DE3721684A1 - METHOD FOR WET REMOVING SULFUR DIOXIDE - Google Patents
METHOD FOR WET REMOVING SULFUR DIOXIDEInfo
- Publication number
- DE3721684A1 DE3721684A1 DE19873721684 DE3721684A DE3721684A1 DE 3721684 A1 DE3721684 A1 DE 3721684A1 DE 19873721684 DE19873721684 DE 19873721684 DE 3721684 A DE3721684 A DE 3721684A DE 3721684 A1 DE3721684 A1 DE 3721684A1
- Authority
- DE
- Germany
- Prior art keywords
- suspension
- absorption
- water
- stage absorption
- absorbent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000010521 absorption reaction Methods 0.000 claims abstract description 30
- 239000003546 flue gas Substances 0.000 claims abstract description 22
- 239000000725 suspension Substances 0.000 claims abstract description 17
- 150000003839 salts Chemical class 0.000 claims abstract description 16
- 239000013535 sea water Substances 0.000 claims abstract description 14
- 239000002250 absorbent Substances 0.000 claims abstract description 11
- 230000002745 absorbent Effects 0.000 claims abstract description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 6
- 235000019738 Limestone Nutrition 0.000 claims abstract description 4
- 239000006028 limestone Substances 0.000 claims abstract description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 3
- 239000010440 gypsum Substances 0.000 claims abstract description 3
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 14
- 239000002243 precursor Substances 0.000 claims description 9
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 3
- 239000000779 smoke Substances 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 3
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 2
- 239000004291 sulphur dioxide Substances 0.000 abstract 2
- 239000003595 mist Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 235000002639 sodium chloride Nutrition 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- HBYOLNPZXLHVQA-UHFFFAOYSA-J dicalcium dicarbonate Chemical compound [Ca+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HBYOLNPZXLHVQA-UHFFFAOYSA-J 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
- C01F11/464—Sulfates of Ca from gases containing sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Geology (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Abstract
Description
Gegenstand der vorliegenden Erfindung ist ein Verfahren zum nassen Entfernen von Schwefeldioxid aus Rauchgasen unter Verwendung einer Kalkstein enthaltenden Absorpti onsmittelsuspension, bei demThe present invention relates to a method for wet removal of sulfur dioxide from flue gases using an absorbent containing limestone onsmittelspension, at which
- a) im Sumpf einer Vorstufenabsorption im pH-Bereich von 4 bis 5 durch Einleiten von Luft in die Suspension Sulfit zum Sulfat oxidiert und grobkörniger Gips als feststoffreiche Suspension aus dem System ausge schleust wird,a) in the swamp of a precursor absorption in the pH range of 4 to 5 by introducing air into the suspension Oxidized sulfite to sulfate and coarse-grained gypsum as high-solids suspension out of the system is smuggled
- b) in einer Nachstufenabsorption im pH-Bereich von ca. 6 das Schwefeldioxid des Rauchgases durch die Absorp tionsmittelsuspension als Sulfit gebunden und diese in einem Ablauf separat aufgefangen und in den Vor ratstank für die Absorptionsmittelsuspension zurück geführt wird,b) in a post-stage absorption in the pH range of approx. 6 the sulfur dioxide of the flue gas through the absorber agent suspension bound as sulfite and this collected separately in one process and in the fore Council tank back for the absorbent suspension to be led,
- c) die Wasserverluste der Vorstufenabsorption durch den feststoffarmen Überlauf des Absorptionsmittels aus geglichen,c) the water losses of the precursor absorption by the low solids overflow of the absorbent compared
- d) die Wasserverluste der Nachstufenabsorption durch das Waschwasser einer nachgeschalteten Tropfenabschei dung ausgeglichen werden.d) the water losses due to post-stage absorption the wash water of a downstream droplet separator be balanced.
Ein derartiges Verfahren ist beispielsweise bekannt aus der DE-OS 30 11 592.5. Derartige Anlagen werden von der Anmelderin seit Jahren angeboten und gebaut. Bei diesen Anlagen sind in einem Turm von unten nach oben überein ander gebaut der Sumpf der Vorstufenabsorption, die Sprühanlagen für die Vorstufenabsorption, die schüssel artige Vorrichtung zum separaten Auffangen der Absorp tionsmittelsuspension der Nachstufenabsorption, die Sprüheinrichtungen der Nachstufenabsorption sowie die Tropfenabscheidung. Such a method is known for example from DE-OS 30 11 592.5. Such systems are used by the Applicant offered and built for years. With these Systems are in a tower from bottom to top others built the swamp of precursor absorption, the Sprayers for pre-stage absorption, the bowl like device for collecting the Absorp separately agent suspension of post-stage absorption, the Sprayers of post-stage absorption as well as the Drop separation.
Dieses Verfahren und diese Vorrichtungen haben sich ausgezeichnet bewährt. Sie weisen jedoch den Nachteil auf, daß bei Rauchgasen mit hohem Chloridgehalt ein unerwünscht hoher Anteil des Chlorids auch in die Nach stufenabsorption gelangt. Ein hoher Chloridgehalt in der Absorptionsmittelsuspension der Nachstufenabsorpti on ist jedoch unerwünscht und kann das Absorptionsver mogen der Suspension beeinträchtigen. Der Chloridgehalt des Rauchgases wird bei diesen Verfahren an sich voll ständig von der Vorstufenabsorption abgefangen, jedoch wird durch den Rauchgasstrom stets eine gewisse Menge des Absorptionsmittels der Vorstufenabsorption in den Kreislauf der Nachstufenabsorption mitgerissen, so daß auf diesem mechanischen Wege Chlorid in die Absorpti onsmittelsuspension der Nachstufenabsorption gelangt.This method and these devices have become proven excellent. However, they have the disadvantage on that with flue gases with a high chloride content undesirably high proportion of the chloride also in the night step absorption arrives. A high chloride content in the absorbent suspension of the post-stage absorpti however is undesirable and can absorb the absorption may affect the suspension. The chloride content the flue gas itself becomes full in these processes constantly intercepted by precursor absorption, however is always a certain amount due to the flue gas flow of the absorbent of the precursor absorption in the Cycle of post-absorption absorbed, so that in this mechanical way chloride into the absorpti onsuspension of the post-stage absorption.
Die Erfindung hat sich daher zunächst einmal die Auf gabe gestellt, die Menge an mitgerissenem Chlorid aus der Vorstufenabsorption zu verringern und dadurch das Gesamtverfahren auch bei hohem Chloridgehalt des Rauch gases voll wirksam zu gestalten. Die Erfindung hat sich weiterhin die Aufgabe gestellt, den Verbrauch an Pro zeßwasser zu senken.The invention has therefore first of all the given the amount of entrained chloride to reduce the precursor absorption and thereby the Overall process even with high chloride content in the smoke make gases fully effective. The invention has continued the task of consuming Pro to lower zeßwasser.
Diese Aufgaben können überraschend einfach dadurch ge löst werden, daß die Rauchgase vor der Vorstufenabsorp tion einer Vorwäsche mit Meerwasser und/oder Salzwasser unterzogen werden.These tasks can be surprisingly simple be resolved that the flue gases in front of the pre-absorber prewash with sea water and / or salt water be subjected.
Konstruktiv bedeutet dies, daß vor der Rauchgasent schwefelungsanlage noch ein Vorwäscher mit Sprühein richtungen sowie einem Tropfenabscheider geschaltet ist, der mit Meerwasser und/oder Salzwasser betrieben wird. Constructively, this means that in front of the flue gas sulphurization plant still a pre-washer with spray directions and a droplet separator is operated with sea water and / or salt water becomes.
Es hat sich nämlich überraschenderweise herausgestellt,Surprisingly, it turned out
daß durch die erfindungsgemäße Vorwäsche mit Meerwasser und/oder Salzwasser der Gehalt an Chlorid und Fluorid in den Rauchgasen so stark verringert, daß in der ei gentlichen Rauchgasentschwefelungsanlage nahezu kein Chlorid und Fluorid mehr in der Gasphase vorhanden ist.that by the prewash according to the invention with sea water and / or salt water the chloride and fluoride content so greatly reduced in the flue gases that in the egg conventional flue gas desulfurization plant almost none Chloride and fluoride are more present in the gas phase.
Insbesondere um eine Verunreinigung der Rauchgasent schwefelungsanlage durch Meerwasser und/oder Salzwasser zu vermeiden, wird vorzugsweise zwischen der Vorwäsche und der Vorstufenabsorption eine Tropfenabscheidung durchgeführt. Der hohe Chloridgehalt von Meerwasser und/oder Salzwasser führt nicht zu der an sich zu er wartenden Erhöhung des Chloridgehaltes in Rauchgasen,In particular, contamination of the smoke gas sulfurization plant by sea water and / or salt water to avoid is preferably between the prewash and droplet separation of the precursor absorption carried out. The high chloride content of sea water and / or salt water does not lead to it itself waiting increase in the chloride content in flue gases,
sonder sogar zu einer nahezu vollständigen Auswaschung der Chloride und Fluoride aus den Rauchgasen.but even to an almost complete washout the chlorides and fluorides from the flue gases.
Das erfindungsgemäße Verfahren kann besonders vorteil haft dort eingesetzt werden, wo Meerwasser und/oder Salzwasser in ausreichenden Mengen zur Verfügung steht.The method according to the invention can be particularly advantageous be used wherever sea water and / or Salt water is available in sufficient quantities.
Durch die erfindungsgemäße Maßnahme der Vorwäsche mit Meerwasser und/oder Salzwasser vermindert sich der Be darf an Prozeßwasser erheblich, da die Rauchgase bei der Vorwäsche mit Meerwasser und/oder Salzwasser abge kühlt und mit Wasserdampf beladen werden und damit für die Rauchgasentschwefelung konditioniert werden. Nach dem Stand der Technik mußte diese Wassermenge zusätz lich als Prozeßwasser dem Verfahren zugeführt werden.The measure of prewashing according to the invention Sea water and / or salt water reduce the loading is allowed to process water considerably, since the flue gases at the prewash with sea water and / or salt water cools and be loaded with water vapor and thus for the flue gas desulfurization must be conditioned. To this amount of water had to be additional to the state of the art Lich the process water supplied to the process.
Insbesondere in südlichen Ländern mit hohen Kosten für Prozeßwasser, aber ausreichenden Mengen an Meerwasser und/oder Salzwasser ist dies ein wesentlicher wirt schaftlicher Vorteil. Aber selbst an Standorten mit ausreichenden Mengen von Prozeßwasser kann das erfin dungsgemäße Verfahren vorteilhaft eingesetzt werden, um einen chloridarmen bzw. chloridfreien Gips zu erhalten.Especially in southern countries with high costs for Process water, but sufficient amounts of sea water and / or salt water this is an essential host economic advantage. But even at locations sufficient quantities of process water can do this methods according to the invention are advantageously used to to get a low-chloride or chloride-free plaster.
Die Vorwäsche erfolgt dann mit einem künstlich herge stellten Salzwasser. The prewash is then carried out with an artificial herge provided salt water.
Durch die Absorption der Chloride und Fluoride aus den Rauchgasen sinkt der pH-Wert des Salzwassers und/oder Meerwassers. Es kann daher erforderlich sein, diesen gesunkenen pH-Wert anschließend durch Zugabe von Lauge zu neutralisieren. Bei Verwendung von Natronlauge ent steht weiteres Kochsalz. Bei Verwendung von Calciumhy droxid und/ oder Calciumcarbonat entsteht Calciumchlo rid, das ebenfalls problemlos in das Meer zurückgelei tet werden kann. Insbesondere durch den hohen Gehalt an Chlorid und den niedrigen pH-Wert des Meer- und/oder Salzwassers wird in der Vorwaschstufe praktisch kein Schwefeldioxid ausgewaschen, so daß auch aus diesem Grunde einer Rückleitung des benutzten Meerwassers ins Meer nichts im Wege steht.Due to the absorption of chlorides and fluorides from the Flue gases decrease the pH value of the salt water and / or Sea water. It may therefore be necessary to do so then the pH dropped by adding lye to neutralize. When using caustic soda ent there is more table salt. When using calcium hy droxid and / or calcium carbonate calcium chlo rid, which also easily returned to the sea can be tet. Especially because of the high content of Chloride and the low pH of the sea and / or Salt water is practically none in the prewash stage Sulfur dioxide washed out, so that from this Due to a return of the used sea water to the Nothing stands in the way of the sea.
Das erfindungsgemäße Verfahren ist in der anliegenden Fig. 1 näher erläutert.The method according to the invention is explained in more detail in the attached FIG. 1.
In dieser Figur bedeutenMean in this figure
-
1: Rauchgas
2: Meerwasser und/oder Salzwasser
3: verbrauchtes Meer- und/oder Salzwasser
4: Luft
5: Gips
6: Filtrat
7: Filtrat
7: gereinigtes Rauchgas
8: Prozeßwasser und
9: Kalkstein 1 : flue gas
2 : sea water and / or salt water
3 : used sea and / or salt water
4 : air
5 : plaster
6 : filtrate
7 : filtrate
7 : cleaned flue gas
8 : process water and
9 : limestone
Claims (4)
- a) im Sumpf einer Vorstufenabsorption im pH-Bereich von 4 bis 5 durch Einleiten von Luft in die Suspension Sulfit zum Sulfat oxidiert und grobkörniger Gips als feststoffreiche Suspension aus dem System ausge schleust wird,
- b) in einer Nachstufenabsorption im pH-Bereich von ca.
- a) in the bottom of a precursor absorption in the pH range from 4 to 5, sulfite is oxidized to sulfate by introducing air into the suspension and coarse-grained gypsum is discharged from the system as a high-solids suspension,
- b) in a post-stage absorption in the pH range of approx.
- c) die Wasserverluste der Vorstufenabsorption durch den feststoffarmen Überlauf des Absorptionsmittels aus geglichen,
- d) die Wasserverluste der Nachstufenabsorption durch das Waschwasser einer nachgeschalteten Tropfenabschei dung ausgeglichen werden, dadurch gekennzeichnet, daß die Rauchgase vor der Vor stufenabsorption einer Vorwäsche mit Meerwasser und/ oder Salzwasser unterzogen werden.
- c) the water losses of the precursor absorption are compensated for by the low solids overflow of the absorbent,
- d) the water losses of the post-stage absorption are compensated for by the wash water of a downstream drop separator, characterized in that the flue gases are subjected to a pre-wash with sea water and / or salt water before the pre-stage absorption.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873721684 DE3721684A1 (en) | 1987-07-01 | 1987-07-01 | METHOD FOR WET REMOVING SULFUR DIOXIDE |
| IT21110/88A IT1218256B (en) | 1987-07-01 | 1988-06-27 | WET REMOVAL PROCESS FOR SULFUR DIOXIDE |
| ES8802060A ES2007250A6 (en) | 1987-07-01 | 1988-06-30 | Process for the wet removal of sulphur dioxide |
| GB8815742A GB2208163B (en) | 1987-07-01 | 1988-07-01 | Process for the wet removal of sulphur dioxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873721684 DE3721684A1 (en) | 1987-07-01 | 1987-07-01 | METHOD FOR WET REMOVING SULFUR DIOXIDE |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3721684A1 true DE3721684A1 (en) | 1989-01-12 |
Family
ID=6330643
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19873721684 Withdrawn DE3721684A1 (en) | 1987-07-01 | 1987-07-01 | METHOD FOR WET REMOVING SULFUR DIOXIDE |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE3721684A1 (en) |
| ES (1) | ES2007250A6 (en) |
| GB (1) | GB2208163B (en) |
| IT (1) | IT1218256B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19638844A1 (en) * | 1996-09-21 | 1998-04-02 | Lentjes Bischoff Gmbh | Process for cleaning exhaust gas from fossil fuel combustion plants |
| EP0891804A2 (en) * | 1997-07-19 | 1999-01-20 | Lentjes Bischoff GmbH | Device for removing SO2 from exhaust gases and preparation of an ammonium sulfate solution |
| EP1967253A1 (en) * | 2007-03-09 | 2008-09-10 | Enviroserv Gmbh | Washing tower |
| EP3135364A1 (en) * | 2015-08-31 | 2017-03-01 | Steinmüller Engineering GmbH | Method and device for exhaust gas desulfurization |
| CN109952418A (en) * | 2016-10-28 | 2019-06-28 | 三星重工业株式会社 | Exhaust emission device |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105169795A (en) | 2005-12-19 | 2015-12-23 | 氟石科技公司 | Two-stage quench scrubber |
| BRPI0821515A2 (en) | 2007-12-28 | 2019-09-24 | Calera Corp | co2 capture methods |
| US20100239467A1 (en) | 2008-06-17 | 2010-09-23 | Brent Constantz | Methods and systems for utilizing waste sources of metal oxides |
| WO2010009273A1 (en) | 2008-07-16 | 2010-01-21 | Calera Corporation | Co2 utilization in electrochemical systems |
| US7993500B2 (en) | 2008-07-16 | 2011-08-09 | Calera Corporation | Gas diffusion anode and CO2 cathode electrolyte system |
| US8869477B2 (en) | 2008-09-30 | 2014-10-28 | Calera Corporation | Formed building materials |
| TW201026597A (en) | 2008-09-30 | 2010-07-16 | Calera Corp | CO2-sequestering formed building materials |
| US7815880B2 (en) | 2008-09-30 | 2010-10-19 | Calera Corporation | Reduced-carbon footprint concrete compositions |
| US9133581B2 (en) | 2008-10-31 | 2015-09-15 | Calera Corporation | Non-cementitious compositions comprising vaterite and methods thereof |
| CN101918614A (en) | 2009-02-10 | 2010-12-15 | 卡勒拉公司 | With hydrogen and electro catalytic electrode low-voltage alkaline production |
| EP2250127A4 (en) | 2009-03-02 | 2011-04-06 | Calera Corp | Gas stream multi-pollutants control systems and methods |
| TW201105406A (en) | 2009-03-10 | 2011-02-16 | Calera Corp | Systems and methods for processing CO2 |
| CN102266708B (en) * | 2011-07-15 | 2015-10-14 | 攀钢集团攀枝花钢钒有限公司 | A kind of flue gas desulfurization absorption process |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2133481A1 (en) * | 1971-02-24 | 1973-04-12 | Mitsubishi Kakoki Kk | METHOD AND EQUIPMENT FOR SCREENING GAS CLEANING FOR CRUDE OIL TANKS OF SHIPS |
| DE3011592A1 (en) * | 1979-03-30 | 1980-10-30 | Cottrell Res Inc | METHOD FOR REMOVING SULFUR DIOXIDE FROM SMOKE GAS |
| DE3305120A1 (en) * | 1983-02-15 | 1984-08-16 | Uhde Gmbh, 4600 Dortmund | Process for flue gas purification |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5850767B2 (en) * | 1980-08-19 | 1983-11-12 | 呉羽化学工業株式会社 | Flue gas desulfurization method |
-
1987
- 1987-07-01 DE DE19873721684 patent/DE3721684A1/en not_active Withdrawn
-
1988
- 1988-06-27 IT IT21110/88A patent/IT1218256B/en active
- 1988-06-30 ES ES8802060A patent/ES2007250A6/en not_active Expired
- 1988-07-01 GB GB8815742A patent/GB2208163B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2133481A1 (en) * | 1971-02-24 | 1973-04-12 | Mitsubishi Kakoki Kk | METHOD AND EQUIPMENT FOR SCREENING GAS CLEANING FOR CRUDE OIL TANKS OF SHIPS |
| DE3011592A1 (en) * | 1979-03-30 | 1980-10-30 | Cottrell Res Inc | METHOD FOR REMOVING SULFUR DIOXIDE FROM SMOKE GAS |
| DE3305120A1 (en) * | 1983-02-15 | 1984-08-16 | Uhde Gmbh, 4600 Dortmund | Process for flue gas purification |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19638844A1 (en) * | 1996-09-21 | 1998-04-02 | Lentjes Bischoff Gmbh | Process for cleaning exhaust gas from fossil fuel combustion plants |
| EP0891804A2 (en) * | 1997-07-19 | 1999-01-20 | Lentjes Bischoff GmbH | Device for removing SO2 from exhaust gases and preparation of an ammonium sulfate solution |
| EP0891804A3 (en) * | 1997-07-19 | 1999-11-03 | Lurgi Lentjes Bischoff GmbH | Device for removing SO2 from exhaust gases and preparation of an ammonium sulfate solution |
| EP1967253A1 (en) * | 2007-03-09 | 2008-09-10 | Enviroserv Gmbh | Washing tower |
| EP1970116A1 (en) * | 2007-03-09 | 2008-09-17 | Enviroserv Gmbh | Washing tower |
| WO2008110194A1 (en) * | 2007-03-09 | 2008-09-18 | Enviroserv Gmbh | Wash tower |
| EP3135364A1 (en) * | 2015-08-31 | 2017-03-01 | Steinmüller Engineering GmbH | Method and device for exhaust gas desulfurization |
| WO2017037076A1 (en) * | 2015-08-31 | 2017-03-09 | Steinmüller Engineering GmbH | Method and device for flue gas desulfurization |
| CN109952418A (en) * | 2016-10-28 | 2019-06-28 | 三星重工业株式会社 | Exhaust emission device |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2208163A (en) | 1989-03-08 |
| IT1218256B (en) | 1990-04-12 |
| GB8815742D0 (en) | 1988-08-10 |
| IT8821110A0 (en) | 1988-06-27 |
| ES2007250A6 (en) | 1989-06-01 |
| GB2208163B (en) | 1991-05-01 |
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