DE3023121C2 - Verfahren zum Reduzieren von teilchenförmigen Metallerzen - Google Patents
Verfahren zum Reduzieren von teilchenförmigen MetallerzenInfo
- Publication number
- DE3023121C2 DE3023121C2 DE3023121A DE3023121A DE3023121C2 DE 3023121 C2 DE3023121 C2 DE 3023121C2 DE 3023121 A DE3023121 A DE 3023121A DE 3023121 A DE3023121 A DE 3023121A DE 3023121 C2 DE3023121 C2 DE 3023121C2
- Authority
- DE
- Germany
- Prior art keywords
- gas
- cooling
- loop
- zone
- reaction vessel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 20
- 229910052751 metal Inorganic materials 0.000 title description 4
- 239000002184 metal Substances 0.000 title description 4
- 239000007789 gas Substances 0.000 claims description 133
- 238000001816 cooling Methods 0.000 claims description 83
- 238000006243 chemical reaction Methods 0.000 claims description 42
- 239000000112 cooling gas Substances 0.000 claims description 29
- 230000005484 gravity Effects 0.000 claims description 27
- 230000001105 regulatory effect Effects 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 230000001276 controlling effect Effects 0.000 claims description 5
- 239000003507 refrigerant Substances 0.000 claims description 3
- 239000002923 metal particle Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 68
- 238000006722 reduction reaction Methods 0.000 description 36
- 229910052742 iron Inorganic materials 0.000 description 34
- 239000000203 mixture Substances 0.000 description 16
- 238000005255 carburizing Methods 0.000 description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 229910001567 cementite Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000001465 metallisation Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0073—Selection or treatment of the reducing gases
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0086—Conditioning, transformation of reduced iron ores
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
- C21B13/029—Introducing coolant gas in the shaft furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
- C21B2100/44—Removing particles, e.g. by scrubbing, dedusting
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
- C21B2100/64—Controlling the physical properties of the gas, e.g. pressure or temperature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Manufacture Of Iron (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/067,665 US4224057A (en) | 1979-08-20 | 1979-08-20 | Method for carburizing sponge iron |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3023121A1 DE3023121A1 (de) | 1981-03-26 |
| DE3023121C2 true DE3023121C2 (de) | 1985-06-13 |
Family
ID=22077547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3023121A Expired DE3023121C2 (de) | 1979-08-20 | 1980-06-20 | Verfahren zum Reduzieren von teilchenförmigen Metallerzen |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US4224057A (show.php) |
| JP (1) | JPS5818962B2 (show.php) |
| BR (1) | BR8003887A (show.php) |
| CA (1) | CA1149176A (show.php) |
| DD (1) | DD151768A5 (show.php) |
| DE (1) | DE3023121C2 (show.php) |
| EG (1) | EG14430A (show.php) |
| ES (1) | ES8105396A1 (show.php) |
| FR (1) | FR2463815A1 (show.php) |
| GB (1) | GB2058139A (show.php) |
| GR (1) | GR69632B (show.php) |
| IN (1) | IN152563B (show.php) |
| IT (1) | IT1143923B (show.php) |
| MA (1) | MA18865A1 (show.php) |
| MX (1) | MX155373A (show.php) |
| SE (1) | SE8004625L (show.php) |
| SU (1) | SU963475A3 (show.php) |
| ZA (1) | ZA803033B (show.php) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2084610B (en) * | 1980-09-29 | 1983-10-12 | Woods Jack L | Anodic oxidation of aluminium and aluminum alloys |
| US4584016A (en) * | 1982-03-23 | 1986-04-22 | Hylsa, S.A. | Method for controlling metallization and carburization in the reduction of metal ores to sponge iron |
| DE3317701C2 (de) * | 1983-05-16 | 1986-08-07 | Hylsa S.A., Monterrey, N.L. | Verfahren zum Betreiben eines Bewegtbett-Reduktionsreaktors mit vertikalem Schacht zum Reduzieren von Eisenerz zu Schwammeisen |
| US4528030A (en) * | 1983-05-16 | 1985-07-09 | Hylsa, S.A. | Method of reducing iron ore |
| DE3437913C2 (de) * | 1984-10-12 | 1987-05-07 | Korf Engineering GmbH, 4000 Düsseldorf | Verfahren und Vorrichtung zur Herstellung von Eisenschwamm und/oder flüssigem Roheisen |
| US4897113A (en) * | 1985-09-23 | 1990-01-30 | Hylsa, S.A. | Direct reduction process in reactor with hot discharge |
| US4734128A (en) * | 1985-09-23 | 1988-03-29 | Hylsa, S.A. | Direct reduction reactor with hot discharge |
| US4752329A (en) * | 1986-03-21 | 1988-06-21 | Midrex International B.V. Rotterdam, Zurich Branch | Apparatus and method for increasing carbon content of hot directly reduced iron |
| US4702766A (en) * | 1986-03-21 | 1987-10-27 | Midrex International, B.V. Rotterdam, Zurich Branch | Method of increasing carbon content of direct reduced iron and apparatus |
| AT402938B (de) * | 1994-06-23 | 1997-09-25 | Voest Alpine Ind Anlagen | Verfahren und anlage zur direktreduktion von verfahren und anlage zur direktreduktion von eisenoxidhältigem material eisenoxidhältigem material |
| CN1995402B (zh) * | 2006-01-06 | 2011-11-16 | 伊尔技术有限公司 | 利用焦炉气等将氧化铁直接还原成金属铁的方法 |
| US10508314B2 (en) | 2015-06-24 | 2019-12-17 | Midrex Technologies, Inc. | Methods and systems for increasing the carbon content of sponge iron in a reduction furnace |
| US10316376B2 (en) | 2015-06-24 | 2019-06-11 | Midrex Technologies, Inc. | Methods and systems for increasing the carbon content of sponge iron in a reduction furnace |
| JP2017082312A (ja) * | 2015-10-30 | 2017-05-18 | 株式会社神戸製鋼所 | 還元鉄の製造方法 |
| DE102019217631B4 (de) * | 2019-11-15 | 2024-05-29 | Thyssenkrupp Steel Europe Ag | Verfahren zur Direktreduktion von Eisenerz |
| US12084730B2 (en) | 2020-03-24 | 2024-09-10 | Midrex Technologies, Inc. | Methods and systems for increasing the carbon content of direct reduced iron in a reduction furnace |
| DE102021122351A1 (de) * | 2021-08-30 | 2023-03-02 | Thyssenkrupp Steel Europe Ag | Verfahren zur Herstellung einer Eisenschmelze |
| CN114622155B (zh) * | 2021-11-01 | 2023-06-30 | 杭州永磁集团有限公司 | 一种钐铁氮粉体的真空渗氮方法 |
| IT202300020244A1 (it) | 2023-10-02 | 2025-04-02 | Piergiorgio Luigi Fontana | Processo di riduzione di minerale di ferro alimentato con idrogeno |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA508951A (en) * | 1955-01-11 | D. Pike Robert | Direct production of steel from oxides of iron | |
| US2873183A (en) * | 1954-07-07 | 1959-02-10 | Kenneth B Ray And The St Trust | Continuous iron ore reduction process |
| US3136624A (en) * | 1961-05-24 | 1964-06-09 | Pullman Inc | Method for reducing metal oxides |
| DE1201377B (de) * | 1961-11-23 | 1965-09-23 | Huettenwerk Oberhausen Ag | Verfahren und Anlage zur Herstellung von Eisen-schwamm aus Eisenerz in einem Reduktions-schacht mittels Reduktionsgas |
| US3375098A (en) * | 1964-07-22 | 1968-03-26 | Armco Steel Corp | Gaseous reduction of iron ores |
| US3369888A (en) * | 1965-06-01 | 1968-02-20 | Armco Steel Corp | Treatment and reduction of pelletized iron ores |
| US3551138A (en) * | 1968-03-14 | 1970-12-29 | Exxon Research Engineering Co | Iron ore reduction process |
| US3782920A (en) * | 1970-04-29 | 1974-01-01 | Dravo Corp | Process for direct reduction of iron oxide compacts |
| GB1347785A (en) * | 1970-07-15 | 1974-02-27 | Fierro Esponja | Method of reducing particulate metal ores |
| US3765872A (en) * | 1970-12-16 | 1973-10-16 | Fierro Esponja | Method and apparatus for the gaseous reduction of iron ore to sponge iron |
| US3748120A (en) * | 1971-04-15 | 1973-07-24 | Midland Ross Corp | Method of and apparatus for reducing iron oxide to metallic iron |
| US4046557A (en) * | 1975-09-08 | 1977-09-06 | Midrex Corporation | Method for producing metallic iron particles |
| US4049440A (en) * | 1975-05-19 | 1977-09-20 | Midrex Corporation | Method for producing metallic iron pellets |
| US4054444A (en) * | 1975-09-22 | 1977-10-18 | Midrex Corporation | Method for controlling the carbon content of directly reduced iron |
| US4150972A (en) * | 1977-11-17 | 1979-04-24 | Fierro Esponja, S.A. | Controlling carburization in the reduction of iron ore to sponge iron |
-
1979
- 1979-08-20 US US06/067,665 patent/US4224057A/en not_active Expired - Lifetime
-
1980
- 1980-05-21 ZA ZA00803033A patent/ZA803033B/xx unknown
- 1980-05-22 GB GB8016882A patent/GB2058139A/en active Granted
- 1980-05-27 FR FR8011714A patent/FR2463815A1/fr active Granted
- 1980-05-28 GR GR62068A patent/GR69632B/el unknown
- 1980-05-29 CA CA000352976A patent/CA1149176A/en not_active Expired
- 1980-05-30 MX MX182576A patent/MX155373A/es unknown
- 1980-06-02 MA MA19063A patent/MA18865A1/fr unknown
- 1980-06-06 IN IN675/CAL/80A patent/IN152563B/en unknown
- 1980-06-20 IT IT49026/80A patent/IT1143923B/it active
- 1980-06-20 DE DE3023121A patent/DE3023121C2/de not_active Expired
- 1980-06-23 BR BR8003887A patent/BR8003887A/pt unknown
- 1980-06-23 JP JP55085051A patent/JPS5818962B2/ja not_active Expired
- 1980-06-23 SU SU802937832A patent/SU963475A3/ru active
- 1980-06-23 SE SE8004625A patent/SE8004625L/ not_active Application Discontinuation
- 1980-06-24 DD DD80222095A patent/DD151768A5/de unknown
- 1980-06-25 ES ES492768A patent/ES8105396A1/es not_active Expired
- 1980-06-28 EG EG384/80A patent/EG14430A/xx active
Also Published As
| Publication number | Publication date |
|---|---|
| IT1143923B (it) | 1986-10-29 |
| CA1149176A (en) | 1983-07-05 |
| GB2058139B (show.php) | 1900-01-01 |
| SE8004625L (sv) | 1981-02-21 |
| ZA803033B (en) | 1981-05-27 |
| EG14430A (en) | 1984-06-30 |
| IN152563B (show.php) | 1984-02-11 |
| ES492768A0 (es) | 1981-05-16 |
| ES8105396A1 (es) | 1981-05-16 |
| DE3023121A1 (de) | 1981-03-26 |
| FR2463815B1 (show.php) | 1985-03-29 |
| DD151768A5 (de) | 1981-11-04 |
| US4224057A (en) | 1980-09-23 |
| MA18865A1 (fr) | 1980-12-31 |
| FR2463815A1 (fr) | 1981-02-27 |
| IT8049026A0 (it) | 1980-06-20 |
| GR69632B (show.php) | 1982-07-06 |
| MX155373A (es) | 1988-02-24 |
| BR8003887A (pt) | 1981-04-22 |
| JPS5629610A (en) | 1981-03-25 |
| JPS5818962B2 (ja) | 1983-04-15 |
| GB2058139A (en) | 1981-04-08 |
| SU963475A3 (ru) | 1982-09-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| 8125 | Change of the main classification | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |