DE4003765A1 - Protective material for wind and rain - in which elastic plastic membrane bonded to adsorbing particles and covered with fabric is impervious to water but permeable to water vapour - Google Patents

Protective material for wind and rain - in which elastic plastic membrane bonded to adsorbing particles and covered with fabric is impervious to water but permeable to water vapour

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Publication number
DE4003765A1
DE4003765A1 DE4003765A DE4003765A DE4003765A1 DE 4003765 A1 DE4003765 A1 DE 4003765A1 DE 4003765 A DE4003765 A DE 4003765A DE 4003765 A DE4003765 A DE 4003765A DE 4003765 A1 DE4003765 A1 DE 4003765A1
Authority
DE
Germany
Prior art keywords
water
material according
permeable
water vapor
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE4003765A
Other languages
German (de)
Inventor
Ernest De Dr Ruiter
Hasso Von Bluecher
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Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE4003765A priority Critical patent/DE4003765A1/en
Publication of DE4003765A1 publication Critical patent/DE4003765A1/en
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D5/00—Composition of materials for coverings or clothing affording protection against harmful chemical agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B01J20/28019—Spherical, ellipsoidal or cylindrical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28026—Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/02—Cellular or porous
    • B32B2305/026—Porous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/10—Fibres of continuous length
    • B32B2305/18—Fabrics, textiles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Business, Economics & Management (AREA)
  • Toxicology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Management (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

A material which is porous to water vapour but impervious to water consists of a substrate bonded to an elastic membrane which is water-proof but porous to water vapour and yet is free from pores; adsorbing particles are applied to bond to this membrane and they can be covered over with a textile material. Pref. material for the membrane is a masked isocyanate polymer which, after splitting off the masking gps., reacts with a polyamine. ADVANTAGE - For the prodn. of civilian or military protective clothing the prod. requires no coated spots for comfortable wear. The bonding in the product is a continuous barrier against liquids and hence provides excellent protection against wind and rain.

Description

Die DE 33 04 349 A1 beschreibt ein luftdurchlässiges Schutzmate­ rial, welches insbesondere als Filterschicht für Schutzanzüge gegen chemische Gifte gedacht ist und sowohl militärische als auch zivile Anwendungen kennt. Die DE 37 16 303 A1 beschreibt ein Schuhinnenmaterial, welches den Träger gegen durch das Leder ein­ dringende chemische Gifte schützen soll. In beiden Fällen wird von einer besonders abriebfesten kugelförmigen Aktivkohle Ge­ brauch gemacht, welche mit Hilfe einer diskontinuierlich aufgetra­ genen Haftmasse auf dem Trägermaterial zum Haften gebracht wird. Besonders gut haben sich als Haftmasse die High Solids® der Bayer AG bewährt. Das sind präpolymere Systeme, welche erst ab ca. 130°C in den eigentlichen Kunststoff (ein Pulyurethan) umgesetzt werden, vorher aber ein ausgeprägtes, zur Erzielung einer hohen Haftung sehr günstiges Viskositätsminimum durchlaufen.DE 33 04 349 A1 describes an air-permeable protective mat rial, which in particular as a filter layer for protective suits is intended against chemical poisons and both military and also knows civil applications. DE 37 16 303 A1 describes a Shoe inner material, which the wearer against through the leather to protect urgent chemical poisons. In both cases from a particularly abrasion-resistant spherical activated carbon Ge made need, which with the help of a discontinuously applied gene adhesive mass is adhered to the carrier material. The High Solids® from Bayer have proven particularly good as adhesive AG proven. These are prepolymer systems, which only 130 ° C in the actual plastic (a Pulyurethan) implemented become, but previously a pronounced, to achieve a high Adhesion go through a very favorable viscosity minimum.

Es wurde inzwischen gefunden, daß durch Einbau hydrophiler Segmen­ te in das präpolymere Isocyanat mit den erwähnten High Solids Mem­ branen hoher Wasserdampfdurchlässigkeit erzeugt werden können, so daß ein punktförmiger Auftrag nicht mehr nötig ist, um einen gu­ ten Tragekomfort zu gewährleisten. Eine kontinuierlich aufgetrage­ ne Haftschicht hat aber noch eine ganze Reihe von Vorteilen: Bei dem erwähnten Material für Schutzanzüge bildet die nicht mehr un­ terbrochene Haftschicht eine Sperre gegen Flüssigkeiten, die, wenn sie bis zur Aktivkohle durchdringen, diese oft überfordern. Gleichzeitig bildet die Haftschicht einen ausgezeichneten Regen­ schutz bzw. Windschutz. Bei den üblichen textilen Trägern kann das Eindringen der Haftmasse in das Gewebe zu einer gewissen Ver­ steifung führen, die bei Anwendungen für Schutzbekleidung uner­ wünscht ist. Dem kann abgeholfen werden, indem man die Haftmasse auf Umkehrpapier aufträgt, anschließend mit Adsorbern in Über­ schuß bestreut, den Überschuß entfernt und schlußendlich ver­ netzt. Man erhält so eine wasserdampfdurchlässige, wasserdichte Membran, auf der die Adsorberteilchen haften. Diese Membran kann anschließend punktförmig mit einem Textil verbunden werden.It has now been found that by incorporating hydrophilic segments te in the prepolymer isocyanate with the mentioned High Solids Mem branches of high water vapor permeability can be generated, so that a punctual order is no longer necessary to complete a gu to ensure comfort. A continuously applied ne adhesive layer has a number of advantages: the material mentioned for protective suits is no longer un broken adhesive layer a barrier to liquids that, if they penetrate to the activated carbon, often overwhelm them. At the same time, the adhesive layer forms an excellent rain protection or wind protection. The usual textile carriers can the penetration of the adhesive into the tissue to a certain extent  lead stiffness, which is essential in applications for protective clothing wishes. This can be remedied by using the adhesive on reverse paper, then with adsorbers in over sprinkled shot, the excess removed and finally ver nets. A water-vapor-permeable, watertight is thus obtained Membrane on which the adsorber particles adhere. This membrane can then be connected to a textile in a punctiform manner.

Schließlich ist es vorteilhaft, die Adsorberschicht mit einem leichten Textil abzudecken.Finally, it is advantageous to use an adsorbent layer cover light textile.

Beim Schuhinnenmaterial wird mit der eine geschlossene Schicht bildenden Haftmasse ein sehr guter Nässeschutz erzielt.The inner material of the shoe is a closed layer very good moisture protection.

Claims (7)

1. Wasserdampfdurchlässiges, wasserdichtes Material, bestehend aus einem Trägermaterial, einer damit verbundenen elasti­ schen, wasserdichten, jedoch wasserdampfdurchlässigen, keine Poren aufweisenden Membran, an der Adsorberteilchen zum Haf­ ten gebracht sind, die ihrerseits durch ein leichtes Textil­ material abgedeckt sein können.1. Water vapor permeable, waterproof material, consisting of from a carrier material, an associated elasti waterproof, but permeable to water vapor, none Pore-containing membrane, on the adsorber particles to the harbor ten, which in turn are made of a light textile material can be covered. 2. Material nach Anspruch 1, dadurch gekennzeichnet, daß das Trägermaterial ein Textil ist.2. Material according to claim 1, characterized in that the Carrier material is a textile. 3. Material nach Anspruch 1 und/oder 2, dadurch gekennzeichnet, daß die Haftschicht auf den Träger aufgetragen wird und vor dem Aushärten der Haftschicht die Adsorber aufgestreut wer­ den.3. Material according to claim 1 and / or 2, characterized in that that the adhesive layer is applied to the carrier and before the hardening of the adhesive layer sprinkled on the adsorbers the. 4. Material nach Anspruch 1 und/oder 2, dadurch gekennzeichnet, daß die Haftschicht auf Umkehrpapier hergestellt wird, vor dem Aushärten mit Adsorbern beaufschlagt wird und nach dem Aushärten auf einem Träger punktförmig aufkaschiert wird.4. Material according to claim 1 and / or 2, characterized in that the adhesive layer is made on reverse paper the curing with adsorbers is applied and after the Curing is laminated onto a carrier in a punctiform manner. 5. Material nach einem oder mehreren der vorhergehenden Ansprü­ che, dadurch gekennzeichnet, daß die wasserdampfdurchlässige Membran aus einem präpolymeren Material, insbesondere einem polymeren, maskierten Isocyanat, welches nach Abspalten der maskierenden Gruppen mit einem Polyamin reagiert, gefertigt ist, wobei ausreichend hydrophile Segmente vorhanden sind, um die Wasserdampfdurchlässigkeit zu gewährleisten. 5. Material according to one or more of the preceding claims che, characterized in that the water vapor permeable Membrane made of a prepolymer material, in particular a polymeric, masked isocyanate, which after splitting off the masking groups reacted with a polyamine, manufactured with sufficient hydrophilic segments to to ensure water vapor permeability.   6. Material nach einem oder mehreren der vorhergehenden Ansprü­ che, dadurch gekennzeichnet, daß die Adsorber Aktivkohle sind.6. Material according to one or more of the preceding claims che, characterized in that the adsorber activated carbon are. 7. Material nach einem oder mehreren der vorhergehenden Ansprü­ che, dadurch gekennzeichnet, daß die Adsorber Aktivkohlekügel­ chen mit hoher Festigkeit und Abriebfestigkeit sind und einen mittleren Durchmesser von 0,1-1,0 mm, insbesondere 0,2-0,7 mm, und eine innere Oberfläche von 600-1800 m2/g, insbe­ sondere 800-1500 m2/g, besitzen.7. Material according to one or more of the preceding claims, characterized in that the adsorber activated carbon spheres are of high strength and abrasion resistance and have an average diameter of 0.1-1.0 mm, in particular 0.2-0.7 mm, and have an internal surface area of 600-1800 m 2 / g, in particular 800-1500 m 2 / g.
DE4003765A 1990-02-08 1990-02-08 Protective material for wind and rain - in which elastic plastic membrane bonded to adsorbing particles and covered with fabric is impervious to water but permeable to water vapour Withdrawn DE4003765A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE4003765A DE4003765A1 (en) 1990-02-08 1990-02-08 Protective material for wind and rain - in which elastic plastic membrane bonded to adsorbing particles and covered with fabric is impervious to water but permeable to water vapour

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4003765A DE4003765A1 (en) 1990-02-08 1990-02-08 Protective material for wind and rain - in which elastic plastic membrane bonded to adsorbing particles and covered with fabric is impervious to water but permeable to water vapour

Publications (1)

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DE4003765A1 true DE4003765A1 (en) 1991-08-14

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DE4003765A Withdrawn DE4003765A1 (en) 1990-02-08 1990-02-08 Protective material for wind and rain - in which elastic plastic membrane bonded to adsorbing particles and covered with fabric is impervious to water but permeable to water vapour

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0783016A2 (en) 1996-01-02 1997-07-09 Akzo Nobel N.V. Polyetherester membrane pigmented with carbon particles, water vapour-permeable and waterproof
WO2004020089A2 (en) * 2002-08-29 2004-03-11 BLüCHER GMBH Adsorbing material and use thereof
DE10240548A1 (en) * 2002-08-29 2004-03-18 BLüCHER GMBH Adsorbent material, for atomic/biological/chemical protective clothing, is in a lightweight multi-layer structure with carrier and barrier and adsorbent layers which allow the escape of perspiration
WO2005049147A1 (en) 2003-10-22 2005-06-02 BLüCHER GMBH Protective clothing providing abc protection
DE19842274B4 (en) * 1998-09-16 2006-11-09 BLüCHER GMBH Laminated, water and airtight water vapor permeable composite material
US8069496B2 (en) 1991-11-25 2011-12-06 Als Enterprises, Inc. Odor absorbing article of clothing
US9522207B1 (en) 2011-12-01 2016-12-20 Scentlok Technologies, Inc. Systems and methods for controlling odor
US9579626B1 (en) 2011-12-01 2017-02-28 Scentlok Technologies, Inc. Systems and methods for controlling odor

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3010061A1 (en) * 1979-07-20 1981-01-22 Hiraoka & Co Ltd WATERPROOF FILM
DE8201316U1 (en) * 1982-01-21 1982-10-07 Chemische Fabrik Stockhausen GmbH, 4150 Krefeld TRAIN SHAPED HYDROPHOBIC FILM
DE3210070A1 (en) * 1981-03-20 1982-11-18 Toyo Boseki K.K., Osaka PROTECTIVE MATERIAL
DE3304349A1 (en) * 1983-02-09 1984-08-09 Hasso von 4000 Düsseldorf Blücher AREA FILTER
DE3716303A1 (en) * 1987-05-15 1988-11-24 Bluecher Hubert FOOTWEAR MATERIAL WITH ADSORBING PROPERTIES
DE3813563A1 (en) * 1988-04-22 1989-11-02 Hasso Von Bluecher Adsorption filter with high air permeability
DE3815720A1 (en) * 1988-05-07 1989-11-16 Hasso Von Bluecher Material which is permeable to water vapour but impermeable to liquid water and its manufacture

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3010061A1 (en) * 1979-07-20 1981-01-22 Hiraoka & Co Ltd WATERPROOF FILM
DE3210070A1 (en) * 1981-03-20 1982-11-18 Toyo Boseki K.K., Osaka PROTECTIVE MATERIAL
DE8201316U1 (en) * 1982-01-21 1982-10-07 Chemische Fabrik Stockhausen GmbH, 4150 Krefeld TRAIN SHAPED HYDROPHOBIC FILM
DE3304349A1 (en) * 1983-02-09 1984-08-09 Hasso von 4000 Düsseldorf Blücher AREA FILTER
DE3716303A1 (en) * 1987-05-15 1988-11-24 Bluecher Hubert FOOTWEAR MATERIAL WITH ADSORBING PROPERTIES
DE3813563A1 (en) * 1988-04-22 1989-11-02 Hasso Von Bluecher Adsorption filter with high air permeability
DE3815720A1 (en) * 1988-05-07 1989-11-16 Hasso Von Bluecher Material which is permeable to water vapour but impermeable to liquid water and its manufacture

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DE-B.: Ullmanns Encyklopädie der technischen Chemie, Keramische Farben bis Kork, Verlag Chemie,Weinheim, New York, 1977, 4.Aufl., Bd.14, S.626-628 *
DE-Z: MARXMEIER, H.: Wetterschutzbekleidung mit einer waserdamfdurchlässigen Membran. In: Kunststoffe 78, H.6, 1988, S.530-534 *

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8069496B2 (en) 1991-11-25 2011-12-06 Als Enterprises, Inc. Odor absorbing article of clothing
EP0783016A2 (en) 1996-01-02 1997-07-09 Akzo Nobel N.V. Polyetherester membrane pigmented with carbon particles, water vapour-permeable and waterproof
US5859083A (en) * 1996-01-02 1999-01-12 Akzo Nobel Nv Water vapor permeable and waterproof polyester membrane pigmented with carbon particles
US6028019A (en) * 1996-01-02 2000-02-22 Akzo Nobel, Nv Water vapor permeable and waterproof polyester membrane pigmented with carbon particles
DE19842274B4 (en) * 1998-09-16 2006-11-09 BLüCHER GMBH Laminated, water and airtight water vapor permeable composite material
DE10240548C5 (en) * 2002-08-29 2011-06-16 BLüCHER GMBH Adsorption material, process for its preparation and its use
WO2004020089A3 (en) * 2002-08-29 2004-06-03 Bluecher Gmbh Adsorbing material and use thereof
DE10240548B4 (en) * 2002-08-29 2005-07-28 BLüCHER GMBH Adsorption material, process for its preparation and its use
DE10240548A1 (en) * 2002-08-29 2004-03-18 BLüCHER GMBH Adsorbent material, for atomic/biological/chemical protective clothing, is in a lightweight multi-layer structure with carrier and barrier and adsorbent layers which allow the escape of perspiration
US7410693B2 (en) 2002-08-29 2008-08-12 Blucher Gmbh Adsorbing material and use thereof
WO2004020089A2 (en) * 2002-08-29 2004-03-11 BLüCHER GMBH Adsorbing material and use thereof
WO2005049147A1 (en) 2003-10-22 2005-06-02 BLüCHER GMBH Protective clothing providing abc protection
US7465490B2 (en) 2003-10-22 2008-12-16 Blucher Gmbh Protective clothing providing nbc protection
US10034505B1 (en) 2011-12-01 2018-07-31 Scentlok Technologies, Inc. Systems for controlling odor
US9579626B1 (en) 2011-12-01 2017-02-28 Scentlok Technologies, Inc. Systems and methods for controlling odor
US9522207B1 (en) 2011-12-01 2016-12-20 Scentlok Technologies, Inc. Systems and methods for controlling odor
US10034506B1 (en) 2011-12-01 2018-07-31 Scentlok Technologies, Inc. Systems for controlling odor
US10624401B1 (en) 2011-12-01 2020-04-21 Scentlok Technologies, Inc. Systems for controlling odor
US11452318B2 (en) 2011-12-01 2022-09-27 Scentlok Technologies, Inc. Systems for controlling odor

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