DE3262517D1 - Process for producing ethyl acetate by homologation of methyl acetate - Google Patents

Process for producing ethyl acetate by homologation of methyl acetate

Info

Publication number
DE3262517D1
DE3262517D1 DE8282830082T DE3262517T DE3262517D1 DE 3262517 D1 DE3262517 D1 DE 3262517D1 DE 8282830082 T DE8282830082 T DE 8282830082T DE 3262517 T DE3262517 T DE 3262517T DE 3262517 D1 DE3262517 D1 DE 3262517D1
Authority
DE
Germany
Prior art keywords
homologation
ethyl acetate
producing ethyl
acetate
methyl acetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8282830082T
Other languages
German (de)
English (en)
Inventor
Giuseppe Braca
Glauco Sbrana
Giorgio Valentini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consiglio Nazionale delle Richerche
Original Assignee
Consiglio Nazionale delle Richerche
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consiglio Nazionale delle Richerche filed Critical Consiglio Nazionale delle Richerche
Application granted granted Critical
Publication of DE3262517D1 publication Critical patent/DE3262517D1/de
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE8282830082T 1981-04-06 1982-04-05 Process for producing ethyl acetate by homologation of methyl acetate Expired DE3262517D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT20954/81A IT1144698B (it) 1981-04-06 1981-04-06 Processo di produzione all'acetato di etile mediante omologazione dell'acetato di metile

Publications (1)

Publication Number Publication Date
DE3262517D1 true DE3262517D1 (en) 1985-04-18

Family

ID=11174564

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8282830082T Expired DE3262517D1 (en) 1981-04-06 1982-04-05 Process for producing ethyl acetate by homologation of methyl acetate

Country Status (5)

Country Link
EP (1) EP0063105B1 (enExample)
JP (1) JPS57176927A (enExample)
AT (1) ATE12095T1 (enExample)
DE (1) DE3262517D1 (enExample)
IT (1) IT1144698B (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1161942B (it) * 1983-06-15 1987-03-18 Consiglio Nazionale Ricerche Processo per la produzione di acetato di etile per omologazione di acetato di metile
DE3413021A1 (de) * 1984-04-06 1985-10-17 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von carbonsaeureethylestern
JPH02257798A (ja) * 1989-03-29 1990-10-18 Matsushita Electric Ind Co Ltd スピーカシステム内蔵型テレビセット

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE426583B (sv) * 1975-03-10 1983-01-31 Halcon Res & Dev Sett att framstella etylidenacetat
NL7708158A (nl) * 1976-07-28 1978-01-31 Montedison Spa Werkwijze ter bereiding van esters.
JPS5538369A (en) * 1978-09-01 1980-03-17 Texaco Development Corp Manufacture of carboxylic acids and their esters
WO1981000856A1 (en) * 1979-10-01 1981-04-02 Texaco Development Corp Production of carboxylic acids and their esters
DE3064657D1 (en) * 1979-12-21 1983-09-29 Shell Int Research Process for the co-production of carboxylic acids and carboxylic acid esters
US4265828A (en) * 1979-12-31 1981-05-05 Texaco Development Corp. Manufacture of ethylene glycol from synthesis gas

Also Published As

Publication number Publication date
IT1144698B (it) 1986-10-29
JPS57176927A (en) 1982-10-30
IT8120954A0 (it) 1981-04-06
JPS645587B2 (enExample) 1989-01-31
ATE12095T1 (de) 1985-03-15
EP0063105B1 (en) 1985-03-13
EP0063105A1 (en) 1982-10-20

Similar Documents

Publication Publication Date Title
ZA801509B (en) Process for producing hydrogen from synthesis gas containing c.o.s.
AU525478B2 (en) Process for the manufacture of oxygen-containing carbon compounds from synthesis gas
GB2016702B (en) Process for producing solid electrolyte oxygen gas sensor
IL52043A (en) Process for the exchange of hydrogen isotopesusing a catalyst bed assembly
EP0144506A3 (en) Catalyst for the production of synthesis gas or of hydrogen, and process for its production
DE3270812D1 (en) Catalysts for the production of alcohols from olefins and synthesis gas and process employing such catalysts
ATE86959T1 (de) Verfahren zur herstellung von alkoholen (einstufig).
ZA807592B (en) Process for producing methanol from synthesis gas with palladiumcalcium catalysts
DE2960788D1 (en) Process for preparing acetaldehyde
JPS5625128A (en) Manufacture of acetoaldehyde
DE3467569D1 (en) Catalytic process for the production of alcohols from carbon monoxide, hydrogen and olefins
GB2106511B (en) Process for preparing oxygen-containing organic compounds from synthesis gas
JPS57176927A (en) Manufacture of ethyl acetate by homologation of methyl acetate
ES8201518A1 (es) Un procedimiento de preparacion de etilenglicol
AU9116382A (en) Production of acetic anhydride, acetic acid, ethylidene diacetate
NZ221464A (en) Manufacture of 1,3-glycols
DE2861439D1 (en) Process for the production of acetaldehyde by the reaction of methanol with synthesis gas
AU7331487A (en) Process and apparatus for the production of gas containing hydrogen and carbon monoxide from solid fuel
EP0034292A3 (en) Process for the preparation of anthranilic acid derivatives
GB2036975B (en) Process for producing a solid electrolyte oxygen gas sensor element
AU9032982A (en) Acetic acid and anhydride from acetate, ether, carbon monoxide, hydrogen
GB2099844B (en) Process for producing synthesis gas
ES8202845A1 (es) Procedimiento para formar compuestos de aminas secundarias
ZA791566B (en) Process for the manufacture of oxygen-containing carbon compounds from synthesis gas
EP0079592A3 (en) Catalyst stabilization

Legal Events

Date Code Title Description
8339 Ceased/non-payment of the annual fee