DE294817C - - Google Patents
Info
- Publication number
- DE294817C DE294817C DENDAT294817D DE294817DA DE294817C DE 294817 C DE294817 C DE 294817C DE NDAT294817 D DENDAT294817 D DE NDAT294817D DE 294817D A DE294817D A DE 294817DA DE 294817 C DE294817 C DE 294817C
- Authority
- DE
- Germany
- Prior art keywords
- metals
- sodium
- parts
- butadiene
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- -1 butadiene hydrocarbons Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910000528 Na alloy Inorganic materials 0.000 description 1
- 229910000573 alkali metal alloy Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910001023 sodium amalgam Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT,PATENT OFFICE,
Im Patent 287787 ist ein Verfahren zur Darstellung von kautschukartigen Substanzen beschrieben, welches darin besteht, daß Butadien und seine Homologen mit Metallen, wie Natrium, bei Gegenwart von Kohlensäure behandelt werden.In patent 287787 is a method for the preparation of rubbery substances described, which consists in the fact that butadiene and its homologues with metals such as Sodium, to be treated in the presence of carbonic acid.
Es hat sich nun gezeigt, daß es unter Umständen vorteilhaft sein kann, Gemische oder Legierungen von Alkalimetallen unter sich oder mit anderen Metallen zu verwenden. Die Polymerisation kann in diesen Fällen rascher verlaufen als bei Verwendung von einzelnen Alkalimetallen. It has now been shown that it can be advantageous under certain circumstances, mixtures or To use alloys of alkali metals among themselves or with other metals. The polymerization can run faster in these cases than when using individual alkali metals.
. Beispiel 1.. Example 1.
100 Teile 2 · 3-Dimethyl-i · 3-butadien werden mit 5 Teilen feinem Natriumdraht und 5 Teilen Eisenfeilspänen in einem mit Kohlensäure gefüllten Gefäß etwa 3 bis 4 Tage geschüttelt, bis die ganze Masse in ein schwarzes voluminöses Produkt übergeführt ist; dieses wird durch Eintragen in Wasser, Alkohol o. dgl. von Alkalimetall und zugleich mechanisch von einem Teil des Eisens befreit; der Rest des letzteren kann durch Nachbehandeln mit Salzsäure entfernt werden.100 parts of 2 · 3-dimethyl-i · 3-butadiene will be with 5 parts of fine sodium wire and 5 parts of iron filings in a carbonated one Vessel shaken for about 3 to 4 days, until the whole mass turns into a black voluminous Product is transferred; this is done by adding it to water, alcohol or the like. from alkali metal and at the same time mechanically freed from some of the iron; the rest of the the latter can be removed by treating with hydrochloric acid.
Wendet man andere Metalle an, wie z. B. Zink, Zinn, Blei, Nickel usw., so kann man im wesentlichen in gleicher Weise arbeiten, ebenso wenn ein anderer Kohlenwasserstoff der Butadienreihe verwendet wird.If you use other metals, such as. B. zinc, tin, lead, nickel, etc., so you can work essentially in the same way, even if a different hydrocarbon the butadiene series is used.
Beispiel 2. ■ - . . tExample 2. ■ -. . t
100 Teile 2 · 3-Dimethyl-i · 3-butadien werden mit so viel flüssigem oder festem feingepulverten Natriumamalgam, als etwa 2 Teilen Natrium entspricht, in einer Kohlensäureatmosphäre einige Tage geschüttelt, bis die Masse schwarz und fest geworden ist. Nach dem Eintragen in Wasser usw. kann das weiß gewordene Produkt von dem noch anhaftenden Quecksilber durch Zentrifugieren befreit werden. Analog kann man bei Benutzung anderer Butadiene sowie anderer Natriumlegierungen, beispielsweise Bleinatrium, verfahren. .-■-..100 parts of 2 · 3-dimethyl-i · 3-butadiene are finely powdered with as much liquid or solid Sodium amalgam, equal to about 2 parts sodium, in a carbonic acid atmosphere Shaken for a few days until the mass has turned black and solid. After this The product which has become whitened can be removed from the still adhering product when it is added to water, etc. Mercury can be freed by centrifugation. Similarly, when using other butadienes and other sodium alloys, for example lead sodium, proceed. .- ■ - ..
Die nach vorliegendem Verfahren gewonnenen Produkte lassen sich ebenso wie diejenigen des Hauptpatents entsprechend dem Zusatzpatent 294816 zur Polymerisation weiterer Mengen von Butadienen benutzen.The products obtained by the present process can be just like those of the main patent corresponding to the additional patent 294816 for the polymerization of others Use amounts of butadienes.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE294817C true DE294817C (en) |
Family
ID=549347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT294817D Active DE294817C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE294817C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2994725A (en) * | 1958-06-30 | 1961-08-01 | Shell Oil Co | Organic chemical reactions |
-
0
- DE DENDAT294817D patent/DE294817C/de active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2994725A (en) * | 1958-06-30 | 1961-08-01 | Shell Oil Co | Organic chemical reactions |
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