DE3334590A1 - Diffusion coated, wear-resistant components - Google Patents

Diffusion coated, wear-resistant components

Info

Publication number
DE3334590A1
DE3334590A1 DE19833334590 DE3334590A DE3334590A1 DE 3334590 A1 DE3334590 A1 DE 3334590A1 DE 19833334590 DE19833334590 DE 19833334590 DE 3334590 A DE3334590 A DE 3334590A DE 3334590 A1 DE3334590 A1 DE 3334590A1
Authority
DE
Germany
Prior art keywords
components
wear
layer
diffusion
coated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19833334590
Other languages
German (de)
Inventor
Bernd Gebes
Horst Kemnitz
Heinz Dr.-Ing. DDR Berlin Klaas
Margitta DDR 1422 Hennigsdorf Klein
Beate Dipl.-Chem DDR 1422 Hennigsdorf Morgenstern
Winfried Otto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FLORIN STAHL WALZWERK
Original Assignee
FLORIN STAHL WALZWERK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FLORIN STAHL WALZWERK filed Critical FLORIN STAHL WALZWERK
Publication of DE3334590A1 publication Critical patent/DE3334590A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/60Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
    • C23C8/62Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes only one element being applied
    • C23C8/68Boronising
    • C23C8/70Boronising of ferrous surfaces

Abstract

The invention relates to diffusion-coated, wear-resistant components which, as shaping tools, cutting tools, guiding devices and wearing parts, are subjected to high mechanical stresses and should reach a relatively long service life. In addition to an extension of service life, a purpose of the invention is the reuse of these components. The object is to provide a boride layer which permits mechanical working of the components, both for reaching the required accuracy of shape and dimensions, and the reprocessing or regeneration of these components for the next dimensional group. According to the invention, the base body has a diffusion layer which consists of a homogeneous single-phase boride layer having a minimum layer thickness of 320 mu m.

Description

titel der Erfindungtitle of the invention

Diffusionsbeschichtete, verschleißfeste Bauteile Anwendungsgebiet der Erfindung Die Erfindung betrifft diffusionsbeschichtete, verschleißfeste Bauteile, die als Umformwerkzeuge, Schnittwerkzeuge, 1?ührungseinrichtungen und Verschleißteile hohen mechanischen Beanspruchungen ausgesetzt sind und eine relativ lange Lebensdauer erreichen sollen. Diese Bauteile können überall dort eingesetzt werden, wo Stahl- oder Eisenwerkstoffe solchen Verschleißmechanismen wie Adhäsion, Tribooxidation oder Abrasion unterworfen sind. Auch beim Verschleiß durch Oberflächenzerrütung können unter Umständen positive Ergebnisse beim Einsatz solcher beschichteten Bauteile erreicht werden.Diffusion-coated, wear-resistant components Area of application of the invention The invention relates to diffusion-coated, wear-resistant components, as forming tools, cutting tools, guide devices and wear parts are exposed to high mechanical loads and have a relatively long service life should achieve. These components can be used wherever steel or ferrous materials such wear mechanisms as adhesion, tribo-oxidation or are subject to abrasion. Also in the case of wear due to surface disruption may possibly have positive results when using such coated components can be achieved.

Charakteristik der benannten technischen Lösungen Es sind eine Reihe von Borierverfahren bekannt, mit aenen mittels fester, flüssiger oder gasförmiger, borabgebender Komponenton auf Bauteilen aus Eisen oder Stahl Boridschichten aufgebracht werden können. Diese Boridschichten bestehen vorwiegend aus Zweiphasen, nämlich der T'ieB und Fe2B-Phase, wobei sich diese Zweiphasigkeit nachteilig auf das Verschleißverhalten der aufgebrachten Boridschichten auswirkt.Characteristics of the named technical solutions There are a number of them known from boriding processes, with aenes by means of solid, liquid or gaseous, Boron-releasing component clay applied to components made of iron or steel Boride layers can be. These boride layers exist mainly from two phases, namely the T'ieB and Fe2B phase, this two-phase being disadvantageous the wear behavior of the applied boride layers.

Denn hierbei entstehen zwischen den beiden Phasen Spannungen, die zu Rissen und Abplatzungen führen0 Mit diesem Borierverfahren wurden bisher Schichtdicken bis erreicht , wobei besonders bei dickeren Boridschichten die Gefahr der Abplatzungen aufgrund der Zweiphasigkeit zunimmt.Because this creates tensions between the two phases lead to cracks and flaking0 With this boriding process, layer thicknesses until reached, with the risk of flaking off, especially with thicker boride layers increases due to the two-phase nature.

Zur Vermeidung dieser Mängel sind Pulverborierverfahren bekannt bei denen einphasige Boridschichten erzeugt werden können9 die darauf beruhen9 das zur Reaktion vorhandene Borpotential durch Zusatz nichtreaktionsfähiger Füllstoffe, wie z. B. Siliziumcarbid, Tonerde bzw. reaktionsfähiger Stoffe, z. B. Fe-Oxid zu reduzieren. Jedoch können auch mit diesen Mitteln einphasige Boridschichten nur mit Schichtdicken bis 320 µm erzeugt werden.To avoid these deficiencies, powder borating processes are known from which single-phase boride layers can be produced9 which are based on9 the for Reaction existing boron potential due to the addition of non-reactive fillers, such as B. silicon carbide, alumina or reactive substances such. B. Fe oxide too to reduce. However, single-phase boride layers can only be used with these means can be produced with layer thicknesses of up to 320 µm.

Ein Nachteil ist hierbei darin zu sehen, daß die geringen Schichtdicken nachfolgend keinen Fertigschleifprozeß zur Erhöhung der Maßgenauigkeit erlaubt Ziel der Erfindung Die Erfindung bezweckt die Nachteile der nach bekannten Verfahren borierten Bauteile zu vermeiden und neben der Standzeiterhöhung eine Wiederverwendung dieser Bauteile zu erreichen Darlegung des Wesens der Erfindung Der Erfindung liegt die Aufgabe zugrunde9 diffusionabeschichtete, verschleißfeste Bauteile mit einer Boridschicht bereitzustellen. die eine mechanische Bearbeitung der Bauteile, sowohl zur Erreichung der geforderten Form- und Maßgenauigkeit als auch die Aufarbeitung bzw. Regenerierung dieser Bauteile für die nächsten Abmessungsgruppen zuläßt.A disadvantage here is that the thin layers subsequently no finish grinding process to increase the dimensional accuracy allowed target of the invention The invention aims at the disadvantages of the known methods Avoid boronized components and, in addition to increasing the service life, reuse them to achieve these components Explain the essence of the invention The invention lies the task is based on 9 diffusion-coated, wear-resistant components with a Provide boride layer. mechanical processing of the components, both to achieve the required form and dimensional accuracy as well as the processing or regeneration of these components for the next dimension groups.

Erfindungsgemäß wird diese Aufgabe dadurch gelöst, daß der Grundkörper eine Diffusionsschicht aufweist, die aus einer homogenen, einphasigen Boridschicht mit einer Mindestschichtdicke von 320K" m besteht.According to the invention this object is achieved in that the base body has a diffusion layer, which consists of a homogeneous, single-phase boride layer with a minimum layer thickness of 320K "m.

Ausführungsbeispiel Die Erfindung soll anhand von drei Ausführungsbeispielen näher erläutert werden.Exemplary embodiment The invention is intended to be based on three exemplary embodiments are explained in more detail.

1. Werkstoff des Grundkörpers: Stahl C 45 Glühdauer: 100 Stunden Glühtemperatur: 950 °C tuftabkühlung: Erreichte Schichtdicke: 620 Schichtanalyse: Homogenes Fe2B 2. Werkstoff des Grundkörpers: Stahl C 45 Glühdauer: 500 Stunden Glühtemperatur: 950 °C Luftabkühlung: Erreichte Schichtdicke: 1890 µm Schichtanalyse: Homogenes Fe2B 3. Werkstoff des Grundkörpers: Stahl C 45 Glühdauer: 100 Stunden Glühtemperatur: 1050 °C LuStabkühlung: Erreichte Schichtdicke: 1200 µ m Schichtanalyse: Homogenes Fe2B Für die vorstehend dargestellten Ausführungsbeispiele wurde ein Boriermittel, bestehend aus Borcarbid, Borax, Kaliumtetrafluoroborat, Eisenoxid und mineralischen Zuschlägen verwendet.1. Material of the base body: Steel C 45 Annealing duration: 100 hours Annealing temperature: 950 ° C tuft cooling: Achieved layer thickness: 620 Layer analysis: Homogeneous Fe2B 2. Material of the base body: Steel C 45 Annealing duration: 500 hours Annealing temperature: 950 ° C air cooling: Achieved layer thickness: 1890 µm Layer analysis: Homogeneous Fe2B 3. Material of the base body: Steel C 45 Annealing duration: 100 hours Annealing temperature: 1050 ° C Lu rod cooling: Achieved layer thickness: 1200 µm Layer analysis: Homogeneous Fe2B For the embodiments shown above, a boriding agent was used, consisting of boron carbide, borax, potassium tetrafluoroborate, iron oxide and mineral Supplements used.

Ebenso können auch Boriermittel mit anderen Schwermetalloxidzusätzen wie beispielsweise Chromoxid, verwendet werden.Boriding agents with other heavy metal oxide additives can also be used such as chromium oxide can be used.

Claims (1)

Erfindungsanspruch 1. Diffusionsbeschichtete, verschleißfeste Bauteile, dadurch gekennzeichnet, daß der Grundkörper eine Diffusionsschicht aufweist, die aus einer homogenen einphasigen Fe2B-Boridschicht mit einer Mindestschichtdicke von 320 µm besteht.Invention claim 1. Diffusion-coated, wear-resistant components, characterized in that the base body has a diffusion layer which from a homogeneous single-phase Fe2B boride layer with a minimum layer thickness of 320 µm.
DE19833334590 1983-02-23 1983-09-24 Diffusion coated, wear-resistant components Withdrawn DE3334590A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DD24818283A DD213695A1 (en) 1983-02-23 1983-02-23 DIFFUSION-COATED, WEAR-RESISTANT COMPONENTS

Publications (1)

Publication Number Publication Date
DE3334590A1 true DE3334590A1 (en) 1984-10-11

Family

ID=5545126

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19833334590 Withdrawn DE3334590A1 (en) 1983-02-23 1983-09-24 Diffusion coated, wear-resistant components

Country Status (2)

Country Link
DD (1) DD213695A1 (en)
DE (1) DE3334590A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2600551A1 (en) * 1986-06-26 1987-12-31 Ahlstroem Oy Wear-resistant perforated sheet, especially for filter screens and drums

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2600551A1 (en) * 1986-06-26 1987-12-31 Ahlstroem Oy Wear-resistant perforated sheet, especially for filter screens and drums

Also Published As

Publication number Publication date
DD213695A1 (en) 1984-09-19

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