DE307163C - - Google Patents
Info
- Publication number
- DE307163C DE307163C DENDAT307163D DE307163DA DE307163C DE 307163 C DE307163 C DE 307163C DE NDAT307163 D DENDAT307163 D DE NDAT307163D DE 307163D A DE307163D A DE 307163DA DE 307163 C DE307163 C DE 307163C
- Authority
- DE
- Germany
- Prior art keywords
- oxydiazobenzene
- oxynaphthalene
- derivatives
- sulfonic acid
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000975 dye Substances 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 125000000449 nitro group Chemical class [O-][N+](*)=O 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims 1
- 238000006011 modification reaction Methods 0.000 claims 1
- 210000002268 Wool Anatomy 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000008049 diazo compounds Chemical class 0.000 description 2
- VLZVIIYRNMWPSN-UHFFFAOYSA-N 2-Amino-4-nitrophenol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1O VLZVIIYRNMWPSN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- QXYMVUZOGFVPGH-UHFFFAOYSA-N Picramic acid Chemical compound NC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O QXYMVUZOGFVPGH-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 230000001808 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- XKUUMWKWUZRRPD-UHFFFAOYSA-N heptan-2-amine;sulfuric acid Chemical compound [O-]S([O-])(=O)=O.CCCCCC(C)[NH3+].CCCCCC(C)[NH3+] XKUUMWKWUZRRPD-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/14—Monoazo compounds
- C09B45/16—Monoazo compounds containing chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
In dem Patent 307162 wurde ein Verfahren zur Herstellung von o-Oxyazofarbstoffen beschrieben, darin bestehend, daß man HaIogenderivate des 2-Oxydiazobenzols mit einer 8-Halogen-i-oxynaphthalin-5-sulfosäure kuppelt. In the patent 307162 a method for the preparation of o-oxyazo dyes, consisting in that one Halogenderivate of 2-oxydiazobenzene is coupled with an 8-halo-i-oxynaphthalene-5-sulfonic acid.
Es wurde nun gefunden, daß man zu einer neuen Reihe wertvoller Farbstoffe für das Echtfärben der Wolle gelangt, wenn man im ίο Verfahren des. Hauptpatents die Halogenderivate des 2-Oxydiazobenzols durch Nitro- oder Nitrohalogenderivate des 2-Oxydiazobenzols ersetzt.It has now been found that a new series of valuable dyes for the Real dyeing of the wool is achieved if the halogen derivatives are used in the ίο process of the main patent of 2-oxydiazobenzene by nitro or nitrohalogen derivatives of 2-oxydiazobenzene replaced.
15,4 Teile 4-Nitro-2-aminophenol werden in der üblichen Weise in Gegenwart von Salzsäure mit Natriumnitrit diazotiert. Die Diazoverbindung vereinigt man mit einer durch Soda alkalisch gehaltenen Lösung von 26 Teilen S-Chlor-i-oxynaphthalin-S-sulfosäure. Nach beendeter Kuppelung salzt man den Farbstoff aus und arbeitet ihn wie üblich auf. Er färbt Wolle aus saurem Bade bordeauxrot; der Chromlack ist schwarz.15.4 parts of 4-nitro-2-aminophenol are in the usual manner in the presence of Hydrochloric acid diazotized with sodium nitrite. The diazo compound is combined with one solution of 26 parts of S-chloro-i-oxynaphthalene-S-sulfonic acid kept alkaline by soda. After the coupling is complete, the dye is salted out and worked as usual on. He dyes wool from acid baths claret-red; the chrome paint is black.
19,9 Teile 4,6-Dinitro-2-aminophenol werden in die Diazoverbindung übergeführt und diese wird dann mit 26 Teilen 8-Chlor-i-oxynaphthalin-5-sulfosäure in sodaalkalischer Lösung vereinigt. Der Farbstoff färbt Wolle aus saurem Bade bläulich korinth; die in Ge- genwart von Chromat und Ammonsulfat hergestellte Färbung ist gedeckt grün.19.9 parts of 4,6-dinitro-2-aminophenol are converted into the diazo compound and this is then mixed with 26 parts of 8-chloro-i-oxynaphthalene-5-sulfonic acid combined in soda-alkaline solution. The dye dyes wool from acid baths bluish corinthian; those in the present The coloration produced by chromate and ammonium sulphate is opaque green.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE307163C true DE307163C (en) |
Family
ID=560519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT307163D Active DE307163C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE307163C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE913458C (en) * | 1951-02-06 | 1954-06-14 | Ciba Geigy | Process for the production of complex chromium compounds of monoazo dyes |
-
0
- DE DENDAT307163D patent/DE307163C/de active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE913458C (en) * | 1951-02-06 | 1954-06-14 | Ciba Geigy | Process for the production of complex chromium compounds of monoazo dyes |
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