DE3229558C2 - Impregnation casting compound for electrical components - Google Patents

Impregnation casting compound for electrical components

Info

Publication number
DE3229558C2
DE3229558C2 DE19823229558 DE3229558A DE3229558C2 DE 3229558 C2 DE3229558 C2 DE 3229558C2 DE 19823229558 DE19823229558 DE 19823229558 DE 3229558 A DE3229558 A DE 3229558A DE 3229558 C2 DE3229558 C2 DE 3229558C2
Authority
DE
Germany
Prior art keywords
potting
filler
viscosity
hardener
accelerator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE19823229558
Other languages
German (de)
Other versions
DE3229558A1 (en
Inventor
Irene 7057 Winnenden Jennrich
Kristian Dipl.-Ing.(FH) 7151 Burgstetten Leo
Werner Dipl.-Ing. 7012 Fellbach Pfander
Wolfgang 7000 Stuttgart Scholz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
Original Assignee
Robert Bosch GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Robert Bosch GmbH filed Critical Robert Bosch GmbH
Priority to DE19823229558 priority Critical patent/DE3229558C2/en
Publication of DE3229558A1 publication Critical patent/DE3229558A1/en
Application granted granted Critical
Publication of DE3229558C2 publication Critical patent/DE3229558C2/en
Expired legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/40Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • C08G59/226Mixtures of di-epoxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32Epoxy compounds containing three or more epoxy groups
    • C08G59/38Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)

Abstract

Es wird eine aushärtbare Vergußmasse vorgeschlagen, die dem Imprägnieren und Vergießen elektrischer Bauteile dient und aus einem Harz, einem Härter, einem Beschleuniger und einem Füllstoff besteht. Als Harz wird ein Epoxid auf Basis Bisphenol A und Cycloaliphat mit einer Viskosität < 5000 mPas bei 25 ° C, als Härter ein modifiziertes Dicarbonsäureanhydrid, als Beschleuniger ein Imidazol und als Füllstoff Kreide eingesetzt. Der Füllstoff ist vorzugsweise in einer Menge von mehr als 53 Gew.-%, bezogen auf die Gesamtmasse, enthalten. Die vorgeschlagene Vergußmasse weist eine niedrige Viskosität auf, so daß sich Imprägnieren und Vergießen in einem einzigen Arbeitsgang durchführen lassen. Der thermische Ausdehnungskoeffizient sowie der Volumenschwund sind kleiner als bei im Handel erhältlichen Massen und die Vergußmasse weist einen hohen Glasübergangspunkt auf, was zu einer hohen Wärme- und Temperaturwechselbeständigkeit der Masse führt. wird der Kunstpenis mit den Gefühlssonden in die Scheide eingeführt, um das glA hardenable potting compound is proposed which is used for impregnating and potting electrical components and consists of a resin, a hardener, an accelerator and a filler. An epoxy based on bisphenol A and cycloaliphatic with a viscosity of <5000 mPas at 25 ° C is used as the resin, a modified dicarboxylic acid anhydride as the hardener, an imidazole as the accelerator and chalk as the filler. The filler is preferably contained in an amount of more than 53% by weight, based on the total mass. The proposed potting compound has a low viscosity, so that impregnation and potting can be carried out in a single operation. The coefficient of thermal expansion and the volume shrinkage are smaller than in the case of commercially available compounds and the potting compound has a high glass transition point, which leads to a high resistance to heat and temperature changes in the compound. the artificial penis with the sensory probes is inserted into the vagina to remove the gl

Description

6060

Verwendet wird ein Epoxidharz auf Basis Bisphenol A und einem Cycloolefln Im Verhältnis 70:30 Gew.-Tellen, das bei 25'C eine Viskosität kleiner als 5000 mPa · s hat. Dazu wird ein modifiziertes Dlcarbonsäureanhydrld, z. B. Phialsäureanhydrld als Härter, sowie ein Imidazol, z. B. Pyrazol als Beschleuniger und Kreide alsAn epoxy resin based on bisphenol is used A and a cycloolefin in a ratio of 70:30 parts by weight, which at 25 ° C has a viscosity of less than 5000 mPa · s has. For this purpose, a modified carboxylic acid anhydride is used, z. B. Phialsäureanhydrld as a hardener, and an imidazole, z. B. pyrazole as an accelerator and chalk as

Claims (1)

Patentanspruch:Claim: Imprägniervergußmasfür elektrische Bauteile, die aus einem Harz, einem Härter, einem Beschleuniger und einem Füllstoff besteht, dadurch gekennzeichnet, daß als Harz ein Epoxid auf Basis Bisphenol A und Cycloolefln Im Verhältnis 70:30 Gewichtsteile mit einer Viskosität < 5000 mPa · s bei 25° C, als Härter ein modifiziertes Dicarbonsäure- anhydrld, als Beschleuniger ein Imidazol und als Füllstoff Kreide In einer Menge von 53 bis 60 Gew.-%, bezogen auf die Gesamtmasse, eingesetzt wird und Harz, Härter und Beschleuniger ein Verhältnis vqnJOO: 100:0,5 Gew.-Tellen aufweisen. Imprägniervergußmas -ä for electrical components, which consists of a resin, a hardener, an accelerator and a filler, characterized in that an epoxy based on bisphenol A and cycloolefin in a ratio of 70:30 parts by weight with a viscosity <5000 mPas at 25 ° C, a modified dicarboxylic acid anhydride as a hardener, an imidazole as an accelerator and chalk as a filler in an amount of 53 to 60% by weight, based on the total mass, and resin, hardener and accelerator a ratio of 100: 100: 0.5 parts by weight. 1010 1515th Füllstoff zugegeben, wobei Harz, Härter und Beschleuniger im Verhältnis 100:100:0,5 Gew.-Telle eingesetzt weiden und der Füllstoff In einer Menge von 55 Gew.-%, bezogen auf die Gesamtmischung, zugegeben wird. Das Ganze wird gut gemischt und stellt dann eine niedrigviskose Masse dar. Zum Imprägnieren und Vergießen einer Hochspannungs-Zündspule wird zunächst die Lagenwicklung getrocknet, die Scheibenwicklung auf eine Temperatur von etwa 100° C temperiert, der Vorratsbehälter, in welchem sich die Vergußmasse befindet, evakuiert, um die Vergußmasse zu entgasen, und schließlich das Imprägnieren und Vergießen unter Vakuum vorgenommen. Nach dem Entformen wird die Vergußmasse schließlich gehärtet, und zwar zunächst l'/i Stunden bei 90°C und dann nochmals 2 Stunden bei 120° C.Filler added, resin, hardener and accelerator being used in a ratio of 100: 100: 0.5 parts by weight Weiden and the filler in an amount of 55 wt .-%, based on the total mixture, added will. The whole thing is mixed well and then makes a low-viscosity mass. To impregnate and cast a high-voltage ignition coil, first the layer winding dried, the disc winding heated to a temperature of about 100 ° C, the Storage container in which the potting compound is located, evacuated in order to degas the potting compound, and finally the impregnation and potting are carried out under vacuum. After demolding, the Sealing compound finally hardened, initially for an hour and a half at 90 ° C. and then for another 2 hours at 120 ° C. Bei dieser beschriebenen Imprägnler-Vergußmasse ergeben sich die folgenden Eigenschaften:In the case of this impregnator potting compound described the following properties result: Die Erfindung geht aus von einer Vergußmasse nach der Gattung des Hauptanspruchs. Käufliche derartige Vergußmassen, mit denen elektrische Bauteile umgös sen werden, um sie vor mechanischen Einwirkungen zu schützen, und die aus einem härtbaren Harz bestehen, zeigen bei einer Aushärtung zwei Stunden bei 80°C 2s und anschließend zwei Stunden bei 120° C einen verhältnismäßig niedrigen Glasübergangspunkt von 80° C, verhältnismäßig hohe lineare thermische Ausdehnungskoeffizienten zwischen 44 und 129.10"6 1/° C bei 50 bzw. oberhalb 900C sowie einen Volumenschwund, der mit 2,2% auch verhältnismäßig groß 1st. Schließlich weisen diese Harze mit mehr als 10 000 mPa · s bei 25" C eine verhältnismäßig hohe Viskosität auf, was zu Vergußmassen führt, mit der einwandfreie Imprägnierungen, beispielsweise von elektrischen Spulen, nur schwer möglich sind. Auch Ist bei diesen käuflichen Vergußmassen die Temperaturwechselbeständigkeit, beispielsweise für eine Anwendung bei Hochspannungs-Zündspulen im Kraftfahrzeug, nicht ausreichend, was mit dem niedrigen Glasübergangspunkt, wie er oben genannt ist, zusammenhängt. The invention is based on a casting compound according to the preamble of the main claim. Commercially available potting compounds of this type, with which electrical components are umgös sen to protect them from mechanical effects, and which consist of a curable resin, show a relatively low cure for two hours at 80 ° C. and then for two hours at 120 ° C. glass transition point of 80 ° C, relatively high linear thermal expansion coefficient between 44 and 129.10 "6 1 / ° C at 50 or above 90 0 C, and a volume shrinkage, the 2.2% also relatively 1st large. Finally, these resins have with more than 10,000 mPa · s at 25 "C has a relatively high viscosity, which leads to casting compounds with which perfect impregnations, for example of electrical coils, are difficult to achieve. In the case of these commercially available casting compounds, the resistance to temperature changes, for example for use in high-voltage ignition coils in motor vehicles, is also not sufficient, which is related to the low glass transition point, as mentioned above. Vorteile der ErfindungAdvantages of the invention Die erfindungsgemaße Imprägniervergußmasse mit den kennzeichnenden Merkmalen des Hauptanspruchs hat demgegenüber den Vorteil, daß sie eine niedrige Viskosität, einen kleinen thermischen Ausdehnungskoeffizienten, einen hohen GlasUbergangspunkt sowie tine hohe Temperaturwechselbeständlgkelt und Wärmebeständigkelt aufweist; so sind Hochspannungs-Zündspulen, die mit dieser erfindungsgemäßen Vergußmasse imprägniert und ve;gössen sind, zwischen mindestens -40° C und mindestens 120° C temperaturwechselbeständlg und elektrisch funktionsfähig bei Temperaturen In der Wicklung von mehr als 100° C. Durch die geringe Viskosität wird es ermöglicht, derartige elektrische Bauteile in einem Arbeltsgang zu imprägnieren und zu umhüllen.The impregnation potting compound according to the invention with the characterizing features of the main claim has the advantage that it has a low Viscosity, a small coefficient of thermal expansion, a high glass transition point as well tine has high thermal shock resistance and heat resistance; so are high voltage ignition coils, impregnated with this sealing compound according to the invention and poured, between at least -40 ° C and at least 120 ° C resistant to temperature changes and electrically functional at temperatures in the winding of more than 100 ° C. Due to the low viscosity makes it possible to impregnate such electrical components in one operation and to envelop. Beschreibung eines AusführungsbelsplelsDescription of an implementation area Viskosität 25° CViscosity 25 ° C < 10000 mPa· s<10000 mPas 60° C60 ° C < 1 000 mPa · s<1,000 mPas GlasübergangspunktGlass transition point ca. 140° Capprox. 140 ° C VolumenschwundVolume loss 1,5%1.5% Linearer therm.Linear therm. AusdehnungskoeffizientExpansion coefficient bis 110° Cup to 110 ° C 38· 10-« 1/°C38 x 10- «1 / ° C 110 bis 130° C110 to 130 ° C 57· ΙΟ"6 1/°C57 · ΙΟ " 6 1 / ° C >130°C> 130 ° C 115· ΙΟ"6 1/°C115 · ΙΟ " 6 1 / ° C
Die auf die beschriebene Welse Imprägnierten und vergossenen Zündspulen weisen eine Temperaturwechselbeständigkeit von mindestens -40° C bis mindestens 120° C auf und sind elektrisch funktionsfähig bei Temperaturen in der Wicklung von mehr als 100° C.The impregnated on the catfish described and Cast ignition coils are resistant to temperature changes from at least -40 ° C to at least 120 ° C and are electrically functional at Temperatures in the winding of more than 100 ° C.
DE19823229558 1982-08-07 1982-08-07 Impregnation casting compound for electrical components Expired DE3229558C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19823229558 DE3229558C2 (en) 1982-08-07 1982-08-07 Impregnation casting compound for electrical components

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19823229558 DE3229558C2 (en) 1982-08-07 1982-08-07 Impregnation casting compound for electrical components

Publications (2)

Publication Number Publication Date
DE3229558A1 DE3229558A1 (en) 1984-02-09
DE3229558C2 true DE3229558C2 (en) 1984-11-08

Family

ID=6170398

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19823229558 Expired DE3229558C2 (en) 1982-08-07 1982-08-07 Impregnation casting compound for electrical components

Country Status (1)

Country Link
DE (1) DE3229558C2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0668012B2 (en) * 1987-09-15 1994-08-31 インターナショナル・ビジネス・マシーンズ・コーポレーション Encapsulating composition and electronic device using the composition
US5189080A (en) * 1989-04-25 1993-02-23 Robert Bosch Gmbh Epoxy resin composition for encapsulating electric circuit components
DE4138411C2 (en) * 1991-11-22 1995-01-26 Bosch Gmbh Robert Curing potting compounds
HU220297B (en) * 1994-07-01 2001-11-28 Robert Bosch Gmbh. Epoxy resin casting composition
DE19523897C2 (en) * 1995-06-30 2002-10-24 Bosch Gmbh Robert Use of silicone-modified epoxy resins as casting compounds for electrotechnical or electronic components
US6001902A (en) * 1996-03-27 1999-12-14 Ciba Specialty Chemicals Corp. Wollastonite-containing curable epoxy resin mixture
EP0984463B1 (en) 1997-05-23 2003-03-19 Hitachi, Ltd. Ignition coil unit for engine and engine provided with plastic head cover

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NICHTS-ERMITTELT

Also Published As

Publication number Publication date
DE3229558A1 (en) 1984-02-09

Similar Documents

Publication Publication Date Title
EP0129819B1 (en) Method of impregnating and enveloping electrical coils
DE2428816A1 (en) ELECTRIC HIGH VOLTAGE COMPONENT WITH A MULTIPLE NUMBER OF EACH OTHER HIGH VOLTAGE STRUCTURE CONNECTED BY AT LEAST ONE PREPREG
DE3229558C2 (en) Impregnation casting compound for electrical components
DE2655367C2 (en) Heat-curing reaction resin mixture for the impregnation of insulation in electrical devices and for the production of molded materials with or without inserts
DE2142571B1 (en) INSULATING TAPE FOR THE PRODUCTION OF AN INSULATING SLEEVE FOR ELECTRIC CONDUCTORS IMPREGNATED WITH A HEAT-CURING EPOXY RESIN-ACID ANHYDRIDE HARDER MIXTURE
CH261736A (en) Method of manufacturing a dry-type transformer.
DE2354087A1 (en) OIL-FILLED ELECTRICAL APPLIANCE AND METHOD FOR MANUFACTURING IT
DE1032351B (en) Conductor insulation made from a cast resin based on epoxy resin, especially for winding insulation in electrical machines
EP0658527B1 (en) Process for making a castable ceramic
DE3234544C2 (en) Electrical component with a thermoset insulating layer and method for insulating this component
DE2514107A1 (en) IGNITION COIL FOR COMBUSTION ENGINES, ENCLOSED IN INSULATING RESIN
DE1540133A1 (en) Use of an insulating material composed of two strips for the production of winding insulation, in particular of high-voltage coils
DE4001968C2 (en) Method for producing an ignition coil for ignition systems of internal combustion engines, in particular for motor vehicles
DE3137898A1 (en) Epoxy resin composition for the embedding of components of automobile electronics
DE1171038B (en) Group of electrical components that is embedded in a casting compound block, possibly surrounded by a metallic housing
DE2230645B2 (en) Process for impregnating one or more electrical coils with a curable resin
DE1595404A1 (en) Process for the production of mechanically stressed construction elements from glass fiber reinforced epoxy resins
DE1263928B (en) Process for impregnating and encapsulating electrical coils
DE1490529C3 (en) Process for the production of electrical high-voltage insulators from cast resin
DE1514231A1 (en) Electrical winding encased with thermosetting insulating compound, in particular high-voltage winding for voltage converters, and method for producing such a winding
SU149818A1 (en) The method of obtaining the electrically insulating compound
DE1162901B (en) Implementation for high voltage and process for their production
AT205237B (en) Method for producing a synthetic resin combination
DE2409979C3 (en) Lubricant for wires with enamel insulation
DE1540455A1 (en) Wet wound insulation, especially for high voltage and methods of its manufacture

Legal Events

Date Code Title Description
OP8 Request for examination as to paragraph 44 patent law
D2 Grant after examination
8364 No opposition during term of opposition
8320 Willingness to grant licences declared (paragraph 23)
8339 Ceased/non-payment of the annual fee