DE3823157A1 - Process for producing a beflocked sheet material by means of high-energy rays starting from low molecular weight polymerisable compounds - Google Patents
Process for producing a beflocked sheet material by means of high-energy rays starting from low molecular weight polymerisable compoundsInfo
- Publication number
- DE3823157A1 DE3823157A1 DE19883823157 DE3823157A DE3823157A1 DE 3823157 A1 DE3823157 A1 DE 3823157A1 DE 19883823157 DE19883823157 DE 19883823157 DE 3823157 A DE3823157 A DE 3823157A DE 3823157 A1 DE3823157 A1 DE 3823157A1
- Authority
- DE
- Germany
- Prior art keywords
- monomer
- layer
- beflocked
- flocked
- flock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H11/00—Non-woven pile fabrics
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45C—PURSES; LUGGAGE; HAND CARRIED BAGS
- A45C5/00—Rigid or semi-rigid luggage
- A45C5/02—Materials therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/16—Flocking otherwise than by spraying
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
- B05D3/065—After-treatment
- B05D3/067—Curing or cross-linking the coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/10—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation for articles of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/24—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length
- B29C41/28—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length by depositing flowable material on an endless belt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
- B29C70/12—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of short length, e.g. in the form of a mat
- B29C70/14—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of short length, e.g. in the form of a mat oriented
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C19/00—Tyre parts or constructions not otherwise provided for
- B60C19/002—Noise damping elements provided in the tyre structure or attached thereto, e.g. in the tyre interior
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
- B05D1/06—Applying particulate materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2252/00—Sheets
- B05D2252/02—Sheets of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0002—Condition, form or state of moulded material or of the material to be shaped monomers or prepolymers
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Plasma & Fusion (AREA)
- Thermal Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Composite Materials (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Die Erfindung bezieht sich auf ein Verfahren zur Herstellung eines beflockten Flächengebildes, wobei abweichend von den bisher bekannten Methoden von einem niedermolekularen Trä germaterial ausgegangen wird, das erst nach der Beflockung ohne thermische Behandlung zu einem filmbildenden Substrat polymerisiert wird.The invention relates to a method of manufacture of a flocked fabric, deviating from the previously known methods of a low molecular weight Germ material is assumed that only after the flocking without thermal treatment to a film-forming substrate is polymerized.
Die übliche Beflockung wird in der Weise durchgeführt, daß ein textiles Substrat mit einem hochmolekularen Kleber in Form einer wäßrigen Dispersion oder einer organischen Lösung beschichtet, anschließend elektrostatisch beflockt und dann die Kleberschicht durch eine Hitzebehandlung getrocknet wird. Danach wird durch eine zweite thermische Behandlung die Flockfaser im Kleber verankert. Die Kurzfasern werden also mit Hilfe eines hochmolekularen Klebers auf dem Textil material fixiert. Diese Verfahrensweise ist in der DE-PS 10 81 857 beschrieben.The usual flocking is carried out in such a way that a textile substrate with a high molecular adhesive Form of an aqueous dispersion or an organic solution coated, then electrostatically flocked and then the adhesive layer is dried by heat treatment becomes. After that, a second thermal treatment the flock fiber anchored in the adhesive. The short fibers are with the help of a high molecular adhesive on the textile material fixed. This procedure is in DE-PS 10 81 857.
Eine Weiterentwicklung der Flocktechnik wurde dadurch er reicht, daß wie in der DE-PS 34 14 505 beschrieben, kein textiles Substrat zur Herstellung beflockter Flächengebilde mehr nötig ist. Nach diesem Verfahren wird ein hochmolekula rer Kleber in Form wäßriger Dispersionen oder in Form von Lösungen in organischen Lösungsmitteln auf einen Zwischen träger aufgebracht, elektrostatisch beflockt, getrocknet um das Wasser oder das Lösungsmittel zu verdampfen und in einem weiteren Hitzeprozess die Fasern im Kleber fixiert. An schließend wird das beflockte Material vom Zwischenträger abgezogen.He became a further development of flock technology is enough that as described in DE-PS 34 14 505, no textile substrate for the production of flocked fabrics more is needed. After this procedure, a high molecular weight adhesive in the form of aqueous dispersions or in the form of Solutions in organic solvents on an intermediate applied, electrostatically flocked, dried around to evaporate the water or solvent and in one further heat process the fibers are fixed in the adhesive. On the flocked material then closes from the intermediate carrier deducted.
Eine weitere Vereinfachung und Rationalisierung wurde nun erfindungsgemäß dadurch erreicht, daß als Substrat für die Flockfasern keine hochmolekularen Substanzen sondern nieder molekulare flüssige Verbindungen eingesetzt werden, die dann erst nach dem Beflocken zu einem Polymerfilm auspolymeri siert werden. Die Polymerisation erfolgt bei Raumtemperatur entweder durch Bestrahlen mit Elektronenstrahlen oder mit UV-Licht. Als Trägermaterial wird eine Warenbahn verwendet von der sich das beflockte Flächengebilde leicht trennen läßt, z. B. ein silikonisiertes Papier oder ein Teflonband. Als Trägermaterial kann auch eine PP-, PVC-, PES- oder PA-Folie verwendet werden.A further simplification and rationalization has now been made achieved according to the invention in that as a substrate for the Flock fibers are not low molecular weight substances but low molecular liquid compounds are used, which then auspolymeri only after flocking to a polymer film be settled. The polymerization takes place at room temperature either by irradiation with electron beams or with UV light. A web is used as the carrier material from which the flocked fabric easily separates lets, e.g. B. a siliconized paper or a Teflon tape. A PP, PVC, PES or PA film can also be used as the carrier material be used.
Um die Trennung der Flockschicht vom Substrat zu erleich tern, kann das Substrat mit einem Schmelzkleber beschichtet werden. Die Flockschicht kann dann in der Wärme vom Substrat abgezogen werden.To facilitate the separation of the flock layer from the substrate tern, the substrate can be coated with a hot melt adhesive will. The flock layer can then heat away from the substrate subtracted from.
In manchen Fällen bildet das Monomere auf dem silikonisier ten Papier keine zusammenhängende Flüssigkeitsschicht. Es tritt Inselbildung ein. Um dies zu vermeiden kann das sili konisierte Papier mit einer geeigneten Polymerschicht, z. B. Ethylcellulose oder Polyvinylbutyral beschichtet werden. Auf diese Schicht kann dann das Monomere gleichmäßig aufgetragen werden. Nach der Bestrahlung und Polymerisation läßt sich die Flockbahn leicht vom silikonisierten Papier abziehen.In some cases the monomer forms on the siliconizer paper has no continuous layer of liquid. It island formation occurs. To avoid this, the sili butted paper with a suitable polymer layer, e.g. B. Ethyl cellulose or polyvinyl butyral can be coated. On this layer can then apply the monomer evenly will. After irradiation and polymerization, pull the flock sheet slightly off the siliconized paper.
Das Aufbringen der Monomerschicht auf das Trägermaterial kann mit einer Rakel, einem Rollstab oder mit einer Auf tragswalze erfolgen. Die bei der Polymerisation nicht fi xierten Fasern können durch eine Absaugvorrichtung entfernt werden (siehe beiliegende Zeichnung). Die aufgebrachte Mono merschicht kann eine Dicke von 10-300 µm vorzugsweise von 50-150 µm aufweisen. Bei Verwendung von aufgeschäumten Monomeren kann die Schichtdicke bis zu 1000 µm betragen.The application of the monomer layer to the carrier material can with a squeegee, a roller bar or with an on support roller. The fi not in the polymerization Fixed fibers can be removed by a suction device (see attached drawing). The angry mono The layer can have a thickness of 10-300 μm, preferably of Have 50-150 microns. When using foamed Monomers can have a layer thickness of up to 1000 µm.
Der Vorteil des neuen Verfahrens besteht u. a. darin, daß für die Fixierung der Flockfasern keine Hitzebehandlung erforderlich ist und kein Wasser bzw. kein organisches Lö sungsmittel verdampft werden muß. Es handelt sich um ein neues energiesparendes und schadstoffarmes Verfahren zur Herstellung beflockter Flächengebilde. Die Energieeinsparun gen gegenüber den bisherigen Verfahren betragen bis zu 50%.The advantage of the new method is u. a. in that no heat treatment for fixing the flock fibers is required and no water or organic sol must be evaporated. It's about a new energy-saving and low-pollutant process for Manufacture of flocked fabrics. The energy saving conditions compared to previous methods are up to 50%.
Es war überraschend, daß trotz der Abdeckung der Monomer schicht durch die Flockfasern bei der Bestrahlung mit Elek tronenstrahlen oder UV-Strahlen eine vollkommene Durch härtung der Monomerschicht erreicht wird. Bei Verwendung von Geweben findet auf der Rückseite des Gewebes keine vollstän dige Aushärtung des Monomeren statt. Die Elektronenstrahlen bzw. UV-Strahlen werden von einem Gewebe offenbar viel stär ker absorbiert als von der Flockschicht.It was surprising that despite the coverage of the monomer layer through the flock fibers when irradiated with elec Tronen rays or UV rays a perfect passage curing of the monomer layer is achieved. When using There is no complete fabric on the back of the fabric curing of the monomer instead. The electron beams or UV rays are obviously much stronger from a tissue ker absorbed than by the flock layer.
Durch Verwendung von Monomeren anstelle von Polymeren Kle bern wird eine besonders stabile Verankerung der Flockfasern im entstandenen Polymerfilm erzielt. Das flüssige Monomer umhüllt die Flockfasern in optimaler Weise und das entste hende Polymer kann sich beim Kettenwachstum präzise an die Oberflächenstruktur der Fasern anpassen.By using monomers instead of polymers Kle A particularly stable anchoring of the flock fibers is also used achieved in the resulting polymer film. The liquid monomer wraps the flock fibers in an optimal way and the worst polymer can precisely follow the chain growth Adjust the surface structure of the fibers.
Bei der bisherigen Herstellung von beflockten Flächengebil den wird durch die Bildung von Dampfblasen beim Trocknen der wasser- oder lösungsmittelhaltigen Kleberschicht kein opti maler Kontakt zwischen Fasermaterial und Substrat erreicht.In the previous production of flocked surface structures is caused by the formation of vapor bubbles when drying the water- or solvent-based adhesive layer no opti Painterly contact between the fiber material and the substrate is achieved.
Das beflockte Flächengebilde kann auf der Rückseite mit einer Kleberschicht versehen und auf ein Dehäsivpapier auf gebracht werden. Auf diese Weise kann das Flockmaterial wie Haftetiketten oder DC-Fix-Folien auf jede Unterlage übertra gen werden.The flocked fabric can on the back with an adhesive layer and on a adhesive paper to be brought. This way the flock material can be like Transfer self-adhesive labels or DC-Fix foils to every surface be.
Das beflockte Flächengebilde kann auch schon bei der Her stellung auf der Rückseite mit einer Kleberschicht versehen werden in der Weise, daß ein geeignetes Monomer verwendet wird, das bei der Bestrahlung nicht voll durchpolymerisiert, so daß die Rückseite klebrig bleibt. Eine andere Möglichkeit besteht darin, daß man das Trägerpapier mit einer Kleber schicht versieht, dann das Monomere aufträgt und anschlie ßend die Beflockung und Polymerisation durchführt. Man er hält so das beflockte Material direkt als Abziehfolie auf dem Dehäsivpapier.The flocked fabric can also be used in the manufacture position on the back with an adhesive layer are used in such a way that a suitable monomer is not fully polymerized during the irradiation, so the back stays sticky. Another possibility consists in that the backing paper with an adhesive layer, then applies the monomer and then eats the flocking and polymerization. Man he thus holds the flocked material directly as a peel-off film the adhesive paper.
Die erfindungsgemäß hergestellten beflockten Flächengebilde haben Samt- bzw. Velour-Charakter und können für dekorative Zwecke eingesetzt werden, z. B. zum Auskleiden und Bekleben von Schmuck- und Geschirrbehältnissen von Koffern, Taschen u. a. Weiterhin kann das Material zur Innenausstattung von Kraftfahrzeugen, als Ersatz für Textiltapeten und als schallisolierendes Material verwendet werden.The flocked fabrics manufactured according to the invention have a velvet or velor character and can be used for decorative purposes Purposes are used, e.g. B. for lining and pasting of jewelry and crockery containers, suitcases, bags u. a. Furthermore, the material for the interior of Motor vehicles, as a replacement for textile wallpapers and as soundproofing material can be used.
Ein Urethanacrylat, wie z. B. Ebecryl 284, wird mit einem Coatingstab auf ein silikonisiertes Papier aufgebracht, so daß eine Schichtdicke von ca. 50 µm entsteht und anschlie ßend in bekannter Weise mit Polyamidkurzfasern von 0,5-3 mm beflockt. Danach wird das beflockte Material im Elektro nenbeschleuniger mit 40 KGy bei einer Spannung von 180 KV bestrahlt. In Bruchteilen von Sekunden härtet das Monomere aus. Der entstandene Flockfilm kann sehr leicht vom siliko nisierten Papier abgezogen werden.A urethane acrylate, such as. B. Ebecryl 284, with a Coating stick applied to a siliconized paper, see above that a layer thickness of approx. 50 µm arises and then ßend in a known manner with short polyamide fibers of 0.5-3 mm flocked. Then the flocked material is in the electro accelerator with 40 KGy at a voltage of 180 KV irradiated. The monomer hardens in a fraction of a second out. The resulting flock film can easily be removed from the silicone peeled paper.
Ein Silikonacrylat, z. B. Silikonfinish SLM, wird mit Hilfe einer Gummituchrakel mit einer Schichtdicke von 50-100 µm auf ein Teflonband aufgetragen, anschließend in bekannter Weise mit Polyamidkurzfasern von 0,5-3 mm Länge beflockt. Die Bestrahlung erfolgt mit einer Dosis von 60 KGy und einer Spannung von 180 KV. Der entstandene flexible Flockfilm läßt sich leicht vom Teflonband trennen. A silicone acrylate, e.g. B. Silicon finish SLM, is with the help a rubber squeegee with a layer thickness of 50-100 µm applied to a Teflon tape, then in a known one Flocked with short polyamide fibers 0.5-3 mm long. The radiation is carried out with a dose of 60 KGy and one Voltage of 180 KV. The resulting flexible flock film leaves easily separate from the teflon tape.
Ein silikonisiertes Trägerpapier wird mit einem Esteracry lat, z. B. Polytron 309, das 5% Benzophenon und 5% Hy droxyethylmorpholin als Photoinitiator enthält, mit einer Schichtdicke von 50-100 µm beschichtet und dann mit einer Quecksilberdampflampe (80 W/cm) bei einer Warengeschwindig keit von 5 m/min bestrahlt. Das Monomere härtet vollständig aus und das beflockte Flächengebilde kann leicht vom Papier getrennt werden.A siliconized backing paper is made with an Esteracry lat, e.g. B. Polytron 309, the 5% benzophenone and 5% Hy contains droxyethylmorpholine as a photoinitiator, with a Layer thickness of 50-100 microns coated and then with a Mercury vapor lamp (80 W / cm) at a speed of goods irradiated at 5 m / min. The monomer cures completely and the flocked fabric can easily be removed from the paper be separated.
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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DE19883823157 DE3823157A1 (en) | 1988-07-08 | 1988-07-08 | Process for producing a beflocked sheet material by means of high-energy rays starting from low molecular weight polymerisable compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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DE19883823157 DE3823157A1 (en) | 1988-07-08 | 1988-07-08 | Process for producing a beflocked sheet material by means of high-energy rays starting from low molecular weight polymerisable compounds |
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DE3823157A1 true DE3823157A1 (en) | 1990-02-08 |
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DE19883823157 Withdrawn DE3823157A1 (en) | 1988-07-08 | 1988-07-08 | Process for producing a beflocked sheet material by means of high-energy rays starting from low molecular weight polymerisable compounds |
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Cited By (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994002300A1 (en) * | 1992-07-18 | 1994-02-03 | Hp-Chemie Pelzer Research & Development Ltd. | Moulded articles with leather-like surface properties for use in the automobile industry |
EP0887166A2 (en) * | 1997-06-24 | 1998-12-30 | ERA BESCHICHTUNG GmbH & CO. KG | Method for producing a bonding layer |
WO2000053438A1 (en) * | 1999-03-10 | 2000-09-14 | Hp-Chemie Pelzer | Vehicle wheel, notably for a private motor car |
DE102007042917A1 (en) | 2007-09-08 | 2009-03-12 | Contitech Antriebssysteme Gmbh | Bend-elastic drive belt, in particular V-ribbed belt, with a textile support on its wear-prone working side |
DE102007044436A1 (en) | 2007-09-18 | 2009-03-19 | Contitech Antriebssysteme Gmbh | Endless elastic drive belt, in particular V-belt or V-ribbed belt, with reduced tension loss |
DE102008026965A1 (en) | 2008-06-05 | 2009-12-10 | Contitech Antriebssysteme Gmbh | Drive belt i.e. ribbed drive belt, has force transmission zone provided with flock support, where adhesion of flock support within force transmission zone takes place via chlorine paraffin solution that comprises specific chlorine content |
DE102008045453A1 (en) | 2008-09-02 | 2010-03-04 | Contitech Antriebssysteme Gmbh | Drive belt i.e. high-power ribbed v-belt, for transmitting force, has elastic textile support layers coated on elastic polymer layers so that textile support layers are stably connected with elastic polymer layers |
DE102008037415A1 (en) | 2008-10-06 | 2010-04-08 | Contitech Antriebssysteme Gmbh | Driving belt, particularly V-ribbed belt, comprises cover layer as belt back, and subframe having power transmission zone, where power transmission zone is typically equipped with textile cover |
DE102008037561A1 (en) | 2008-11-18 | 2010-05-27 | Contitech Antriebssysteme Gmbh | Articles, in particular drive belts, with a textile support and method for producing a drive belt |
DE102008055497A1 (en) | 2008-12-10 | 2010-06-24 | Contitech Antriebssysteme Gmbh | Elastic article, in particular drive belt, with a textile cover and a bonding agent of fusible plastic |
DE102009003763A1 (en) | 2009-04-08 | 2010-10-14 | Contitech Antriebssysteme Gmbh | Drive belt i.e. V-ribbed belt, has base frame and/or force transmission zone equipped with wear-resistant and/or medium-resistant coating, where belt is provided with detectable magnetic marking in belt longitudinal direction |
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-
1988
- 1988-07-08 DE DE19883823157 patent/DE3823157A1/en not_active Withdrawn
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