DE3576436D1 - FUEL CELL. - Google Patents

FUEL CELL.

Info

Publication number
DE3576436D1
DE3576436D1 DE8585109997T DE3576436T DE3576436D1 DE 3576436 D1 DE3576436 D1 DE 3576436D1 DE 8585109997 T DE8585109997 T DE 8585109997T DE 3576436 T DE3576436 T DE 3576436T DE 3576436 D1 DE3576436 D1 DE 3576436D1
Authority
DE
Germany
Prior art keywords
anode
cathode
mineral acid
hydroxide
fuel cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE8585109997T
Other languages
German (de)
Inventor
Wolfgang Habermann
Ernst-Heinrich Dr Pommer
Peter Dr Hammes
Hubert Engelhardt
Wolfgang Geiger
Werner Dr Simmler
Guenther Huber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE8585109997T priority Critical patent/DE3576436D1/en
Application granted granted Critical
Publication of DE3576436D1 publication Critical patent/DE3576436D1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F1/46114Electrodes in particulate form or with conductive and/or non conductive particles between them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/96Carbon-based electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1009Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • C02F2001/46138Electrodes comprising a substrate and a coating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46152Electrodes characterised by the shape or form
    • C02F2001/46157Perforated or foraminous electrodes
    • C02F2001/46161Porous electrodes
    • C02F2001/46166Gas diffusion electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/36Organic compounds containing halogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Fuel Cell (AREA)
  • Inert Electrodes (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

In a fuel cell which has an activated carbon-containing anode and an activated carbon-containing cathode and is preferably used for the oxidative treatment of waste waters containing oxygen or oxygen-containing compounds, the cathode has been subjected to partial anodic oxidation in a mineral acid at a potential epsilon h of from +1.3 to +10V and then doped with molybdenum(VI) and/or tungsten(VI) and/or vanadium(V) compounds, and the anode has been subjected to partial anodic oxidation in an aqueous mineral acid, cathodically reduced in an aqueous mineral acid and then impregnated with cobalt hydroxide and/or nickel hydroxide and/or copper hydroxide and/or zinc hydroxide, the anode and the cathode being separated by a porous polyelectrolyte through which the waste water flows.
DE8585109997T 1984-08-18 1985-08-08 FUEL CELL. Expired - Lifetime DE3576436D1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE8585109997T DE3576436D1 (en) 1984-08-18 1985-08-08 FUEL CELL.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19843430485 DE3430485A1 (en) 1984-08-18 1984-08-18 FUEL CELL
DE8585109997T DE3576436D1 (en) 1984-08-18 1985-08-08 FUEL CELL.

Publications (1)

Publication Number Publication Date
DE3576436D1 true DE3576436D1 (en) 1990-04-12

Family

ID=6243394

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19843430485 Withdrawn DE3430485A1 (en) 1984-08-18 1984-08-18 FUEL CELL
DE8585109997T Expired - Lifetime DE3576436D1 (en) 1984-08-18 1985-08-08 FUEL CELL.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE19843430485 Withdrawn DE3430485A1 (en) 1984-08-18 1984-08-18 FUEL CELL

Country Status (5)

Country Link
US (1) US4670360A (en)
EP (1) EP0172505B1 (en)
AT (1) ATE50888T1 (en)
CA (1) CA1257646A (en)
DE (2) DE3430485A1 (en)

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US5217900A (en) * 1984-08-18 1993-06-08 Basf Aktiengesellschaft Biological reactor
DE69019229T2 (en) * 1989-05-19 1996-01-04 Sakai Chemical Industry Co Ozone splitting.
US5232882A (en) * 1989-05-19 1993-08-03 Sakai Chemical Industry Co., Ltd. Ozone decomposing reactor regeneration
EP0398765B1 (en) * 1989-05-19 1995-05-10 Sakai Chemical Industry Co., Ltd., Ozone decomposition
DE4031609A1 (en) * 1990-03-16 1991-09-19 Kodak Ag METHOD AND DEVICE FOR PROCESSING LIQUID RESIDUES FROM PHOTOGRAPHIC PROCESSES
NL9200989A (en) * 1992-06-04 1994-01-03 Eco Purification Syst METHOD AND APPARATUS FOR PURIFYING FLOWS
US5419816A (en) * 1993-10-27 1995-05-30 Halox Technologies Corporation Electrolytic process and apparatus for the controlled oxidation of inorganic and organic species in aqueous solutions
US6402916B1 (en) 1993-10-27 2002-06-11 Richard L. Sampson Electrolytic process and apparatus controlled regeneration of modified ion exchangers to purify aqueous solutions and adjust ph
US6024850A (en) 1993-10-27 2000-02-15 Halox Technologies Corporation Modified ion exchange materials
ES2080686B1 (en) * 1994-02-16 1996-10-16 S E De Carburos Metalicos S A ELECTROLYTIC DEPURATION PROCESS AND EQUIPMENT IN CONTAMINATED WASTEWATER USING OXYGEN CATODES.
US5614077A (en) * 1995-04-10 1997-03-25 Electro-Petroleum, Inc. Electrochemical system and method for the removal of charged species from contaminated liquid and solid wastes
DE19526609A1 (en) * 1995-07-21 1997-01-23 Siemens Ag Tubular assembly of electrodes and membrane forming fuel cell
DE19548743A1 (en) * 1995-12-23 1997-06-26 Frank Luecking Treatment of water contaminated with oxidisable, e.g. organic substances
EP0986832A1 (en) * 1997-05-14 2000-03-22 The Smart Chemical Company Limited Electrolytic reactor such as fuel cell with zeolite membrane
US6291090B1 (en) 1998-09-17 2001-09-18 Aer Energy Resources, Inc. Method for making metal-air electrode with water soluble catalyst precursors
US6153323A (en) * 1998-10-16 2000-11-28 Ballard Power Systems Inc. Electrode treatment method for improving performance in liquid feed fuel cells
DE10002733A1 (en) * 2000-01-22 2001-07-26 Bwt Privatstiftung Hintersee Electrolysis cell which can improve reaction efficiency, e.g., for chlorination of water, includes a porous electrode which allows communication between an electrolyte and a neutral area
GB0012095D0 (en) * 2000-05-19 2000-07-12 British Nuclear Fuels Plc Improvements in and relating to fuel cell constructions
GB0025661D0 (en) 2000-10-19 2000-12-06 British Nuclear Fuels Plc Improvements in and relating to fuel cells
WO2003027029A1 (en) * 2001-09-19 2003-04-03 Fluid Dynamics International Ltd. Method and apparatus for the destruction of dyes and other organic molecules
WO2004038839A1 (en) * 2002-10-22 2004-05-06 Lg Chem, Ltd. Sheet silicate mineral and fuel cell including intercalation complex thereof as solid electrolyte membrane
CN100561784C (en) * 2002-10-22 2009-11-18 Lg化学株式会社 Utilize the Proton Exchange Membrane Fuel Cells of the solid electrolyte film of layer silicate mineral and lamellar compound
US7097933B2 (en) 2003-06-09 2006-08-29 Ovonic Battery Company, Inc. Catalyst for fuel cell oxygen electrodes
US20060078782A1 (en) * 2004-10-07 2006-04-13 Martin Jerry L Single-pass, high fuel concentration, mixed-reactant fuel cell generator apparatus and method
DE102005013499A1 (en) * 2005-03-23 2006-10-05 Epcos Ag Gas filled discharge line
DE102008044845B4 (en) * 2008-08-28 2015-04-09 Epcos Ag Bias network
DE102009019737A1 (en) * 2009-05-02 2010-11-04 Dräger Safety AG & Co. KGaA A sorbent comprising an activated carbon impregnated with a zinc and a molybdenum compound and a gas-filtering element containing the sorbent
DE102015122486A1 (en) * 2015-12-22 2017-06-22 Coulomb Water Technology GmbH Electrode arrangement for an electrolytic cell
CN114931948B (en) * 2022-03-25 2023-04-07 山东大学 Potassium intercalation molybdenum oxide nano array material and preparation method and application thereof

Family Cites Families (16)

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DE747203C (en) * 1941-06-10 1944-09-15 Dr Kurt Schwabe Process for the electromotive combustion of alkali-soluble lignin-containing substances in elements
US3284332A (en) * 1961-05-29 1966-11-08 Exxon Research Engineering Co Fuel cell electrode
US3506493A (en) * 1964-08-05 1970-04-14 Electrochimica Corp Electrochemical cell having barrier with microporous openings
DE1571985A1 (en) * 1966-07-06 1971-02-25 Chemie Technik Gmbh Process for the anodic oxidation of sulfidic compounds
FR96366E (en) * 1967-12-26 1972-06-16 Gen Electric Improvements in electrodes for fuel cells, and fuel cells.
US3793173A (en) * 1969-02-03 1974-02-19 K Price Wastewater treatment using electrolysis with activated carbon cathode
BE794191A (en) * 1972-01-21 1973-05-16 Licentia Gmbh OXYGEN ELECTRODE WITH CHARCOAL CATALYST FOR ELECTROCHEMICAL BATTERIES WITH ACID ELECTROLYTE
US3915822A (en) * 1974-05-22 1975-10-28 Grace W R & Co Electrochemical system with bed sections having variable gradient
FR2316196A1 (en) * 1975-06-30 1977-01-28 Sorapec Electrochemical purification of industrial effluent - esp. from paper mills, by continuous anodic oxidation of organic pollutants
DE2713991C3 (en) * 1977-03-30 1980-06-04 Kernforschungsanlage Juelich Gmbh, 5170 Juelich Process for the oxidation of oxidizable pollutants contained in aqueous solution
JPS551818A (en) * 1978-06-19 1980-01-09 Hitachi Ltd Electrode catalyst
US4202934A (en) * 1978-07-03 1980-05-13 United Technologies Corporation Noble metal/vanadium alloy catalyst and method for making
US4472257A (en) * 1980-04-29 1984-09-18 Sklyarov Alexandr T Electrode for electrochemical processes and process for producing same
DE3023703A1 (en) * 1980-06-25 1982-01-21 Kernforschungsanlage Jülich GmbH, 5170 Jülich METHOD FOR THE OXIDATION OR REDUCTION OF SUBSTANCES IN AQUEOUS SOLUTION ON A CATALYST THAT IS ELECTROCHEMICALLY EFFECTIVE AND APPLIED ON POROESIC CARRIER MATERIAL, AS WELL AS THE CARRIER BODY FOR THE CATALYST AND METHOD FOR THE PRODUCTION OF THE PRODUCT THOUGHT
NL8006774A (en) * 1980-12-13 1982-07-01 Electrochem Energieconversie FUEL CELL ELECTRODE AND METHOD FOR PRODUCING A FUEL CELL ELECTRODE
US4445990A (en) * 1981-11-12 1984-05-01 General Electric Company Electrolytic reactor for cleaning wastewater

Also Published As

Publication number Publication date
EP0172505A3 (en) 1988-03-02
US4670360A (en) 1987-06-02
EP0172505A2 (en) 1986-02-26
CA1257646A (en) 1989-07-18
ATE50888T1 (en) 1990-03-15
EP0172505B1 (en) 1990-03-07
DE3430485A1 (en) 1986-02-27

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee