nun während einiger Zeit im ausgedehnten Körper aufrechterhalten, so werden die Wände verfestigt, und der Körper behält bei Verringerung oder Behebung des Druckes die einmal angenommene Gestalt bei. Die Zeit, während welcher der Druck zwecks Erreichung einer genügenden. Verfestigung angewendet werden muß, ist der Hauptsache nach eine Funktion des atmosphärischen Zustandes und der Wanddicke. Im allgemeinen ist sie von der Größenordnung von Sekunden und Minuten. Während der Druckperiode kann vollständig getrocknet werden, doch kann dies ebenfalls nach Behebung des Drukkes geschehen.According to the invention one proceeds in principle that from coagulum first a hollow body is formed, the walls of which with the help of a gaseous, liquid or solid pressure medium. Will the pressure now for some time sustained in the expanded body, the walls are solidified, and the When the pressure is reduced or eliminated, the body retains the one it assumed Shape. The time during which the pressure is applied in order to achieve a sufficient. Solidification must be applied is mainly a function of the atmospheric Condition and wall thickness. Generally it is on the order of seconds and minutes. It can be completely dried during the printing period, but it can this is also done after removing the pressure.
Bei Anwendung des oben in allgemeinen Zügen beschriebenen Verfahrens kann man vorteilhaft von einer andern Eigenschaft des Koagulüms Gebrauch machen, nämlich daß Felle dieses Stoffes, unter geringem Druck zusammengepreßt, sehr gut aneinander haften. Obgleich die Erfindung hierauf keineswegs beschränkt ist, wird man in der Praxis ,dann" auch vorzugsweise folgendermaßen vorgehen.When using the procedure described in general terms above one can make advantageous use of another property of the coagulum, namely, that skins of this material, compressed under slight pressure, are very good stick together. Although the invention is in no way limited to this, is one in practice, then "also preferably proceed as follows.
Felle von Köagulum, welche in beliebiger Weise erhalten sein können, u. a. durch Koagulation, beispielsweise von Latex in sehr flachen Behältern, durch Zerschneiden von Koagulum oder durch Walzen, werden an den Rändern zusammengepreßt oder -gedrückt, wobei eine kleine Öffnung freigelassen wird. In diese Öffnung wird nun Idas Mundstück einer Luftpumpe gebracht und der erhaltene Sack aufgeblasen, bis die gewünschte Wanddicke erreicht ist. - Nach einiger Zeit wird das Mundstück aus dem aufgeblasenen Ballon entfernt, wobei dieser zwar zusammenfällt, seine Form aber beibehält.. Die erhaltene große Oberfläche ermöglicht nunmehr eine schnelle Trocknung.Koagulum skins, which can be preserved in any way, i.a. by coagulation, for example of latex in very shallow containers Cutting up coagulum or by rolling are applied to the Margins compressed or squeezed, leaving a small opening. In this opening is now brought to Ida's mouthpiece of an air pump and the one obtained Inflate the bag until the desired wall thickness is achieved. - After some time the mouthpiece is removed from the inflated balloon, whereby it collapses, but retains its shape .. The resulting large surface now enables a quick drying.
Man kann nach dem beschriebeneri Verfahren sowohl ein Halbfabrikat, und zwar getrockneten Rohkautschuk, bereiten wie- auch Fertigfabrikate. Im letzteren Falle wird man dem Anfangsgegenstand eine solche Form erteilen, daß daraus nach Aufblasen der gewünschte Gegenstand entsteht. Auch kann man dabei Hohlformen verwenden, die mit dem herzustellenden Gegenstand übereinstimmen, wobei die Formen eventuell evakuiert werden können.You can use the described process to produce a semi-finished product, namely dried raw rubber, prepare as well as finished products. In the latter Case one will give the initial object such a form that from it after Inflate the desired object. You can also use hollow molds, which match the object to be manufactured, the shapes possibly can be evacuated.
Im allgemeinen ist diese Methode nur geeignet zur Herstellung einfacher Gegenstände, wie Spielbälle, Luftreifen für Fahrräder und Automobile, doch kann man nach ihr auch Teile komplizierter Gegenstände herstellen, welche darauf zu einem Ganzen vereinigt werden. Es hat sich gezeigt, daß die in dieser Weise hergestellten Kautschukfelle und -gegenstände viel strammer sind wie andere Kautschukfelle gleichen Durchschnitts.In general, this method is only suitable for making it simpler Objects such as play balls, pneumatic tires for bicycles and automobiles, however, can you can also make parts of complicated objects according to it, which then turn into one Whole to be united. It has been shown that the manufactured in this way Rubber heads and objects are much tighter than other rubber heads Average.
Der Hauptvorteil des Verfahrens nach. der Erfindung muß jedoch in seiner Einfachheit gesehen werden, und die Anwendung des Verfahrens ist sogar dermaßen einfach, daß die Fabrikation von Kautschukgegenständen von jetzt an sofort an den Fundstellen des Milchsaftes, also auf den Plantagen selbst, vorgenommen werden kann. Die Herstellung getrockneten Koagulums in Fellen als Halbfabrikat kann nach der Erfindung -sehr bedeutend schneller geschehen als sonst; das er= haltene Produkt ist den sogenannten »Blanket-CrApes« wenigstens ebenbürtig.The main advantage of the procedure after. the invention must, however, in its simplicity can be seen, and the application of the procedure is even so simply that the manufacture of rubber articles can be carried out immediately from now on Places of discovery of the milky juice, i.e. on the plantations themselves, can be made. The production of dried coagulum in pelts as a semi-finished product can be carried out according to the Invention - happened much faster than usual; the product received is at least equal to the so-called »Blanket CrApes«.
Es ist klar, daß die nach der Erfindung hergestellten Gegenstände sich ausgezeichnet eignen zur Vulkanisation auf kaltem Wege, z. B. zur Vulkanisation mit Hilfe von Dämpfen von Chlorschwefel und zur Gasvulkani-_ sation nach P e a c h y, wobei der Kautschuk abwechselnd einer Atmosphäre von Schwefelvvasserstoff und Schwefeldioxyd ausgesetzt wird. Auch die nach der Erfindung hergestellten vulkanisierten Gegenstände besitzen im allgemeinen eine größere Strammheit als die, welche durch Kalandern (Walzen) oder unmittelbar aus Latex durch Vulkanisation erhalten werden.It is clear that the articles made according to the invention are excellently suited for vulcanization by cold means, e.g. B. for vulcanization with the help of vapors of chlorosulphur and for gas vulcanization according to P e a c h y, the rubber alternating between an atmosphere of hydrogen sulfide and Exposure to sulfur dioxide. Also the vulcanized ones made according to the invention Objects generally have a greater tightness than those which are through Calendering (rolling) or obtained directly from latex by vulcanization.
Die in der beschriebenen Weise hergestellten Gegenstände können in bekannter Weise durch Bemalung oder Färbung oder in anderer Weise verschönert werden sowie zu verschiedenen Zwecken oder Verwendungsarten mit anderen Stoffen bedeckt oder verstärkt werden.The articles produced in the manner described can be used in be embellished in a known manner by painting or staining or in some other way as well as covered with other fabrics for various purposes or uses or be strengthened.
Die Färbung der Gegenstände kann in bekannter Weise schon im Milchsaft geschehen, auch kann man dem Milchsaft schon vor der Koagulation die nötigen Füllstoffe zusetzen.The coloring of the objects can already be in the milky juice in a known manner happen, you can also add the necessary fillers to the milk juice before coagulation to add.
Es ist keine Bedingung, von ganz frischem Koagulum auszugehen, weil man das nämliche Verfahren auch auf Koagulum anwenden kann, welches längere Zeit aufbewahrt wurde. Im allgemeinen wird die Anwendungsmöglichkeit desto .größer sein, je frischer das Koagulum ist.It is not a requirement to start with completely fresh coagulum, because the same procedure can also be applied to coagulum, which is longer was kept. In general, the possible application will be the greater, the fresher the coagulum is.
Claims (2)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL600265X | 1924-07-11 | ||
NL476998X | 1924-07-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE476998C true DE476998C (en) | 1929-05-28 |
Family
ID=26643689
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEM89378D Expired DE476998C (en) | 1924-07-11 | 1925-04-23 | Process for the preparation of rubber or for the production of objects from rubber, as well as the vulcanized and unvulcanized objects produced by this process |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE476998C (en) |
FR (1) | FR600265A (en) |
-
1925
- 1925-04-23 DE DEM89378D patent/DE476998C/en not_active Expired
- 1925-07-02 FR FR600265D patent/FR600265A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR600265A (en) | 1926-02-03 |
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