DE2918363A1 - DETERGENT FOR TEXTILES - Google Patents

Abstract

1. A powder-form softening detergent for light-wash textiles based on nonionic polyoxyalkylene surfactants, amphoteric-ion surfactants, cationic substances, alkanolamides and at least 50% by weight of other standard ingredients of a light-wash detergent, characterized in that it contains a) from 5 to 20% by weight of an aliphatic polyglycol ether or of a mixture of several polyglycol ethers corresponding to the following formula see diagramm : EP0019734,P6,F2 in which R**1 represents a straight-chain C8 -C20 alkyl or alkenyl group, R**2 represents hydrogen or a C1 -C4 alkyl group, and n has a value of from 2 to 20 and/or of a C8 -C15 alkylarylpolyglycol ether containing from 3 to 15 ethoxy units, b) from 1 to 10% by weight of a C12 -C18 fatty acid ethanolamide, c) from 1 to 10% by weight of an amphoteric-ion compound corresponding to the following formula see diagramm : EP0019734,P6,F3 in which R**3 represents a C10 -C22 aliphatic, cycloaliphatic or alkylaromatic radical and preferably a C12 -C22 straight-chain alkyl radical, R**4 represents a C1 -C4 alkyl radical or a C2 -C4 hydroxyalkyl radical or a polyether radical corresponding to the following formula (CH2 -CH2 -O)m -H with m=2-5, R**5 has the same meaning as R**4 or represents a phenyl, benzyl or tolyl radical, R**6 represents an alkylene or hydroxyalkylene radical containing from 1 to 4 C-atoms, X represents the groups -COO**- , -O-SO3 **-- or -SO3 **-- , d) from 2 to 10% by weight of a textile-softening quaternary ammonium salt selected from derivatives of ammonia and/or imidazoline containing two aliphatic radicals each with 16-20 carbon atoms and at least one quaternary nitrogen atom in the molecule, e) from 50 to 91% by weight of standard ingredients of a light-wash detergent except for anionic surfactants.

Description

HENKELKGaA

4000 Düsseldorf, May 4, 1979 ZR-FE / Patents

Henkelstrasse 67 Dr Ms-sch

Patent application

D 5955
"Laundry detergents for textiles"

The invention relates to a powdery or granular detergent with a fabric softening effect at the same time Washing and caring for delicate items in the washing machine or by hand.

There has long been a need for a powdery or granular mild detergent containing textile softeners, which gives the textiles the desired softening and antistatic properties during the washing process. Because of the known incompatibility of the usual textile softeners of the quaternary ammonium or Imidazolinium compounds with anionic surfactants was the use of anionic surfactants in such preparations locked out. It therefore made sense to use combinations of nonionic surfactants and quaternary ammonium compounds to use. Thus, GB-PS 8j5O 364 are liquid detergents known the nonionic surfactants and quaternary ammonium compounds, which have a long chain alkyl radical and three short-chain alkyl radicals, known. According to the information in the journal Seifen-Öle-Fette-Wachse (1965), 4, p. 78, the washing effect of such combinations is particularly good if the ratio of the nonionic surfactant to the quaternary ammonium compound is im Quantity ratio 4: 1 to 1: 1 is.

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Patent application D 5955 - / - HENKELKGaA

ifi ZR-FE / patents

Powder detergents for machine washing based on non-ionic addition products of ethylene oxide of certain alkylphenols, fatty alcohols, mercaptans, fatty acid monoethanolamides or fatty amines as nonionic Surfactant component that is cationic for foam suppression Containing ammonium compounds are in DE-AS 12 20 described.

From DE-OS 28 28 61 19 a detergent with nonionic polyoxyalkylene surfactants, a small proportion of zwitterionic or semipolar surfactants and small amounts (up to about 1.5 wt .- ^) of a cationic surface-active substance is known. According to the teaching of this patent application, the small proportions of zwitterionic or semipolar surfactants and cationic surface-active substances cause a reduction in color transfer when colored and white textiles are washed at the same time. In US Patent 3,351,557 emulsions are described comprising from about 1-15 wt .- ^ polyoxyalkylene surfactants, 2-10 wt -.% Of a sulfobetaine or amine oxide and 0.1 - 0.5 wt .- ^ quaternary ammonium salt may contain as a germicidal agent.

However, these proposed solutions are unsatisfactory because these detergents are not in balance Washing power, softening performance and acid behavior in the washing machine and when washing by hand can be reached. The person skilled in the art could not derive any suggestion from this prior art, such as a powdery one Detergent would have to be composed with an optimal combination of the desired properties. Of the Rather, the expert had to assume that a detergent

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Patent application T) 5955 - Y "'h HENKELKGaA

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Surfactant the textile softener present in the Viaschiauge Remove or remove from the textile fibers together with the dirt. would keep away and therefore the desired fabric softening effect could not occur. It would be the other way around to achieve a good softening effect but with an insufficiently cleaning surfactant.

The invention was therefore based on the object of providing a powdery or granular detergent for clean detergents, the optimum in washing power, in terms of fabric softening Properties and also in terms of foam behavior and which can be used both in the washing machine and for washing by hand. Another The object of the invention is to provide a detergent formulation, which in the production by spray drying a detergent with a reduced bulk density supplies.

The object was achieved according to the invention by a powder detergent which

a) 5-20 wt. $ of an aliphatic polyglycol ether or a mixture of several polyglycol ethers of the formula

R ¹

XHCHO (CH ₂ CH ₂ O) _n H (I)

in which R is a straight-chain alkyl or

Alkenyl group with "8-20 carbon atoms,

ρ
R is hydrogen or a Cj ^ -Cw-alkyl group

and η is a value of 2-20, and / or of a Cg-Cjc-alkylaryl polyglycol ether with 5-15 ethoxy units, b) 1-10 wt .- ^ of a CgCg fatty acid ethanolamide,

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Patent application D 5955 - / (<■ £ HENKELKGaA

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c) 1-10 wt .- ^ of a zwitterionic compound the formula

-MR ⁰ - * (II)

in which R ^ is an aliphatic, cyclcali-

phatic or alky! aromatic residue with

10 - 22 carbon atoms, preferably a straight

chain alkyl radical with 12 - 22 carbon atoms,

R is an alkyl radical with 1-4 carbon atoms or

a hydroxyalkyl radical with 2-4 carbon atoms

or a polyether radical of the formula

(CH ₂ -CH ₂ -O) _1n -H with m = 2 - 5,

R- * the radical R or a phenyl, benzyl

or tolyl radical,

R is an alkylene or hydroxyalkylene radical

with 2-4 carbon atoms,

X the groups -COO ", -0-SO," or -S0_

mean,

d) 2-10 wt -.% of a fabric softening quaternary

Ammonium salt selected from the derivatives of ammonia and / or imidazoline with preferably 2 long-chain aliphatic Residues in the molecule,

e) 50-91 wt .- ^ usual constituents of a delicate wash

by means of

contains.

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Patent application Ü 5955 - 5 ^ -4 HENKEL KGaA

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The polyglycol ethers of the formula I which are suitable according to the invention as constituent a) are derived from natural or synthetic primary fatty alcohols or oxo alcohols. Oxo alcohols are produced by reacting linear olefins with carbon monoxide and hydrogen by the known oxo process by hydroformylation and subsequent hydrogenation. Händelsüblicne oxo alcohol mixtures, which are for the production of the surfactant component a) are, for example, under the trade name "Dobanol" available oxo-alcohols Deutsche Shell Chemical Company, which is about 25 percent -.% Alkyl-branched 2-of alcohols exhibit; other suitable oxo alcohols are available under the name "Synprol" from Imperial Chemical Industries Ltd. obtainable with approx. 50-70% by weight of 2-alkyl branched alcohols; Other suitable products based on oxo-alcohols include various "Lutensol" types from BASF with about ^ O - 35 wt .- ^ of branched alcohols and some "Lial""types of Liqulchimica SpA with about 60 wt. - % of branched alcohols. Typical preferred products are, for example, "Dobanol 45-7", which consists of at least 95% C ^ / Cj ^ -oxo alcohol with an average of 7 moles of ethylene oxide; furthermore "Lutensol AO-8", which is a C ^ / Cjc-oxo-alcohol ethoxylate with an average of 8 moles of ethylene oxide and "Lutensol ON-70", which is a Cg / C ^ -oxo-alcohol sthoxylate with an average of 7 moles of ethylene oxide represents.

Typical surfactants derived from fatty alcohols are based, for example, on tallow fatty alcohol or the commercial products "Lorol" with 8-18 carbon atoms from Henkel. Typical preferred products are, for example, “Dehydol TA 5” and “Dehydol TA 14” (Henkel), which are tallow fatty alcohol polyglycol ethers with 5 and 14 moles of ethylene oxide per mole of alcohol, respectively. Another preferred product is, for example, the commercial product “Marlipal KF” (Chemische Werke Hüls), a C ₁₀ / C ₁₂ fatty alcohol ethoxylate with an average of 6 moles of ethylene oxide. / 6

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Patent application D 5955 - fi ^ HENKELKGaA

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Further suitable and preferred polyglycol ethers are the addition products derived from oleyl alcohol or cetyl alcohol with 5-10 moles of ethylene oxide or technical Mixtures of predominantly oleyl and cetyl alcohol with 5-10 moles of ethylene oxide, the iodine number of which is between approx. and about 60 lies. The commercial product "Dehydol LS 4" (Henkel), a C ^ / C ^ fatty alcohol ethoxylate, is also preferred with about 4 moles of ethylene oxide. These polyglycol ethers, individually or as a mixture, form component a) of the agents according to the invention. They are contained in the finished product in an amount of 5 to 20% by weight, preferably 7 to 15% by weight and can be completely or partially replaced by the Cg-C ^ c-alkylaryl polyglycol ethers known as nonionic surfactants, such as nonylphenol with approx. 5 to approx. 15 mol Ethylene oxide to be replaced. ''

Fatty acid mono- or diethanolamides with a fatty acid residue with 12-18 carbon atoms are suitable as component b) of the agents according to the invention. Both the compounds with a uniform number of carbon atoms in the fatty acid residue and mixtures of fatty acid ethanolamides with fatty acid residues of different lengths can be used here. A preferred product is derived from coco fatty acid with a proportion of more al3 50 wt .- ^ to C ₁₂ fatty acid, about 20 wt .- ^ C ^ fatty acid, about 10 wt -.% C »g fatty acid and a further proportion of saturated and unsaturated C ^ g fatty acids. Such a product is commercially available under the name "uomperlan 100" (Henkel). Another suitable product is coconut fatty acid diethanolamide, which is commercially available as "Comperlan KD" (Henkel). The fatty acid ethanolamides contain 1 to 10 wt. #, Preferably 2 to 5 wt. #, In the agents according to the invention.

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Patent application 3 5955 ~ ^ / ΙΛ HENKELKGaA

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Examples of component c) of the agents according to the invention are N-alkyl-NjN-dimethyl-ammonium acetate, N-alkyl-N-methyl-N-benzyl-ammonium acetate, N-alkyl-N-bis (2-hydroxyethyl) ammonium acetate, N-alkyl-N-diethyl-ammonium propionate, 2-alkyl-l- (2-hydroxyethyl) -imidazolinium-l-acetate, 3- (N-alkyl-N-dimethylammonium) -2 * -hydroxypropyl sulfate, 3- (N-alkyl-N-dimethylammonium) propanesulfonate and 1- (3-trimethylammonium) alkanesulfonate, in which the alkyl or alkane groups, preferably straight-chain hydrocarbon radicals with 10 - 22, preferably 12 - 18 carbon atoms and are, for example, from natural fat residues, such as coconut or sebum fat. These compounds are obtainable by taking tertiary amines of the Formula R- ^ R R ^ N with halocarboxylic acids, e.g. chlorine or Bromoacetic acid or ÄT-chloropropionic acid converts or by aminocarboxylic acids or reaction products of secondary amines with acrylic acid in a suitable manner quaternized. Sulphate betaines are done in an analogous manner Implementation of tertiary amines with haloalkylsulfuric acid esters or their salts available. Sulphobetaines are made by reacting the tertiary amines with haloalkylsulphonic acids or sultones, especially with propane sultone. The betaines are 1-10% by weight, preferably 2-6 Orew .- # in the agents according to the invention contain.

The quaternary ammonium compounds are preferably used as textile-softening active ingredients (component d)) two long-chain, preferably saturated aliphatic radicals each with 14-26, preferably 16-20 carbon atoms and at least one quaternary nitrogen atom in the molecule. The long-chain aliphatic radicals can be straight-chain or branched and accordingly of fatty acids or of fatty amines, Guerbetamines, or from the alkylamines obtainable by reducing nitroparaffins descend. These quaternary ammonium compounds are, in particular, derivatives of / g

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Patent application D 5955 "K" HENKELKGaA

ή2

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Ammonia, i.e. the quaternary salts obtainable by alkylation of long-chain secondary amines, e.g. the compounds distearyldimethylammonium chloride or ditallowalkyldimethylammonium chloride, or by the reaction of 1 mole of a ^ s Aminoalkylethylendiamins or Hydroxyalkylethylenediamine with 2 moles of a long-chain, C ^ -Cgg fatty acid or its ester available imidazoline compounds, which are then converted into the quaternary imidazolinium compounds by alkylation. In these quaternary ammonium compounds, the anion generally consists of the acid residue which is derived from the Quaternization used alkylating agents emerged is. For example, the anion is chloride, bromide, methyl sulfate, ethyl sulfate, methane, ethane or toluene sulfonate, preferably chloride and / or methyl sulfate, typical preferred textile softeners are for example Ditalgalkyldimethylammoniuinchlorid (for example the commercial products "Prepagen WK" and "Prepagen WKT", Hoechst. "Adogen 442", Ashland) or distearyldimethylammonium chloride (for example "Arosurf TA 100 '% Ashland) and 2-heptadecyl-1-methyl-1-oleoylamidethyl-imidazolinium methosulfate.

The active ingredients are textilweiehmaehenden to 2 - 10 contain preferably 3-7 wt .- ^ in the inventive compositions, wherein the active ingredient fcexfcilweichmaehende preferably d) to more than 25 _9, in particular more than 30 wt ₈ - ^ ₁ based on the total weight of the from the Polyglycol ether a), the fatty acid ethanol b) and the textile-softening active ingredient d) existing koia components contain lsfc. / ^

Patent application D 5955 "/ if HENKELKGaA

yw ZR-FE / patent a

In addition to the poly glycols, the fatty acid ethanolamide, the zwitterionic compound and the quaternary ammonium compounds, the agents according to the invention contain 50-91 wt .- ^ additives usually present in detergents as further components. These are, for example, builders, fragrances, dyes, as well as dirt carriers, enzymes, optical brighteners or small amounts of water. The builders include calcium precipitating or complexing inorganic or organic compounds. Inorganic precipitating bsw. Complexing substances are, for example, pyrophosphate, triphosphate, higher polyphosphates and metaphosphates and the cation-exchanging alkali metal aluminosilicates, as described, for example, in DE-AS 24 12 857, in particular the zeolites A and X. Suitable organic compounds are, for example, polycarboxylic acids, hydroxycarboxylic acids, aminocarboxylic acids, carboxyalkyl ethers , polyanionic polymeric carboxylic acids., Phosphonic acids.- Further structural substances are weakly acidic, neutral or alkaline reacting inorganic salts, such as bicarbonates, carbonates, borates or silicates of alkalis, alkali sulfates, as well as the alkali salts of organic, non-capillary-active, 1-8 C -Atom-containing sulfonic acids, carboxylic acids and sulfocarboxylic acids. The agents according to the invention preferably contain about 10-50 wt .- ^ sodium tripolyphosphate, 2-10 wt .- ^ water glass with a Na ₂ O: SiOg ratio of, for example, 1: 3.4 and sodium sulfate as builders.

The agents according to the invention are in the form of a powder. This is understood to mean fine to grainy or spherical Products that are easy to pour. They can be produced by any of the methods known in the art. So you can e.g. mix the powdery ingredients together

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Patent application D 5955 - led'- HENKELKGaA

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Mix and spray oily or pasty ingredients such as non-ionic surfactants onto the product. One Another manufacturing possibility is that the ingredients of the agent are made into a paste with water, which is converted into a powder by evaporating the water, e.g. on rollers or in atomizing towers. After this Heat-sensitive or volatile substances, such as fragrances, can then be hot-dried incorporate. Products according to the invention produced by spray drying have a bulk density of approx. 150 g / l up to approx. 3OO g / l.

The detergents according to the invention can be used for washing and, at the same time, softening clean laundry articles made of wool, synthetic fibers such as polyester, polyacrylonitrile, polyamide and mixtures of wool and synthetic pasarn. The washing and softening process can be carried out either in the washing machine or by hand at washing temperatures of up to about 60 ^° C., preferably up to about 30 ^° C. The use concentration of the agents is generally from 1 to 10 g / l wash liquor, preferably at 2 to 5 g / l · The detergents are characterized by the fact that they clean the textiles perfectly and at the same time give them a pleasant feel and antistatic properties. When washed by hand in the sink, they form a dense, pleasant foam; when washed in the washing machine, no over-foaming is observed. In addition, the foam can be rinsed out without any problems.

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Patent application D 5955 - J & -

HENKEL KGaA ZR-FE / Patents

The following examples describe detergents according to the invention. ·

example 1

5 wt -.% Tallow fatty alcohol with about 14 moles of ethylene oxide

( "Dehydol TA l4", Henkel) 3 wt -.% Coconut fatty acid monoethanolamide

("Coisperlan lOO", handle)

Cocoalkyl-dimethylammonium% - 3 wt.

( "Dehyton AB 30", Henkel) 5 wt -.% Distearyldimethylammonium, about 95 ^ ig

("Arosurf TA 100", Ashland) Remaining builders, small amounts of moisture.

Example 2

4 wt .- ^ C ₁ ^ / C ₁₅ -oxo alcohol ethoxylate with about 7 mol

Ethylene oxide

("Dobanol 45-7" »Shell) 2.5 wt .- ^ C ₁₀ / C ₁₂ -Pettalkohol-EthoxFlat with approx. 6 mol

Ethylene oxide

( "KF Marlipal" Chemische Werke Huls) 4 wt -.% Coconut fatty acid diethanolamide

("Comporlan 103", Henkel) 3.5% by weight coconut alkyl dimethyl ammonium acetate

( "Dehyton AB 50", Henkel) 5.5 wt -.% Ditalgalkyldimethylammoniiimehlorid, used as 75 ^ ^ strength liquid residual isopropyl alcohol

and water ("Prepagen WIST", Hoechst) Remaining structural materials j, small amounts of water.

Patent application P 5955 - γέ - HENKEL KGaA

Α (λ ZR-FE / patents

Example 3

• 4 wt .- ^ tallow fatty alcohol with approx. 5 moles of ethylene oxide

( "Dehydol TA 5", Henkel) j5 wt. "% C ₁₅ / C ₁₅ oxo alcohol ethoxylate with about 8 moles

Ethylene oxide

( "Lutensol AO 8", BASF) 4.5 wt -.% Coconut fatty acid monoethanolamide

("Comperlan 100", Henkel)

5 wt .- ^ tallow alkyl dimethylammoniumpropionat 5 wt -.% Dltalgalkyldlmethylammoniumchlorid, ca.

lQO & Lg

("Prepagen WK", Hoechst) 50 wt .- ^ sodium tripolyphosphate 4.5 wt .- £ sodium silicate (Na ₂ O: SiO ₂ = 1: 5,> 5)

as an aqueous solution
0.5% by weight perfume oil
Residual sodium sulfate, water.

An agent of the above composition sets Laundry detergent according to the invention containing conventional additives in conventional amounts. It was produced by spray drying manufactured and has a bulk density of approx. 250 g / l.

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Patent application D 5955 - JO - HENKELKGaA

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Example 4

Wt .- # of an oleyl / cetyl fatty alcohol ethoxylate with approx. 10 moles of ethylene oxide and an iodine number of the alcohol mixture of approx. 50

Wt .- ^ a C ^ g / C ^ fatty alcohol ethoxylate with about 4 moles of ethylene oxide ( "Dehydol LS 4", Henkel) wt .- $ coconut fatty acid monoethanolamide with a proportion of more than 50 wt -.% C. ₂ - irn fatty acid fatty acid residue ( "Comperlan 100", Henkel) wt -.% coco-dimethylammoniumcacetat ( "Dehyton AB 30", Henkel)

% By weight ditallow alkyldimethylammonium chloride, used as 75% paste, the rest isopropyl alcohol and water ("Prepagen WK", Hoechst)

The rest of the builders, water.

Example 5

Wt -.% Of a Ncnylphenolpolyglykolethers with about 6.5 moles of ethylene oxide ( "Dehydrophen 65", Henkel)

Wt -.% Of a Gg / C. ^ - fatty alcohol ethoxylate with about 4 moles of ethylene oxide ( "Dehydol LS 4", Henkel) wt -.% Coconut fatty acid monoethanolamide
("Comperlan 100", Henkel)

% By weight coconut alkyl dimethylammonium acetate ("Dehyton AB 30", Henkel)

% By weight of ditallow alkyldimethylammonium chloride,

approx. 95 ig, ("Prepagen WK", Hoechst). The rest of the builders, water.

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Patent application D 5955 "^ KO HENKELKGaA

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The detergents according to the invention listed in Examples 1-5 have been found to wash fine textiles made of wool, polyacrylonitrile or wool / polyacrylonitrile mixtures, as well as polyamide / cotton mixtures in the washing machine up to 60 ^° C., preferably up to approx by hand as products with a balanced combination of properties in terms of their washing power, their softening effect and their foaming behavior.

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Claims (5)

Patent application D 5955 - A - HENKEL KGaA ZR-FE / PatentQ "detergents for textiles" claims 1. Powdered, softening detergent for painful washing -Textile! based on nonionic surfactants with a content of quaternary ammonium compounds, characterized in that it a) 5-20 -. $> of an aliphatic polyglycol ether or of a mixture of several polyglycol ethers of the formula R ¹ ./Ii ₀ U ) ti \ X) ρ / ^& C έ η BT ' in the P. a straight-chain alkyl or Alkenyl group with 8-20 carbon atoms, 2
R is hydrogen or a C.-Cjj-alkyl group and η has a value of 2-20 mean and / or a Cg-C _lt --Alkylarylpolyglykolethers with 3-15 ethoxy units, b) 1-10 wt -.% of a Cp-C ^ ^ n-Pettsr areethanolamids, 030048/0022 ORIGINAL INSPECTED Patent application D 5955-2 - HENKELKGaA ZR-FE / patents c) 1-10 wt .- ^ of a zwitterionic compound the formula I _ß > _N — R ^D ~ X (II) R * in which R ^ is an aliphatic, cycloaliphatic or alkyl aromatic radical with 10-22 carbon atoms, preferably a straight-chain alkyl radical with 12-22 carbon atoms, R is an alkyl radical with 1-4 carbon atoms or a hydroxyalkyl radical with 2-4 carbon atoms Atoms or a polyether radical of the formula (CH ₂ —CH ₂ —O) _1n —H with IK = 2 - 5, ■ B? the radical R or a phenyl, Benayl or tolyl radical, R is an alkylene or hydroxyalkylene radical with 2-4 carbon atoms, X the groups -COO "-0-SO,", or -SO, mean d) 2-10 wt .- # "of a quaternary fabric softening agent Amir.oniurn & alzes, selected from the derivatives of ammonia and / or imidazoline with preferably 2 long-chain aliphatic radicals in the molecule, e) 50-91 wt .- ^ usual constituents of a delicate wash by means of contains. / 5 030 048/0022 Patent application D 5955-3 - HENKELKGaA ZR-FE / patents 2. Means according to claim 1, characterized in that it a) 7 - 15 wt -.% polyglycol ethers of the formula I, b) 2 - 5% by weight of fatty acid ethanolamide, c) 2 - 6 wt -.% zwitterionic compounds of formula II, d) J - 7 wt .- ^ textile softening quaternary Ammonium salt contains. 3. Means according to claim 1 and 2, characterized in that it contains component d) to more than 25 wt .- ^, in particular more than J> 0 wt. % _T based on the sum of the components a), b) and el ), contains. 4. Means according to claim 1 to 3, characterized in that that it a) 3 - 6 wt .- ^ of an adduct of one from Oleyl and cetyl alcohol existing fatty alcohol mixture with about 10 moles of ethylene oxide and 1-4 Gewi- ^ of an adduct of a C ₁₂ / C.ji fatty alcohol mixture with about 4 moles of ethylene oxide b) 2 - 4 wt .- ^ of a coconut fatty acid mono- or di- ethanolamids c) 2-6 wt .- # cocoalkyl-dimethylammonium acetate d) 3 -% of a quaternary ammonium salt represented by - 6 wt. 2 long chain aliphatic residues in the molecule derived from ammonia and its anion from the chloride, bromide, methyl sulfate, ethyl sulfate, methane, ethane or Toluenesulfonat comprehensive group selected is e) 74 to 89 wt -.% of conventional components of a fine-washing by means of contains. / 4 0300A8 / 0022 Patent application D 5955-4 - HENKELKGaA ZR-FE / patents 5. Means according to claim 1 to 4, characterized in that that it's off % of an adduct from a - a) 4.0 wt. Oleyl and cetyl alcohol existing fatty alcohol mixture the iodine number 50 with about 10 moles of ethylene oxide and 2.0 wt .- ^ of an adduct of a C ₁₂ / C., 2I fatty alcohol mixture with approx. 4 moles of ethylene oxide, b) 2.0 wt .- ^ coconut fatty acid monoethanolamide, c) 4.0 wt .- ^ coconut alkyl dimethylammonium acetate, d) 4.0 Gev »- $ ditallow alkyldimethylarranonium chloride, e) 4.5 wt .- # sodium silicate (Na ₂ O: SiO ₂ = 1: 5.4), 30.0 wt .- ^ sodium tripolyphosphate, 59.5 wt .- ^ sodium sulfate,
10.0 wt -.% Water consists. 030048/0022