DE26308C - Process for the separation of azo dyes of mixed naphthol sulfonic acids using, in part, the process protected by Patent No. 18027 - Google Patents
Process for the separation of azo dyes of mixed naphthol sulfonic acids using, in part, the process protected by Patent No. 18027Info
- Publication number
- DE26308C DE26308C DENDAT26308D DE26308DA DE26308C DE 26308 C DE26308 C DE 26308C DE NDAT26308 D DENDAT26308 D DE NDAT26308D DE 26308D A DE26308D A DE 26308DA DE 26308 C DE26308 C DE 26308C
- Authority
- DE
- Germany
- Prior art keywords
- acid
- azo dyes
- mixed
- separation
- sulfonic acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000987 azo dye Substances 0.000 title claims description 5
- 238000000926 separation method Methods 0.000 title claims description 3
- 238000000034 method Methods 0.000 title claims 4
- -1 naphthol sulfonic acids Chemical class 0.000 title description 3
- 239000002253 acid Substances 0.000 claims description 16
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-Naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 claims description 11
- 239000011780 sodium chloride Substances 0.000 claims description 6
- MBENGEYDAUUYCZ-UHFFFAOYSA-N 1-diazo-2H-naphthalene Chemical compound C1=CC=C2C(=[N+]=[N-])CC=CC2=C1 MBENGEYDAUUYCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- 235000015450 Tilia cordata Nutrition 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- KVUMAMKEDVSBSO-UHFFFAOYSA-N [N+](=[N-])=C1C(C=CC=C1)N=NC1=CC=CC=C1 Chemical compound [N+](=[N-])=C1C(C=CC=C1)N=NC1=CC=CC=C1 KVUMAMKEDVSBSO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052601 baryte Inorganic materials 0.000 claims description 3
- 239000010428 baryte Substances 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims description 2
- 229950011260 betanaphthol Drugs 0.000 description 8
- 239000000975 dye Substances 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 235000002639 sodium chloride Nutrition 0.000 description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
- NPAYBXSLOLNULX-UHFFFAOYSA-N 2-diazo-1H-naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)C(=[N+]=[N-])C=CC2=C1 NPAYBXSLOLNULX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Description
KAISERLICHESIMPERIAL
'ipATE'rfÄ'M'ipATE'rfÄ'M
Anstatt die Naphtolsulfosäuren zu trennen und Azofarbstoffe aus den reinen Naphtolsulfosäuren darzustellen, kann man gewisse Azoverbindungen durch die verschiedene Löslichkeit ihrer Thonerde-, Kalk-, Baryt- und Strontiansalze von einander scheiden.Instead of separating the naphthol sulfonic acids and azo dyes from the pure naphthol sulfonic acids one can represent certain azo compounds by the different solubility their alumina, lime, barite and strontian salts separate from each other.
Diese Trennung läfst sich besonders gut anwenden bei Azofarbstoffen, welche dargestellt sind aus einem Gemenge der Alpha- und Betamonosulfosäure des Betanaphtols mit Diazonaphtalinmonosulfosäure und Diazoazobenzolmonosulfosäure (Anspruch L), sowie aus einem Gemenge der Di- und Trisulfosäure des Betanaphtols mit Diazonaphtalinmonosulfosäure, Diazoazobenzol und Diazoazobenzolmonosulfosäure (Anspruch IL).This separation can be used particularly well in the case of azo dyes, which are shown are made from a mixture of alpha and beta monosulphonic acid of betanaphthol with diazonaphthalene monosulphonic acid and diazoazobenzene monosulfonic acid (claim L), as well as from a mixture of the di- and trisulfonic acid of betanaphthol with diazonaphthalene monosulfonic acid, diazoazobenzene and diazoazobenzenesulfonic acid (claim IL).
Beispiel zu Anspruch I.Example for claim I.
50 kg Farbstoff, dargestellt aus Alphadiazonaphtalinmonosulfosäure und den gemischten Alpha- und Betamonosulfosäuren des Betanaphtols, werden in ca. 1000 1 Wasser heifs gelöst; es wird so lange eine Lösung von schwefelsaurer Thonerde und Ammoniak zugegeben, als noch ein Niederschlag beim Erkalten erfolgt. Man läfst nun erkalten und filtrirt von dem Thonerdelack des Farbstoffes der Betasulfosäure des Betanaphtols ab. Im Filtrat fällt man den Farbstoff der Alphasulfosäure des Betanaphtols mit Kochsalz aus.50 kg of dye, prepared from alphadiazonaphthalene monosulfonic acid and the mixed alpha and betamonosulphonic acids of betanaphthol become hot in approx. 1000 liters of water solved; a solution of sulfuric alumina and ammonia is added so long when there is still a precipitate on cooling. It is now allowed to cool and filtered off the alumina varnish of the dye of the beta sulfonic acid of betanaphthol. Falls in the filtrate the pigment of the alpha sulfonic acid of betanaphthol with table salt.
Beispiel zu Anspruch II.Example for claim II.
50 kg Farbstoff, dargestellt aus den ge^ mischten Di- und Trisulfosäuren des Beta-' naphtols (durch Einwirkung von rauchender Schwefelsäure auf Betanaphtol bei 130 bis 1400C.) und Diazoazobenzolmonosulfosäure, werden in ca. 1000 1 Wasser heifs gelöst und so lange mit einer Lösung von schwefelsaurer Thonerde und Ammoniak versetzt, als noch ein Niederschlag beim Erkalten erfolgt. Man läfst erkalten und filtrirt von dem Thonerdelack des Farbstoffes der Betanaphtoldisulfosäure ab. Im Filtrat fällt man den Farbstoff der Betanaphtoltrisulfosäure mit Kochsalz aus.50 kg dye represented from the ge ^ mixed di- and Trisulfosäuren of beta 'naphthol (by exposure to fuming sulfuric acid to Betanaphtol at 130 to 140 0 C.) and Diazoazobenzolmonosulfosäure, are dissolved in 1000 1 of water remains hot, and so long mixed with a solution of sulfuric alumina and ammonia when a precipitate still occurs on cooling. It is allowed to cool and the alumina varnish of the dye of betanaphthol disulphonic acid is filtered off. The dye of betanaphtholtrisulfonic acid is precipitated in the filtrate with common salt.
An Stelle der Thonerdesalze können auch die Kalk-, Baryt- und Strontiansalze angewendet werden.The lime, barite and strontian salts can also be used in place of the clay salts will.
Wendet man z. B. zur Trennung des Farbstoffes (Anspruch L), der aus gemischter Alpha- und Betamonosulfosäure des Betanaphtols und Alphadiazonaphtalinmonosulfosäure gewonnen ist, anstatt Thonerde einen Ueberschufs von Chlorcalcium an, so scheidet sich das Kalksalz des F'arbstoffes der Alphasulfosäure des Betanaphtols beim Erkalten in Krystallen aus.If you apply z. B. to separate the dye (claim L), which consists of mixed alpha and betamonosulfonic acid of betanaphthol and alphadiazonaphthalene monosulfonic acid is obtained, instead of alumina with an excess of calcium chloride, the calcium salt separates out The dye of the alpha sulfonic acid of betanaphthol is removed in crystals when it cools.
Claims (3)
2. Diazoazobenzolmonosulfosäure,
und zwar unter theilweiser Benutzung des durch das Patent No. 18027 geschützten "Verfahrens zur Darstellung von Azofarbstoffen; ι. Alphadiazonaphthalene monosulfonic acid,
2. diazoazobenzenesulfonic acid,
with partial use of the patent no. 18027 protected "process for the preparation of azo dyes;
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE26308C true DE26308C (en) |
Family
ID=302692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT26308D Active DE26308C (en) | Process for the separation of azo dyes of mixed naphthol sulfonic acids using, in part, the process protected by Patent No. 18027 |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE26308C (en) |
-
0
- DE DENDAT26308D patent/DE26308C/en active Active
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