DE2737756A1 - Laminates incorporating microporous PTFE membranes - giving waterproof and breathing properties for clothing, etc. - Google Patents
Laminates incorporating microporous PTFE membranes - giving waterproof and breathing properties for clothing, etc.Info
- Publication number
- DE2737756A1 DE2737756A1 DE19772737756 DE2737756A DE2737756A1 DE 2737756 A1 DE2737756 A1 DE 2737756A1 DE 19772737756 DE19772737756 DE 19772737756 DE 2737756 A DE2737756 A DE 2737756A DE 2737756 A1 DE2737756 A1 DE 2737756A1
- Authority
- DE
- Germany
- Prior art keywords
- layer
- laminate
- polyamide
- ptfe membrane
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/10—Impermeable to liquids, e.g. waterproof; Liquid-repellent
- A41D31/102—Waterproof and breathable
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B7/00—Footwear with health or hygienic arrangements
- A43B7/12—Special watertight footwear
- A43B7/125—Special watertight footwear provided with a vapour permeable member, e.g. a membrane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/026—Knitted fabric
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G9/00—Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
- A47G2009/001—Anti-allergen; Anti-mite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/712—Weather resistant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Laminated Bodies (AREA)
Abstract
Description
BESCHREIBUNG DESCRIPTION
Laminate mit mindestens einer mikroporösen PTFE-Membrane und aus diesen Laminaten hergestellte Endprodukte Die Erfindung betrifft Laminate mit mindestens einer mikroporösen PTFE-Membrane und aus diesen Laminaten hergestellte Endprodukte. Laminates with at least one microporous PTFE membrane and made of End products made these laminates. The invention relates to laminates having at least a microporous PTFE membrane and end products made from these laminates.
Es ist bekannt, Wetterbekleidungsstoffe aus imprägnierten textilen Flächengebilden oder aus kunststoffbeschichteten textilen Flächengebilden herzustellen. Die imprägnierten Stoffe sind zwar in der Regel hinreichend atmungsfähig, aber nur bedingt wasserdicht. Bei den kunststoffbeschichteten Stoffen verhält es sich gerade umgekehrt, das heißt sie sind in der Regel hinreichend wasserdicht, aber nur sehr bedingt atmungsfähig. Bei der Suche nach einem sowohl wasserdichten als auch atmungsfähigen Material hat sich eine mikroporöse PTFE-Membrane als sehr brauchbar erwiesen, die in einem mehrschichtigen Laminat zu einem Wetterbekleidungsstoff verarbeitet wird.It is known that weather clothing fabrics made from impregnated textiles Fabrics or from plastic-coated textile fabrics. The impregnated fabrics are generally sufficiently breathable, but only conditionally waterproof. This is exactly the case with plastic-coated fabrics conversely, that is, they are usually sufficiently waterproof, but only very well conditionally breathable. When looking for one that is both waterproof and breathable A microporous PTFE membrane has proven to be very useful in the material is processed in a multi-layer laminate into a weather clothing fabric.
Die Aufgabe der vorliegenden Erfindung besteht-darin, die bekannten Laminate mit mindestens einer mikroporösen PTFE-Membrane so weiterzuentwickeln, daß sie in unterschiedlichen Einsatzgebieten, wie z.B. in der Berufs- und Sportwelt oder im klinischen Bereich, eingesetzt werden können.The object of the present invention is to provide the known To further develop laminates with at least one microporous PTFE membrane, that they can be used in different areas of application, e.g. in the professional and sports world or in the clinical area.
Diese Aufgabe wird gemäß der Erfindung durch Laminate gemäß dem kennzeichnenden Teil des Anspruchs 1 gelöst. Die einzelnen Lagen dieser Laminate können hierbei nach bekannten Verfahren veredelt oder verarbeitet werden.This object is achieved according to the invention by laminates according to the characterizing part Part of claim 1 solved. The individual layers of these laminates can here refined according to known processes or processed.
Vorteilhafte Endprodukte, wie z.B. Bekleidungsstücke, Schuhe, Handschuhe, Kopfbekleidungsstücke, Schlafsäcke, Tragebehälter, Planen usw., aus Laminaten bestimmter Zusammensetzung sind in den Unteransprüchen angeführt. Diese Produkte (vgl. hierzu auch insbesondere die nachstehende tabellarische Übersicht) bieten insbesondere Schutz gegen aggressive Materialien wie Säuren, Laugen oder dergleichen, so daß sie vorteilhaft als Schutzkleidung in der Berufswelt eingesetzt werden können. Außerdem ist ihr Einsatz im militärischen Bereich aufgrund ihres Wetter- und Kälteschutzes und ihres Schutzes gegen biologische und chemische Waffen sehr vorteilhaft. Da PTFE physiologisch unbedenklich ist, können diese Produkte auch vorteilhaft im klinischen Bereich eingesetzt werden. Weitere Eigenschaften und Einsatzgebiete von erfindungsgemäßen Laminaten bzw. aus diesen Laminaten hergestellten Endprodukten ergeben sich aus der weiter unten angeführten tabellarischen Übersicht.Advantageous end products such as clothing, shoes, gloves, Headgear, sleeping bags, carrying cases, tarpaulins, etc., made of certain laminates Composition are given in the subclaims. These products (see also in particular the following table overview) offer in particular Protection against aggressive materials such as acids, alkalis or the like, so that they can be used advantageously as protective clothing in the professional world. aside from that is their use in the military sector due to their weather and cold protection and their protection against biological and chemical weapons are very beneficial. Since PTFE Physiologically harmless, these products can also be beneficial in clinical Area can be used. Further properties and areas of application of the invention Laminates or end products produced from these laminates result from the table overview below.
Im nachfolgenden werden kurz die Eigenschaften der mikroporösen PTFE-Membrane beschrieben. Das mikroporöse PTFE-Material für die Membrane wird insbesondere gemäß einem Verfahren hergestellt, wie es z.B. aus der DT-AS 21 23 316 oder der DT-OS 24 17 901 bekannt ist. Die Membrane weist beispielsweise eine Dicke von nur 0,025 mm und 1,4 Milliarden Poren pro Quadratzentimeter auf. Die maximale Porengröße beträgt 0,2 p. PTFE ist wasserabstoßend. Aufgrund aieser Eigenschaft und der geringen Porengröße ist ein sehr großer Druck, ca. 40 m WS, nötig, um Wasser durch die Poren pressen zu können. Wassertropfen sind ca. 20 000 mal größer als die Poren der mikroporösen PTFE-Membrane. Die Moleküle von Wasserdampf sind jedoch 700 mal kleiner als die Poren. Sie können deshalb in hohem Maß durch die Membrane diffundieren. Tests in Labor und Praxis haben dieses Modell bestätigt. Die mikroporöse PTFE-Membrane ist daher unter allen in der Praxis auftretenden Bedingungen sowohl absolut wasserdicht als auch atmungsfähig.The following briefly describes the properties of the microporous PTFE membrane described. The microporous PTFE material for the membrane is in particular according to produced by a process, such as from DT-AS 21 23 316 or DT-OS 24 17 901 is known. The membrane has, for example, a thickness of only 0.025 mm and 1.4 billion pores per square centimeter. The maximum pore size is 0.2 p. PTFE is water repellent. Because of this property and the small pore size a very high pressure, approx. 40 m WS, is necessary to force water through the pores to be able to. Water droplets are around 20,000 times larger than the pores of the microporous ones PTFE membrane. However, the molecules of water vapor are 700 times smaller than that Pores. You can therefore diffuse to a large extent through the membrane. Tests in Laboratory and practice have confirmed this model. The microporous PTFE membrane is therefore both absolutely waterproof under all conditions occurring in practice as well as breathable.
Eine solche mikroporöse PTFE-Membrane kann je nach den gewünschten technischen únd ästhetischen Eigenschaften mit einer oder mehreren Lagen aus verschiedenen Materialien ein- oder beidseitig kaschiert werden. Die Kaschierung erfolgt hierbei je nach den Materialien der zusätzlichen Lagen z.B. mittels Kleber, Haftvermittler, Temperatur und/oder Druck.Such a microporous PTFE membrane can depending on the desired technical and aesthetic properties with an or several Layers of different materials can be laminated on one or both sides. The lamination takes place depending on the materials of the additional layers, e.g. by means of glue, Adhesion promoter, temperature and / or pressure.
Folgende Materialien können für diese zusätzlichen Lagen verwendet werden: a) Chemiefasern wie Viskosefasern, Cupro-Fäden, Acetatfasern, Polyamidfasern, Polyesterfasern, Polyacrylfasern, Polyacrylnitrilfasern, Polyurethanfäden, Polyolefinfasern, Polyvinylalkoholfasern, Polyvinylcyanidfasern, Polyvinylchloridfasern, Polytetrafluoräthylenfasern, Zwei-Komponenten-Fasern oder Naturfasern aus Baumwolle, Flachs, Jute, Rami, Kokos, Wolle, Seide oder dergleichen oder Kombinationen von Naturfasern und Chemiefasern in beliebigen Verhältnissen.The following materials can be used for these additional layers are: a) man-made fibers such as viscose fibers, cupro threads, acetate fibers, polyamide fibers, Polyester fibers, polyacrylic fibers, polyacrylonitrile fibers, polyurethane fibers, polyolefin fibers, Polyvinyl alcohol fibers, polyvinyl cyanide fibers, polyvinyl chloride fibers, polytetrafluoroethylene fibers, Two-component fibers or natural fibers made from cotton, flax, jute, rami, coconut, Wool, silk or the like or combinations of natural fibers and man-made fibers in any proportions.
Diese Materialien können in bekannter Weise zu textilen Flächengebilden verarbeitet werden, z.B. durch Weben, Wirken, Stricken, Tuften, Verfilzen oder Velourieren.These materials can be used in a known manner to form textile fabrics processed, e.g. by weaving, knitting, knitting, tufting, felting or velor.
b) Schaumstoffe mit offenen oder geschlossenen Poren, z.B. aus PVC, Polyurethan, Polyäthylen, Polystyrol, Chloropren, usw.b) foams with open or closed pores, e.g. made of PVC, Polyurethane, polyethylene, polystyrene, chloroprene, etc.
c) Leder oder Lederaustauschstoffe d) Papier oder papierähnliche Stoffe, e) Gazestoffe, Netz- oder Gitterwerkstoffe f) Kunststoffolien Die hierbei entstehenden Laminate bzw. die aus diesen Laminaten hergestellten Endprodukte vereinigen in sehr vorteilhafter Weise die oben angeführten Eigenschaften der mikroporösen PTFE-Membrane und der aufkaschierten Zusatzlagen, wie z.B. die Griffigkeit, Weichheit und Ästhetik von Veloursstoffen oder die Elastizität von Schaumstoffen.c) Leather or leather substitutes d) Paper or paper-like materials, e) Gauze, netting or lattice materials f) Plastic foils The resulting Laminates or the end products made from these laminates combine in a very good way advantageous way the above properties of the microporous PTFE membrane and the additional layers laminated on, such as the grip, softness and aesthetics of velor fabrics or the elasticity of foams.
In der nachfolgenden tabellarischen Übersicht werden konkrete Ausführungsbeispiele
von Laminaten mit ihren besonderen Eigenschaften, von aus diesen Laminaten hergestellten
Endprodukten und von bevorzugten Einsatzgebieten angeführt. Der Schichtaufbau der
Laminate ist hierbei immer in der Reihenfolge von außen nach innen angegeben. Da
alle Laminate mindestens eine mikroporöse PTFE-Membrane enthalten, sind natürlich
alle Produkte wasserdicht und atmungsfähig. Diese Eigenschaften sind nur bei den
Laminaten besonders hervorgehoben, bei denen sie im Hinblick auf das Endprodukt
und das Einsatzgebiet von besonderer Bedeutung sind.
Claims (30)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19772737756 DE2737756A1 (en) | 1977-08-22 | 1977-08-22 | Laminates incorporating microporous PTFE membranes - giving waterproof and breathing properties for clothing, etc. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19772737756 DE2737756A1 (en) | 1977-08-22 | 1977-08-22 | Laminates incorporating microporous PTFE membranes - giving waterproof and breathing properties for clothing, etc. |
Publications (1)
Publication Number | Publication Date |
---|---|
DE2737756A1 true DE2737756A1 (en) | 1979-03-01 |
Family
ID=6016982
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19772737756 Withdrawn DE2737756A1 (en) | 1977-08-22 | 1977-08-22 | Laminates incorporating microporous PTFE membranes - giving waterproof and breathing properties for clothing, etc. |
Country Status (1)
Country | Link |
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DE (1) | DE2737756A1 (en) |
Cited By (67)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1981003148A1 (en) * | 1980-05-08 | 1981-11-12 | Aquata Wassersport & Meerestec | Protection garment for nautical sports |
DE3132324A1 (en) * | 1981-08-17 | 1983-03-03 | Hasso von 4000 Düsseldorf Blücher | "WATER- AND AIR-TIGHT MOISTURE-CONTROLLING TEXTILE MATERIAL" |
DE3147202A1 (en) * | 1981-11-27 | 1983-06-01 | W.L.Gore & Co. GmbH, 8011 Putzbrunn | WATER VAPOR PERMEABLE (WELDABLE) FOOTWEAR |
EP0081850A2 (en) * | 1981-12-16 | 1983-06-22 | W.L. Gore & Associates GmbH | Piece of cloth provided with a water-proof and steam-pervious layer |
FR2522587A1 (en) * | 1982-03-05 | 1983-09-09 | Cardis Philippe | Composite fabrics with conventional and hydrophobic textiles - plus aluminised film to combine insulation and ventilation in waterproof garment |
EP0110627A2 (en) * | 1982-11-19 | 1984-06-13 | W.L. Gore & Associates, Inc. | Polytetrafluorethylene laminate for footwear articles |
EP0117085A2 (en) * | 1983-02-22 | 1984-08-29 | Imperial Chemical Industries Plc | Production of shaped article |
US4469744A (en) * | 1980-07-11 | 1984-09-04 | E. I. Du Pont De Nemours And Company | Protective clothing of fabric containing a layer of highly fluorinated ion exchange polymer |
US4518650A (en) * | 1980-07-11 | 1985-05-21 | E. I. Du Pont De Nemours And Company | Protective clothing of fabric containing a layer of highly fluorinated ion exchange polymer |
EP0143204A1 (en) * | 1983-09-02 | 1985-06-05 | W.L. Gore & Associates GmbH | Jacket for a cyclist |
FR2560553A1 (en) * | 1984-03-01 | 1985-09-06 | Nitto Electric Ind Co | ROLLED SHEET WITH IMPERMEABILITY AND EXTENSIBILITY PROPERTIES |
EP0185373A2 (en) * | 1984-12-21 | 1986-06-25 | Pall Corporation | Supported microporous membrane and method of making |
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DE3927185A1 (en) * | 1989-05-27 | 1991-02-21 | Ruiter Ernest De | Protective clothing material - uses plastic with hydropic fine segment content |
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US5264276A (en) * | 1992-04-06 | 1993-11-23 | W. L. Gore & Associates, Inc. | Chemically protective laminate |
US5268212A (en) * | 1989-10-17 | 1993-12-07 | Malden Mills Industries, Inc. | Windproof and water resistant composite fabric with barrier layer |
US5321861A (en) * | 1990-06-20 | 1994-06-21 | Elizabeth Dancey | Protective cover |
WO1994021536A1 (en) * | 1993-03-24 | 1994-09-29 | W. L. Gore & Associates, Inc. | Insulative food container employing breathable polymer laminate |
USRE34890E (en) * | 1981-08-06 | 1995-04-04 | Gore Enterprise Holdings, Inc. | Waterproof shoe construction |
US5418044A (en) * | 1988-05-07 | 1995-05-23 | Akzo N.V. | Irreversibly stretchable laminate comprising layers of woven or knitted fabrics and water-vapor permeable films |
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