DE3245140C1 - Construction material for underground mining - Google Patents
Construction material for underground miningInfo
- Publication number
- DE3245140C1 DE3245140C1 DE3245140A DE3245140A DE3245140C1 DE 3245140 C1 DE3245140 C1 DE 3245140C1 DE 3245140 A DE3245140 A DE 3245140A DE 3245140 A DE3245140 A DE 3245140A DE 3245140 C1 DE3245140 C1 DE 3245140C1
- Authority
- DE
- Germany
- Prior art keywords
- building material
- gypsum
- underground mining
- cement
- flue gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005065 mining Methods 0.000 title claims description 4
- 239000004035 construction material Substances 0.000 title 1
- 239000004566 building material Substances 0.000 claims description 16
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 239000004568 cement Substances 0.000 claims description 10
- 239000010440 gypsum Substances 0.000 claims description 10
- 229910052602 gypsum Inorganic materials 0.000 claims description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 8
- 239000003546 flue gas Substances 0.000 claims description 8
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 2
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 2
- 239000010881 fly ash Substances 0.000 claims description 2
- 239000004571 lime Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims 1
- 229910052925 anhydrite Inorganic materials 0.000 description 4
- 239000002956 ash Substances 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000012717 electrostatic precipitator Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- ZHZFKLKREFECML-UHFFFAOYSA-L calcium;sulfate;hydrate Chemical compound O.[Ca+2].[O-]S([O-])(=O)=O ZHZFKLKREFECML-UHFFFAOYSA-L 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 239000000021 stimulant Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
- C04B18/062—Purification products of smoke, fume or exhaust-gases
- C04B18/064—Gypsum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Ceramic Engineering (AREA)
- Combustion & Propulsion (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Description
- 40 bis 50 Gew.-* Naturanhydrit in der Körnung < 20 mm- 40 to 50 wt .- * natural anhydrite in the grain size <20 mm
- 20 bis 30 Gew.-% Rauchgasentschwefelungsgips - 20 to 30% by weight of flue gas desulphurisation gypsum
- 25 bis 35 Gew.-* suifatresisienier Zement- 25 to 35 wt .- * suifatresisienier cement
- < 1,5 Qtw.-% CaCI,- <1.5 Qtw .-% CaCI,
3. Baumaterial nach Anspruch 1, gekennzeichnet durch folgende Zusammensetzung:3. Building material according to claim 1, characterized by the following composition:
- 10 bis 20 Gew.-* Naturanhydrit einer Körnung < 20 mm- 10 to 20 wt .- * natural anhydrite with a grain size <20 mm
- 5 bis 15 Gew.-* Rauchgasentschwefelungsgips- 5 to 15 wt .- * flue gas desulphurisation gypsum
- 55 bis 70 Gew.-* Elektrofilterasche- 55 to 70 wt .- * electrostatic precipitator ash
-8 bis 14 Gew.-* Tonerdeschmelzzement
-< 1.5 Gew.-% CaCb-8 to 14 wt .- * high-alumina cement
- <1.5% by weight CaCb
Die Erfindung bezieht sich auf ein Baumaterial für den untertägigen Bergbau, insbesondere zur Herstellung von Streckenbegleitdämmen und Ausbaupfeilern, welches ais Hauptbestandteile aus auf Kalkbasis betriebenen Rauchgasentschwefelungsanlagen stammenden Gips, Zement und ggf. Flugasche enthält, wobei Gips als Kalzlunisulfatdlhydrat (CaSO4 χ 2HjO) eingesetzt wird, gemäß Patent 32 19 197.The invention relates to a building material for underground mining, in particular for the production of roadside embankments and expansion pillars, which contains gypsum, cement and possibly fly ash originating from lime-based flue gas desulphurisation systems as the main components, with gypsum being used as calcium sulphate hydrate (CaSO 4 χ 2HjO) , according to patent 32 19 197.
Die In dem Hauptpatent beschriebene Baumaterialmischung ist relativ feinkörnig. Dies führt bei der Verarbeitung im Untertagebereich zu unerwünschten, die Arbeitsbedingungen verschlechternden Staubbildungen. Hinzu kommt, daß bei langen Blasstrecken Verstopfungen In den Rohrleitungen auftreten können.The building material mixture described in the main patent is relatively fine-grained. When processing in underground areas, this leads to undesired Dust formation worsening working conditions. In addition, blockages occur in the case of long blow lines Can occur in the pipelines.
Es sind Baumaterialien für den untertägigen Bergbau bekannt, die auch Anhydrit enthalten. In diesen Baumaterialien dient der aus Dlhyclrat gebrannte Anhydrit im wesentlichen als Bindemittel. d. h. es muß einen hohen Feinkornanteil aufweisen, was wiederum zu Staubbildung bei der Handhabung soleher Baumaterialien führt.There are known building materials for underground mining that also contain anhydrite. In these In building materials, the anhydrite burnt from Dlhyclrate is used essentially as a binding agent. d. H. it must have a high proportion of fine grains, which in turn leads to dust formation when handling such building materials leads.
Aufgabe der vorliegenden Erfindung ist es daher, das In dem Hauptpatent beschriebene Baumaterial im Hinblick auf eine günstigere Handhabung der zu verarbeitenden Baumaterialmischung zu verbessern.The object of the present invention is therefore to provide the building material described in the main patent in the With regard to a more favorable handling of the to be processed Improve building material mix.
Diese Aufgabe wird erflndungsgemüß dadurch gelöst, daß der Mischung als weitere Komponente bis zu 50According to the invention, this object is achieved by that the mixture as a further component up to 50
25 Gew.-* Naturanhydrit in einer Körnung von < 20 mm zugegeben ist. 25 wt .- * natural anhydrite in a grain size of <20 mm is added.
Es hat sich gezeigt, daß durch den erfindungsgemäßen Zusatz von Naturanhydrit zu den in dem Hauptpatent vorgeschlagenen Baumaterialmischungen die Staubentwicklung erheblich reduziert wird, da infolge der Grobkörnigkeit des Anhydrits der Feinkornanteil der Mischung insgesamt verringert wird. Als Bindemittel dient in erster Linie der in den erfindungsgemäßen Mischungen enthaltene Zement.It has been shown that the addition of natural anhydrite according to the invention to those in the main patent proposed building material mixtures, the dust is significantly reduced, as a result the coarse grain of the anhydrite, the fine grain fraction of the mixture is reduced overall. As a binder The cement contained in the mixtures according to the invention is primarily used.
Darüber hinaus werden durch die Wirkung des Anhydrits als Fegekorn Verstopfungen von Blasleitungen weitgehend vermieden.In addition, the effect of the anhydrite as a sweeping grain blocks blowpipes largely avoided.
Es hat sich weiterhin gezeigt, daß im Gegensatz zu mit sauren Anregern versetztem Naturannydrit, der für sich betrachtet oberhalb einer Temperatur von ca. 30° C nicht mehr genügend aushärtet, das erfindungsgemäße Baumaterial sich auch bei den in Frage \ommenden hohen Gebirgstemperaturen bis etwa 60° C genügend schnell verfestigt und die erreichte Endfestigkeit auch beibehält.It has also been shown that in contrast to acidic stimulants added natural anhydrite, which for considered no longer cures sufficiently above a temperature of approx. 30 ° C, the inventive Building material is sufficient even at the high mountain temperatures in question, up to around 60 ° C solidifies quickly and also maintains the final strength achieved.
Im folgenden sind zwei besonders vorteilhafte Rezepturen des erfindungsgemäßen Baumaterials dargestellt:The following are two particularly beneficial recipes of the building material according to the invention:
45 Gew.-* Naturanhydrit mit einer Körnung < 20 mm 25 Gew.-% Dihydrat aus der Rauchgasentschwefelung
mit 2,5 bis 5 Gew.-* CaCI2
30 Gew.-* sulfatresistenter Zement45 wt .- * natural anhydrite with a grain size <20 mm 25 wt .-% dihydrate from flue gas desulphurisation with 2.5 to 5 wt .- * CaCl 2
30 wt .- * sulphate-resistant cement
Ein solches Baumaterial, bei dem relativ großeSuch a building material, which is relatively large
Mengen Rauchgasentschwefelungsgips verarbeitet sind, entwickelt bei einem Wasser-Feststoffwert von 0,193 nach 24 Stunden Standzelt bei 25° C eine Druckfestlg-Quantities of flue gas desulphurisation gypsum are processed, developed at a water solids value of 0.193 after 24 hours of standing tent at 25 ° C a pressure-resistant
keit von 146 daN/cm2 und bei 40° C von 200 daN/cm2.speed of 146 daN / cm 2 and at 40 ° C of 200 daN / cm 2 .
14 Gew.-* Naturanhydrit mit einer Körnung < 20 mm 9 Gew.-* Rauchgasentschwefelungsgips mit 2,5 bis 514 wt .- * natural anhydrite with a grain size <20 mm 9 wt .- * flue gas desulphurisation gypsum with 2.5 to 5
Gew.-* CaCl2 Weight * CaCl 2
65 Gew.-* Elektrofilterasche
12 Gew.-* Tonerdeschmelzzement65 wt .- * electrostatic precipitator ash
12 wt .- * high alumina cement
Dieses Baumaterial, bei dem zusätzlich große Mengen Elektrofilterasche verwendet sind, entwickelt bei einem Wasser-Feststoffwert von 0,174 nach 6 Stunden Standzelt bei 25° C eine Druckfestigkeit von 84 daN/cm2. und nach 24 Stunden von 100 daN/cm2. Auch hler verbessern erhöhte Temperaturen die i-estigkeitswerte.This building material, which also uses large amounts of electrostatic precipitator ash, develops a compressive strength of 84 daN / cm 2 after 6 hours of standing tent at 25 ° C with a water solids value of 0.174. and after 24 hours from 100 daN / cm 2 . Increased temperatures also improve the strength values.
Es liegt auf der Hand, daß je nach den gestellten Anforderungen auch andere Mischungsverhältnisse
möglich sind.
Als Zemente eignen sich Im Grunde alle derzeit auf dem Markt befindlichen Zementarten, wobei auch hler
entsprechend der Zementqualität der Anteil an der Mischung schwanken kann.It is obvious that other mixing ratios are also possible depending on the requirements.
Basically all types of cement currently on the market are suitable as cements, although the proportion of the mixture may vary depending on the quality of the cement.
Ein ganz wesentlicher Vorteil der erfindungsgemäßen Baumaterialmischungen ist auch darin zu sehen, daß der Rauchgasentschwefelungsgips lediglich getrocknet werden muß. Ein Pelletisieren bzw. Kontaktieren des Gipses, wie es in der DE-OS 31 09 632 offenbart Ist, ist vor dessen Verarbeitung nicht erforderlich. Hierdurch können erhebliche Kosten eingespart werden.A very important advantage of the building material mixtures according to the invention is also to be seen in the fact that the flue gas desulphurisation gypsum only has to be dried. Pelletizing or contacting the Gypsum, as it is disclosed in DE-OS 31 09 632, is not required before processing. This can save considerable costs.
Claims (2)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3245140A DE3245140C1 (en) | 1982-12-07 | 1982-12-07 | Construction material for underground mining |
FR8308408A FR2527107A1 (en) | 1982-05-21 | 1983-05-20 | Utilisation of gypsum plaster from gas desulphurisation - by mixing with other cement and mfr. of pit props and barrages |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3245140A DE3245140C1 (en) | 1982-12-07 | 1982-12-07 | Construction material for underground mining |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3245140C1 true DE3245140C1 (en) | 1984-07-19 |
Family
ID=6179954
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE3245140A Expired DE3245140C1 (en) | 1982-05-21 | 1982-12-07 | Construction material for underground mining |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE3245140C1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3612931A1 (en) * | 1986-04-17 | 1987-10-22 | Hoelter Heinz | Mining mortar from waste dirt of coal extraction |
DE3827612A1 (en) * | 1988-08-13 | 1990-02-15 | Viktor Dr Ing Gobiet | Building material for use in underground operation |
DE102006040712A1 (en) * | 2006-08-30 | 2008-03-20 | Agn Rohstoffverwertung Gmbh | Ground consolidation mixture for e.g. road- and building foundations and other civil engineering works, includes fly ash, gypsum, quicklime or plaster and cement |
CN104045297A (en) * | 2013-03-14 | 2014-09-17 | 浙江天达环保股份有限公司 | Fly ash type plastering gypsum |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2833382A1 (en) * | 1978-07-29 | 1980-02-07 | Saarbergwerke Ag | METHOD FOR RECYCLING THE Gypsum generated in flue gas desulphurization plants that are operated on lime-based |
DE3104001A1 (en) * | 1980-02-08 | 1981-12-17 | Canon K.K., Tokyo | Electromagnetically driven shutter |
DE3109879A1 (en) * | 1981-03-14 | 1982-09-23 | Hölter, Heinz, Dipl.-Ing., 4390 Gladbeck | Process for disposing of waste products inevitably formed downstream of coal-fired power stations and their utilisation with use of waste heat from the power station for production of preferably dam building materials for underground mining |
-
1982
- 1982-12-07 DE DE3245140A patent/DE3245140C1/en not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2833382A1 (en) * | 1978-07-29 | 1980-02-07 | Saarbergwerke Ag | METHOD FOR RECYCLING THE Gypsum generated in flue gas desulphurization plants that are operated on lime-based |
DE3104001A1 (en) * | 1980-02-08 | 1981-12-17 | Canon K.K., Tokyo | Electromagnetically driven shutter |
DE3109879A1 (en) * | 1981-03-14 | 1982-09-23 | Hölter, Heinz, Dipl.-Ing., 4390 Gladbeck | Process for disposing of waste products inevitably formed downstream of coal-fired power stations and their utilisation with use of waste heat from the power station for production of preferably dam building materials for underground mining |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3612931A1 (en) * | 1986-04-17 | 1987-10-22 | Hoelter Heinz | Mining mortar from waste dirt of coal extraction |
DE3827612A1 (en) * | 1988-08-13 | 1990-02-15 | Viktor Dr Ing Gobiet | Building material for use in underground operation |
DE102006040712A1 (en) * | 2006-08-30 | 2008-03-20 | Agn Rohstoffverwertung Gmbh | Ground consolidation mixture for e.g. road- and building foundations and other civil engineering works, includes fly ash, gypsum, quicklime or plaster and cement |
CN104045297A (en) * | 2013-03-14 | 2014-09-17 | 浙江天达环保股份有限公司 | Fly ash type plastering gypsum |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8100 | Publication of the examined application without publication of unexamined application | ||
AF | Is addition to no. |
Ref country code: DE Ref document number: 3219197 Format of ref document f/p: P |
|
D1 | Grant (no unexamined application published) patent law 81 | ||
8363 | Opposition against the patent | ||
8378 | Instruction for suspension has been quashed | ||
8362 | Rights of main patent transferred to additional patent | ||
8330 | Complete disclaimer |