DE4328569A1 - Neutralisation of toxic materials - including using a number of chambers and peripheral systems for electro catalytic processing and recovery of material - Google Patents

Abstract

For the conversion and/or neutralisation of synthetic, biological or chemical poisons, a number of chambers are used together with peripheral appts. and assemblies for catalytic processing in the form of watery solutions and/or with solvents and/or emulsions and/or suspension and/or dispersions and/or gels. The material, in safe containers, is carried to an expansion dosing chamber which has a remote control to open the container for the material to be inserted, and has a connection to a safety container holding a supply of concentrated neutraliser. The diluted poison is inserted into the circuit of the neutralising assembly in the mixing chamber, and the pH is adjusted by alkali and/or acid, for the solution to be filtered to remove floating particles and flocks. If there are no particles or flocks, the material is passed without filtering direct to the circuit with the neutralising chamber and working electrodes at the lowest point of the neutralising chamber. A tube exhaust at the upper part leads to the expansion chamber. The expansion chamber has a separate outlet to a catalyst with a lambda-type control to remove intermediate gas products such as oxygen, hydrogen, hydrocarbons, nitrogen compounds and the like. A second tube link leads to a regeneration assembly for recycling. A heating and/or cooling system is at the walls of the first neutralising chamber and at the regeneration assembly, integrated in the shrouding to give temp. increase and/or decrease during the process. An overflow from the upper part of the container leads to a dwell stretch in the assembly similar to a dwell stretch for the second neutralising assembly. Additional systems include filter and/or dialysis and/or flotation and/or sedimentation and/or electro dialysis for electroflotation and/or sludge filter press or centrifuge filters and/or anaerobic fermentation for the sludge and peripheral gas cleaners through anaerobic degrading, with return feeds to the mixing vessel in front of the filter. A catalyst carrier is inserted between the working electrodes, as the flow has to be upwards in the second stage of the neutralising assembly. A system to distribute the reactants is at the upper part of the neutralising chamber for the recovery of raw material and/or separation of toxic matter. The sludge is incinerated and toxic-free solution can be fed to the supply network. The electrodes and the electrical assemblies are linked to the current supply. Each stage has measurement probes with one or more current supplies with an integrated micro power where the electrodes have a working contact surface of a few micron or smaller for a continuous monitoring of the reaction condition, with a multi-channel laboratory evaluation system for quantitative and/or qualitative and/or print-out indications through ion spectroscopy. USE/ADVANTAGE - The system is for the neutralisation of poisons, especially in military applications, and also radio active contaminating and atomic wash with recovery of useful material for safe use. The action gives an effective neutralising of toxic matter and also gives good recovery such as of super radio active isotopes for peaceful use.

Description

Due to the changed political, economic and ecological world situation, we face the need for efficient problem solving methods To develop elimination of biological and / or chemical poisons. This process patent contributes to a large part, which is mainly in military field used synthetically manufactured biological and / or chemical poisons, in the systems described by us - after the decomposition process - to dispose of effectively, with the bulk of here resulting decomposition products, returned to peaceful use could be. On the possibility of radioactive contaminated materials on the We only point out the same way of disposal, as this is ours has not been checked, although there is reasonable reason to suspect that the Functionality of the systems described by us especially for this one Area - especially for the recovery of ultra pure radioactive isotopes - for the peaceful use is appropriate.

Process for cleavage and / or conversion and / or decomposition and / or Neutralization of solutions and / or suspensions and / or emulsions and / or dispersions etc., one or more synthetically produced biological and / or chemical poisons, which are in an aqueous and / or organic electrolyte solution as a suspension and / or as a dispersion and / or are presented as a gel and / or as a solution in an installation, wherein this system consists of several cells and for the purpose of implementation chemical processes with various apparatus and / or devices is equipped to carry out electrochemical catalysis (e.g. oxidation, reduction, hydrogenation, etc.) and / or the subsequent ones Treatment methods, in the form of e.g. B. electroflotation and / or Electrophoresis and / or electrodialysis and / or filtration and / or dialysis and / or distillation and / or anaerobic and / or thermal treatment in filtration and / or sedimentation and / or flotation and / or one anaerobic process (this is the use of an Procedure, or a combination of the procedures with each other) - the after following filtration before further processing - enables where the electrolytes with toxin content presented during the course, the then by adding reagents to the pretreated one Electrolytic solution after the course of the first electrolytic Neutralization chamber before feeding the second electrocatalytic Waste coagulates arising in the neutralization chamber must be eliminated. Ensuring the neutralization balance and / or that of Decomposition of gases occurs through excess enrichment of water and oxygen (where water and oxygen during the catalytic Reaction in the corresponding stoichiometric reaction form only partially are consumed), and since these are already in excess during the reaction are present and cannot then be transferred into the solution. The gases escaping from the solution, which during the passage through the Reaction path were present in excess and therefore the saturation of the After the solution has been exceeded, the other processes are left  no longer available. It is therefore necessary to continuously add these gases remove. The removal is carried out on a catalyst with lambda-like Control. It should be borne in mind that when removing the Gas mixture which contains a higher amount of free oxygen and / or Contains hydrogen and / or additional hydrocarbons, etc. explosive mixture can occur, a preventive Precaution must be used. Especially in the treatment of synthetically produced chemical poisons can at higher temperatures an additional contamination of such gas mixtures by them arise. The tail gases of such plants must pass through the Cleaning process of the treatment chamber are recycled, and after the use of an intermediate cleaning stage, which is the task has to retain substances that are caused by the use of a catalyst control similar to lambda cannot be disposed of. However, one can upstream of this catalyst stage a removal device, the here Separation of partial reactants for delivery to the end user can take place (in the treatment of industrial waste water from production chemical companies can recycle raw materials chemical substances, e.g. B. metal catalyst).

The excess and existing in the reaction process Gas components have been subjected to a cleaning process, whereby the cleaned gas of the cleaning stage (with lambda-like control) can escape. The gas purification system we have provided continue to fulfill the task of a pressure relief valve function, since at the Electrolysis in each stage an indefinite amount of gaseous oxygen and / or hydrogen and other compounds escape, especially not full amount of separated water and / or oxygen through which Reactions themselves, can be consumed in stoichiometric reaction form and this must already be in excess.

After the other processes involved in the implementation and / or decomposition and / or neutralization and / or elimination occur, it is recommended each individual stage, one / more plant (s) to carry out a Electrodialysis and / or electrophoresis and / or distillation and / or Chromatography and / or dialysis, also with a elevated temperature, for example in the range of up to 500 ° C. can be. The quantities of gas generated in the processes are preferably on a catalyst structure - in its execution and Control similar to lambda - catalytic at a temperature of up to 500 ° C decomposed to nitrogen, carbon dioxide, oxygen, hydrogen etc., whereby various others between the individual stages Production processes that involve the separation and / or selection of individual Decomposition products are used for electrocatalysis, can be upstream. What is important here is that by an additional process independently made filtration, and / or neutralization stage, the  resulting oxidation products, by precipitation and / or adsorption, e.g. B. on a carbon filter or a metal oxide, can be eliminated. The Object is achieved in the sense of the invention in that in a divisible wrapping, the z. B. from at least one partition exists and, depending on the version, at least one ceramic cassette (which as Carrier for a catalyst is used and has long been highly porous in the direction of flow and is preferably made in honeycomb form) between the Working electrodes is placed so that in the solution to be cleaned by the Electrolysis a supersaturation of oxygen and / or hydrogen, as well as a Enrichment of free hydroxyl radicals, oxygen and / or hydrogen in the Status nascendi, as well as in particular of ozone and the responsive "Singlet oxygen" ¹₂O₂, an oxidative and / or reductive decomposition and / or implementation and / or deposition of the above Impurities in the solution and / or dispersion and / or Suspension and / or emulsion in particular, can take place on the catalyst. This arrangement of the working electrodes is so important because it is must be avoided that the water and / or oxygen formed and / or others (e.g., halogens, i.e. chlorine, bromine, iodine and fluorine) have long since become the anode and / or cathode can move because the formed water and / or oxygen and / or others, must / must by the predetermined flow rate of the electrolyte, in the same solved and in the given direction by the shortest route Catalyst part are supplied. The educational relationship of the inert "Triplet oxygen" ³₂O₂ to a briefly existing ozone and / or "Singlet oxygen" must be made using a working electrode (Anode) with the highest possible overvoltage - in favor of the latter - postponed, including the production of short-lived ozone under the use of high energy rays should be considered.

The method enables a large number of different ones Embodiments.

The process can also be designed so that the use of non-aqueous Solvents such as B. ammonia, hydrogen fluoride, hydrogen iodide, Hydrogen cyanide, sulfur dioxide, bromine, iodine etc., dissociated organic Solvents (e.g. formamide) and / or a combination of the solvents with each other and / or with water and / or with an appropriate one Graduation of different flow cells according to solvent, current density and Voltage, application, where there is a wide variety of redox potentials and / or the reducing and / or oxidizing agents used let insert. The process is further expanded by the Transfer of the catalyst carrier and / or the electrodes with different semi-permeable membranes.

The catalyst carrier is made of a chemically resistant ceramic material  of porous morphology and with the largest possible relative surface manufactured.

The honeycomb shape and / or in particular meets these requirements Sphere accumulation. The length of the catalyst carrier is variable, but should in all suitable plants the thickness (thickness of the catalyst cake) Do not exceed 50 mm. Particular attention is paid to the placement of the Dedicated catalyst support, since the application of those described by us Technology, to increase the voltage and thus to reduce the Current effect curve leads, which in turn by the resulting change in Flow conditions is more than justified, especially since the narrowing of the Gaps due to the presence of the catalyst carrier Increasing the flow rate and the fact that the The catalyst carrier can also be placed between two diaphragms can must. For the purpose of preventing possible contact of the Catalyst part through the electrode, should be a specially designed Spacer ring are used, this one from a chemically good resistant, non-conductive material should be made. The Catalyst materials are preferably transition metals and / or their Oxides. It is advantageous if the catalyst components are both occupied, as well as unoccupied d orbitals. Becomes elementary in electrolysis Formed fluorine, lanthanoid fluorides are special catalyst materials well suited. It is advantageous here if the catalyst components, have both occupied and unoccupied f orbitals. Suitable in this sense a combination of cerium (III) fluoride, praseodymium (III) fluoride, Europium (III) fluoride, gadolonium (III) fluoride, terbium (III) fluoride, dyprosium (III) fluoride, thulium (III) fluoride and / or yttebrium (III) fluoride. Significant is that for neutralization and / or decomposition and / or implementation and / or cleavage certain substrates, through the use of Chemical compounds that lower the surface tension electrochemical and / or catalytic process made accessible can / must be.

Because of the high toxicity of synthetically produced biological and / or chemical poisons are already in the construction of such Neutralization systems to observe certain requirements. The there are synthetically produced biological and / or chemical poisons in an airtight container up to several hundred kg Tara. These containers must therefore be in a well insulated, airtight chamber - equipped with the various techniques. To the opening of the container may contain its contents, consisting of a synthetic manufactured toxin and / or a combination of toxins, not all at once, but only by continuously feeding small amounts of synthetic manufactured biological and / or chemical poisons, the first Treatment chamber of the system are fed. The establishment of the first Treatment chamber consists of an electrode package, which predominantly  made of a non-soluble conductive material, such as. B. stainless steel, titanium, etc., and / or glassy carbon, etc., the electrode package, for the purpose of oxygen and / or hydrogen separation of an overvoltage is exposed.

It is important that the electrode pack is equipped so that the Employment ratio of the cathode min. 1: 1.1, but at most 1: 60, predominantly however, is up to 1:10.

Particular importance must be attached to the type of electrode arrangement and the direction of flow of the electrolyte movement. ( Fig. 8)

Thus, an excess of electrons and an electron deficiency arise on the working electrodes. B. the water is decomposed into positively charged hydrogen and atomic oxygen and two electrons are released. ( Fig. 5, Fig. 6, Fig. 8, Fig. 17)

The method according to the invention can be used in particular for neutralization and / or decomposition and / or implementation and / or Removal and / or recycling of production residues Waste water from chemical companies and thus a return of the recovered raw materials of production are made possible. The one there resulting connections, e.g. B. metal halides, must then Course of the continuation to the second neutralization tank eliminated (Appendix 1).

The treatment chamber of the first stage must therefore be designed so that the dosing device of the toxins is in the lowest level of the container must be, the dosage of the neutralization and / or cleavage and / or decomposition and / or chemical conversion of the reaction supplied reactants in a previous dilution continuously and with constant stirring directly in the area of Working electrodes must be made.

The container must be with a dosing device of the toxins to the first Treatment chamber be connected, it being important that during the first reaction stage of electrochemical neutralization and / or disposal and / or cleavage of biological and / or chemical Poisons that are already diluted in the first one Have undergone expansion chamber and being so prepared Poison solution continuously (and in small amounts) the circulation in Mixing chamber is added, with the pH value also here predicted values, brought by the addition of alkali or acids  and then into the lowest part of the first treatment chamber and the Solution is led directly to the working electrodes, here the Toxin supply in the lowest part of the circuit of the plant should not flow into the fresh water supply line may.

After the reaction solution thus prepared has flowed into the working electrodes in the reaction chamber, the first reactions to anions and cations take place and the first substitution reactions take place on the reactants supplied. The size of the parameters presented with regard to current density, voltage, temperature, dwell times etc. is of importance here, with the focus here being on chemical separation and physical separation of the functional groups acting as catalyst poison and their replacement as far as possible exclusively by the electrolytically generated ones To cause hydrogen, oxygen and hydroxyl groups. ( Fig. 5; Fig. 6; Fig. 17)

Using combined and / or non-aqueous solvents the course of the reactions can be controlled so that a prerequisite for the production and development of new processes for the purpose of synthesis new products and structures are already being given. For cleaning purposes of the solution passing through the first reaction stage are through us different processes and / or their combinations next to each other / one below the other, with the focus always on the electrochemical process is to be sought. During the process of electrochemical reaction that is released in the first stage Foreign radicals, such as B. halogens, z. B. by dialysis, filtration, Electrodialysis, electrophoresis, ion exchangers, iontophoresis, Eliminate electrophoresis, sedimentation, etc. in the form of salts. It can it can also be demonstrated that with some chemical compounds the Cleavage of the compound of synthetically produced chemical poisons up to the Starting products of the synthesis reaction can take place. Here too there is Possibility to separate these products by a suitable process and to feed a new technology process as a raw material for regeneration.

Of course, other procedures can also be included in our procedures and / or attachments, u. a. the use of a soluble Anode, e.g. B. of iron, aluminum, zinc, etc., which lead to an ion exchange, for the purpose of binding the z. B. lead free halogen radicals. Here care must be taken that between the first treatment chamber and the Catalyst part a sufficiently large calming section of the to be treated Electrolyte is provided, which by the soluble anodes in Exchange metal ions, as well as their anion radicals, in the through facilities of the calming section provided to us, in an insoluble form, by connecting a suitable device level. Here  can also the removal of the first reaction products and / or Decomposition products of neutralization and / or cleavage, such as. B. alcohols etc., the subsequent regeneration z. B. by dialysis, distillation, etc. are fed, are aimed for.

The use of soluble working electrodes, e.g. B. Ag, Cu, Se, etc., is mainly with the elimination of biological and bacteriological Material connected.

It is also likely that the use of high molecular weight Flocculants that are used to support flotation processes in the Sedimentation of heavy metal salts and / or suspended solids used be an advantage. Not enough time to purifying reaction solution of the toxins in the calming zone, the between the first and second electrolytic neutralization chambers Is placed, can be transferred to the second working chamber of the Neutralization system a contaminated by fine particles of suspended matter Result in a reaction solution. This can then be the cause that, for. B. a blockage of the diaphragms used and / or Exchange membranes of dialysis, electrodialysis machines and / or Catalyst parts etc. takes place, which with a temporal failure of the Neutralization systems connected by their cleaning.

Here you can see the importance of the existence of the calming section and / or the systems integrated here and especially the Cleaning level.

Already with the construction, the necessary dosing device and / or Expansion device and / or monitoring device and the whole Neutralization system, it must be taken into account that the systems are airtight must be locked, with each level an additional security level and sheathing is mandatory. The casing must then with any possible damage to the inner casing, an immediate one Have the damaged chamber closed and it must go through a Neutralizing agent concentrate for the purpose of chemical neutralization of the remaining toxins, flooding the damaged chamber respectively. It goes without saying that the expansion chamber the neutralization system, before each new supply of toxin, even before opening the chamber, through one for neutralization used concentrate is cleaned. This cleaning must be automatic respectively. Because here worked with different compositions is / was, is not only the damage of the chambers by corrosion in possible in every area, but is also the focus in the expansion and / or dosing chamber to search, since in the supplied for neutralization  Storage containers after all, the existence of the detonators and that Presence of the explosive charge, the necessary dispersal and initiate the action of the toxins, not be excluded can.

The reaction temperatures of the decomposition, reaction, neutralization Processes etc. of synthetically produced biological and / or chemical Poisons can range in temperature from -70 ° C to 0 ° up to 500 ° C and higher. Mainly you work here in the temperature range from 20 ° -80 ° C, the implementation of electrolytic and / or electrocatalytic processes do not always run in a liquid phase must, but is also well known in the solid and / or gas phases, d. H. is possible in the temperature range above 100 ° C. The temperature can easily reach 500 ° C and higher in the catalytic converter area. Consequently may well be post-combustion catalysts with lambda-like controlled system for the - in the upper part of the treatment chamber itself forming gaseous mixtures - are used.

When using the method, care must be taken that, especially with the catalytic decomposition and / or chemical conversion of pollutants, the atoms contain such. B. halogen and / or phosphorus and / or arsenic and / or sulfur and / or silicon and / or boron etc., it easily becomes one Poisoning and / or impairing the effect of the metal and / or metal oxide layer of the catalyst comes, which is why this disruptive atoms in the form of an exchange of corresponding ones Molecular fragments must be replaced and removed beforehand. (Attachment 1)

The catalytic treatment of all existing compounds in such Gas mixtures should be periodically subjected to an exact analysis undergo, as not all reactants are fed to a reaction are, by the initiated reaction processes, as reaction products of Gas phase can be transferred, especially since the majority of the running Reaction have an exothermic course and it is therefore quite possible - that is, it is all the more likely - that one often looks at the increase the temperature can do without, because in what we described Closed loop process is what a Increasing the working pressure in the individual working chambers of the Neutralization system causes.

Care should be taken that during the electrochemical processes in the Inside the reactor is not just water, as a donor of electrolytic Decomposition reaction to water and oxygen should be there, but it can also other different mixtures and / or admixtures Reaction solutions are used, which in turn leads to different  Side reactions can lead to the working electrodes.

However, when overvoltage is applied to the working electrodes, it does happen not with all of these mixtures and / or admixtures to one Separation of hydrogen and / or oxygen, this for the purpose of formation a new reaction product is desired.

Therefore, it is in electrocatalytic disposal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons necessary that during the entire reaction process for a sufficient amount of reactive Acid and hydrogen and / or other reactants, or their excess, available to the neutralization process over the course of the reaction stands, is taken care of.

The individual chemical-physical processes are already during the Work flow during the introduction and at all important points during of the neutralization and / or decomposition and / or implementation and / or Splitting process in all parameters for further industrial evaluation to monitor spectrophotometrically, here a new measurement method, the we call ion spectroscopy.

For the purpose of continuous control of such complex chemical Reaction processes with regard to their decomposition and / or chemical Until recently, there was no suitable implementation and / or response quality Working method available.

This led to the development of a new spectrophotometric method, the we refer to as "ION SPECTROSCOPY", which is a new, independent working method of SPECTROSCOPY. This Working method is with no already known spectrophotometric Method identical or comparable, whereby the similarity to the name ION CYCLOTRONIC RESONANCE SPECTROSCOPY is purely coincidental. The Construction of the work cell largely does not only allow implementation of synthetic processes, but also the implementation of a novel Evaluation of electrophoretically traces of genetic materials in their individual fragments. Therefore, with a significant reduction in costs research and development, as well as in industrial recycling count.

This could contradict the claims of neutralization and / or Decomposition and / or implementation and / or disposal synthetic manufactured biological and / or chemical poisons, however  "ION SPECTROSCOPY" allows us to create the fastest possible Conditions of neutralization, their documentation about the capabilities of the Process in all its process stages as well as the practical implementation of the thus achieved working conditions for industrial evaluation, which in a Procedures are implemented to create inexpensively.

The technology of "ION SPECTROSCOPY" is in development new working methods and in researching new work products set groundbreaking accents.

The process of ION SPECTROSCOPY, however, is not only limited on the procedure registered by us for protection and its Devices, but also shows their basic importance in that they for the construction of small cells in a wide variety of variants Volumes of <0.001 ml is suitable, which is also the simulation of chemical Operations by any combination of individual fragments of the Measuring cell, which are combined in a measuring unit, allowed.

Also for the simulation of complicated chemical-physical Reaction processes, working conditions and various chemical Reactions in all stages of the production process is the new process excellently suited.

For this reason, the term "ION SPECTROSCOPY" as well as the Device for carrying out and using the "ION SPECTROSCOPY" to be regarded as the subject of the patent content and therefore under copyright law protect.

In order to ensure a promising course of the reaction processes, a separate package of stable or non-stable working electrodes has to be used, the electrolytes used being set in the acidic to alkaline pH range from 1 to 13 and with an anodic current density of up to 100 A / cm ² and with a volume flow of 0.01 to 1000 liters and an overvoltage, adjusted to the determination reaction, of up to 180 volts.

In the treatment of biological and chemical poisons in individual The overvoltage applied to the working electrodes can be up to 1 MV and a frequency of up to 1 GHz (applies to pulse current).

The conditions apply to all those equipped with working electrodes  Treatment chambers. The operation with high voltage, however, takes place mainly in the field of catalytic treatment of in the vapor phase are synthetically produced chemical poisons and / or in Field of disposal and / or neutralization of synthetically manufactured biological poisons.

Of the presented majority of synthetically produced biological and / or Chemical poisons are only a few without the use of emulsifiers and / or other anionic and / or cationic surface tension reducing agents and / or nonionic surfactants, soluble and / or emulsifiable in water. The amount of surfactants and / or emulsifiers used here is from Initial concentration of the concentration leading to neutralization the synthetically produced biological and / or chemical poisons determined and required in an amount of up to 10 g / l.

The use of ceramic carriers is becoming increasingly popular Form of solid acids - which have their own catalytic effect can - in importance.

The catalytic effect of such solid acids can be up to a factor of 10 increased by the use of metal or metal oxide catalysts become. As solid acids such. B. KieseIäure-alumina gels or microporous aluminum phosphates, etc.

It is fundamental for the construction of the neutralization system that the smallest changes in the system's schedule, this also when it is removed of residues with a radioactive character is applicable.

It is important to ensure that the neutralization in two different Directions can run. For the first variant you use for the Working electrodes (anodes) radioactive carbon material, which in their crystalline lattice also have the metallic crystals of the radioactive metals can.

During electrolysis, these metal crystals can dissolve through the analytical process. If this solution is saturated by metallic ions, radioactive materials can be deposited on the cathode. ( Fig. 14)

Whether these radioactive materials after the electrochemical deposition as metallic layer will also have the same half-value again are neither confirmed nor denied by the inventors.  

A similar approach is followed in the second variant. Here must radioactive materials merge into an ionic solution and become thereafter cleaned by an electrolytic process.

These systems are based on a similar design solution as the Plants for the disposal of synthetically produced biological and / or chemical poisons. To improve the separation processes, the ionic solutions also by means of one / multi-stage dialysis and / or Electrodialysis systems or be cleaned by another method.

Since metallic elements are advantageous here in the highly pure state let it separate and also the possibility to separate one there is a very broad one Range of applications. In this context we also refer to the possibility of the radioactive metallic elements thus obtained or metal - ceramic layers as starting material for fuel rods in To use nuclear power plants. In the past, were such elements such as B. Be, Ti and Zr also used for the production of A weapons, so the new techniques can restore these substances to peaceful Be used.

Another advantage of the method is that the constructive solution the systems are also characterized by a high level of corrosion resistance. Most of the plants are made of glassy carbon. This material is more oxidative or reductive chemical compared to the action Substances or substances are extremely resistant and guarantee one excellent hardness - comparable to a diamond - and has one comparable to platinum and / or special platinum compounds Corrosion resistance. In addition, glassy carbon - due to its crystalline structure - ideally suited, especially for the construction of plants, which are intended for the treatment of radioactive materials. Of course the further safety regulations for dealing with radioactive Substances are strictly observed.

When dissolving radioactive materials in acidic or alkaline media and when diluting radioactive materials in aqueous and / or organic solvents, it is more than likely that radioactive gases, such as. B. radioactive oxygen or hydrogen can arise. These gases are also generated during the operation of the electrolysis and must not be allowed to enter an open environment. ( Fig. 14, Fig. 15, Fig. 16)

Therefore, in the chemical dissolution of the radioactive metals and in the metallic salts of radioactive isotopes formed by electrolysis and in the equivalent amount of gaseous reaction products, such as. As hydrogen, to ensure the necessary discharge into different safety containers, separated by type of product. The degree of purity, the degree of contamination, etc. are then carried out in these security containers. The aftertreatment of the stored, cleaned and dried gases must be in accordance with the safety regulations for handling radioactive substances 15125 00070 552 001000280000000200012000285911501400040 0002004328569 00004 15006t. For safety reasons (risk of radiation!), The system must also be surrounded by an additional casing. The use of glassy carbon for the systems used allows the designers to meet even the highest safety regulations. Another advantage is that you can work in circulation systems. The treatment and aftertreatment of the radioactive waste materials requires the conversion into a soluble form during processing, which enables the electrolysis to be carried out and thus the possibility of electrolytic elaboration or storage of the metallic ions in the solution in the form of metal wires, foils and sheets allowed. ( Fig. 15)

It would also be conceivable to use the raw materials recovered in this way for the Manufacture of fuel elements for nuclear power plants and still for the Use in ship and space travel as well as in medicine etc.

There are various theoretical, patent-protected ones Treatises on rocket propulsion engines that contain radioactive materials the basis of their membrane pump behavior as an ion compressor in Pump systems of drive accelerators can be used. For for these purposes the techniques for which a patent has been applied would be secure suitable.

We point out that the splitting of emulsions and / or Dispersions of organic substances is a process known to us. The process of emulsion splitting from alkaline degreasing baths is State of the art since 1969 and was in its basic conception as an electrolytic degreasing system e.g. B. in the SCHERING systems AG, Berlin integrated.

Various patents, e.g. B. EP 85 903 814 and 85 903 985 des Mr. Renzlers are not in favor of the procedures we are aiming for relevant because the techniques and procedures described there in their basic reaction courses were known before the registration and also in school books, practical manuals and technical ones Manuals of physical chemistry were found.

One might also think that Renzler 's theses in their Attempts have been made to demonstrate that the application of Noble metal electrodes or insoluble coated with noble metal  Working electrodes have an industrially significant catalytic effect pull.

This stands in the way - and this can even be done by laypeople Test series are confirmed - that the use of precious metal electrodes or the use of electrodes coated with precious metal Insertion of overvoltage the redissolution of the precious metal layer by a partial dissolution of the precious metal layer and therefore an enrichment of the Solution by precious metal ions!

It should be borne in mind that the noble metal layer alone can be made unusable in the presence of Heavy metal ions in the electrolyte partially on the cathode can be deposited, which then the precious metal layer in their alleged catalytic effect is immediately disruptive.

With the anode, the overvoltage leads to such a strong one oxidative process that that formed on the precious metal anode Decomposition products pre-program poisoning of the catalyst, whereby the dissolution of the precious metal layer is only a matter of time.

The possible origins known in practice also became apparent an organic barrier layer - the one in the presence of organic Residual substances form on the anodes when overvoltage is applied is not taken into account when granting a patent.

Also the use of the others recommended by Mr. Renzler Working electrodes, such as B. Al, Fe etc., is without the most expensive Post-treatment techniques and without falsifying data for Enrichment of the electrolyte to be treated with heavy metal ions perform what an extremely costly post-treatment of the electrolyte with leads.

Even the alleged removal of PCP and other toxins - as by Mr. Renzler described - can with his "patented" device too no industrially significant oxidative or reductive disposal or Reduce the concentration of pollutants.

Rather, this enrichment of the solution to be treated is carried out Heavy metal ions, organometallic complexes, decomposition products of Electrolysis or that present and / or presented in the same solution organic substances very often to form an even more toxic solution  of the decomposition products (e.g. reaction product from PCP to TCP - depending on the accompanying substances with up to approx. 10 times (!) toxicity of the Starting product) of the described neutralizations, with which the the intended effect is certain to be absent!

In this context, the question arises, what is the novelty of Renzler's theses exist in the sense of the patent law.

For the sake of clarity, some are now being added by us Terms such as B. "Power source JKB", "ION SPECTROSCOPY", "synthetic produced biological and / or chemical poisons ".

Under the term "power source JKB" is one by Dr. Knedla developed power source to understand that allows the user to work with direct and / or alternating and / or pulse current as well as single-channel and multi-channel operation when performing the work ( Fig. 9, Fig. 10).

The power source is with a microcomputer to control the individual Parameter equipped, the individual parameters among themselves in the various forms can be combined, such as. B. voltage, Current, time, frequency, pulse and curve type form etc., the operation this power source is designed to work with high voltage and high frequency is possible.

A synthetically made biological poison is an artificially made one bacteriological material which, for. B. by genetic manipulation a cell in the laboratory for possible use as Weapons of mass destruction were created, isolated and manufactured.

A synthetic chemical poison is one, through synthesis prepared organic compound, such as. B. Sarin, Soman, Tabun, PCP, TCCD, phosgene etc., which are also used as a means of mass destruction can be.

The term "ION SPECTROSCOPY" means that the Measurement of the change in light wave absorption in time Dependency between two / more working electrodes connected to the Current sensors JKB are connected.

The time dependence of voltage is shown in the light wave absorption and / or current and / or frequency and / or pulse and / or type of curve etc. measured. The technique of carrying out is with the technique of ion  Cyclotron resonance spectroscopy not identical; rather, it represents one independent measurement method.

The application of this technique using an ion spectroscopic converter according to Dr. Knedla especially enables a smaller company with a conventional UV / VIS spectrophotometer in the measuring range 180- 52 000 nm, the fastest quantitative and qualitative evaluations. Additional fluorescence, chemiluminescence and / or IR spectrophotometers are then no longer required for the safe performance of this work. We would like to point out that the new techniques can also significantly increase the detection limit of pollutants. Development costs can also be substantially reduced. B. in the course of the technical reaction for new organic compounds ( Fig. 11, Fig. 12, Fig. 13)

Attachment 1 Example of a neutralization process for the synthetically produced toxin SARIN

The toxin is passed through the opening chamber into the Dilution chamber mixed with solvent and with an alkali or Acid solution brought to the reaction pH and then in the electrochemical Pumped reaction chamber.

After splitting off the halogen and / or other functional Groups will pass through the solution of the first chamber after the run the calming section led into the second electrocatalytic chamber.

After about 20 min. Response time are the org. Decomposition products such as methyl alcohol, formic acid, trimethylene oxide or another organic compound has been separated by dialysis and the contaminated Phosphate and / or fluoride solutions become the reaction chamber again fed and only after the enrichment by the decomposition products subjected to a separation process.

The decomposition products created by electrocatalysis are one Regeneration has undergone, the regenerates obtained a technical as well as being of the highest purity.  

Installation of FIG. 1

Schematic representation of a neutralization system for disposal synthetically produced chemical poisons (e.g. soman, sarin, etc.)

The system can be expanded as required.

1. The wagon device from the warehouse to the expansion chamber

2. The expansion chamber with an integrated storage container with neutralization concentrate for cleaning the container and equipped with an automatic opening system for the poison storage container supplied to the chamber ( FIG. 2).

3. Dilution chamber with integrated system for pH adjustment and integrated filter system ( Fig. 3).

4. Flocculation system with integrated mud press ( Fig. 4).

5. A first stage electrochemical neutralization cell. When Working electrodes become insoluble and / or soluble metallic and / or non-metallic electrodes are used. The material used in the Working electrodes depend on the type of poison to be neutralized. At the electrolytic cleavage of a synthetically produced chemical Poison (e.g. sarin) is exchanged in the first stage of neutralization foreign radical ions due to the oxygen generated during electrolysis and / or hydrogen atoms. An additional partial oxidation or partial reduction the starting products are possible. The ones in the solution Foreign metal ions are deposited on the cathode. The working electrodes should never be covered with a layer of precious metal!

For an optimal course of the electrochemical neutralization, the Placement of the electrodes and the initiation of the flow of the neutralizing electrolyte.

The working electrodes must always be placed in such a way that the electrolyte can still take over the oxygen and / or hydrogen generated during the electrolysis in a reactive state and still occurs from the bottom to the top during transport to the counterelectrode. A heating and / or cooling system must be integrated in the walls of the first stage system. This system works at from -70 ° C to + 500 ° C. An opening is integrated in the cover of the system. This opening is connected to a collecting container, the rectification system, which is equipped, among other things, with a lambda-like afterburning system. And this collecting container can have feed lines from other points in the neutralization system, one line of the boiler leading to the rectification column and another line leading to the lambda-like afterburning system. The intended monitoring systems can be connected to any part of the system and allow quantitative and qualitative monitoring of the course of the neutralization. The use of soluble metal electrodes is required for the electrocatalytic neutralization of biological poisons. The overflow of the tank must be fixed to the still tank ( Fig. 5).

6. The overflow of the neutralization tank of the first stage must be integrated in the tank and connected to a calming section. This is where the required amount of flocculants is added and the pH is adjusted while stirring the solution. The dewatered sediment is then sent to an incinerator as dangerous goods. The filtrate contained here is returned to the systems of the rectification collection tanks and only then to the solvent cycle. The sludge from the removal of biological poisons is sent to anaerobic fermentation for biogas production ( Fig. 7). The biogas obtained in this way can then be used for the heating system and also for the generation of electrical current.

7. Plant for pH adjustment. In its design similar to the system 4 ( Fig. 3).

8. Auxiliary system for preparing the electrolyte solution before the final electrocatalytic decomposition and / or reaction by adding reaction aids with subsequent filtration of the solution ( Fig. 4).

9. Plant for electrocatalytic decomposition and / or conversion of organic substances. The electrodes used in both cases are insoluble glassy carbon electrodes. At least one catalyst ring is located between the working electrodes. The flow of the electrolyte must be carried out in such a way that the solution is led to the catalyst ring only after the oxygen and / or hydrogen obtained by the electrolysis has been enriched. The flow must always be from bottom to top, the flow rate should be chosen so high that the oxygen is still present in the reactive state (as singlet or triplet oxygen). The working electrode is connected to an alternating current and / or direct current and / or pulse current source. A stirrer is installed to improve the reaction yield. Heating and cooling systems that can work in the temperature range from -70 ° C to + 500 ° C are integrated in the ceiling of the rectification system tank. In the ceiling of the container there is an overflow connection which is connected to a collecting container of the rectification system. In the wall of the container there is an overflow which is attached to the calming section ( Fig. 6, 8, 17).

10. Integrated calming section, similar in design to the calming section ( Fig. 7).

Claims (65)

1. The invention relates to a method and the technical solution for carrying out the method, wherein the device described here characterizes an electrocatalytic neutralization system ( Fig. 1), which is composed of several chambers and among other things also several devices and / or apparatus are connected as auxiliary systems and / or for the purpose of performing the tasks described and / or specified by us below and for the purpose of catalytic disposal and / or decomposition and / or implementation and / or neutralization and / or cleavage of synthetically produced biological and / or chemical poisons which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels and before the first treatment chamber of the neutralization system ( FIG. 2) the volumes to be neutralized on the synthetically produced biological and / or chemical Poisons, fed are, which are stored in storage containers and transported on a conveyor and pushed into an expansion dosing chamber ( Fig. 2), the expansion dosing chamber should be equipped with a remote-controlled opening system for opening the storage container and the expansion dosing chamber with a connection to a safety container (in the a neutralization concentrate is available) and the poisons released in an expansion storage chamber are fed to the expansion dosing chamber and the poisonous substances diluted here are introduced into the mixing chamber ( FIG. 3) in the circuit of the neutralization system in the prescribed reaction dilution, the pH value also being Control - for the purpose of adjusting the pH value, by adding alkali and / or acids - should be made to the then pretreated solution of the filter system, which may be removed in the chamber ( FIG. 4) end particles should serve to supply (should there be no flocculation or particle formation during pH adjustment in the chamber ( Fig. 3), the solution prepared in this way can be used directly in the circuit of the working electrodes without using the filter system directly connected neutralization system ( Fig. 5) are supplied, which is connected to the lowest part of the neutralization chamber, a tube version being connected to the expansion chamber II ( Fig. 6) in the upper part of the neutralization system, the expansion chamber II being connected to a separate version a catalyst with lambda-like control ( Fig. 5 Fig. 12 and 13) of the removal of gaseous intermediates, such as. B. oxygen, hydrogen, hydrocarbons, nitrogen compounds etc., is used, the second pipe of the container to a regeneration system ( Fig. 14), for recycling, is performed, being in the walls of the first neutralization chamber ( Fig. 5) and in the regeneration system is a heating and / or cooling system, which is then integrated into the casing of the systems in the interior of the container, to ensure the temperature rise by heating and / or the temperature decrease by cooling during the process and by the one in the upper one Part of the container ( Fig. 5) built-in overflow of the calming section of the neutralization system is connected, similar to the calming section ( Fig. 7), the execution of the calming section ( Fig. 7) of the second neutralization chamber ( Fig. 6) is further described, wherein various plants z. B. filter system and / or dialysis system and / or flotation system and / or sedimentation system and / or systems for electrodialysis, systems for electroflotation and / or sludge filter press (can also be centrifugal filter systems) and / or systems for anaerobic fermentation of the resulting sludge from the sedimentation systems and Sludge filter presses of the auxiliary systems, which are intended to purify the gas obtained by anaerobic decomposition, can be switched on, whereby all systems of the calming section, through their outflows, can be connected to the main outflow of the calming section and / or can be led to a regeneration plant and / or the intermediate products formed should be returned to the settling section of the solution and / or emulsion and / or suspension and / or dispersion to be cleaned in the mixing tank in front of the filter system, which should be introduced between the settling section and the second neutralization chamber, hi he should adjust the pH value before introducing the filtrate into the catalyst part of the second stage of the neutralization system ( FIG. 6) to the working electrode ( FIG. 16), whereby between the working electrodes (cathode / anode / cathode) ( FIG. 16) a catalyst support must always be placed, the direction of flow in the second stage of the neutralization system must be from bottom to top, a heating and cooling system should be integrated in the jacket of the neutralization system and that the flow of the synthetically produced biological to be neutralized and / or chemical poisons must always behave from bottom to top, with a distribution system in the upper part of the neutralization chamber, for the purpose of dividing the individual reactants from the neutralization carried out in the individual secondary areas and for the recovery of raw materials and / or for the removal of pollutants from a catalyst part with lambda-like control or in the second calming section of the neutralization system, which, among other things, can also be connected to various systems (as already described in the case of the first calming section), with the sludge accumulating being fed to and removed from the incineration system connected to the drain circuit, with the contaminated part of the neutralizing solution is returned to the line of the first calming section before being introduced into the filter system, after which the pollutant-free solution can be returned to the supply network, the working electrodes of the first neutralization stage being fed to the current generator, the working electrodes of the second neutralization stage being passed to the current generator; the electrical auxiliary systems of the first calming section must be connected to the current transmitter, and the electrical auxiliary systems of the second calming section must be connected to the current transmitter, and each working stage has several measuring probes which, during operation, also have one or more current transmitters, a micro-power stage being integrated here, since at the electrodes used here can have a working contact area of a few µm ² or smaller) must be connected, which must serve the continuous monitoring of the reaction state in the neutralization of the synthetically produced biological and / or chemical poisons, with a multi-channel laboratory evaluation system, the The course of the neutralization in the individual stages of the neutralization process, through the process of "ION SPECTROSCOPY" must be shown and / or documented quantitatively and / or qualitatively. 2. The invention relates to a method and the technical solution for Implementation of the method, the device described here a features an electrocatalytic neutralization system consisting of several Chambers is composed and also among other things several devices and / or apparatuses are connected as auxiliary systems and / or for the purpose of carrying out those described below and / or predetermined tasks and / or in the catalytic removal and / or decomposition and / or conversion and / or neutralization synthetic manufactured biological and / or chemical poisons, which as aqueous and / or solvent-containing solutions and / or suspensions and / or Dispersions and / or emulsions and / or gels are present and after Claim 1 characterized in that the system described here for Recycling of chemical substances in the field of recovery Raw materials from the waters of the chemical industry as additional system and / or independent system is used for the purpose of returning the recycled Substances in the industrial production flow. 3. The invention relates to a method and the technical solution for Implementation of the method, the device described here a features an electrocatalytic neutralization system consisting of several Chambers is composed and also among other things several devices and / or apparatuses are connected as auxiliary systems and / or for the purpose of carrying out those described below and / or predetermined tasks and / or in the catalytic removal and / or decomposition and / or conversion and / or neutralization synthetic manufactured biological and / or chemical poisons, which as aqueous and / or solvent-containing solutions and / or suspensions and / or Dispersions and / or emulsions and / or gels are present and after Claim 1 characterized in that the system described here for Recovery of single / multiple radioactive metal elements, too of higher purity, as well as its metallic alloy (s) with non-metals from the old fuel rods transferred into the solutions and / or other radioactive materials due to acid and / or alkalis and / or organic solvents and / or that as organometallic salts are presented and these solutions in the system described by us  can be subjected to a galvanic separation process, the Question of the further treatment of the radioactive accruing in the processes Waste such as acids, alkalis etc. are not the subject of this claim is. 4. The invention relates to a method and the technical solution for carrying out the method, the device described here characterizing an electrocatalytic neutralization system which is composed of several chambers and which, inter alia, also a number of devices and / or apparatuses are connected as secondary systems and / or for the purpose of carrying out the tasks described and / or specified by us below and / or for the catalytic disposal and / or decomposition and / or conversion and / or neutralization and / or cleavage of synthetically produced biological and / or chemical poisons which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 3 characterized in that the neutralization system is composed of several chambers, the first treatment chamber of the neutralization system ( Fig. 1) , an expansion and dosing chamber must be upstream, into which the supplied volumes of the synthetically produced biological and / or chemical poisons (which are stored in storage containers of up to 2000 kg) are transported and pushed into the expansion dosing chamber by a conveyor device, only here the Opening of the container, in the absence of air and can be done by automatic systems and the outflow of the synthetically produced toxins is fed into the expansion dilution chamber by a pump system and in the mixing chamber, the work-related dilution and pH adjustment of the toxins supplied for neutralization takes place . 5. The invention relates to a method and the technical solution for Implementation of the method, the device described here a features an electrocatalytic neutralization system consisting of several Chambers is composed and also among other things several devices and / or apparatuses are connected as auxiliary systems and / or, for the purpose of carrying out those described below and / or predetermined tasks and in the catalytic disposal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claim 1 and 4, characterized in that the neutralization system must have a mixing chamber which u. a. the pH adjustment of the Neutralization of synthetically produced biological and / or chemical Poisons should serve, the solution being in the expansion chamber must be prediluted.   6. The invention relates to a method and the technical solution for carrying out the method, the device described here characterizing an electrocatalytic neutralization system which is composed of several chambers and which, among other things, also has several devices and / or apparatuses connected as auxiliary systems and / or for the purpose of carrying out the tasks described and / or specified by us below and for the catalytic disposal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 5, characterized in that the expansion chamber of the neutralization system ( Fig. 1) has a casing which through the expansion chamber in the event of damage to the inner walls egg ne accidental explosion of the storage or transport container in the inner neutralization chamber, connected by a separate line to a neutralization reservoir, which must allow the damaged systems to be quickly flooded by the existing neutralization solution. 7. The invention relates to a method and the technical solution for Implementation of the method, the device described here a characterizes electrocatalytic neutralization stage, which consists of several Chambers is composed and also among other things several devices and / or apparatuses are connected as auxiliary systems and for the purpose of performing the following and / or described by us given tasks and for the purpose of catalytic disposal and / or Decomposition and / or conversion and / or neutralization synthetic produced biological and / or chemical poisons, which as aqueous and / or solvent-based solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 6 characterized in that the working electrodes on one / more Power source (s) with integrated possibility of setting individual current and Time parameters that are necessary for the operation of the system are connected are. 8. The invention relates to a method and the technical solution for carrying out the method, the device described here characterizing an electrocatalytic neutralization system which is composed of several chambers and which, among other things, also has several devices and / or apparatuses connected as auxiliary systems and / or for the purpose of performing the tasks described and / or specified by us below and for the catalytic disposal and / or decomposition and / or conversion and / or cleavage and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels and according to claims 1 to 7, characterized in that the current generator (s) ( 39 ; 40 ; 41 ; 42; ), ( a) Current generator for generating direct and / or alternating and / or pulse current can be , which one or more controllable voltage stage (s) of up to 1 MV, but mainly of up to +180 - 0 - -180 V, one / more freely controllable current stage (s) of up to 100 A / cm ² , mainly of up to 25 A / cm ² (for a 1 dm ^{2 of} the working electrodes), one / several time steps, as well as a freely controllable signal generation for the used impulses of the working frequency from 0 Hz to 1 MHz, as well as a freely controllable time step of the pulses used by the freely adjustable signal generator is / are connected to this current generator (s), which, however, is then connected as an output stage (s) in the individual signal (X parameter) to the electrodes by its output /are. 9. The invention relates to a method, as well as the technical solution for performing the method, the device described here characterizing an electrocatalytic neutralization system which is composed of several chambers and which, among other things, also has several devices and / or apparatuses connected as auxiliary systems and / or for the purpose of performing the tasks described and / or specified by us below and for the purpose of catalytic disposal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 8, characterized in that in the electrocatalytic neutralization system ( Fig. 1) a stirring system, the better distribution of the solutions supplied for reaction by stirring de the same should (mainly in the reactor vessels) and where, among other things, an ultrasonic agitation can be carried out, which can serve to increase the reaction rate, should be present. 10. The invention relates to a method, as well as the technical solution for carrying out the method, wherein the device described here characterizes an electrocatalytic neutralization system, which is composed of several chambers and which, among other things, also several devices and / or apparatuses are connected as auxiliary systems and / or for the purpose of performing the tasks described and / or specified by us below and for the purpose of catalytic disposal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 9 characterized in that at the highest point of the ceiling and / or on the side-mounted tubular connection with a storage container (which also the overpressure valve a pump system can be connected upstream and which should serve for the removal of the gaseous substrates from the free space above the liquid level in the containers and / or chambers and for the liquefaction of the gaseous substrates, the removed gases being fed to further separation, whereby here the substrates intended for recycling are processed with the appropriate separation methods into industrially usable raw materials and the non-usable parts can and / or must be fed to the catalyst with lambda-like control, here the catalytic decomposition of the non-usable gaseous reactants up to carbon dioxide, Water and nitrogen can be reacted in order to prevent an undesired reaction between two / more compound (s) of the separated gases under the changed technical conditions inside the first neutralization chamber and inside de r second catalyst chamber and inside the collecting tank, as well as inside one or more connection system (s) of the calming section and inside the two neutralization chambers, as well as inside the calming section, with the aim of preventing the accumulation of gaseous intermediate products, so that even in one / several working chamber (s) of the neutralization system, at any point in the system ( FIG. 1), a pump system and / or compression chamber and / or comparable others, the formation of a gas mixture with a high explosion density having a preventive and / or preventive effect got to. 11. The invention relates to a method and the technical solution for carrying out the method, the device described here designating an electrolytic neutralization system which is composed of several chambers and which, among other things, also has several devices and / or apparatuses connected as auxiliary systems and / or for the purpose of performing the tasks described and / or specified by us below and for the purpose of catalytic disposal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 10, characterized in that the neutralization system ( Fig. 1) to the expansion tank, for the purpose of eliminating gaseous decomposition products that do not further regeneration below can be drawn, a post-combustion catalyst connected to the first neutralization chamber with lambda-like control is supplied. 12. The invention relates to a method and the technical solution for Implementation of the method, the device described here a  electrocatalytic neutralization system characterizes those of several Chambers is composed and also among other things several devices and / or apparatuses are connected as auxiliary systems and / or for the purpose of carrying out those described below and / or predetermined tasks and for the purpose of catalytic disposal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claim 1 to 11, characterized in that on the Expansion tank a regeneration system, for insulation and recycling of raw materials, must be connected. 13. The invention relates to a method and to the technical solution for carrying out the method, the device described here characterizing an electrocatalytic neutralization system which is composed of several chambers and which, among other things, also has several devices and / or apparatuses connected as secondary systems and / or for the purpose of performing the tasks described and / or specified by us below and for the purpose of catalytic disposal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 13 characterized in that in the casing of the first neutralization chamber ( Fig. 6) a heating and / or cooling system is integrated, which for Compliance with the optimal response or Working temperature from -70 ° C to 500 ° C is absolutely necessary and must be available. 14. The invention relates to a method and the technical solution for carrying out the method, the device described here characterizing an electrocatalytic neutralization system which is composed of several chambers and which, among other things, also has several devices and / or apparatuses connected as auxiliary systems and / or for the purpose of performing the tasks described and / or specified by us below and for the purpose of catalytic disposal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 13 characterized in that the first neutralization chamber ( Fig. 5) equipped with an overflow and connected with a pipe connection to the calming section and wherein the Be rest area must be sealed airtight. 15. The invention relates to a method and the technical solution for Implementation of the method, the device described here a features an electrocatalytic neutralization system consisting of several Chambers is composed and also among other things several devices and / or apparatuses are connected as auxiliary systems and / or for the purpose of carrying out those described below and / or predetermined tasks and for the purpose of catalytic disposal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 14, characterized in that the used Working electrodes, made of a non-soluble material, such as. B. metal, bimetal, Carbon etc. are made, the area ratio of the cathode to Anode at least 1: 1 max. 1:60, but mainly up to 1:10. 16. A method, as well as the technical solution for carrying out the method, the device described here characterizing an electrocatalytic neutralization system which is composed of several chambers and which, among other things, also has several devices and / or apparatuses connected as auxiliary systems and / or for the purpose Carrying out the tasks described and / or specified by us below and for the purpose of catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 15, characterized in that in one or more used working electrode pack (s) ( Fig. 5), in addition to the pack of non-soluble working electrodes (the number n <2 ), also one / more package (s) from soluble u nd non-soluble working electrodes (the number n <2) is / are, the material of the soluble electrodes being e.g. B. is copper and / or silver etc. and the material of the insoluble electrodes is metal, such as. As stainless steel, tungsten, platinum, titanium, gold, etc. and also the bimetals, such as. B. platinized titanium etc. and / or around carbon or glassy carbon etc. must be present in the elongated form of surface electrodes and the system ( FIG. 1) can be used for the purpose of neutralization and / or removal of biological and / or bacteriological materials got to. 17. A method, as well as the technical solution for carrying out the method, the device described here characterizing an electrocatalytic neutralization system which is composed of several chambers and which, among other things, also has several devices and / or apparatuses as auxiliary systems, for the purpose of carrying out the following described and / or specified tasks and in the catalytic removal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons which are in the form of aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 16, characterized in that the calming section consists of a sedimentation system, the system 1 ( Fig. 7) between the first electrolyte chamber ( Fig. 5) and the second electrolyte catalyst chamber ( Fig. 6 ) must perform their function u nd the calming section ( Fig. 7) is connected to the overflow of the electrolytic catalyst chamber ( Fig. 6)) and the existing calming sections ( Fig. 7) can also be connected to various auxiliary systems. 18. A method, as well as the technical solution for carrying out the method, which consists of an electrolytic neutralization system ( Fig. 1), the device described here characterizing an electrocatalytic neutralization system ( Fig. 1), which is composed of several chambers, the under In addition, several devices and / or apparatuses are also additionally connected and / or for the purpose of performing the tasks described and / or specified below and for the catalytic removal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons , which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels and according to claims 1 to 17, characterized in that the filter systems are switched on at the systems of the calming sections ( FIG. 7) and / or must be and / or can be connected en. 19. A method, as well as the technical solution for carrying out the method, which consists of an electrolytic neutralization system ( Fig. 1), the device described here identifying an electrocatalytic neutralization system ( Fig. 6), which is composed of several chambers, among others also several devices and / or apparatuses are additionally connected and / or for the purpose of performing the tasks described and / or specified below and for the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels, suspensions and / or dispersions and / or gels are present and according to claims 1 to 18, characterized in that for the purpose of raw material recovery, the calming stretch to the dialysis System and / or electrodialysis system and the calming section is connected and / or connected to the dialysis system and / or the electrodialysis system. 20. A method, as well as the technical solution for performing the method, which consists of an electrolytic neutralization system ( Fig. 1), the device described here identifying an electrocatalytic neutralization system ( Fig. 6), which is composed of several chambers and among others also several devices and / or apparatuses are additionally connected and / or for the purpose of performing the tasks described and / or specified below and for the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels and according to claims 1 to 19, characterized in that a flotation system and / or an electroflotation system are connected for the purpose of raw material recovery of the calming section can. 21. A method and the technical solution for carrying out the method, which consists of an electrolytic neutralization system ( Fig. 1), the device described here identifying an electrocatalytic neutralization system ( Fig. 1), which is composed of several chambers, among others also several devices and / or apparatuses are additionally connected and / or for the purpose of performing the tasks described and / or specified below and for the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels and according to claims 1 to 21, characterized in that one or more sludge filter press (s) are connected to the calming zones. 22. A method and the technical solution for carrying out the method, which consists of an electrolytic neutralization system ( Fig. 1), the device described here identifying an electrocatalytic neutralization system ( Fig. 6) which is composed of several chambers, among others also several devices and / or apparatuses are additionally connected and / or for the purpose of performing the tasks described and / or specified below and for the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels and according to claims 1 to 21, characterized in that the neutralization system is a system for the anaerobic treatment of the sludge resulting from the neutralization , for the purpose of biogas gas is connected. 23. A method, as well as the technical solution for carrying out the method, which consists of an electrolytic neutralization system ( Fig. 1), the device described here identifying an electrocatalytic neutralization system ( Fig. 6), which is composed of several chambers, among others also several devices and / or apparatuses are additionally connected and / or for the purpose of performing the tasks described and / or specified below and for the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels and according to claims 1 to 23, characterized in that the resulting sludges are fed to the connected incinerator for the purpose of pollutant removal and raw material extraction, w obe supplying the incinerator with energy e.g. B. is carried out by biogas of our own production and the excess energy from the electrocatalytic neutralization system described by us ( Fig. 1) is used for the production of electrical energy and is supplied to the supply network. 24. A method and the technical solution for carrying out the method, the device described here characterizing an electrocatalytic neutralization system ( FIG. 1) which is composed of several chambers and which, among other things, also connects several devices and / or apparatuses as auxiliary systems are and / or for the purpose of performing the tasks described and / or specified below and in the catalytic removal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 23, characterized in that the filtrates occurring during the auxiliary system operation of the calming section ( 14/1 ) are returned to the solvent circuit of the expansion chamber ( 4 ) . 25. A method, as well as the technical solution for carrying out the method, the device described here characterizing an electrocatalytic neutralization system ( FIG. 1) which is composed of several chambers and which, among other things, also connects several devices and / or apparatuses as auxiliary systems are and / or for the purpose of performing the tasks described and / or specified below and in the catalytic removal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 24, characterized in that the solution to be neutralized, which is taken from the overflow of the calming section, is fed to the mixing tank for further processes before being fed and before being introduced i n the filter system is subjected to a pH adjustment. 26. A method and the technical solution for carrying out the method, the device described here consisting of an electrocatalytic neutralization system ( FIG. 1), which is composed of several chambers and which, among other things, also has several devices and / or apparatuses switched on and / or for the purpose of performing the tasks described and / or specified below and in the catalytic removal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or Emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 25, characterized in that the outlet of the filter system is connected to the lowest part of the second electrocatalytic neutralization chamber. 27. A method, as well as the technical solution for carrying out the method, the device described here for this consisting of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers and which also has several devices and / or apparatus for the purpose of carrying out the of the tasks described and / or specified below and in the catalytic removal and / or decomposition and / or implementation and / or neutralization of synthetically produced biological and / or chemical poisons, which are aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 26, characterized in that the substance solutions and / or dispersion solutions to be neutralized are fed directly to the working electrodes, the working electrodes being made of non-soluble material, but predominantly made of stretched metal such as e.g. . B. stainless steel, titanium etc. and / or perforated glassy carbon are made. 28. A method and a device for this, which consists of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers and which also has several devices and / or apparatuses, for the purpose of carrying out the tasks described and / or specified and in the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels and according to claims 1 to 27, characterized in that between the working electrodes one or more existing ceramic carrier (s) which have been coated with a thin metal and / or metal oxide layer and / or metal / metal oxide mixture layer as catalyst, must be placed. 29. A method and a device for this purpose, which consists of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers and which also has several devices and / or apparatus, for the purpose of carrying out the tasks described and / or specified and in the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels and before the first treatment chamber of the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which are in the form of aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and thereby according to claims 1 to 28 Note that a heating and / or cooling system is integrated in the wall of the second neutralization system. 30. A method and a device for this, which consists of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers and which also has several devices and / or apparatus, for the purpose of carrying out the tasks described and / or specified below and in the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels and according to claims 1 to 29, characterized in that the electrocatalytic neutralization chamber has in its uppermost part a connection to the expansion chamber located here, to which an existing catalyst with lambda-like control (for the purpose of removing gaseous pollutants) and a plant for raw material recovery are connected. 31. A method and a device for this purpose, which consists of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers and which also has several devices and / or apparatus, for the purpose of carrying out the tasks described and / or specified and in the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels according to claims 1 to 30, characterized in that the overflow of the second electrolytic neutralization chamber is connected to the calming section. 32. A method and a device for this, which consists of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers and which also has several devices and / or apparatus for the purpose of performing the tasks described and / or specified and in the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels according to claims 1 to 31, characterized in that the current source used ( Fig. 9) of the second neutralization chamber is a multi-channel current source integrator JKB. 33. A method and a device for this, which consists of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers and which also has several devices and / or apparatus for the purpose of performing the tasks described and / or specified below and in the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels according to claims 1 to 32, characterized in that the current source used in the systems ( Fig. 9) have a freely controllable output stage, for the voltage range of -180 volts - 0 - +180 volts; for the current range from 0.000000001 - 10 A / cm ² , mainly in the range up to 0.25 A / cm ² ; Frequency range from 0 to 1 MHz, predominantly in the range of up to 200 KHz, whereby the freely selectable conversion of the individual operating mode to direct and / or alternating and / or pulse current and / or the freely selectable mixing type and / or current curve type of individual operating modes also with each other and / or with a freely adjustable way of selecting individual time parameters of up to 3600 min, as well as the type of current and voltage curve used (should also be possible with the setting - mixed operation). 34. A method and a device for this, which consists of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers and which also has several devices and / or apparatuses, for the purpose of carrying out the tasks described and / or specified below and in the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons, which are in the form of aqueous and / or solvent-containing solutions and / or emulsions and / or aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels are present and according to claims 1 to 33, characterized in that in the systems and in the current sources additional, freely controllable voltage output stages for direct and / or pulse current of up to 1 MV, and the freely adjustable time constant T1: T2 from 0.001 to 1000 sec for T1 and / or from 0.001 to 1000 sec are available for T2, whereby the electrode package ( FIG. 5) of the first stage of the neutralization system can have at least one / more soluble working electrode (s), which are predominantly made of metallic copper and / or silver and / or their alloy is / are manufactured in elongated sheet form, the soluble / insoluble working electrodes being made of metal material in elongated form, for the purpose of the method using the combination of soluble and insoluble electrodes, mainly in the area of destruction and / or decomposition and / or Neutralization in biological and / or bacteriological toxic materials is carried out. 35. A method and a device for this, which consists of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers and which also has several devices and / or apparatus for the purpose of performing the tasks described and / or specified below and in the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or suspensions and / or dispersions and / or gels according to Claims 1 to 34, characterized in that the residence time of the solution (s) led to the neutralization in the reaction chambers is from 1 min to 3600 min - predominantly from up to 30 min. 36. A method and a device for this, which consists of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers and which also has several devices and / or apparatus for the purpose of carrying out the tasks described and / or specified and in the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or dispersions and / or gels and according to claim 1 to 35 characterized in that the course of neutralization in all work areas of the plants for the disposal and / or neutralization and / or decomposition and / or implementation and / or recycling by the new measuring method of "ION SPECTROSCOPY", for the purpose of non-contact measurement value acquisition, the plant specially designed measuring probes, which is a combined measured value acquisition in egg nem aisle by simply moving the measuring cells to the measuring chamber, which are located between two / more electrodes and / or diaphragms and / or catalyst diaphragms and can thus simulate the course of a reaction, with simultaneous documentation of the individual processes in the cell and whereby the new cell can be integrated in any existing UV / VIS and / or IR spectrophotometer and only with a small deviation in the design of the cells and with the aid of fiber optic cables then also in industrial evaluation in daily operational practice such as B. the light scattering dependency of the recorded UV / VIS and / or IR spectra on the conductivity, current and / or voltage and / or frequency curves etc. can be used for the purpose of qualitative and quantitative control practical application. 37. The invention relates to a method and the technical solution for Implementation of the method, the device described here a features an electrocatalytic neutralization system consisting of several Chambers is composed and also among other things several devices and / or apparatuses are connected as auxiliary systems and / or for the purpose of carrying out those described below and / or predetermined tasks and / or in the catalytic removal and / or decomposition and / or conversion and / or neutralization synthetic manufactured biological and / or chemical poisons, which as aqueous and / or solvent-containing solutions and / or suspensions and / or Dispersions and / or emulsions and / or gels are present and after Claims 1 to 36 characterized in that the pH adjustment is set in the range from 1 to 13 for the purpose of initiating the reaction. 38. A method and a device for this, which consists of an electrolytic neutralization system ( Fig. 1), which is composed of several chambers - which also several devices and / or apparatus, for the purpose of performing the tasks described and / or specified and in the catalytic removal and / or decomposition and / or conversion and / or neutralization of synthetically produced biological and / or chemical poisons which are present as aqueous and / or solvent-containing solutions and / or emulsions and / or dispersions and / or gels according to claims 1 to 37 characterized in that the microcell used for the "ION SPECTROSCOPY", which can be regarded as a miniaturizing version of the neutralization system ( FIG. 1) of synthetically produced biological and / or chemical poisons, the individual parts of the microcell used here being made of glass and / or a glass-like material is made, which is a volume ina can already have from 1 µl, whereby auxiliary systems such as heating, cooling, stirring etc. (only applies to volumes over 25 µl) can be installed at one / more points of industrially usable systems for the purpose of recording measured values and the measuring devices in a UV / VIS and / or IR spectrophotometers were integrated and when supplying the working electrodes of the measuring cells a direct and / or alternating and / or pulse current from a conventional or a special current transmitter is used and the evaluation of several such measuring cells is made possible by simultaneous operation got to. 39. Apparatus according to claim 38, characterized in that the Micro measuring cell can be composed of several parts, wherein one / more diaphragms and / or between the individual intermediate stages can be a catalyst layer applied to the diaphragm and the functional volume of the measuring cell is greater than 1 microliter. 40. Apparatus according to claim 38 and 39, characterized in that the Contacts of the working electrodes of the measuring cell to a current source according to Dr. Knedla are connected, the power source being synchronous the stepper motor of the spectrophotometer owns and enables and through an additional facial expression of the measuring cell, the recording of spectra in the dependency on the specified setpoint of the current source on several Placement of the assembled measuring cell allowed. 41. A method according to claim 1 to 40, characterized in that the Device of electrocatalytic neutralization described here with a Temperature from -70 ° C to 500 ° C, but mainly at one temperature works from 20 ° C to 100 ° C. 42. A method according to claim 1 to 41, characterized in that the device described here ( Fig. 1) is used in the electrocatalytic conversion of synthetically produced biological poisons in the first stage of neutralization ( Fig. 5) and the working electrodes to be used from one soluble metal material (e.g. Cu, Ni etc.). 43. A method according to claims 1 to 42, characterized in that a radioactive material for chemical treatment is converted into a soluble state in the expansion chamber of the device ( Fig. 16) and subsequently this radioactive material is separated into metallic and non-metallic ions and then one Cleaning is done, e.g. B. by filtration and / or sedimentation and / or dialysis etc. and the electrolyte solution thus cleaned is passed into the electrolysis chamber and the radioactive suspended matter and / or sediments etc. obtained by the cleaning process can be subjected to aftertreatment and preparation for landfill and / or have to. 44. A method according to claim 1 to 43, characterized in that the Acid or alkalis and / or aqueous solutions and / or in organic Polyelectrolytes and / or in dielectrics and / or in their mixtures dissolved radioactive metallic materials only after cleaning be fed to the further process of electrolysis. 45. A method according to claims 1 to 44, characterized in that the radioactive substances in the solution are subjected to an electrochemical treatment and this using non-soluble working electrodes which are connected to a multi-channel AC and / or DC and / or pulse current source, these work according to the intended information ( Fig. 9 + 10). 46. A method according to claim 1 to 45, characterized in that the solution remaining after the electrolysis of a filtration and / or Undergoes regeneration and then again the cycle of Separation system as a solution and / or as a water-solvent mixture and / or is supplied as a solvent concentrate. 47. A method according to claim 1 to 46, characterized in that the electrochemically deposited metallic layers with radioactive Character after the discovery of radioactive data, which in advance determining application goal. 48. A method according to claim 1 to 47, characterized in that pure metallic radioactive material directly in the electrolytic chamber Anode material is used and the anodic and cathodic Rooms of the system are separated from each other by a diaphragm need and after the discovery of the radioactive data, which in advance determining application goal. 49. A method according to claim 1 to 48, characterized in that the radioactive metallic layer recovered during electrolysis is a pure one Single metal layer is and after the determination of the radioactive data, the application target to be determined in advance. 50. A method according to claim 1 to 49, characterized in that the radioactive metallic layer recovered in the electrolysis is a purely metallic alloy layer, the use of the multi-channel current source ( Fig. 9 + 10) according to Dr. Knedla in its capacity as a supply system for the working electrodes, which allows the crystalline structures to be obtained and / or their chemical composition to be calculated in advance. 51. A method according to claim 1 to 50, characterized in that the radioactive metallic layer recovered in the electrolysis is a so-called combination layer, such as. B. a glass-ceramic, metal-ceramic or ceramic-metallic layer, the application of the multi-channel current source ( FIG. 8) according to Dr. Knedla in its capacity as a supply system for the working electrodes, which allows the crystalline structures to be obtained and / or their chemical composition to be calculated in advance. 52. A method according to claim 1 to 51, characterized in that the power source used is a multi-channel power source ( Fig. 8) and all required work areas, such as. B. voltage, current, frequency, pulse, time constant etc. are freely adjustable. 53. A method according to claim 1 to 52, characterized in that the pre-cleaned and pre-treated electrolyte solution of radioactive substances electrolytically in an aqueous and / or solvent-containing form and / or as an emulsion and / or as a suspension and / or as a dispersion and / or as Gel and / or can be presented as a solid solution. 54. A method according to claim 1 to 53, characterized in that the electrolytic deposition of the radioactive metallic layer from a Electrolyte (e.g. a melt electrolyte) at a working temperature of up to 2000 ° C can take place. 55. A method according to claim 1 to 54, characterized in that the deposition of the radioactive metallic layer and / or a metallic alloy layer and / or a metal-ceramic layer and / or a ceramic-metallic layer takes place at a temperature of up to 100 ° C and at an effective cathodic current density of up to 100 A / cm ² , but predominantly at up to 0.1 A / cm ² in immersion baths and / or at up to 10 A / cm ² in the gap electrode ( Fig. 15 ) and / or in an immersion bath / gap-electrode combination process ( FIG. 16). 56. A method and the device according to claims 1 to 55, characterized characterized in that the system - since gases are produced during electrolysis - with must be equipped with an overpressure safety device and the system under pressure stands or has to stand so that the residual risk of a possible one Escape of gases is kept to an absolute minimum. 57. A method according to claim 1 to 56, characterized in that in the treatment of water contaminated with production residues in the chemical industry, a similar treatment principle as in the removal and / or implementation of synthetically produced biological and chemical poisons ( Fig. 1) is used. 58. A method according to claim 1 to 57, characterized in that the used catalysts in the form of pure metals, metal combination nations as well as metal oxides and / or their combinations with other pure Metals or metal mixtures and / or in the form of dust, colloid, etc. are presented for the purpose of expanding the effects on the surfaces of so-called Solid acids applied and / or in the crystalline structure of such Solid acids or their salts are incorporated, these Solid acids themselves can have a catalytic effect. 59. A method according to claim 1 to 58, characterized in that the catalyst carrier should or may have a cassette shape, wherein the carrier can have a self-supporting honeycomb shape or can be accommodated in a cassette, z. B. the ceramic support of the catalyst can have any geometric shape and the maximum thickness of the cassette ( Fig. 16 + 17 + 8) should be 50 mm, it being important that the spaces of the catalyst allow free passage of the solution thus treated guarantee. 60. A method according to claims 1 to 59, characterized in that each Part of the facility due to increased toxicity, insulated and corrosion resistant must be sealed airtight. 61. A method according to claims 1 to 60, characterized in that each Treatment chamber with separate discharges for security neutralization  concentrates must be equipped, these separate introductions in In the event of a malfunction, switch on automatically and the faulty one Chamber is flooded and another safety route is activated in the system becomes. 62. A method according to claim 1 to 61, characterized in that the used catalysts in the form of pure metals and / or Metal combinations and / or metal oxides and / or their combinations with one / more metal (s) or metal mixture (s) and / or in the form of Dust, colloids, etc. are presented on the surface of the carrier in a super-thin layer are present, the carrier itself being an acidic one Clay layer is and this clay layer itself has a catalytic effect can have. 63. A method according to claim 1 to 62, characterized in that the used catalysts, in the form of pure metals and / or Metal combinations and / or metal oxides and / or their combinations with one / more metal (s) or metal mixture (s) and / or in the form of Dust, colloids etc. are presented, being the carrier layer of the catalyst e.g. B. a so-called lanthanum-yttrium zeolite material is used and this material itself can have a catalytic effect. 64. A method according to claim 1 to 63, characterized in that the used catalysts in the form of pure metals and / or metal combinations nations and / or metal oxides and / or their combinations with one / more metal (s) or mixed metal (s) and / or in the form of Dust, colloids etc. are presented, being the carrier layer of the catalyst e.g. B. a microporous aluminum phosphate is used and wherein this material itself can have a catalytic effect. 65. A method according to claim 1 to 64, characterized in that the used catalysts in the form of pure metals and / or metal combinations nations and / or metal oxides and / or their combinations with one / more metal (s) or metal mixture (s) and / or in the form of Dust, colloids etc. are presented, being the carrier layer of the catalyst e.g. B. a silica-alumina gel is used and this material itself can have a catalytic effect.