DE4339707A1 - Pollutant-emitting packing elimination from expansion joints - Google Patents

Pollutant-emitting packing elimination from expansion joints

Info

Publication number
DE4339707A1
DE4339707A1 DE4339707A DE4339707A DE4339707A1 DE 4339707 A1 DE4339707 A1 DE 4339707A1 DE 4339707 A DE4339707 A DE 4339707A DE 4339707 A DE4339707 A DE 4339707A DE 4339707 A1 DE4339707 A1 DE 4339707A1
Authority
DE
Germany
Prior art keywords
expansion joint
flame
aliphatic
expansion joints
packing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE4339707A
Other languages
German (de)
Inventor
Michael Dr Mahr
Ralf Dr Zuber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE4339707A priority Critical patent/DE4339707A1/en
Publication of DE4339707A1 publication Critical patent/DE4339707A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/30Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
    • A62D3/37Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by reduction, e.g. hydrogenation
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/10Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by subjecting to electric or wave energy or particle or ionizing radiation
    • A62D3/19Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by subjecting to electric or wave energy or particle or ionizing radiation to plasma
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/20Organic substances
    • A62D2101/22Organic substances containing halogen
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/20Organic substances
    • A62D2101/28Organic substances containing oxygen, sulfur, selenium or tellurium, i.e. chalcogen

Landscapes

  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Toxicology (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Thermal Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Processing Of Solid Wastes (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

Treatment of expansion joints packed with material that emits halogenated aromatic and/or aliphatic cpds. comprises exposing the joint to high temp. in a reducing atmos. to: (a) burn out the packing material, and (b) render the halogenated cpds. harmless by redn.

Description

Die Erfindung betrifft ein Verfahren und Einrichtungen zur Beseitigung halogenierter Aromaten oder Aliphaten emittierender Dicht- und Dehnungsfugenmassen.The invention relates to a method and devices for eliminating halogenated Aromatic or aliphatic emitting sealing and expansion joint compounds.

Dauerelastische Dehnungsfugenmassen sind häufig schadstoffbelastet, z. B. durch polychlorierte Biphenyle (PCB), polyzyklische aromatische Kohlenwasserstoffe (PAH), polychlorierte Dibenzodioxine und Furane (PCDD/PCDF) etc. Durch die aus den Dehnungsfugen austretenden Schadstoffe sind die benachbarten Bauteile bzw. die entsprechenden geschlossenen Bauanordnungen häufig mit den Schadstoffen an der Oberfläche gleichfalls kontaminiert. Eine entsprechende Kontamination kann bei der Herstellung der Bauteile oder Bauanordnungen auch über die Aufnahme von Schalöl oder dgl. auftreten.Permanently elastic expansion joint compounds are often contaminated, e.g. B. by polychlorinated biphenyls (PCB), polycyclic aromatic hydrocarbons (PAH), polychlorinated dibenzodioxins and furans (PCDD / PCDF) etc. through the The contaminants emerging from the expansion joints are the neighboring components or the corresponding closed building arrangements often with the pollutants the surface is also contaminated. Corresponding contamination can the manufacture of the components or building arrangements also via the inclusion of Formwork oil or the like occur.

Bauteile bzw. Bauanordnungen mit den zuvor erörterten Voraussetzungen müssen saniert werden. Dazu sind mechanische Räumverfahren bekannt (US-PS 3 110 054). Eine Weiterentwicklung demgegenüber ist schon vorgeschlagen worden EP 01 62 389 A2).Components or building arrangements with the previously discussed requirements must be refurbished. Mechanical clearing methods are known for this purpose (US Pat. No. 3,110,054). A further development, on the other hand, has already been proposed (EP 01 62 389 A2).

Das bekannte Verfahren nutzt zum Entfernen der Dehnungsfugenmasse zwei an beiden Seiten in der Dehnungsfuge geführte Schneidmesser. Dadurch wird der Streifen der Dehnungsfuge herausgetrennt. Dieses Verfahren hat zunächst keine vollständige Entfernung der Dehnungsfugenmasse zur Folge, da die Vernetzung der Dehnungsfugenmasse mit den angrenzenden Kontaktflächen der Bauteile wegen der Dauerelastizität und der normalerweise gewählten Einbringungsart sehr eng ist. Deshalb wird hier eine Nachbearbeitung der Dehnungsfuge derart vorgenommen, daß die anhaftenden Rückstände der Dehnungsfugenmasse mittels eines Stickstoffstrahls versprödet und durch drehende Stahlbürsten entfernt werden.The known method uses two to remove the expansion joint compound Cutting knives guided on both sides in the expansion joint. This will make the Strips of the expansion joint cut out. Initially, this procedure has none complete removal of the expansion joint compound as a result of the crosslinking of the Expansion joint compound with the adjacent contact surfaces of the components because of the Permanent elasticity and the type of application normally chosen is very narrow. Therefore, the expansion joint is reworked in such a way that the adhering residues of the expansion joint compound by means of a nitrogen jet embrittled and removed by rotating steel brushes.

Weiterhin ist in Patentschrift DE 40 28 434 C2 ein Vereisungsverfahren zur Entfernung von Dehnungsfugen beschrieben, das unmittelbar vor dem mechanischen Entfernen eines bestimmten Abschnitts der Dehnungsfugenmasse diese auf eine erheblich unter 273 K liegende Temperatur schockartig abkühlt und so erhärtet und versprödet, daß ein mechanisches Entfernen durch Herausschlagen erfolgen kann.Furthermore, patent specification DE 40 28 434 C2 describes an icing process for removal described by expansion joints immediately before mechanical removal of a certain section of the expansion joint compound this significantly temperature below 273 K cools suddenly and thus hardens and embrittled that mechanical removal can take place by knocking out.

Der angemeldeten Erfindung liegt die Aufgabe zugrunde, ein staubfreies und schadstoffemissionsfreies Verfahren zu entwickeln, das ohne den oben genannten mechanischen Aufwand auskommt und dennoch kostengünstig und frei von Schadstoffbildung arbeitet. Außerdem soll eine vollständige Entfernung der Fugenmasse gewährleistet sein und keine Nachbehandlung nötig sein.The registered invention is based on the object, a dust-free and pollutant-free Process to develop that without the mechanical above Effort comes out and yet inexpensive and free of pollutants is working. In addition, a complete removal of the grout should be guaranteed be and no after-treatment is necessary.

Diese Aufgabe wird gemäß Anspruch 1 gelöst.This object is achieved according to claim 1.

Durch das Verfahren gemäß Anspruch 1 werden die Fugenmassen und die beinhalteten Schadstoffe thermisch zerstört. Dabei wird die Bildung der hochgiftigen Schadstoffe (polychlorierte Dibenzodioxine und Furane (PCDD/PCDF etc.) bei der Verwendung einer Langmuirfackel durch die Anwesenheit von atomarem Wasserstoff und bei Verwendung eines Brenners durch die reduzierte Atmosphäre verhindert. Die bei dem Prozeß entstehenden Gase, die Abbauprodukte der Dehnungsmasse und der enthaltenen Schadstoffe enthalten, werden mit Hilfe einer Absaugvorrichtung entsprechend Anspruch 5 entfernt. Vorteilhaft ist die Verwendung einer Langmuirfackel nach Anspruch 3, da hier die höchsten Temperaturen, die selbst vorhandenes Restdioxin thermisch spalten, erreicht werden. Auch werden durch die reduktive Kraft des atomaren Wasserstoffs die polychlorierten Biphenyle sehr leicht dehalogeniert bzw. zerstört und die Bildung von Dioxin ausgeschlossen. Bei Verwendung einer reduzierenden Flamme nach Anspruch 4 können die oben genannten Bedingungen unter günstigen Umständen ebenfalls erreicht werden.By the method according to claim 1, the grout and the included Thermally destroyed pollutants. This causes the formation of highly toxic pollutants (polychlorinated dibenzodioxins and furans (PCDD / PCDF etc.) when using a Langmuir torch due to the presence of atomic hydrogen and prevented by the reduced atmosphere when using a burner. The gases generated in the process, the degradation products of the expansion compound and of the contained pollutants are removed with the help of a suction device removed according to claim 5. The use of a Langmuir torch is advantageous according to claim 3, since here the highest temperatures, the existing ones Thermally split residual dioxin can be achieved. Also through the reductive Due to the atomic hydrogen, the polychlorinated biphenyls are very easily dehalogenated or destroyed and the formation of dioxin excluded. Using a reducing flame according to claim 4 can meet the above conditions can also be achieved under favorable circumstances.

Claims (5)

1. Verfahren und Einrichtungen zur Beseitigung von halogenierten Aromaten und/oder Aliphaten emittierenden Dicht- und/oder Dehnungsfugenmassen, dadurch gekennzeichnet, daß man die einen halogenierten Aromaten und/oder Aliphaten enthaltende Dicht- und Dehnungsfuge mit hohen Temperaturen und gleichzeitiger reduzierender Atmosphäre behandelt, so daß die Fugenmasse entfernt werden kannn und die halogenierten Aromaten oder Aliphaten dabei gleichzeitig durch reduktive Prozesse unschädlich gemacht werden.1. Process and equipment for the removal of halogenated aromatics and / or aliphatic sealing and / or expansion joint compounds, characterized in that the sealing and expansion joint containing a halogenated aromatic and / or aliphatic is treated with high temperatures and a simultaneously reducing atmosphere, so that the grout can be removed and the halogenated aromatics or aliphatics are simultaneously rendered harmless by reductive processes. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die hohen Temperaturen bei gleichzeitiger reduzierender Atmosphäre durch eine reduzierende Flamme und/oder ein Plasma erzeugt werden.2. The method according to claim 1, characterized, that the high temperatures combined with a reducing atmosphere by a reducing flame and / or a plasma are generated. 3. Verfahren nach Anspruch 2, dadurch gekennzeichnet, daß die Flamme und/oder das Plasma durch eine Langmuirfackel und/oder eine atomaren Wasserstoff erzeugende Vorrichtung erzeugt wird.3. The method according to claim 2, characterized, that the flame and / or the plasma by a Langmuir torch and / or a atomic hydrogen generating device is generated. 4. Verfahren nach Anspruch 2, dadurch gekennzeichnet, daß die Flamme unter Sauerstoffmangel und gleichzeitigem Überschuß eines herkömmlichen Brenngases wie Acetylen und/oder Methan und/oder Wasserstoff und/ oder Propan und/oder Butan und/oder allen übrigen Kohlenwasserstoffen betrieben wird.4. The method according to claim 2, characterized, that the flame under oxygen deficiency and at the same time excess of a conventional Fuel gas such as acetylene and / or methane and / or hydrogen and / or operated propane and / or butane and / or all other hydrocarbons becomes. 5. Verfahren nach Anspruch 2, dadurch gekennzeichnet, daß der Entfernungsprozeß durch eine starke Absaugung unterstützt wird.5. The method according to claim 2, characterized, that the removal process is supported by strong suction.
DE4339707A 1993-11-22 1993-11-22 Pollutant-emitting packing elimination from expansion joints Withdrawn DE4339707A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE4339707A DE4339707A1 (en) 1993-11-22 1993-11-22 Pollutant-emitting packing elimination from expansion joints

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4339707A DE4339707A1 (en) 1993-11-22 1993-11-22 Pollutant-emitting packing elimination from expansion joints

Publications (1)

Publication Number Publication Date
DE4339707A1 true DE4339707A1 (en) 1995-05-24

Family

ID=6503111

Family Applications (1)

Application Number Title Priority Date Filing Date
DE4339707A Withdrawn DE4339707A1 (en) 1993-11-22 1993-11-22 Pollutant-emitting packing elimination from expansion joints

Country Status (1)

Country Link
DE (1) DE4339707A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4437345A1 (en) * 1994-04-22 1995-10-26 Svt Brandschutz Vertriebsgesel Decontamination of porous waste materials, esp. plaster work covering walls
CN114100522A (en) * 2021-11-29 2022-03-01 青岛伊克斯达智能装备有限公司 Internal rotation type waste rubber-plastic thermal cracking equipment

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4437345A1 (en) * 1994-04-22 1995-10-26 Svt Brandschutz Vertriebsgesel Decontamination of porous waste materials, esp. plaster work covering walls
CN114100522A (en) * 2021-11-29 2022-03-01 青岛伊克斯达智能装备有限公司 Internal rotation type waste rubber-plastic thermal cracking equipment
CN114100522B (en) * 2021-11-29 2023-09-26 青岛伊克斯达智能装备有限公司 Internal rotation type waste rubber and plastic thermal cracking equipment

Similar Documents

Publication Publication Date Title
DE3426059C2 (en)
DE3922383C2 (en) Process for the destruction of toxic waste products and device for carrying out the process
EP0578925B1 (en) Method for the removal of contaminants, in particular from soil
MX9300997A (en) METHOD AND APPARATUS TO MINIMIZE THE EXHAUST OF VOLATILE COMPOSITIONS USED IN THE CLEANING OF ARTICLES.
ES2083021T3 (en) PROCEDURE AND DEVICE FOR DEPURATION OF EXHAUST GASES FROM FURNACE FACILITIES.
JPS6127932A (en) Removal of polyhalogenated biphenyl from organic liquid
DD200305A1 (en) METHOD FOR REMOVING FLUOR AND / OR SULPHATE ELECTRICITY FROM FLUOROUS AND FLUID MEDIA
DE4339707A1 (en) Pollutant-emitting packing elimination from expansion joints
EP2408587A2 (en) Device and method for machining a surface contaminated by temperature-sensitive contaminants
ATE134157T1 (en) METHOD FOR DEGRADING HIGHLY TOXIC HALOGENATED ORGANIC COMPOUNDS CONTAINED IN GASES
DE4028434C2 (en)
Birke et al. Dechlorination of recalcitrant polychlorinated contaminants using ball milling
NO952065D0 (en) Method and apparatus for removing asbestos and / or asbestos-containing materials and from residues from waste incinerators as well as active coke and / or activated charcoal as well as low temperature coke and / or pyrolysis dust
EP0712944A3 (en) Ternary mixtures of solvents and their use for removing oily substances
ITTO950702A1 (en) PROCEDURE FOR DECONTAMINATION AND OXIDANT COUNTERFLOW TREATMENT OF A LIQUID, GASEOUS OR SOLID MATRIX.
EP0424865B1 (en) Removal of dioxins and furans
DE19621339C1 (en) Process for the destruction of chlorinated, aromatic compounds
JP3084731B2 (en) Decomposition method of halogenated dioxins in incineration ash
DE19514309A1 (en) Process for rendering chlorine-containing substances harmless in industrial waste
DE4013340A1 (en) Breaking down polyhalogenated hydrocarbon cpds. - contg. adsorbed mercury, by heating in absence of oxygen to desorb mercury and breakdown halo-cpds.
Kolak et al. Trial burns—plasma arc technology
JP3314309B2 (en) Method of detoxifying polychlorinated biphenyl
Smith et al. Applying plasma arc technology to asbestos cleanup
DE4414404A1 (en) Decontamination of solids, e.g. fly ash from a waste incineration process
Fairfax et al. OSHA Compliance Issues Fiery Death aboard a Vessel at a Shipyard

Legal Events

Date Code Title Description
8139 Disposal/non-payment of the annual fee