DE381551C - Process for developing copies from diazo anhydrides - Google Patents
Process for developing copies from diazo anhydridesInfo
- Publication number
- DE381551C DE381551C DEK75371D DEK0075371D DE381551C DE 381551 C DE381551 C DE 381551C DE K75371 D DEK75371 D DE K75371D DE K0075371 D DEK0075371 D DE K0075371D DE 381551 C DE381551 C DE 381551C
- Authority
- DE
- Germany
- Prior art keywords
- diazo
- anhydrides
- exposed
- positive
- developed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/18—Diazo-type processes, e.g. thermal development, or agents therefor
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
Entwicklungsverfahren für Kopien aus Diazoanhydriden. Im Patent 376385 ist gezeigt worden, daß sich von positiven Bildern unmittelbar positive Lichtpausen (oder aus negativen Bildern negative Pausen) in der Weise herstellen lassen, daß man Diazoanhydride auf eine geeignete Unterlage aufträgt, die Schicht unter der Vorlage belichtet und alsdann das Bild durch Einführung in ein Bad von Phenolen oder Aminen entwickelt. Als Diazoanhydride werden die Diazoverbindungen der i -:2- oder 2 - z-Aminooxynaphthaline oder deren Derivate oder solche von heterozyklischen Verbindungen verwendet.Process for developing copies from diazo anhydrides. In patent 376385 it has been shown that positive blueprints immediately result from positive images (or negative pauses from negative images) in such a way that one applies diazoanhydrides to a suitable surface, the layer under the The original is exposed and then the image is introduced into a bath of phenols or amines developed. The diazo compounds of the i -: 2- or 2 - z-aminooxynaphthalenes or their derivatives or those of heterocyclic ones Connections used.
Es ist nun gefunden worden, daß man auch mit den im Hauptpatent beschriebenen lichtempfindlichen Schichten Positive aus einem Positiv in der Weise herstellen kann, daß man die lichtempfindliche Schicht -nach dem Belichten durch die Vorlage hindurch noch einige Zeit ohne die Vorlage dem freien Licht aussetzt und die Schicht alsdann mit einem Alkali entwickelt.It has now been found that one can also do with those described in the main patent Light-sensitive layers create positive from a positive in the same way can that you the photosensitive layer -after exposure through the original through it for some time without the template exposed to free light and the layer then developed with an alkali.
Beispiel. Der Träger für die lichtempfindliche Schicht, z. B. Papier, wird mit einer Lösung aus der z-Diazo-2-oxynaphthalin-d.-sulfosäure bestrichen und getrocknet. Die so erhaltene lichtempfindliche Schicht wird unter einem Positiv belichtet. Nachdem die Stellen, an ' denen das Licht Durchgang hatte, ausgebleicht sind, wird die Vorlage entfernt und das Bild noch kurze Zeit an freiem Licht ohne die Kopiervorlage belichtet. Dadurch entsteht an den Stellen, die beim Kopieren unter der Vorlage nicht belichtet waren, d. h. an den Stellen, wo sich die Zeichnung des Positivs befand, eine Substanz, die sich in alkalischer Lösung sofort mit der noch unveränderten Diazoverhindung, die sich an den dunklen Stellen befand, zu einem Farbstoff vereinigt.Example. The support for the photosensitive layer, e.g. B. paper, is coated with a solution of the z-diazo-2-oxynaphthalene-d.-sulfonic acid and dried. The photosensitive layer thus obtained becomes under a positive exposed. After the places where the light had passed through, bleached out the original is removed and the image is exposed to free light for a short time the master is exposed. This creates in the places that are copied were not exposed under the original, d. H. in the places where the drawing is of the positive, a substance which in alkaline solution immediately reacts with the still unchanged diazo compound, which was in the dark places, into one Dye combined.
Aus diesem Grunde entstehen auch sehr kräftige Bilder, wenn man die Kopie in vollem Sonnenlicht oder elektrischem Licht in alkalischer Lösung entwickelt.For this reason, very powerful images are created when you use the Copy developed in full sunlight or electric light in alkaline solution.
Zu diesem Verfahren können alle ausbleichenden Diazoanhydride verwendet werden.All bleaching diazo anhydrides can be used for this process will.
Die Bilder können nachträglich getönt werden.The images can be tinted afterwards.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEK75371D DE381551C (en) | 1920-11-29 | 1920-11-30 | Process for developing copies from diazo anhydrides |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEK0075371 | 1920-11-29 | ||
DEK75371D DE381551C (en) | 1920-11-29 | 1920-11-30 | Process for developing copies from diazo anhydrides |
Publications (1)
Publication Number | Publication Date |
---|---|
DE381551C true DE381551C (en) | 1923-09-21 |
Family
ID=25984434
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEK75371D Expired DE381551C (en) | 1920-11-29 | 1920-11-30 | Process for developing copies from diazo anhydrides |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE381551C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE887731C (en) * | 1938-11-19 | 1953-08-27 | Anciens Etablissements Salvado | Process for making positive copies of positive originals using diazo compounds |
-
1920
- 1920-11-30 DE DEK75371D patent/DE381551C/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE887731C (en) * | 1938-11-19 | 1953-08-27 | Anciens Etablissements Salvado | Process for making positive copies of positive originals using diazo compounds |
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