DE3727132A1 - Method for destabilizing and destroying foams by thermal energy - Google Patents
Method for destabilizing and destroying foams by thermal energyInfo
- Publication number
- DE3727132A1 DE3727132A1 DE19873727132 DE3727132A DE3727132A1 DE 3727132 A1 DE3727132 A1 DE 3727132A1 DE 19873727132 DE19873727132 DE 19873727132 DE 3727132 A DE3727132 A DE 3727132A DE 3727132 A1 DE3727132 A1 DE 3727132A1
- Authority
- DE
- Germany
- Prior art keywords
- foam
- thermal energy
- introduction
- destroyed
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M27/00—Means for mixing, agitating or circulating fluids in the vessel
- C12M27/02—Stirrer or mobile mixing elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
- C12M41/02—Means for regulation, monitoring, measurement or control, e.g. flow regulation of foam
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Genetics & Genomics (AREA)
- Sustainable Development (AREA)
- General Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Biotechnology (AREA)
- Biomedical Technology (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zur Destabilisierung und Zerstörung von Schäumen mit thermischer Energie.The invention relates to a method for destabilizing and Destruction of foams with thermal energy.
Das Problem der Schaumbildung tritt in vielen chemischen und biologischen Prozessen auf. Die Schaumbildungsraten (d.h. das pro Zeiteinheit gebildete Schaumvolumen) können in vielen Fäl len so hoch sein, daß die Prozeßführung ohne Schaumzerstörungs maßnahmen sehr stark erschwert wird.The problem of foam formation occurs in many chemicals and biological processes. The foaming rates (i.e. the foam volume formed per unit of time) can in many cases len be so high that the process control without foam destruction measures is made very difficult.
Besonders bei Fermentationsprozessen kann es während des Mikro organismenwachstums zu einer starken Schaumbildung kommen. Die Schaumbildung wird bei aeroben Prozessen durch die notwendige Belüftung und das Rühren des Substrates, bei anaeroben Gärungs prozessen durch erzeugtes Gas, sowie durch Proteine, die als Stoffwechselprodukte der Mikroorganismen entstehen, bedingt. Proteine gehören zur Gruppe der Ampho-Tenside. Sie besitzen sowohl hydrophobe als auch hydrophile Gruppen innerhalb ihres Kettengerüstes. Dadurch wirken Proteine wie waschaktive Sub stanzen, die die Oberflächenspannung der Kulturbrühe herabset zen und so die Schaumbildung begünstigen.Especially during fermentation processes, it can happen during the micro organism growth lead to a strong foaming. The Foaming is caused by the necessary in aerobic processes Aeration and stirring of the substrate, for anaerobic fermentation processes by generated gas, as well as by proteins, which as Metabolic products of the microorganisms arise conditionally. Proteins belong to the group of amphoteric surfactants. You own both hydrophobic and hydrophilic groups within their Chain frame. As a result, proteins act like washing-active sub punch, which reduces the surface tension of the culture broth zen and thus promote foam formation.
Schaum läßt sich auf chemische, mechanische und thermische Weise bekämpfen.Foam can be chemical, mechanical and thermal Fight Wise.
Die Zudosierung chemischer Antischaummittel kann nur eingesetzt werden, wenn das erzeugte Produkt durch das Antischaummittel nicht geschädigt wird und wenn es sich leicht vom Produkt tren nen läßt. Chemische Antischaummittel können sich zudem negativ auf die Viskosität und den Sauerstofftransport im Reaktor aus wirken.Chemical anti-foaming agents can only be added when the product produced by the anti-foaming agent is not damaged and if it is easy to separate from the product leaves. Chemical anti-foaming agents can also be negative on the viscosity and the oxygen transport in the reactor Act.
Mechanische Schaumzerstörer liefern bei hohen Schaumbildungs raten unbefriedigende Ergebnisse, aufgrund zu geringer Lei stungsfähigkeit.Mechanical foam destroyers deliver with high foam formation advise unsatisfactory results due to insufficient lei endurance.
Der Erfindung liegt die Aufgabe zugrunde, Schaum effektiv zu zerstören ohne negative Beeinflussung des Produktionsprozes ses.The invention has for its object to effectively foam destroy without adversely affecting the production process ses.
Diese Aufgabe wird erfindungsmäßig dadurch gelöst, daß Dampf oder ein heißes Gas entweder direkt in die Schaumschicht oder oberhalb der Schaumschicht eingeblasen wird. Durch die dabei übertragene Wärme werden die in den einzelnen Gasblasen ein geschlossenen Gasvolumia erwärmt und es kommt zu einer Ver größerung der Schaumblasen. Damit verbunden ist eine Abnahme der Dicke der innerlamellaren Flüssigkeitsschicht zwischen den einzelnen Schaumblasen. Ferner bewirkt die Temperaturer höhung eine Abnahme der Viskosität dieser Schicht der innerla mellaren Flüssigkeit. Aufgrund dieser physikalischen Vorgänge wird die Stabilität des Schaumes so stark herabgesetzt, daß die Schaumblasen entweder während der Wärmeübertragung von selbst platzen, oder durch die Einbringung mechanischer Ener gie leicht und effektiv zerstört werden können. Die mechanische Energie kann durch ein komprimiertes Gas, Ultraschall oder durch einen mechanischen Schaumschneider eingebracht werden.This object is achieved according to the invention in that steam or a hot gas either directly into the foam layer or is blown in above the foam layer. By doing it The heat transferred will be the one in the individual gas bubbles closed gas volumia heated and there is a Ver enlargement of the foam bubbles. This is associated with a decrease the thickness of the inner lamellar liquid layer between the individual foam bubbles. It also causes the temperature increase a decrease in the viscosity of this layer of the inner layer mellar fluid. Because of these physical processes the stability of the foam is reduced so much that the foam bubbles either during the heat transfer from itself burst, or by introducing mechanical energy can be easily and effectively destroyed. The mechanical Energy can be obtained through a compressed gas, ultrasound or by a mechanical foam cutter.
Ob der Schaum allein durch die Einbringung thermischer Ener gie zerstört wird, oder ob der Schaum dabei nur destabili siert wird und durch Einbringung mechanischer Energie zer stört werden muß, ist abhängig von der Konsistenz des er zeugten Schaumes.Whether the foam is just by introducing thermal energy gie destroyed, or whether the foam is only destabili and is broken down by the introduction of mechanical energy must be disturbed depends on the consistency of the he produced foam.
Erfindungsgemäß kann die Schaumhöhe über der Flüssigkeit auf
zwei Arten reguliert werden:
1. durch taktweise Zufuhr thermischer Energie
2. durch kontinuierliche Zufuhr thermischer Energie.
According to the invention, the foam height above the liquid can be regulated in two ways:
1. by supplying thermal energy in cycles
2. by continuously supplying thermal energy.
Bei taktweiser Zufuhr der thermischen Energie wird diese ein gebracht, sobald der Schaum über der Flüssigkeit eine be stimmte Höhe erreicht hat. Dabei wird das gesamte Schaumvo lumen zerstört.When the thermal energy is supplied in cycles, it becomes one brought as soon as the foam over the liquid a be agreed height has reached. The entire foam vo lumen destroyed.
Bei kontinuierlicher Zufuhr der thermischen Energie wird pro Zeiteinheit genau soviel Schaum zerstört, wie an der Flüs sigkeitsoberfläche gebildet wird. So kann die Schaumhöhe auf einem konstanten Level gehalten werden.With continuous supply of thermal energy, pro Unit of time destroyed as much foam as on the rivers liquid surface is formed. So the foam height can be kept at a constant level.
Die kritische Höhe des Schaumlevels wird erfindungsgemäß mit Hilfe eines Niveaumessers (z.B. optisch mittels Differenzial photodiode) erfaßt. Dampf bzw. heißes Gas werden erfindungs gemäß durch Flachschlitz- oder Rundlochdüsen, welche über den Umfang und/oder den Deckel des entsprechenden Behälters ver teilt sind, gleichmäßig eingeblasen. The critical height of the foam level is according to the invention Using a level meter (e.g. optically using a differential photodiode) detected. Steam or hot gas are fiction according to by flat slot or round hole nozzles, which over the Ver volume and / or the lid of the corresponding container parts are blown in evenly.
Mit einer geeigneten Schaummeßsonde 1 wird die Höhe der Schaum krone über der Fermentationsbrühe gemessen. Als Meßmethoden können sowohl optische, als auch nach dem Leitfähigkeitsprinzip arbei tende Meßaufnehmer verwendet werden. Wird eine vorgegebene Schaum höhe überschritten, wird dies von der Schaumsonde 1 registriert und ein entsprechendes Signal an die Regelungseinheit 2 gesandt. Über die Regelungseinheit 2 werden am Dampferzeuger (bzw. Gaser hitzer) Stellventile geöffnet und Dampf (bzw. Heißgas) über Düsen 4 in den Kopfraum des Bioreaktors eingeblasen. Dadurch wird der Schaum über der Fermentationsbrühe zerstört und die Schaumhöhe sinkt unter den vorgegebenen kritischen Wert. Die Regelungseinheit 2 schließt darauf die Stellventile am Dampferzeuger 3.The height of the foam crown above the fermentation broth is measured with a suitable foam measuring probe 1 . Optical as well as working on the conductivity principle can be used as measuring methods. If a predetermined foam height is exceeded, this is registered by the foam probe 1 and a corresponding signal is sent to the control unit 2 . Via the control unit 2 on the steam generator (or gas heater) control valves are opened and steam (or hot gas) is injected via nozzles 4 into the head space of the bioreactor. This destroys the foam above the fermentation broth and the foam height drops below the specified critical value. The control unit 2 then closes the control valves on the steam generator 3 .
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19873727132 DE3727132A1 (en) | 1987-08-14 | 1987-08-14 | Method for destabilizing and destroying foams by thermal energy |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19873727132 DE3727132A1 (en) | 1987-08-14 | 1987-08-14 | Method for destabilizing and destroying foams by thermal energy |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3727132A1 true DE3727132A1 (en) | 1989-02-23 |
Family
ID=6333761
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19873727132 Withdrawn DE3727132A1 (en) | 1987-08-14 | 1987-08-14 | Method for destabilizing and destroying foams by thermal energy |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE3727132A1 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3803263A1 (en) * | 1988-02-04 | 1989-08-17 | Tuchenhagen Otto Gmbh | Method for the destruction of foam |
DE4314521A1 (en) * | 1993-05-03 | 1994-11-10 | Eisenmann Kg Maschbau | Process and plant for purifying organically polluted industrial waste waters |
DE4440629C1 (en) * | 1994-11-14 | 1996-06-27 | Umweltschutztechnik Mbh Ges | Destruction of foam in vapour from evapn. plant |
DE102010007559A1 (en) * | 2010-02-10 | 2011-08-11 | Sartorius Stedim Biotech GmbH, 37079 | Bioreactor container with an optical foam sensor |
CN106430389A (en) * | 2016-10-27 | 2017-02-22 | 浙江大学苏州工业技术研究院 | Defoaming device and method for electrochemical wastewater treatment system |
DE102015015055A1 (en) | 2015-11-03 | 2017-05-04 | Gea Tds Gmbh | Method and device for controlling foam formation in containers for liquids or for foams and register system for such a device |
WO2019149891A1 (en) * | 2018-02-02 | 2019-08-08 | Michael Niederbacher | Biogas plant fermenter tank, service device for mounting on a biogas plant fermenter tank and method for operating a biogas plant fermenter tank |
DE102018121613A1 (en) * | 2018-09-05 | 2020-03-05 | Miele & Cie. Kg | Method and device for removing a cleaning foam solution after a cleaning process of a cooking device and cooking device |
-
1987
- 1987-08-14 DE DE19873727132 patent/DE3727132A1/en not_active Withdrawn
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3803263A1 (en) * | 1988-02-04 | 1989-08-17 | Tuchenhagen Otto Gmbh | Method for the destruction of foam |
DE4314521A1 (en) * | 1993-05-03 | 1994-11-10 | Eisenmann Kg Maschbau | Process and plant for purifying organically polluted industrial waste waters |
DE4440629C1 (en) * | 1994-11-14 | 1996-06-27 | Umweltschutztechnik Mbh Ges | Destruction of foam in vapour from evapn. plant |
DE102010007559A1 (en) * | 2010-02-10 | 2011-08-11 | Sartorius Stedim Biotech GmbH, 37079 | Bioreactor container with an optical foam sensor |
DE102010007559B4 (en) * | 2010-02-10 | 2014-01-09 | Sartorius Stedim Biotech Gmbh | Bioreactor container with an optical foam sensor |
US9809793B2 (en) | 2010-02-10 | 2017-11-07 | Sartorius Stedim Biotech Gmbh | Bioreactor vessel having an optical foam sensor |
DE102015015055A1 (en) | 2015-11-03 | 2017-05-04 | Gea Tds Gmbh | Method and device for controlling foam formation in containers for liquids or for foams and register system for such a device |
DE102015015056A1 (en) | 2015-11-03 | 2017-05-04 | Gea Tds Gmbh | Method and apparatus for controlling foam formation in a degassing device for liquids and register system for such a device |
WO2017076488A1 (en) | 2015-11-03 | 2017-05-11 | Gea Tds Gmbh | Method and device for controlling foaming in a degassing device for liquids and heat-exchanger system for such a device |
WO2017076491A1 (en) | 2015-11-03 | 2017-05-11 | Gea Tds Gmbh | Method and device for controlling foaming in containers for liquids or foams and register system for such a device |
DE102015015056B4 (en) | 2015-11-03 | 2021-07-08 | Gea Tds Gmbh | Method for controlling the foaming in a degassing device for liquids and degassing device for liquids with a device for controlling the foaming |
CN106430389A (en) * | 2016-10-27 | 2017-02-22 | 浙江大学苏州工业技术研究院 | Defoaming device and method for electrochemical wastewater treatment system |
CN106430389B (en) * | 2016-10-27 | 2023-06-09 | 浙江大学苏州工业技术研究院 | Defoaming device and method of wastewater electrochemical treatment system |
WO2019149891A1 (en) * | 2018-02-02 | 2019-08-08 | Michael Niederbacher | Biogas plant fermenter tank, service device for mounting on a biogas plant fermenter tank and method for operating a biogas plant fermenter tank |
DE102018121613A1 (en) * | 2018-09-05 | 2020-03-05 | Miele & Cie. Kg | Method and device for removing a cleaning foam solution after a cleaning process of a cooking device and cooking device |
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Legal Events
Date | Code | Title | Description |
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8141 | Disposal/no request for examination |