DE3063622D1 - Oxidation catalysts and process for the preparation of methacrolein by vapour phase oxidation - Google Patents

Oxidation catalysts and process for the preparation of methacrolein by vapour phase oxidation

Info

Publication number
DE3063622D1
DE3063622D1 DE8080303546T DE3063622T DE3063622D1 DE 3063622 D1 DE3063622 D1 DE 3063622D1 DE 8080303546 T DE8080303546 T DE 8080303546T DE 3063622 T DE3063622 T DE 3063622T DE 3063622 D1 DE3063622 D1 DE 3063622D1
Authority
DE
Germany
Prior art keywords
oxidation
methacrolein
preparation
vapour phase
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8080303546T
Other languages
English (en)
Inventor
Lawrence Samuel Kirch
William James Kennelly
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Application granted granted Critical
Publication of DE3063622D1 publication Critical patent/DE3063622D1/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE8080303546T 1979-10-12 1980-10-09 Oxidation catalysts and process for the preparation of methacrolein by vapour phase oxidation Expired DE3063622D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/084,254 US4280928A (en) 1979-10-12 1979-10-12 Catalyst compositions and their use for the preparation of methacrolein

Publications (1)

Publication Number Publication Date
DE3063622D1 true DE3063622D1 (en) 1983-07-07

Family

ID=22183785

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8080303546T Expired DE3063622D1 (en) 1979-10-12 1980-10-09 Oxidation catalysts and process for the preparation of methacrolein by vapour phase oxidation

Country Status (6)

Country Link
US (1) US4280928A (de)
EP (1) EP0027351B1 (de)
JP (1) JPS5695339A (de)
CA (1) CA1128918A (de)
DE (1) DE3063622D1 (de)
ES (1) ES8201117A1 (de)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
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JPS5715842A (en) * 1980-06-30 1982-01-27 Nitto Chem Ind Co Ltd Manufacture of highly active fluid catalyst from coarse grained catalyst
DE3030243A1 (de) * 1980-08-09 1982-03-18 Basf Ag, 6700 Ludwigshafen Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein
US4347163A (en) * 1980-10-03 1982-08-31 Standard Oil Company Te-containing methacrolein oxidation catalysts and their use
JPS57130548A (en) * 1981-02-05 1982-08-13 Mitsubishi Chem Ind Ltd Catalyst composition
JPS5811041A (ja) * 1981-07-13 1983-01-21 Nitto Chem Ind Co Ltd アンチモン含有金属酸化物触媒の製法
US4537874A (en) * 1982-10-22 1985-08-27 Nippon Shokubai Kagaku Kogyo Co Ltd Catalyst for production of unsaturated aldehydes
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
US4568596A (en) * 1984-07-18 1986-02-04 Hercules Incorporated Nonwoven fabric
JP2720215B2 (ja) * 1989-10-25 1998-03-04 三菱レイヨン株式会社 メタクリル酸製造用触媒の調整法
US7501377B2 (en) 2003-03-31 2009-03-10 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7232788B2 (en) * 2003-03-31 2007-06-19 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
CN100342968C (zh) 2003-12-03 2007-10-17 三菱化学株式会社 生产不饱和醛和不饱和羧酸的催化剂以及此催化剂的制备方法
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
EP3023148B1 (de) * 2014-06-10 2020-04-22 LG Chem, Ltd. Verfahren zur herstellung eines mehrteiligen verbundmetalloxidkatalysators
DE102018200841A1 (de) * 2018-01-19 2019-07-25 Basf Se Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3313856A (en) * 1967-04-11 Preparation of acrolein or methacrolein
DE1125901B (de) * 1959-12-19 1962-03-22 Knapsack Ag Verfahren zur Herstellung von Acrolein
US3238254A (en) * 1961-02-20 1966-03-01 Petro Tex Chem Corp Oxidation of alpha, beta unsaturated aldehydes in the presence of a catalyst containing v, p, cu and o
FR1426166A (fr) * 1964-09-14 1966-01-28 Aquitaine Petrole Catalyseur d'oxydation d'hydrocarbures oléfiniques
FR1425301A (fr) * 1964-09-15 1966-01-24 Aquitaine Petrole Catalyseur perfectionné pour l'oxydation d'hydrocarbures
NL6512930A (de) * 1964-10-06 1966-04-07
NL135123C (de) * 1964-10-06
BE672279A (de) * 1964-11-13
US3471556A (en) * 1964-12-07 1969-10-07 Nippon Kayaku Kk Production of unsaturated aliphatic acids
GB1156544A (en) * 1966-10-01 1969-06-25 Shorrock Dev Improvements in or relating to a Message Transmission Apparatus
US3959384A (en) * 1969-05-02 1976-05-25 Nippon Kayaku Kabushiki Kaisha Oxidation catalyst and process for oxidation of olefins to unsaturated aldehydes
BE757476A (fr) * 1969-10-17 1971-03-16 Nippon Kayaku Kk Procede d'oxydeshydrogenation
CA939676A (en) * 1970-03-24 1974-01-08 David Naden Catalytic oxidation
JPS494441B1 (de) * 1970-11-07 1974-02-01
JPS4852713A (de) * 1971-10-29 1973-07-24
US3925464A (en) * 1971-12-14 1975-12-09 Asahi Glass Co Ltd Process for preparing unsaturated carboxylic acids from the corresponding unsaturated aldehydes
US3966802A (en) * 1972-03-09 1976-06-29 Nippon Kayaku Kabushiki Kaisha Process for preparing acrylic acid and oxidation catalyst
GB1456752A (en) * 1973-05-10 1976-11-24 Japan Synthetic Rubber Co Ltd Catalyst and process for the production of unsaturated carbonyl compounds
US3972920A (en) * 1973-06-11 1976-08-03 Mitsubishi Rayon Co., Ltd. Process for producing unsaturated aldehydes, unsaturated fatty acids or conjugated dienes
US4111984A (en) * 1973-06-11 1978-09-05 Mitsubishi Rayon Co., Ltd. Process for producing unsaturated aldehydes, and unsaturated fatty acids
US3875220A (en) * 1973-10-11 1975-04-01 Standard Oil Co Ohio Process for the preparation of methacrylic acid from methacrolein
US3932551A (en) * 1973-10-12 1976-01-13 The Standard Oil Company Process for the preparation of diolefins from olefins
US4111983A (en) * 1973-10-18 1978-09-05 Union Carbide Corporation Oxidation of unsaturated aldehydes to unsaturated acids
US4075244A (en) * 1973-11-22 1978-02-21 Nippon Zeon Co. Ltd. Process for preparing methacrylic acid
US3976688A (en) * 1973-11-26 1976-08-24 Nippon Zeon Co., Ltd. Process for preparing unsaturated carboxylic acids
IT1001978B (it) * 1973-11-28 1976-04-30 Sir Soc Italiana Resine Spa Procedimento per la produzione di metilacrilato o di miscele di que sto con acido acrilico
IT1045704B (it) * 1973-11-28 1980-06-10 Sir Soc Italiana Resine Spa Perfezionamenti nel procedimento di preparazione dell acido acrilico
IT1001977B (it) * 1973-11-28 1976-04-30 Sir Soc Italiana Resine Spa Procedimento per la preparazione di acrilato di metile o di miscele di acrilato di metile ed acido acri lico
US4083804A (en) * 1974-02-09 1978-04-11 Nitto Chemical Industry Co., Ltd. Catalyst for use in and process for preparing acrylonitrile
US3956377A (en) * 1974-06-17 1976-05-11 The Standard Oil Company (Ohio) Production of unsaturated acids from the corresponding aldehydes
US4162234A (en) * 1974-07-22 1979-07-24 The Standard Oil Company Oxidation catalysts
JPS5242552B2 (de) * 1974-08-01 1977-10-25
US4124634A (en) * 1974-10-23 1978-11-07 Asahi Glass Company, Ltd. Process for producing methacrylic acid from isobutylene by two step oxidation
JPS5341648B2 (de) * 1974-12-06 1978-11-06
GB1490683A (en) * 1975-03-12 1977-11-02 Mitsubishi Rayon Co Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene
US4111985A (en) * 1975-03-12 1978-09-05 Mitsubishi Rayon Co., Ltd. Process for producing unsaturated aldehydes and unsaturated carboxylic acids
JPS51115414A (en) * 1975-04-03 1976-10-12 Mitsubishi Rayon Co Ltd Process for preparation of unsaturated fatty acids
US4136110A (en) * 1975-08-18 1979-01-23 The Standard Oil Company Process for the preparation of unsaturated acids from unsaturated aldehydes
US4051180A (en) * 1976-01-02 1977-09-27 The Standard Oil Company Preparation of acrylic acid and methacrylic acid
US4052332A (en) * 1976-04-20 1977-10-04 E. I. Du Pont De Nemours And Company Catalyst regeneration with impregnation of bismuth and molybdenum
US4335264A (en) * 1976-07-07 1982-06-15 E. I. Du Pont De Nemours And Company High yield, low byproduct α, β-unsaturated aldehydes from olefins
US4065507A (en) * 1976-08-02 1977-12-27 Standard Oil Company Preparation of methacrylic derivatives from tertiary butyl-containing compounds
JPS5319188A (en) * 1976-08-06 1978-02-22 Nippon Zeon Co Ltd Olefin oxidation catalyst
DE2735414A1 (de) * 1976-08-06 1978-02-09 Nippon Zeon Co Oxydation von olefinen
US4110369A (en) * 1976-10-19 1978-08-29 The Standard Oil Company Process for the preparation of unsaturated acids from unsaturated aldehydes
US4148758A (en) * 1977-08-23 1979-04-10 Exxon Research & Engineering Co. Reforming with multimetallic catalysts

Also Published As

Publication number Publication date
US4280928A (en) 1981-07-28
EP0027351B1 (de) 1983-06-01
CA1128918A (en) 1982-08-03
EP0027351A1 (de) 1981-04-22
JPS5695339A (en) 1981-08-01
JPH0149542B2 (de) 1989-10-25
ES495892A0 (es) 1981-12-01
ES8201117A1 (es) 1981-12-01

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Legal Events

Date Code Title Description
8339 Ceased/non-payment of the annual fee