DE444314C - Method and device for cooling down and liquefying gas mixtures - Google Patents
Method and device for cooling down and liquefying gas mixturesInfo
- Publication number
- DE444314C DE444314C DEH70641D DEH0070641D DE444314C DE 444314 C DE444314 C DE 444314C DE H70641 D DEH70641 D DE H70641D DE H0070641 D DEH0070641 D DE H0070641D DE 444314 C DE444314 C DE 444314C
- Authority
- DE
- Germany
- Prior art keywords
- countercurrent
- cooling down
- gas mixtures
- gas
- liquefying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims description 15
- 238000001816 cooling Methods 0.000 title claims description 9
- 238000000034 method Methods 0.000 title claims description 9
- 239000007789 gas Substances 0.000 claims description 26
- 238000000605 extraction Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 230000000246 remedial effect Effects 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
- F25J1/0262—Details of the cold heat exchange system
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0012—Primary atmospheric gases, e.g. air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
- F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0201—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
- F25J1/0202—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration in a quasi-closed internal refrigeration loop
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/40—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Separation By Low-Temperature Treatments (AREA)
Description
Verfahren und Vorrichtung zum Herunterkühlen und Verflüssigen von Gasgemischen. Beim Herunterkühlen von Gasen mit Hilfe des =Joule-Kelvinschen Effektes und Gegenstromwirkung wird eine bessere Wirtschaftlichkeit erzielt, wenn man die hoch komprimierten Gase nur teilweise ganz entspannt und mit dem größeren Bruchteil im Kreislauf arbeitet. Soll die Verflüssigung aber zur Trennung von Gasgemischen führen, so ist dieses Verfahren ohne weiteres nicht anwendbar, da das verarbeitete Gasgemisch stets durch völlig neues ersetzt werden muß. Man hat sich hierbei in dieser Weise zu helfen versucht, daß man mit einem besonderen Kühlgas im geschlossenen Kreisstrom arbeitet. Dies macht jedoch einen besonderen Kompressor für das zu trennende Gasgemisch erforderlich und die Anlage umständlich.Method and device for cooling down and liquefying Gas mixtures. When cooling down gases with the help of the = Joule-Kelvin effect and countercurrent effect, better economy is achieved if the highly compressed gases only partially relaxed and with the larger fraction works in a cycle. Should the liquefaction be used to separate gas mixtures lead, this procedure is not readily applicable since the processed The gas mixture must always be replaced by a completely new one. One has to do this in Tried to help in this way that one with a special cooling gas in the closed Circulating current works. However, this makes a special compressor for the one to be separated Gas mixture required and the system cumbersome.
Andererseits wurde bei Luftverflüssigungs-und Trennungsanlagen eine größere Wirtschaftlichkeit dadurch zu erreichen versucht, daß man die Entspannung der Gase ganz oder teilweise unter gleichzeitiger Arbeitsleistung in Kolbenmaschinen oder Turbinen vor sich gehen läßt. In diesem Falle erhalten diese Maschinen - wie die Düsen - von dem kältesten Ende des Gegenstromes sowohl die Gaszufuhr, als auch puffen sie dorthin aus, um eine möglichst tiefe Temperatur zu erzielen. Temperatursturz, Kälte- und Kraftleistung nehmen aber mit sinkender Temperatur in gleicher Weise stark ab. Dazu kommt noch, daß die Einstrahlungsverluste um so größer werden und um so mehr von der eigentlichen Kälteleistung wieder vernichten, j e tiefer die Temperatur sinkt, unter der in der Maschine gearbeitet wird. Auch rein mechanisch erschweren besonders tiefe Temperaturen den Dauerbetrieb solcher Maschinen sehr.On the other hand, in air liquefaction and separation systems, a Trying to achieve greater economy by relaxing of the gases wholly or partially with simultaneous work performance in piston engines or let turbines go by. In this case, these machines get - like the nozzles - from the coldest end of the countercurrent both the gas supply, and puff it out there in order to achieve the lowest possible temperature. Temperature drop, However, cooling and power output decrease in the same way as the temperature drops strong. In addition, the radiation losses are all the greater and destroy the more of the actual cooling capacity, the deeper it is The temperature below which the machine is being used drops. Also purely mechanically particularly low temperatures make the continuous operation of such machines very difficult.
Uni diesen Übelständen der beiden vorstehend beschriebenen Arbeitsweisen abzuhelfen, läßt man bei dem Verfahren gemäß der Erfindung das hoch komprimierte Gasgemisch zunächst in einer Düse, die am kältesten Ende des Gegenstromes angeordnet ist, teilweise expandieren. Der überwiegende, nicht verflüssigte Teil wird dann im Gegenstrom dem abzukühlenden Gas entlang zurückgeführt, und nachdem er sich bereits mehr oder weniger weitgehend erwärmt hat, in einer Expansionsmaschine unter Leistung äußerer Arbeit weiter entspannt. Das dadurch nochmals abgekühlte Gasgemisch wird an geeigneter Stelle - nicht am. kältesten Teil - zur nochmaligen Entziehung von Wärme in den Gegenstrom ein- und parallel zu den von der Düse kommenden Gasen zurückgeführt. -Bei dieser Arbeitsweise wird mit der Expansionsmaschine unter wesentlich höherer Temperatur gearbeitet, so daß Kälteleistung und Kraftrückgewinnung hoch bleiben, während mechanische Schwierigkeiten vermieden werden.Uni these evils of the two ways of working described above remedial action is left with the procedure according to the invention that high compressed gas mixture first in a nozzle, which is at the coldest end of the countercurrent is arranged to expand partially. The predominant, non-liquefied part is then returned in countercurrent to the gas to be cooled, and afterwards it has already warmed up to a greater or lesser extent in an expansion machine Further relaxed while performing external work. That cooled down again Gas mixture is repeated at a suitable point - not on the coldest part Removal of heat in the countercurrent and parallel to that coming from the nozzle Gases returned. -With this working method, the expansion machine is used under Worked at a much higher temperature, so that cooling capacity and power recovery stay high while avoiding mechanical difficulties.
Das Verfahren arbeitet daher äußerst günstig, und die Wirtschaftlichkeit bleibt erhalten, ganz gleich, ob es sich nur um eine Verflüssigung oder darüber hinaus um eine Zerlegung des Gasgemisches handelt.The process is therefore extremely cheap, and so is the economy remains, regardless of whether it is just a liquefaction or above is also a decomposition of the gas mixture.
Die Zeichnung stellt rein schematisch eine Ausführungsform dieses neuen Verfahrens dar.The drawing shows an embodiment of this purely schematically new procedure.
In derselben ist a die durch den Gegenstrom führende Hochdruckrohrleitung. Das in dieser Leitung auf den Weg durch den Gegenstrom abgekühlte hoch komprimierte Gas wird in der von außen regulierbaren Düse b bis auf einen gewünschten Mitteldruck entspannt und nach Erreichung genügend tiefer Temperaturen teilweise verflüssigt. Die gasförmig gebliebene überwiegende Menge strömt durch die Rohrleitung c vom kältesten Teil des Gegenstromes an durch denselben zurück, wobei sie dem von ihr umhüllten, unter Hochdruck. stehendem Gas in a Wärme entzieht und dabei ihre Temperatur wieder erhöht. Durch die Rohrleitung d verläßt das Gas dann den Gegenstrom, um nach der Kaltluftmaschine e zu gelangen, wo es weiter expandiert, Arbeit an den Kolben und die Kurbelwelle abgibt, um danach durch den Stutzen f wieder in den Gegenstrom auszupuffen. Dort durchströmt es die Leitung g parallel zu dem Gemisch in c und entgegen dem Hochdruckgas in a, um schließlich nach vollständigem Wärmeaustausch den Apparat bei b - zu verlassen. Selbstverständlich können die einzelnen Rohre im Gegenstrom beliebig angeordnet werden, wenn sie nur im Prinzip dem geschilderten Wärmeaustausch entsprechen. - In der Zeichnung ist noch eine zweite Düse i angeordnet, mit der die hinter der ersten Düse gebildete Flüssigkeit weiter entspannt werden kann. Die sich dabei bildenden sehr kalten Dämpfe werden durch die Rohrleitung h ebenfalls im Gegenstrom zur Abkühlung der hoch komprimierten Luft verwertet, um sich dann mit dem Maschinenauspuff in g zu vereinigen. An Stelle der Düsen kann selbstverständlich ein Gastrenner bekannter Konstruktion angeordnet werden. Die Gastrennung muß jedoch dann unter einem Überdruck gegenüber dem Maschinenauspuff erfolgen. Auch ist unter Umständen, wenn Gasgemische aus zwei Anteilen von prozentual annähernd gleicher Zusammensetzung getrennt werden sollen, die Aufstellung und Anordnung von zwei parallel gehaltenen Expansionsmaschinen erforderlich, da in diesem Fall bei Verwendung von nur einer Maschine, also wenn nur der eine Anteil unter Leistung äußerer Arbeit entspannt wird, an der erzielbaren Kälteleistung zuviel verlorengeht. Bei ungleicher Größe der Anteile wird man jedoch für gewöhnlich nur eine Maschine verwenden, in der der überwiegendeAnteil des Gasgemisches unter Leistung äußerer Arbeit vollständig expandiert wird. Den abgeschiedenen kleineren Anteil wird man, ähnlich wie den Dampf in der Leitung h, bezüglich seiner Aufnahmefähigkeit im Gegenstrom ausnutzen.In it, a is the high pressure pipeline leading through the countercurrent. The highly compressed that cooled in this line on its way through the countercurrent Gas is injected into the externally adjustable nozzle b up to a desired medium pressure relaxed and partially liquefied after reaching sufficiently low temperatures. The predominant amount that has remained in gaseous form flows through pipe c from the coldest Part of the countercurrent to through it back, whereby they enveloped by it, under high pressure. stagnant gas in a removes heat and thereby regains its temperature elevated. The gas then leaves the countercurrent through the pipeline d to after the Cold air machine e to get to where it continues to expand, work on the pistons and the crankshaft releases, in order to then puff out again into the countercurrent through the nozzle f. There it flows through the line g parallel to the mixture in c and against it High pressure gas in a, finally after complete heat exchange the apparatus at b - to leave. Of course, the individual tubes can flow in countercurrent can be arranged in any way, if only in principle the described heat exchange correspond. - In the drawing, a second nozzle i is arranged with the the liquid formed behind the first nozzle can be expanded further. the The very cold vapors that are formed in the process are also passed through the pipe h recycled in countercurrent to cool the highly compressed air to then to unite with the engine exhaust in g. Instead of the nozzles, it goes without saying a gas separator of known construction can be arranged. The gas separation must, however then take place under an overpressure compared to the engine exhaust. Also is under Circumstances when gas mixtures of two proportions of approximately the same percentage Composition should be separated, the placement and arrangement of two in parallel held expansion machines required, as in this case when using only one machine, that is, if only one part is performing external work is relaxed, too much of the achievable cooling capacity is lost. With unequal However, one will usually only use one machine in the size of the proportions that the predominant part of the gas mixture with the performance of external work completely is expanded. The separated smaller portion becomes, similar to the steam in line h, take advantage of its capacity in countercurrent.
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEH70641D DE444314C (en) | 1916-07-22 | 1916-07-22 | Method and device for cooling down and liquefying gas mixtures |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEH70641D DE444314C (en) | 1916-07-22 | 1916-07-22 | Method and device for cooling down and liquefying gas mixtures |
Publications (1)
Publication Number | Publication Date |
---|---|
DE444314C true DE444314C (en) | 1927-05-21 |
Family
ID=7163290
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEH70641D Expired DE444314C (en) | 1916-07-22 | 1916-07-22 | Method and device for cooling down and liquefying gas mixtures |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE444314C (en) |
-
1916
- 1916-07-22 DE DEH70641D patent/DE444314C/en not_active Expired
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