DE358050C - Process for improving the odor of turpentine oil obtained from sulphate pulp manufacture or the like - Google Patents
Process for improving the odor of turpentine oil obtained from sulphate pulp manufacture or the likeInfo
- Publication number
- DE358050C DE358050C DEA29135D DEA0029135D DE358050C DE 358050 C DE358050 C DE 358050C DE A29135 D DEA29135 D DE A29135D DE A0029135 D DEA0029135 D DE A0029135D DE 358050 C DE358050 C DE 358050C
- Authority
- DE
- Germany
- Prior art keywords
- odor
- turpentine oil
- improving
- sulphate pulp
- oil obtained
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 title claims description 8
- 239000001293 FEMA 3089 Substances 0.000 title claims description 6
- 229910021653 sulphate ion Inorganic materials 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 239000012670 alkaline solution Substances 0.000 claims 1
- 229910000464 lead oxide Inorganic materials 0.000 claims 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 150000003568 thioethers Chemical class 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 210000000078 claw Anatomy 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F3/00—Obtaining spirits of turpentine
- C09F3/02—Obtaining spirits of turpentine as a by-product in the paper-pulping process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
Description
Verfahren zur Geruchsverbesserung von bei .der Sulfatzellstoffabrikation o. dgl. gewonnenem Terpentinöl. . Bekanntlich enthalten die in der Zellulosefabrikation nach dem Sulfatverfahren o. dgl. als \ebenprodukt entstehenden sogenannten Sulfatterpentinöle übelriechende Sulfidverbindungen (Merkaptane), die die 'Verwertung dieser öle erschweren. Alle Versuche der dauernden Entfernung dieser Sulfidverbindungen sind bisher gescheitert. Vorliegende Erfindung erreicht das Ziel .durch Behandlung genannter S.ulfatterpentinöle mit Metalloxyden oder ,den entsprechenden Metallen, insbesondere auch Eisen, die in Alkalien, wie Ammoniak, Natriumhydroxyd, Kaliumhydroxyd gelöst sind, unter Erhitzen auf ioo bis i2o° mit oder ohne Druckerhöhung und gleichzeitiger Einwirkung von Wasserstoff, wobei die Schwefelverbindungen der entsprechenden Metalle entstehen.Process for improving the odor of sulphate pulp production or the like. Obtained turpentine oil. . It is well known that they are contained in cellulose production So-called sulfate pentine oils formed as a by-product after the sulfate process or the like foul-smelling sulphide compounds (mercaptans) that make it difficult to utilize these oils. All attempts to permanently remove these sulfide compounds have so far failed. The present invention achieves the object by treating said sulphate turpentine oils with metal oxides or the corresponding metals, especially iron, the dissolved in alkalis such as ammonia, sodium hydroxide, potassium hydroxide, with heating to ioo to i2o ° with or without pressure increase and simultaneous exposure to hydrogen, whereby the sulfur compounds of the corresponding metals are formed.
Beispiel. 500 kg Sulfatterpentinöl werden mit 25 kg 2o prozentiger Natronlauge, in der entweder 21/a kg Zinkoxyd oder 2 kg Bleiglätte gelöst sind, im Autoklauen auf ioo bis 12o° erhitzt. Gegebenenfalls kann das Erhitzen auch ohne Druckerhöhung erfolgen. Hierauf wird das so behandelte Terpentinöl gewaschen und fraktioniert. destilliert. An Stelle der Natronlauge können entsprechende Mengen Kalilauge oder Ammoniak, an Stelle der Metalloxyde entsprechende Mengen des entsprechenden Metalles oder Eisen genommen werden. Während der Behandlung läßt man noch Wasserstoff auf das Sulfatterpentinöl einwirken, wobei die ungesättigten Verbindungen des Öles, die wie auch zum Teil die gesättigten Verbindungen als Sulfide (\lerkaptane) vorhanden sind, durch Katalyse beschleunigt schwefelfrei werden und Wasserstoff anlagern bzw. gesättigt und geruchlos werden. Die gewünschte Wirkung tritt bei dieser Behandlung in I bis 5 Stunden ein. Der gegebenenfalls anzuwendende Druck kann beispielsweise 1/" bis 3 Atm. betragen.Example. 500 kg of sulphate turpentine oil are heated in the claws of a car to 100 to 120 ° with 25 kg of 2o percent sodium hydroxide solution, in which either 21 / a kg of zinc oxide or 2 kg of black lead are dissolved. If necessary, the heating can also take place without increasing the pressure. The turpentine oil treated in this way is then washed and fractionated. distilled. Corresponding amounts of potassium hydroxide or ammonia can be used in place of the sodium hydroxide solution, and corresponding amounts of the corresponding metal or iron in place of the metal oxides. During the treatment, hydrogen is allowed to act on the sulphate turpentine oil, whereby the unsaturated compounds of the oil, which, like some of the saturated compounds, are present as sulphides (\ lerkaptans), are accelerated by catalysis and become sulfur-free and hydrogen accumulate or become saturated and odorless . The desired effect occurs in 1 to 5 hours with this treatment. The pressure to be used, if necessary, can be, for example, 1 / "to 3 atm.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA29135D DE358050C (en) | 1917-03-07 | 1917-03-07 | Process for improving the odor of turpentine oil obtained from sulphate pulp manufacture or the like |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEA29135D DE358050C (en) | 1917-03-07 | 1917-03-07 | Process for improving the odor of turpentine oil obtained from sulphate pulp manufacture or the like |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE358050C true DE358050C (en) | 1922-09-04 |
Family
ID=6926830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEA29135D Expired DE358050C (en) | 1917-03-07 | 1917-03-07 | Process for improving the odor of turpentine oil obtained from sulphate pulp manufacture or the like |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE358050C (en) |
-
1917
- 1917-03-07 DE DEA29135D patent/DE358050C/en not_active Expired
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