DE242455C - - Google Patents
Info
- Publication number
- DE242455C DE242455C DENDAT242455D DE242455DA DE242455C DE 242455 C DE242455 C DE 242455C DE NDAT242455 D DENDAT242455 D DE NDAT242455D DE 242455D A DE242455D A DE 242455DA DE 242455 C DE242455 C DE 242455C
- Authority
- DE
- Germany
- Prior art keywords
- silicon
- aluminum
- oxides
- melt
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 230000004907 flux Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 229910052752 metalloid Inorganic materials 0.000 claims 3
- 150000002738 metalloids Chemical class 0.000 claims 3
- 150000002739 metals Chemical class 0.000 claims 1
- 239000006004 Quartz sand Substances 0.000 description 3
- 239000011034 rock crystal Substances 0.000 description 3
- -1 silicon phosphorus Chemical compound 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000131971 Bradyrhizobiaceae Species 0.000 description 1
- 210000003608 Feces Anatomy 0.000 description 1
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- PIGFYZPCRLYGLF-UHFFFAOYSA-N aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000499 pig iron Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910052904 quartz Inorganic materials 0.000 description 1
- 230000000630 rising Effects 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/323—Burning methods involving melting, fusion or softening
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Silicon Compounds (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- M 242455 KLASSE 80 b. GRUPPE- M 242455 CLASS 80 b. GROUP
Die bisherigen Verfahren zur Herstellung von Schmelzflüssen aus Aluminiumoxyd, aus SiIiciumoxyd (Quarzsand oder Bergkristall) u. dgl. leiden an dem kaum oder nur schwer zu beseitigenden Umstände, daß die in den zerkleinerten Oxyden eingeschlossenen Luft- oder Gasblasen nicht aus dem geschmolzenen Gut entfernt werden können. Die zum Schmelzen erforderliche Hitze wird durchweg durch denThe previous processes for the production of melt fluxes from aluminum oxide, from SiIiciumoxyd (Quartz sand or rock crystal) and the like suffer from that which is difficult or difficult to remove Circumstances that the air or entrapped in the crushed oxides Gas bubbles cannot be removed from the molten material. The ones to melt required heat is consistently provided by the
ίο elektrischen Strom oder durch das Knallgasgebläse oder durch Zusammenwirken beider geliefert.ίο electric current or by the oxyhydrogen blower or delivered by the cooperation of both.
Erfinder wurde nun zur Beseitigung der in den Poren verbleibenden Luft auf ein chemisches Verfahren geführt. Den Anlaß hierzu hat ein Verhüttungsverfahren gegeben, nach welchem Sauerstoff in das geschmolzene Roheisen eingeleitet und die darin enthaltenen Verunreinigungen, wie Siliciumphosphor usw., durch den zugeführten Sauerstoff oxydiert wurden. In ähnlicher Weise hat Erfinder bei der Entfernung der Gasblasen aus dem schmelzenden Quarz oder Aluminiumoxyd vorzugehen versucht. Um die hauptsächlich aus Sauerstoff und Stickstoff bestehenden Gasblasen zu beseitigen, mengt man dem Quarzsand oder dem stückigen oder körnigen Bergkristall Siliciumpulver bei. Beim Erhitzen des Gemenges verbindet sich das pulverförmige SiIicium mit dem Sauerstoff zu Siliciumoxyd, das mitgeschmolzen wird, und zu Siliciumstickstoff, der sich ausscheidet.The inventor was now to remove the air remaining in the pores on a chemical Proceedings conducted. The reason for this was a smelting process, according to which oxygen is introduced into the molten pig iron and the contained therein Impurities such as silicon phosphorus, etc. have been oxidized by the supplied oxygen. Similarly, the inventor has in removing the gas bubbles from the melting Quartz or aluminum oxide tried to proceed. To which mainly from oxygen and nitrogen to remove existing gas bubbles, one mixes the quartz sand or the lumpy or granular rock crystal silicon powder. When heating the mixture the powdered silicon combines with the oxygen to form silicon oxide, the is also melted, and to silicon nitrogen, which is precipitated.
In gleicher Weise setzt man beim Schmelzen von Aluminiumoxyd etwas pulverförmiges Aluminium dem zu schmelzenden Material bei, so daß Aluminiumoxyd und Aluminiumstickstoff sich bilden kann und jede Blasenbil-. dung verhindert wird.In the same way, something powdery is added when aluminum oxide is melted Aluminum contributes to the material to be melted, so that aluminum oxide and aluminum nitrogen can form and any blistering. dung is prevented.
Die vorbeschriebene Arbeitsweise läßt sich auch so gestalten: In geschmolzenes Silicium wird ein Sauerstoff strahl eingeblasen, welcher sich mit dem Silicium zu Siliciumoxyd verbindet und so viel Wärme entwickelt, daß die Temperatur bis zum Schmelzen des Siliciumoxyds, etwa zwischen 1700 bis 18500 und noch darüber steigt. Da aber höhere Temperaturen die Qualität des Schmelzflusses beeinträchtigen und verhindern, daß ein klares durchsichtiges Produkt erhalten wird, so muß man ein Steigen der Temperatur über diese Grenzen hinaus verhindern', indem man Bergkristallstücke oder Quarzsand zugiebt. Das Schmelzen des Siliciums geschieht zweckmäßig in einem, Schmelzofen, der elektrisch oder auch durch Sauerstoffgebläse beheizt werden kann.The working method described above can also be designed as follows: An oxygen jet is blown into molten silicon, which combines with the silicon to form silicon oxide and develops so much heat that the temperature until the silicon oxide melts, approximately between 1700 to 1850 0 and even above increases. But since higher temperatures impair the quality of the melt flow and prevent a clear, transparent product from being obtained, one must prevent the temperature from rising beyond these limits by adding pieces of rock crystal or quartz sand. The silicon is expediently melted in a melting furnace which can be heated electrically or by an oxygen blower.
Wie das Silicium kann man in ganz gleicher Weise auch das Aluminium behandeln, obschon dies schwieriger ist, da das Aluminium leichter verdampft.Like silicon, aluminum can be treated in exactly the same way, although this is more difficult as the aluminum evaporates more easily.
Schließlich kann man auch brennbare Verbindungen wie Siliciumäthyl, Siliciummethyl, Aluminiumäthyl usw. mit Sauerstoff verbrennen und so die sich bildenden Oxyde des Siliciums oder Aluminiums zu durchsichtigen Schmelzflüssen in gleicher Weise sich vereinigen lassen. Auch bei dieser Arbeitsweise wird soFinally, you can also use flammable compounds such as silicon ethyl, silicon methyl, Burn aluminum ethyl etc. with oxygen and so the oxides of silicon that are formed or aluminum merge in the same way to form transparent melt flows permit. This is also the case with this way of working
5555
6060
viel überschüssige Verbindungswärme frei, daß die zugesetzten Oxyde mitschmelzen.a lot of excess bonding heat is released so that the added oxides melt with it.
Claims (3)
Publications (1)
Publication Number | Publication Date |
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DE242455C true DE242455C (en) |
Family
ID=501658
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT242455D Active DE242455C (en) |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE242455C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2480473A (en) * | 1945-12-10 | 1949-08-30 | Reynolds Metals Co | Refractory and method of making |
US2678282A (en) * | 1950-06-01 | 1954-05-11 | Pilkington Brothers Ltd | Process for manufacturing synthetic inorganic silicates or the like |
-
0
- DE DENDAT242455D patent/DE242455C/de active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2480473A (en) * | 1945-12-10 | 1949-08-30 | Reynolds Metals Co | Refractory and method of making |
US2678282A (en) * | 1950-06-01 | 1954-05-11 | Pilkington Brothers Ltd | Process for manufacturing synthetic inorganic silicates or the like |
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