DE29720017U1 - Spray can filling - Google Patents
Spray can fillingInfo
- Publication number
- DE29720017U1 DE29720017U1 DE29720017U DE29720017U DE29720017U1 DE 29720017 U1 DE29720017 U1 DE 29720017U1 DE 29720017 U DE29720017 U DE 29720017U DE 29720017 U DE29720017 U DE 29720017U DE 29720017 U1 DE29720017 U1 DE 29720017U1
- Authority
- DE
- Germany
- Prior art keywords
- composition according
- weight
- addition
- propellant gas
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007921 spray Substances 0.000 title claims description 4
- 239000000203 mixture Substances 0.000 claims description 35
- 239000003380 propellant Substances 0.000 claims description 18
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 claims description 11
- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 claims description 9
- 229930195733 hydrocarbon Natural products 0.000 claims description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- FWKQNCXZGNBPFD-UHFFFAOYSA-N Guaiazulene Chemical compound CC(C)C1=CC=C(C)C2=CC=C(C)C2=C1 FWKQNCXZGNBPFD-UHFFFAOYSA-N 0.000 claims description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 8
- OENHQHLEOONYIE-UKMVMLAPSA-N beta-Carotene Chemical compound CC=1CCCC(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C OENHQHLEOONYIE-UKMVMLAPSA-N 0.000 claims description 8
- ZKSVYBRJSMBDMV-UHFFFAOYSA-N 1,3-diphenyl-2-benzofuran Chemical compound C1=CC=CC=C1C1=C2C=CC=CC2=C(C=2C=CC=CC=2)O1 ZKSVYBRJSMBDMV-UHFFFAOYSA-N 0.000 claims description 4
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 claims description 4
- 239000011648 beta-carotene Substances 0.000 claims description 4
- TUPZEYHYWIEDIH-WAIFQNFQSA-N beta-carotene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2=CCCCC2(C)C TUPZEYHYWIEDIH-WAIFQNFQSA-N 0.000 claims description 4
- 235000013734 beta-carotene Nutrition 0.000 claims description 4
- 229960002747 betacarotene Drugs 0.000 claims description 4
- 239000001273 butane Substances 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 4
- 239000001294 propane Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 3
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 3
- 229960002350 guaiazulen Drugs 0.000 claims description 3
- 229940041616 menthol Drugs 0.000 claims description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- QMENLZUTKYTOKT-UHFFFAOYSA-N 1,3,4-trimethyl-7-propan-2-ylazulene Chemical compound CC(C)C1=CC=C(C)C2=C(C)C=C(C)C2=C1 QMENLZUTKYTOKT-UHFFFAOYSA-N 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 description 6
- 239000000975 dye Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- RHAUWYPYSGQECH-UHFFFAOYSA-N 1,2,3-trimethylazulene Chemical compound C1=CC=CC2=C(C)C(C)=C(C)C2=C1 RHAUWYPYSGQECH-UHFFFAOYSA-N 0.000 description 1
- 244000007853 Sarothamnus scoparius Species 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Carbon And Carbon Compounds (AREA)
- Tea And Coffee (AREA)
Description
BESCHREIBUNG H 686-iDESCRIPTION H 686-i
Die -Erfindung betrifft eine Zusammensetzung, die einen bei Raumtemperatur oder leicht -■ erhöhter Temperatur festen leicht sublimierenden Kohlenwasserstoff, beispielsweise Cyclododekan oder Menthol, enthält, der in einem Trägermedium eingebettet ist, dessen Dampfdruck bei den genannten Temperaturen höher ist als der des Kohlenwasserstoffs.The invention relates to a composition which contains a hydrocarbon which is solid at room temperature or slightly elevated temperature and which sublimes easily, for example cyclododecane or menthol, which is embedded in a carrier medium whose vapor pressure at the temperatures mentioned is higher than that of the hydrocarbon.
Bei der Werbung für kurzfristig bevorstehende Ereignisse werden auf Wandflächen von Baukörpern oder Trägern bedruckte oder bemalte Plakate aufgeklebt, die nach dem beworbenen Ereignis zeitraubend entfernt werden müssen.When advertising upcoming events, printed or painted posters are stuck to the walls of buildings or supports, which then have to be removed after the advertised event, which is time-consuming.
Vor allem im Baubereich werden auf die Rohbaukörper häufig Zeichen und Markierungen für nachfolgende handwerkliche Arbeiten angebracht, die nach Ausführung der Arbeiten als unschöne Verunzierungen zurückbleiben und aufwendig entfernt werden müssen.Particularly in the construction sector, signs and markings for subsequent work are often applied to the shell of a building, which remain as unsightly blemishes after the work has been carried out and have to be laboriously removed.
Der Erfindung liegt die Aufgabe zugrunde, sowohl den Auftrag von wasserfesten und witterungsbetsändigen Zeichen oder Markierungen als auch deren Entfernung zu erleichtern.The invention is based on the object of facilitating both the application of waterproof and weather-resistant signs or markings and their removal.
Erfindungsgemäß dient dazu eine eingangs genannte Zusammensetzung, die 1 - 50 Gew% Cyclododekan und/oder Menthol sowie 99 - 50 Gew% eines Treibgases als Trägermedium enthält, welches Butan und/oder Propan und/oder Methan und/oder Äthan oder eine Mischung aus diesen Stoffen sein kann. Mit dieser Zusammensetzung lassen sich leicht übliche Spraydosen befüllen, sodaß die Werbebotschaft oder die Markierung einfach aufgesprüht werden kann, welche auf der Unterlage als weißer Belag erscheint und anschließend je nach den gewählten Bestandteilen der Zusammensetzung innerhalb vorgegebener Zeit von beispielsweise einigen Tagen rückstandsfrei von dem Baukörper oder der Wand abdampft. Besondere Maßnahmen zur Entfernung der Aufsprühung sind nicht erforderlich.According to the invention, a composition mentioned at the beginning is used for this purpose, which contains 1 - 50% by weight of cyclododecane and/or menthol and 99 - 50% by weight of a propellant gas as a carrier medium, which can be butane and/or propane and/or methane and/or ethane or a mixture of these substances. With this composition, standard spray cans can be easily filled so that the advertising message or marking can simply be sprayed on, which appears on the surface as a white coating and then, depending on the selected components of the composition, evaporates from the building or wall without leaving any residue within a specified time of, for example, a few days. Special measures for removing the spray are not required.
Besonders bewährt hat sich eine Zusammensetzung, die etwa 30 Gew% Cyclododekan und etwa 70 Gew% einer Treibgasmischung enthält, welche, bezogen auf die Treibgasmischung, aus etwa 80 Gew% Butan und etwa 20 Gew% Propan besteht.A composition that has proven particularly effective is one that contains about 30% by weight of cyclododecane and about 70% by weight of a propellant gas mixture that, based on the propellant gas mixture, consists of about 80% by weight of butane and about 20% by weight of propane.
Um die Markierung besonders auffallend erscheinen zu lassen empfiehlt sich eine Weiterbildung der Erfindung dahingehend, daß der Zusammensetzung Pigmente, Farbstoffe oder andere farbig erscheinende Substanzen beigegeben werden, die durch chemische.In order to make the marking appear particularly conspicuous, it is recommended to further develop the invention in such a way that pigments, dyes or other substances that appear colored are added to the composition, which are chemically produced.
• ··
• · * &iacgr;• · * &iacgr;
Reaktion zerstört werden oder durch Licht, als auch durch Verdunsten (sublimieren) verschwinden.reaction or disappear through light or through evaporation (sublimation).
Als derartige Farbstoffe haben sich neben einer großen Zahl von chromophoren Kohlenwasserstoffen folgende Substanzen bewährt:In addition to a large number of chromophoric hydrocarbons, the following substances have proven to be suitable as such dyes:
1. ß-Carotin, welches sowohl in Cyclododekan, alsauch in der Treibgasmischung löslich ist. ß-Carotin wird sowohl durch Licht, als auch durch Luftsauerstoff zerstört. Vom ß-Carotin bleibt ein Rückstand als nicht haftendes, weißliches Pulver, das entweder von Hand, mit Lappen oder Besen leicht vom Untergrund abgenommen werden kann oder sogar lediglich von Wind oder Regen abgetragen oder abgewaschen wird.1. ß-carotene, which is soluble in both cyclododecane and the propellant mixture. ß-carotene is destroyed by both light and atmospheric oxygen. A residue of the ß-carotene remains as a non-stick, whitish powder, which can be easily removed from the surface by hand, with a cloth or broom, or can even simply be carried away or washed away by wind or rain.
2. 1,3-Diphenylisobenzofuran, welches sowohl in Cyclododekan, als auch in der Treibgasmischung löslich ist. 1,3-Diphenylisobenzofuran ist sehr lichtempfindlich, gleichzeitig sublimiert es sehr langsam bei Raumtemperatur.2. 1,3-diphenylisobenzofuran, which is soluble in both cyclododecane and the propellant mixture. 1,3-diphenylisobenzofuran is very sensitive to light, but at the same time it sublimates very slowly at room temperature.
3. Azulen (Cyclopentacyclohepten), welches sowohl in Cyclododekan, als auch in der Treibgasmischung löslich ist. Azulen sublimiert langsam bei Raumtemperatur. Eine blaue Markierung ist sowohl in Mischung mit einem anderen Kohlenwasserstoff als auch nur im Treibgas gelöst möglich.3. Azulene (cyclopentacycloheptene), which is soluble in both cyclododecane and the propellant mixture. Azulene sublimates slowly at room temperature. A blue marking is possible both in a mixture with another hydrocarbon and when dissolved in the propellant alone.
4. Guajazulen (7-isopropyl-l,4 dimethylazulen), welches sowohl in Cyclododekan, als auch in der Treibgasmischung löslich ist.4. Guaiazulene (7-isopropyl-l,4-dimethylazulene), which is soluble in both cyclododecane and the propellant mixture.
Guaj azulen sublimiert langsam bei Raumtemperatur. Um eine Reaktion mit Luftsauerstoff zu vermeiden, kann ein Antioxidationsmittel zugesetzt werden. Eine blaue Markierung ist sowohl in Mischung mit einem anderen Kohlenwasserstoff als auch nur im Treibgas gelöst möglich.Guajazulene sublimates slowly at room temperature. To avoid a reaction with atmospheric oxygen, an antioxidant can be added. A blue marking is possible both in a mixture with another hydrocarbon and when dissolved in the propellant gas.
5. 2-Nitrophenol welches sowohl in Cyclododekan, als auch in der Treibgasmischung löslich ist.5. 2-Nitrophenol which is soluble in both cyclododecane and the propellant mixture.
2-Nitrophenol sublimiert langsam bei Raumtemperatur. Eine gelbe Markierung ist sowohl in Mischung mit einem anderen Kohlenwasserstoff als auch nur im Treibgas gelöst möglich.2-Nitrophenol sublimes slowly at room temperature. A yellow marking is possible both in a mixture with another hydrocarbon and when dissolved in the propellant gas.
6. 7-isopropyl-l,354 Trimethylazulen, welches sowohl in Cyclododekan, als auch in der Treibgasmischung löslich ist. Es sublimiert langsam bei Raumtemperatur. Eine6. 7-isopropyl-l,3 5 4 trimethylazulene, which is soluble in both cyclododecane and the propellant mixture. It sublimes slowly at room temperature. A
blaue Markierung ist sowohl in Mischung mit einem anderen Kohlenwasserstoff als auch nur im Treibgas gelöst möglich.Blue marking is possible both in a mixture with another hydrocarbon and or only dissolved in the propellant gas.
Im einzelnen empfiehlt sich ein Gehalt an Farbstoff von 0,1-5 Gew% der Treibgasmischung, bevorzugt etwa 1,5 Gew%.In particular, a dye content of 0.1-5% by weight of the propellant mixture is recommended, preferably about 1.5% by weight.
Claims (11)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE29720017U DE29720017U1 (en) | 1997-03-26 | 1997-11-12 | Spray can filling |
| DE59802795T DE59802795D1 (en) | 1997-03-26 | 1998-03-25 | COMPOSITION IN THE FORM OF A SPRAY CAN FILLING |
| ES98912503T ES2170486T3 (en) | 1997-03-26 | 1998-03-25 | COMPOSITION, ESPECIALLY IN THE FORM OF A FILLER FOR AEROSOL BOAT. |
| EP98912503A EP0970159B1 (en) | 1997-03-26 | 1998-03-25 | Composition in the form of a spray can filling |
| PCT/EP1998/001752 WO1998042794A1 (en) | 1997-03-26 | 1998-03-25 | Composition, especially in the form of a spray can filling |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE29705413U DE29705413U1 (en) | 1997-03-26 | 1997-03-26 | Spray can filling |
| DE29720017U DE29720017U1 (en) | 1997-03-26 | 1997-11-12 | Spray can filling |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE29720017U1 true DE29720017U1 (en) | 1998-03-26 |
Family
ID=8038027
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE29705413U Expired - Lifetime DE29705413U1 (en) | 1997-03-26 | 1997-03-26 | Spray can filling |
| DE29720017U Expired - Lifetime DE29720017U1 (en) | 1997-03-26 | 1997-11-12 | Spray can filling |
| DE59802795T Expired - Lifetime DE59802795D1 (en) | 1997-03-26 | 1998-03-25 | COMPOSITION IN THE FORM OF A SPRAY CAN FILLING |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE29705413U Expired - Lifetime DE29705413U1 (en) | 1997-03-26 | 1997-03-26 | Spray can filling |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59802795T Expired - Lifetime DE59802795D1 (en) | 1997-03-26 | 1998-03-25 | COMPOSITION IN THE FORM OF A SPRAY CAN FILLING |
Country Status (1)
| Country | Link |
|---|---|
| DE (3) | DE29705413U1 (en) |
-
1997
- 1997-03-26 DE DE29705413U patent/DE29705413U1/en not_active Expired - Lifetime
- 1997-11-12 DE DE29720017U patent/DE29720017U1/en not_active Expired - Lifetime
-
1998
- 1998-03-25 DE DE59802795T patent/DE59802795D1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE59802795D1 (en) | 2002-02-28 |
| DE29705413U1 (en) | 1997-08-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R207 | Utility model specification |
Effective date: 19980507 |
|
| R150 | Utility model maintained after payment of first maintenance fee after three years |
Effective date: 20010124 |
|
| R157 | Lapse of ip right after 6 years |
Effective date: 20040602 |