DE27087C - Process for the production of a marble or jasper-like glass by treating a black carbon glass with silver or copper preparations - Google Patents
Process for the production of a marble or jasper-like glass by treating a black carbon glass with silver or copper preparationsInfo
- Publication number
- DE27087C DE27087C DENDAT27087D DE27087DA DE27087C DE 27087 C DE27087 C DE 27087C DE NDAT27087 D DENDAT27087 D DE NDAT27087D DE 27087D A DE27087D A DE 27087DA DE 27087 C DE27087 C DE 27087C
- Authority
- DE
- Germany
- Prior art keywords
- glass
- parts
- silver
- jasper
- marble
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011521 glass Substances 0.000 title claims description 18
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 238000002360 preparation method Methods 0.000 title description 7
- 229910052709 silver Inorganic materials 0.000 title description 4
- 239000004332 silver Substances 0.000 title description 4
- 239000003738 black carbon Substances 0.000 title description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title description 2
- 229910052802 copper Inorganic materials 0.000 title description 2
- 239000010949 copper Substances 0.000 title description 2
- 239000004579 marble Substances 0.000 title description 2
- 238000000034 method Methods 0.000 title description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 6
- NUJOXMJBOLGQSY-UHFFFAOYSA-N Manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 4
- 229910000468 manganese oxide Inorganic materials 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese(II,III) oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- 239000005751 Copper oxide Substances 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- PGWMQVQLSMAHHO-UHFFFAOYSA-N sulfanylidenesilver Chemical compound [Ag]=S PGWMQVQLSMAHHO-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 2
- 235000015450 Tilia cordata Nutrition 0.000 claims description 2
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004571 lime Substances 0.000 claims description 2
- 239000010446 mirabilite Substances 0.000 claims description 2
- 229940072033 potash Drugs 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M Silver chloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 claims 1
- 238000005034 decoration Methods 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 2
- 235000019646 color tone Nutrition 0.000 description 2
- 229910000460 iron oxide Inorganic materials 0.000 description 2
- 239000011324 bead Substances 0.000 description 1
- -1 chlorine silver Chemical compound 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052803 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 235000019571 color Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000010978 jasper Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/44—Lustring
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
KLASSE 32: Glas,CLASS 32: glass,
Patentirt im Deutschen Reiche vom 29. August 1883 ab. Patented in the German Empire on August 29, 1883 .
Zum Zwecke der Herstellung dieser Decoration von schwarzem Glase schmelzen die Erfinder:For the purpose of making this decoration of black glass, the inventors melt:
100 Theile Sand,100 parts of sand,
3 - Glaubersalz,3 - Glauber's salt,
4 - Eisenoxyd (Caput mortuum),
12 - Graphit (oder Holzkohle),
36 - Soda,4 - iron oxide (caput mortuum),
12 - graphite (or charcoal),
36 - soda,
,12 - Kalk,
12 - Potasche., 12 - lime,
12 - Potash.
Das so geschmolzene Glas giebt ein sogenanntes' schwarzes Kohlenglas, welches wieder beim Herausarbeiten folgendermafsen behandelt wird.The glass thus melted gives a so-called black carbon glass, which is again attached to the Working out is treated as follows.
Der Glasmacher nimmt ein kleines Stück an die Pfeife, formt es zu einem kleinen Oval, bis es genügend erstarrt ist, damit er wieder ein wenig Glasmasse aufnehmen kann, mit der er die gleiche Manipulation vornimmt. Diesen Vorgang . wiederholt er drei- bis fünfmal, wodurch das Glas einen graugrünen Kern und eben solche Ringe annimmt.The glassmaker takes a small piece of the pipe, shapes it into a small oval until it has solidified enough so that it can again take up a little glass mass with which it is does the same manipulation. This process . he repeats three to five times, whereby the glass assumes a gray-green core and such rings.
Das derart an der Pfeife behandelte Glas kann' nun beliebig hohl oder massiv, zu Hohloder Prefsglas, zu Stangen, Stengeln u. s. w. verarbeitet werden. Aus diesem Rohglase lassen sich nun wieder Knöpfe, Perlen, sowie alle sonstigen Quincaillerie-Artikel herstellen, wie dies mit anderem Rohglase geschieht.The glass treated in this way on the pipe can now be hollow or solid, hollow or Prefsglas, can be processed into rods, stalks and so on. Let out of this raw glass Now make buttons, beads, and all other quincaillery items again, like this happens with other raw glass.
Alle diese Sachen können, um decorationsfähig zu sein, entweder einfach geprefst oder geschliffen und polirt, sowohl im Feuer als auf der Scheibe hergestellt werden.All of these things can, in order to be capable of decoration, either simply pressed or be ground and polished, both in the fire and on the disc.
Zur Decoration dieses Glases werden verwendet: The following are used to decorate this glass:
ι. ι Theil Schwefelsilber und 5 Theile Eisenocker, was hauptsächlich das Hervortreten der dunkelgrünen Flasern hervorbringt.ι. ι part sulfur silver and 5 parts iron ocher, which mainly brings out the emergence of the dark green fibers.
2. ι Theil Schwefelsilber und 5 bis 10 Theile Manganoxyd (Braunstein); diese Masse bedingt ein Hervortreten von dunkel- und hellbraunen Flasern. An Stelle des Schwefelsilbers kann man überall Chlorsilber anwenden, doch ist dasselbe weniger ausgiebig.2nd part silver and 5 to 10 parts Manganese oxide (brownstone); this mass causes a prominence of dark and light brown Flasers. In place of the sulfur silver one can use chlorine silver everywhere, but it is the same less extensively.
3. ι Theil kohlensaures Kupferoxyd und 1 bis 3 Theile Eisenocker, was eine hell- bis dunkelrothbrauneFärbungbedingt. Eisenocker, Manganoxyd und Thonerde können sich unter einander stets ersetzen, da dieselben vornehmlich nur dazu bestimmt sind, das Silber- bezw. das Kupferoxyd in eine passende Verbindung zu bringen, und weil diese Hülfspräparate bei Hervorbringung der Farbentöne nicht so viel selbstständigen Charakter besitzen, dafs deren Wirkung nicht durch Verwendung eines anderen Materials erreicht werden könnte. Stärkeres oder geringeres Auftragen der Präparate verändern die Farbentöne bis zum intensivsten Cobaltblau.3. Part of carbonate of copper oxide and 1 bis 3 parts iron ocher, which causes a light to dark red-brown color. Iron ocher, manganese oxide and clay can always replace one another, since the same primarily only for this purpose are determined, the silver respectively. to bring the copper oxide into a suitable connection, and because these auxiliary preparations are not so independent in producing the color tones Have character that their effect cannot be achieved by using another material could be. More or less application of the preparations changes the color tones to the most intense cobalt blue.
Die Präparate 1., 2. und 3. lassen sich in verschiedenen Verhältnissen unter einander mischen, und herrscht der Charakter derjenigen vor, welche sich im Gewichtsverhältnisse im Ueberschusse befinden. Auch kann eines dieser Präparate auf das andere aufgetragen und sowohl inPreparations 1., 2. and 3. can be mixed with each other in different proportions, and the character of those who are in excess in relation to weight prevails are located. One of these preparations can also be applied to the other and both in
einem Feuer als in^ mehreren auf einander folgenden Bränden eingebrannt werden.one fire than in ^ several upon one another following fires.
Die Decoration geschieht derart, dafs das Präparat mit Wasser angerieben, mit dem Pinsel oder sonstwie auf das bestimmte Glas aufgetragen, sodann letzteres einer leichten Rothglut ausgesetzt und nach dem Erkalten abgewaschen wird.The decoration is done in such a way that the preparation is rubbed with water with a brush or otherwise applied to the particular glass, then the latter a light red glow exposed and washed off after cooling.
Die Manipulation ist ähnlich der Gelb- und Rothätzung der Tafelgläser, und handelt es sich nicht um ein Aufschmelzen der Decorationsmittel, sondern es haben letztere den Zweck, sich bei Rothglut mit dem überschüssigen, im Glase enthaltenen Eisenoxyd und dem Graphit (Kohle) chemisch zu verbinden und so die verschiedenartig gefärbten und gestalteten Zeiclv nungen hervorzurufen. .The manipulation is similar to the yellow and red etching of the table glasses, and it is not a melting of the decoration means, but the purpose of the latter is to red heat with the excess iron oxide and graphite contained in the glass (Charcoal) to combine chemically and thus the differently colored and shaped Zeiclv evoke voltages. .
Neu ist an dieser Erfindung die Hervorbririgung einer Marmor und Jaspis ähnlichen Structur des Glases, hervorgerufen durch die Behandlung eines übersättigten schwarzen Kohlenglases mit Silber- und Kupferpräparaten.What is new about this invention is the creation of something similar to marble and jasper Structure of the glass caused by the treatment of an oversaturated black carbon glass with silver and copper preparations.
Claims (1)
ι. ι Theil chemisch reinem Schwefelsilber oder Chlorsilber mit 4 bis 12 Theilen Eisenocker, Thonerde oder Manganoxyd; oder aber aus: 2. ι Theil kohlensaurem Kupferoxyd mit 1 bis 3 Theilen Eisenocker, Thonerde oder Manganoxyd. The manufacture of decorations on black glass made of 100 parts sand, 3 parts Glauber's salt, 4 parts iron, 12 parts graphite, 36 parts soda, 12 parts lime, 12 parts potash, by using mixtures which consist either of:
ι. Part of chemically pure silver sulfur or silver chloride with 4 to 12 parts of iron ocher, alumina or manganese oxide; or from: 2nd part carbonate of copper oxide with 1 to 3 parts of iron ocher, alumina or manganese oxide.
Publications (1)
Publication Number | Publication Date |
---|---|
DE27087C true DE27087C (en) |
Family
ID=303419
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT27087D Active DE27087C (en) | Process for the production of a marble or jasper-like glass by treating a black carbon glass with silver or copper preparations |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE27087C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3369846A (en) * | 1966-05-25 | 1968-02-20 | Westinghouse Air Brake Co | Variable load brake control apparatus |
-
0
- DE DENDAT27087D patent/DE27087C/en active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3369846A (en) * | 1966-05-25 | 1968-02-20 | Westinghouse Air Brake Co | Variable load brake control apparatus |
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