DE298320C - - Google Patents
Info
- Publication number
- DE298320C DE298320C DENDAT298320D DE298320DA DE298320C DE 298320 C DE298320 C DE 298320C DE NDAT298320 D DENDAT298320 D DE NDAT298320D DE 298320D A DE298320D A DE 298320DA DE 298320 C DE298320 C DE 298320C
- Authority
- DE
- Germany
- Prior art keywords
- phosphoric acid
- peroxides
- hydrogen peroxide
- acid
- full
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 150000002978 peroxides Chemical group 0.000 claims description 3
- VOTFXKJPNQELOG-UHFFFAOYSA-N arsenic acid Chemical compound O[As](=O)=O VOTFXKJPNQELOG-UHFFFAOYSA-N 0.000 claims description 2
- 229940000488 arsenic acid Drugs 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/03—Preparation from inorganic peroxy compounds, e.g. from peroxysulfates
- C01B15/032—Preparation from inorganic peroxy compounds, e.g. from peroxysulfates from metal peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Das Verfahren geht von der Beobachtung aus, daß die Peroxyde der' Erdalkalien mit den konzentrierten Lösungen der Arsensäure und Phosphorsäure sich schnell in der Weise umsetzen, daß die Erdalkalien in Lösung gehen und eine konzentrierte Lösung von H2O2 entsteht, die eine wesentliche Zersetzung nicht erleidet. Man nimmt z. B. 3 1 Wasser, trägt abwephselnd mit etwa 50 prozentiger Phosphorsäure 600 g Ba O2 ein und bringt durch Rühren letzteres in Lösung; nach Fällung des Erdalkalis mit Schwefelsäure kann man das H2 O2 abdestillieren.The method is based on the observation that the peroxides of the 'alkaline earths react quickly with the concentrated solutions of arsenic acid and phosphoric acid in such a way that the alkaline earths go into solution and a concentrated solution of H 2 O 2 is formed, which causes substantial decomposition does not suffer. One takes z. B. 3 1 water, wephselnd wephselnd with about 50 percent phosphoric acid in 600 g Ba O 2 and brings the latter into solution by stirring; after the alkaline earth has been precipitated with sulfuric acid, the H 2 O 2 can be distilled off.
In der französischen Patentschrift 458158 ist zwar ein Verfahren beschrieben, bei dem zur Herstellung von Wasserstoffsuperoxyd ebenfalls Phosphorsäure zur Anwendung kommt, die aus ihrer wässerigen Lösung mit Ba O2 gefällt wird. Versuche haben aber gezeigt, daßIn the French patent specification 458158 a process is described in which phosphoric acid is also used for the production of hydrogen peroxide, which is precipitated from its aqueous solution with BaO 2. But experiments have shown that
20. das Ba O2 dabei nur sehr unvollkommen aus-, genutzt wird. Das Reaktionsprodukt stellt eine dicke Masse dar, in deren Filtrat die Phosphorsäure nicht vollständig ausgefällt ist.20. The Ba O 2 is only used very imperfectly. The reaction product is a thick mass, in the filtrate of which the phosphoric acid has not completely precipitated.
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE298320C true DE298320C (en) |
Family
ID=552537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT298320D Active DE298320C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE298320C (en) |
-
0
- DE DENDAT298320D patent/DE298320C/de active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE926426C (en) | Process for the production of isopropylbenzene peroxide | |
| DE888096C (en) | Process for the production of oxyaldehydes and oxyketones from formaldehyde or substances that produce formaldehyde | |
| DE298320C (en) | ||
| DE3534371C2 (en) | ||
| DE2804910A1 (en) | METHOD FOR TREATING PRIMARY ORES | |
| DE894841C (en) | Process for the production of essentially iron-free, rapidly filtering orthotitanic acid | |
| DE1592185A1 (en) | Water-containing aluminum nitrate compounds | |
| DE977129C (en) | Process for the production of an extremely finely divided mixture of water-soluble calcium compounds consisting essentially of calcium carbonate | |
| DE296796C (en) | ||
| DE423754C (en) | Process for the production of storage-stable persalts | |
| DE666148C (en) | Manufacture of composite titanium pigments | |
| DE137994C (en) | Process for the extraction of discolored, odorless and tasteless protein substances from blood by means of hydrogen peroxide | |
| DE303281C (en) | ||
| DE228139C (en) | ||
| DE163628C (en) | ||
| DE680428C (en) | Production of solid alkali cyanide | |
| DE145388C (en) | ||
| DE167172C (en) | ||
| DE543530C (en) | Process for the production of mixed fertilizers containing ammonium phosphate or ammonium phosphate by leaching rock phosphate | |
| DE1219476B (en) | Process for the production of sodium or calcium cyclohexyl sulfamate | |
| DE355737C (en) | Process for the preparation of colloidal N-dihydro-1,2,2,1-anthraquinone azine or its substitution products | |
| DE3324003C2 (en) | Process for the production of the finest aluminum hydroxide | |
| DE616187C (en) | Process for the production of non-coloring thio derivatives from phenols | |
| DE721991C (en) | Process for sulfiting fatty acid esters | |
| AT54368B (en) | Process for the production of preparations suitable for the indigo vats, especially the cold vats. |