DE2357335A1 - COSMETIC PREPARATION - Google Patents

Description

16 Nov 1973 Drying. A, van der Werih . . .

Dr. Franz Ladder

P ATENT REQUEST

RAN 6400/9

F. Hoffmann-La Roche & Co. Aktiengesellschaft, Basel / Switzerland

Cosmetic preparation

The present invention relates to a preparation for cleaning skin and hair which has a washing effect softening conditioning film caused, a process for the production of this preparation and its application for cleaning skin and hair.

Both dermatologists and laypeople recognize it mostly that many of the cleaning agents available on the market Remove preparations such as toilet soaps, cleaning agents, foam-forming pastes or creams, etc. from the skin oils and thus a "drying out of the skin, which in the form of roughness, Dandruff formation and sometimes itching can appear. Such preparations can also treat the diseases of the Aggravate skin characterized by such symptoms To eliminate or prevent such symptoms, - especially in women - skin lotions and creams, which

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Moisturizing or emollient substances often contain 'used' to prevent the skin from losing moisture delay and make the outer cell layer soft and supple. Such preparations often have the for the consumer Disadvantage that they have to be carried in the pocket and also mean an unwelcome expense. as As a result, many people who suffer from dry skin refrain from using such preparations from the outset.

A very large number of the soaps or other means for cleaning the skin available on the market neither have a softening effect nor do they additionally contain an emollient substance. The cleansing preparations, which contain emollient substances such as water-in-oil emulsions, fats, oils, etc. and which are claimed to adhere to the skin when used and leave a softening film after washing, often correspond to these claims only unsatisfactorily . This is due to the fact that most organic, animal or vegetable oils in the presence of the amount of detergent which is required to produce a sufficient foam, only have a low adhesive capacity on the skin. As far as the shampoos on the market are concerned , the situation is similar, as very many of them clean the hair sufficiently, but do not give the hair sufficient softness, volume and mobility. As proof that such products do not condition the hair sufficient commercial success is true of "after-shampoo" conditioning detergent or other conditioning agents! For man and woman.

There is thus a real need for a preparation for cleaning skin and hair which cleanses and cleans very well foams, and additionally hair and skin by applying during

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the purification of a tangible, softening film, conditioned. Such a preparation is provided by the present invention.

The present invention relates to a liquid or semi-solid preparation for cleaning and "conditioning" skin and hair. The application of a felt emollient film on the skin and / or on the hair during cleaning. Delayed on the skin such a film prevents moisture loss from the epithelium and maintains or renews the softness and suppleness of the skin surface. On the hair "gives" - that by the invention Film applied to the preparation, combability and mobility. The softening film mentioned contains im essential petrolatum with additional oily or fatty, known plasticizing substances.

More specifically, the present invention relates to a foaming, softening preparation for cleaning Skin and hair consisting of an oil-in-water emulsion containing:

a) 10 to 70 percent by weight petrolatum,

b) 5 to 30 percent by weight of one or more organic foam-forming detergents,

c) 1 to 10 percent by weight of an emulsifying agent,

d) 0.5 to 5 percent by weight of an organic agent for stabilizing foam,

e) Ό to 20 percent by weight of a plasticizing Substance, but not petrolatum

f) 10 to 80 percent by weight water,

wherein the amount of component (b) is no more than twice the amount of component (a) is' and in the oily phase of the emulsion 95 to 98 percent of the particles have a particle size smaller than 5μ, 2 to 5 percent a particle size

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between 5 and ΙΟμ, 0.2 to 1.0 percent a particle size between 10 and ΙΟΟμ and practically none of the particles one Have particle size greater than ΙΟΟμ.

The present invention is based on the finding that by mixing petrolatum with certain organic Cleaning agents water-in-oil emulsions can be produced, which at the same time provide sufficient

Have forming properties, clean extremely well and a PiIm of fine particles of petrolatum on skin and apply hair. This film, which conditions and softens the skin and hair, has sufficient adhesion to to remain on the skin or hair after rinsing with water.

It was found that the distribution of the particles— large in the oil phase of the water-in-oil according to the invention Emulsions must be between certain limits in order to achieve maximum physical stability and functional effectiveness is achieved. More precisely, the great majority of these particles must be used for the maximum stability of the emulsion have a particle size less than 5 microns. On the other hand, for the functional effectiveness a minimal proportion must be on the particles of the oil phase, i.e. petrolatum and possibly other softening substances, a relatively large one Have particle size. For this reason, the particles of the oil phase of the oil-in-water emulsion according to the invention must have approximately the following particle size distribution: Approximately 98 percent of the particles have a particle size smaller than 5μ, approximately 2 percent a particle size of 5μ or more than 5μ and 0.2 percent a particle size of ΙΟμ or more than ΙΟμ. More precisely, own - as already mentioned - 95 to 93 percent of the particles a particle size smaller than 5μ, 2 to 5 percent a particle size between

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5 and 10 μ, 0.2 to 1.0 percent a particle size between 10 and 100 μ and practically none of the particles have a particle size over 100 μ.

The above-mentioned particle size distribution of the particles of the oil phase of the preparation according to the invention can be achieved by continuing the stirring of the emulsion after its preparation. Such stirring is at a temperature below 40 ⁰ C, ie between 20 ⁰ C and 40 ⁰ C, preferably between 20 ⁰ C and -30 ⁰ C, performed. Stirring the emulsion at these temperatures causes the particles of the oil phase to coalesce, which leads to an increase in the average size of these particles and the proportion of oil particles with a particle size between 5 and 100 microns. The time which is required to achieve the desired particle size distribution of the particles depends on the exact composition of the emulsion, the speed and the type of stirrer used, the amount of emulsion and the like. As a rule, however, this time is 1/4 to 4 hours, preferably 2 hours. The increase in the proportion of oil particles with a particle size between 5 and 100 microns increases the amount of oil particles which are applied to the skin and hair when using the preparation according to the invention for cleaning skin and hair. The particle size distribution of the oil phase can can be measured with a counter (Coulter).

The preparations according to the invention generally contain about 10 to 70 percent by weight, preferably 10 to 50 percent by weight, petrolatum; about 5 to 30 percent by weight, preferably 10 to 30 percent by weight, one or more organic foam-forming cleaning agents; approximately 1 to 10 percent by weight, preferably 3 to 8 percent by weight of an emulsifying agent; about 0.5 to 5 weight

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Percent, preferably 1 to 3 percent by weight of an organic Agent for stabilizing foam; about 0 to 20 percent by weight, preferably 3 to 15 percent by weight one or more emollients, but not petrolatum; Water up to 100 percent.

The amount of water in the inventive Preparation is included, depends on the desired thickness. Since the preparations according to the invention Y / water-in-oil Emulsions can - by changing the amount of water, e.g. viscous liquids, semi-liquid creams, pastes and the like. As a rule, the preparations according to the invention contain between 25 and 80 percent by weight V / water in the case of a liquid administration form and between 10 to 50 percent by weight V / water in the case of a Paste. In the case of a paste, they contain the invention Preparations with advantage between 20 to 50 percent by weight water, while in the case of a liquid form of administration between 30 and 80 percent by weight of water are preferred. The preparations, plural marriage contain 30 to 50 percent by weight of water, are - depending on the properties of the non-aqueous components - liquid or semi-solid.

The petrolatum suitable for the purposes of the present invention is any grade of white or yellow Petrolatum, which is widely recognized as being harmless to human skin and hair. Be with advantage Petrolatum USP XVIII and NFXII used. According to the invention, a petrolatum can be mixed with any of those recognized by experts in the field Viscosity and consistency are used. However, the present invention also includes the replacement of one Part of the petrolatum by a mixture of hydrocarbons, which resembles petrolatum in appearance and consistency. Such a mixture can for example bycl

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Melting together of different amounts of mineral oil with substances such as microcrystalline wax, paraffin wax, ceresin and ozokerite can be obtained. The present invention also includes - in the case of hair cleansing preparations - the additive to petrolatum of one or more softening substances, which are known to give the hair shimmer, shine and softness and cause a reduction in static electricity. It is jeioch. required that the inventive Preparations contain at least 10 percent by weight of petrolatum.

The abovementioned softening gels, which are used to increase the softening properties of petrolatum, contain one or more known substances such as fatty alcohols, liquid esters of mono- or di-basic fatty acids, vegetable oils, modified fatty acid glycerides, silicone oils, acetylated lanolin alcohols, esters of Lanolin fatty acid, cholesterol, lanolin, liquid lanolin, myristyl myristate, mineral oils, squalene, squalane (perhydrosqualene) and the like. The proportion qm of these additional softening substances in the preparations according to the invention can be up to 20 percent by weight. The synthetic, organic, foam-forming cleaning agents which are used in the preparations according to the invention can be anionic, nonionic or amphoteric in nature. When selecting a suitable cleaning agent, the irritant properties of the individual cleaning agents are particularly taken into account. Additional criteria that must be met are the ability of each cleaning agent to stabilize the emulsion, to cause viscosity, to bring about the desired degree of foam and at the pH of the preparation, ie at a pH value of 7 to 9, to stay stable. Suitable cleaning agents contain, for example, the following compounds,

Anionic ; Alkali and triethanolamine lauryl sulfates, lauryl ether sulfates, sodium alkylbenzenesulfonates, secondary alkyl sulfate, salts of higher acyl esters of hydroxyethyl sulfonic acid, sodium salts of higher acyl derivatives of taurine or methyl taurine, alkylphenol polyether sulfate, alkylphenol polyether sulfate, higher acyl-higher alkylsulfate, alkylsulfonyl succinate, di-alkyl succinate, higher acyl derivatives of glycine and methyl succinic esters, higher acyl derivatives of glycine and methyl succinic esters. monoglyceride sulfates, alpha-olefin sulfonates;

Non-ionic : alkylaryl polyether alcohols, alphahydro-omega-hydroxy-poly (oxypropylene) -polyoxyethylene block copolymers and

Amphoteric : disodium salts of imidazolinium dicarboxylic acids substituted with higher alkyl, the linking group via which the carboxyl groups are linked to the imidazolinium ring containing an ether linkage; higher acyl betaaminopropionate, higher acyl peptides, higher alkyl amidobetaines, and the like.

The cleaning agent preferred according to the present invention is a mixture of approximately one part by weight Alkali metal lauryl sulfate or lauryl ether sulfate and of about 0.5 to 10 parts by weight, preferably 1 to 4 parts by weight, one or more disodium salts of higher alkyl substituted imidazolinium dicarboxylic acids such as e.g. Miranol cleaning agent, which is available from Miranol Chemical Go., Irvington, New Jersey and the following general formula

^ CH ₀ -CH ₀ -O-CH ₀ COONa

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wherein R is a higher alkyl radical preferably having 9 to 11 carbon atoms and X is hydroxyl or mean a lauryl sulfate residue.

In the preparation according to the invention, these cleaning agents result in the ideal balance of low irritation, quality and Volume of the foam and viscosity.

As already mentioned, the preparations according to the invention contain 5 to 30 percent by weight, preferably 10 to 20 Percentage by weight of detergent. In no case, however, should the amount of cleaning agent be more than double that Amount of petrolatum.

The emulsifiers suitable for the purposes of the present invention include amphiphi3.e organic emulsifiers, which are known to be harmless in preparations for cleaning skin and hair and HLB values (HLB = hydrophilic lipophilic balance) from approximately 1 to 19.

Preferred emulsifiers are those that have HLB values from 1 to 6. For the purposes of the present invention, for example, the following emulsifiers are suitable: Sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, Polyoxyethylene sorbitol esters of fatty acids, lanolin, beeswax and tallow acid, polyoxyethylene fatty acid esters, Polyoxyethylene fatty alcohol ethers, mono- and diglycerides of fatty acids, polyglycerol fatty acid esters, polypropylene glycol fatty acid esters, Fatty alcohol phosphate esters, polyethoxylated Fatty alcohol phosphate esters and the like.

Preferred specific emulsifiers are, for example _, sorbitan ■ monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monostearate, sorbitan tristearate, polyoxyethylene (2) oleyl ether,

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Polyoxyethylene (2) stearyl ether, polyoxyethylene (2) cetyl ether, Ethylene glycol monostearate, diethylene glycol oleate, diethylene glycol stearate, Propylene glycol monostearate, propylene glycol distearate, glyceryl monostearate, glyceryl monooleate, decaglycery octaoleate, Hexaglyceryl distearate and triglyceryl monooleate.

Suitable agents for stabilizing foam, which are additionally used in the preparations according to the invention as thickening agents act, contain, for example, one or more of the following substances. Diethanolamides, Monoethanol- amides and isopropanolamides of lauric acid, myristic acid and Coconut fatty acid; Stearyltrialkanolammoniumchloride, Bimethylaminoxde of fatty acids, diethanolamine oxides of fatty acids and the like. Preferred means of stabilizing Foam are diethanolamides of coconut fatty acid, which mainly contains fatty acids with 12 to 14 carbon atoms, caprylic acid diethanolamide, a mixture of lauric acid monoethanolamide and myristic acid monoethanolamide (70-50) and stearyl trihydroxyammonium chloride.

The present invention also includes the addition of the softening and cleaning preparations according to the invention of certain non-critical ingredients which are known to be commonly used in such preparations will. Such components are e.g. organic or inorganic acids for adjusting the pH-value, dyes, perfumes, Preservatives, antioxidants, and chelating agents like that. In order to adjust the viscosity and reduce irritation, 0 to Percent by weight, preferably 0.5 to 1.5 percent by weight, of polyvinylpyrrolidone are used in the preparations according to the invention will. Oil-soluble medicines, which are known to be used in preparations for cleaning skin and hair,

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ζ »Β. Anti-dandruff remedies can also be used the inventive preparations are added to the softening PiIm, which is applied to the skin and hair, to give therapeutic properties. .

As a rule, the preparations according to the invention are produced by first melting all the fat-like constituents together and melting them with them. the aqueous phase, which contains a mixture of detergents, agents to stabilize the foam and water, mixed with constant stirring. The temperature of the two phases during mixing is between 60 and 80 ^° C. The oily phase can be added to the aqueous phase or vice versa. The mixture is ansehliessend cooled with constant stirring to a temperature below 30 ⁰ G. Perfumes are added to the mixture during the cooling at a temperature between 50 ⁰ and 40 ⁰ C G. After the temperature is decreased to 30 ⁰ C, the emulsion is observed · each quarter of an hour under the microscope at continuous stirring and maintaining the temperature between 25 ⁰ C and 3Q ⁰ G. Stirring is continued until a sufficient proportion - ie approximately 2 percent of the visible oil particles - has a particle size of over 5 microns, with 90 percent of these particles having a particle size between 5 and 10 microns and the remainder having a particle size between 10 and 100 microns. At a temperature below 30 ⁰ C, the average particle size increased in the oil phase of the emulsion very quickly with increasing stirring time or increasing agitation speed.

The amount of oil phase, which when using the The preparation according to the invention is applied to the skin and to the hair depends directly on the average particle flow the particles, in the oil phase of the emulsion. the end For this reason, the application of OeI, by controlling the Time and speed of agitation prior to manufacture

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of the emulsion at a temperature below 30 ⁰ C, must be kept between certain limits. To establish guidelines for stopping agitation, wash tests can be performed on the skin and hair as described below. As a rule the preparations according to the invention after cooling below 3O ⁰ C is stirred with conventional stirring elements, such as with an anchor-type stirrer at a revolution speed of 10-50 rpm for a period of 1/2 to 4 hours, preferably 2 hours. These values depend on the specific equipment used, the desired consistency of the product, the desired amount of oil sedimentation and the like. Varying these parameters must be regarded as obvious to a person skilled in the art on the basis of the present description.

In the context of the present invention can be used to produce of a preparation with certain properties, additional variations can be made. For example, the consistency of the product by adjusting the proportions between water, detergent, oil and thickener or else by changing the melting point of the oil phase. A water content of 20 to 40 percent by weight leads usually a product with the consistency of a thick paste while a water content of more than 40 percent by weight usually results in a product with an increased flow index. The volume of that formed by stirring with water Foam can also be varied by changing the amount and type of foam-forming cleaning agent. So owns E.g. sodium lauryl sulfate has a great foaming power, however also high irritability. Its use in the preparations according to the invention is accordingly limited. It will but preferably at least 3 percent by weight, preferably 5 to 10 percent by weight, in the preparations according to the invention Lauryl sulfate in combination with other foaming agents

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organic detergents, which both have a lower level Foaming power than exhibiting less irritability, too use. .

The tests below are used to examine the Amount of OeI, which in the .Use of the various inventive Preparations applied to the skin and hair will.

For the investigation of the inventive preparations for the cleaning of hair a tuft of human hair .If having a length of about 20 cm _r an average weight of 5 g and a normal thinness, bound together at one end, cleaned by dipping into 3 times 15 ml of hexane and drained after each immersion. The hair is towel-dried, and then allowed to air dry completely. The clean hair is carefully soaked with warm tap water, pressed out to dry and treated with exactly 1 gram of the preparation to be tested. This preparation is spread over the tuft of hair and worked vigorously with the fingers in order to produce a maximum of foam. The cleansing preparation is removed by carefully rinsing the hair with warm tap water in about a minute. The tuft of hair is squeezed out, dried with a towel, combed through and carefully dried in a stream of warm air. The dried tuft of hair is then completely extracted with hexane. The extract is filtered through paper and evaporated to dryness. The oily residue is then precisely weighed and the amount of OeI - in milligrams per gram of the tested preparation - is calculated.

To the amount of OeI, plural marriage by the invention ■ -cleaning preparations are applied to the skin, to check, becomes a rectangular area of 5 cm χ 10 cm with

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drawn with a pencil on the flat, hairless inside of the forearm. The arm is held so that the marked area is directed downwards, this area being sprayed with a stream of hexane, until 25 ml of hexane are used. Vasching with hexane is then given up. The dried and washed surface, which looks white and flaky, is then carefully moistened with water. Exactly 0.25 g sample is evenly distributed over the marked area. With a little water, the preparation will through vigorous rubbing with fingers brought to maximum foam. The arm is carefully rinsed with warm water until the marked area no longer looks slippery and soapy. The marked area is then marked with a Towel and then air dried. The treated area is finally covered with a hexane stream of approximately 25 ml extracted and the extract in a funnel of 50 ml beaker with a diameter of 20 cm. The solvent is then evaporated and the amount of oily Residue - determined in milligrams per gram of the tested product.

A chromatographic analysis of the oily residue extracted with hexane in the above test has shown that this residue contains the same components as the oily phase of the tested preparation.

The invention is illustrated by the examples below explained in more detail. All temperatures are given in degrees Celsius.

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13 ^ 7335-

Example 1 '

A foam-forming emollient preparation for washing of the body when bathing or showering is made with the help of the following ingredients.

Component . Weight percent

White petrolatum 36.0

Acetylated Lanolin Alcohols, Liquid Fraction .2.0

Liquid lanolin 2.0

2
Polyesters of cura chain fatty acids 1.0

Sorbitan sesquioleate 5.0

Sodium Lauryl Sulphate - 9.0.

2-capryl-l-carboxymethyloxyethyl-? L-carboxymethylimidazoliniura 1-hydroxide disodium salt 10.0

Diethanolamide of caprylic acid 1.2

Polyvinyl pyrrolidone. 0.1

Perfume q.s.

V / ater rest

Acetulan-ikierican Cholesterol Products Division of CPC International, Inc.

Neobee-Drew Chemical Corp., Inc.

The first five ingredients (oil phase) are mixed and heated to approximately 80 ° in a stainless container while stirring. The remaining ingredients are in a separate jacketed stainless kettle with a
combined anchor-type stirrer and heated to about 80 °. The sodium lauryl sulfate is in the form of a 42 percent aqueous paste - and the imidazolinium salt in the form of a
.38 percent solution added. The aqueous phase is then slowly added to the oil phase with: rapid stirring (approx. 2000 rpm) with a rotary stirrer. After complete

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Mixing and emulsification of the oil is removed from the electric stirrer and stirring is continued with an anchor-type stirrer at a speed of 30 rpm. The temperature of the emulsion is lowered to 50 ° by circulating cold water through the jacket of the kettle. Perfume is added at 50 ° and the temperature of the emulsion is then gradually reduced to JO ⁰ . Stirring is continued at a temperature of about 25 ° for two more hours. Stirring is continued until the microscopic observation of the emulsion at 100 times magnification indicates that the desired particle size distribution of the particles has been achieved. Finally, the stirring is stopped and the product is packed in suitable containers.

The product is a stable, opaque, viscous, but pourable skin water. Applying this product to the skin and lathering it with v / ater will make a very good one Foam quality achieved. If this product is tested on the forearm - as already described - it turns out found that approximately 30 mg of OeI per gram of product applied is deposited and that the surface of the skin is soft and looks sleek.

Example 2

A foaming, emollient, cleansing face cream is prepared in analogy to Example 1 with the help of the following ingredients:

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Best andteil weight percentages

White petrolatum 27.0

Coconut oil '1.5

Sesame oil 2.5

Squalene O ₀ 5

Sgualan O ₀ 5

Cholesterol 0.2

Lanolin Sterols and Alcohols 1 “5

Spermaceti 1.0

Myristyl myristate Γ _β 0

Sorbitan sesquioleate - 5 * 0

Sodium lauryl sulfate at 7.5

Disodium salt of l-carboxymethyl - l-carboxy ~ ethyl-2-coco-imida ^ olinium-l-hydroxide 4 · 7

Disodium salt of 1-carboxymethyl-l-carboxy-

methyloxyäthyl-2-coco-imidazolinium 1-lauryl-

sulfate '6.8

Stearyltrihydroxymethylammonium chloride. 1 * 5

Polyvinyl pyrrolidone 0.5

Citric acid q _o s "with a pH of 7» 2. 0.2

V / ater 'rest

Amerchol ~ American Cholesterol Products Division of CPC International, Inc.

Since this is a face cream, the pH value reduced to 7 »2 to avoid eye and skin irritation«. A larger amount was also used in this preparation of OeI than vervreidet in the preparation according to Example 1 to make it easier to remove make-up and dry out the skin of the face by applying a thick film of oil fight "The preparation is a mild cream that has one forms massive foam and applies a noticeable film to the skin. In the forearm test already described

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found the product to be .approximately 40 mg OeI per gram. at. applied product and leaves the skin soft and supple.

Example 3

A shampoo for conditioning and caring for male hair is used in analogy to Example 1 with the aid made of the following components:

Best in part ■ Weight percent

White petrolatum 25.0

Liquid Lanolin 3.0

Acetylated Lanolin Alcohols, Liquid Fraction

(Acetulan) 1.0 "

Sorbitan sesqiiioleate 5.0

Sorbitan lauryl sulfate 5.0

Disodium as of l-carboxyraethyl-l-carboxymethyloxyethyl-2-coco-imidazolinium 1-hydroxide 16.0

Disodium salt of l-carboxymethyl-l-carboxymethoxyethyl-2-coco-imidazoliniuai 1- laury 1-

sulfate 3.5 mixture of 70/5 lauric acid monoethanolamide and

30- / ä kyristic acid monoethanolamide 2.0

Water rest

The product is a soft, stable cream that provides sufficient foam and foam on male hair causes excellent conditioning. Hair that is washed with this preparation does not show the unkempt Appearance that can mostly be observed with conventional soaps or shampoos. On the contrary, it is soft and looks more coiffed after drying, without being oily or greasy. In the hair test already described, it was found that the product contains about 30 mg OeI per gram the hair applies.

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Example 4

A. Shampoo for conditioning the female hair ■ is carried out in analogy to Example 1 with the help of the following Components manufactured:

, Component weight percent

Weisaes Petrolatum. 15.0

Light mineral oil 8.0

Liquid lanolin. 5.0

Sorbitan sesquioleate 5.0

I Sodium Lauryl Sulphate 9.0

Disodium salt of. 1-carboxymethyl-l-

carboxymethyloryethyl-2-coco-imidazolinium

1-hydroxide · .16.0

Caprylic acid diethanolamide 2.5

Polyethylene glycol 6000 distearate 0.4

V / ater 'rest

The egg-containing product has good foaming power and excellent conditioning properties. Hair that is washed with this preparation is not unkempt
Appearance and easy to comb through. Except in a few specific cases, there is no need to treat the hair with an after-shampoo conditioner. The dried hair has good shine, volume and hold, is not frizzled and not easy to move. The product is a polygamous stable cream and has a lighter frizier or care effect than the shampoo of Example 3 intended for men and thus achieves the milder embodiment preferred by women.

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Claims (22)

patent claims üche (ΐ) Foaming, softening preparation for cleaning skin and hair consisting of an oil-in-water emulsion containing: a) 10 to 70 percent percent petrolatum j b) 5 to 30 percent by weight of one or more organic foam-forming detergents, c) 1 to 10 percent by weight of an emulsifying agent, d) 0.5 to 5 percent by weight of an organic agent for stabilizing foam, e) 0 to 20 percent by weight of a plasticizing substance, jedocli not petrolatum f) 10 to 80 percent by weight water, wherein the amount of component (b) is not more than twice the amount of component (a) and in the oily phase of the emulsion 95 to 98 percent of the particles a particle size smaller than 5μ »2 to 5 percent a particle size between 5 and 10μ, 0.2 to 1.0 percent a particle size between 10 and 100μ and practically none of the particles have a particle size have over 100μ. 2. Preparation according to claim 1, characterized in that that the amount of component a) 10 to 55 percent by weight, the amount of component b) 10 to 30 percent by weight, the The amount of component c) is 3 to 8 percent by weight and the amount of component d) is 1 to 3 percent by weight » 3. Preparation according to claim 1 or 2, characterized in that that the amount of component e) is 3 to 15 percent by weight. 4. Preparation according to one of claims 1 to 3 »thereby 409823/1106 characterized in that component b) is a mixture of one part by weight of sodium lauryl sulfate and from 0.5 to 10 Parts by weight of one or more amphoteric cleaning agents of the general formula where R is an alkyl radical with 9 to 11 carbon atoms and X is a hydroxyl or lauryl sulfate radical, contains. 5. Preparation according to claim A- _1, characterized in that component b) contains one part by weight of sodium lauryl sulfate and 1 to 5 parts by weight of one or more amphoteric cleaning agents of the formula I * . 6. Preparation according to one of claims 1 to 5> characterized in that component c) is sorbitan sesquioleate. 7. Preparation according to one of claims 1 to 6, characterized characterized that the component b) caprylic acid diethanolamide, Stearyltrihydroxyxetliylammoiiiumchlorid or a mixture of 70 percent by weight of lauric acid monoethanolamide and 30 Weight percent myristyl acid aonoethanolamide is. 8 «, preparation according to one of claims Ibis 7, characterized characterized in that there is an additional 0.5 to 1.5 percent by weight Polyvinylpyrrolidone contains .. - .... . 4 0 9823711 OB 9. Preparation according to one of claims 1 to 8, characterized in that the HLB value of the component, b) between 1 and 6. 10. Method of making a for cleaning Skin and hair suitable shaving agent. which a) 10 to 70 percent by weight petrolatum, b) 5 to 30 percent by weight of one or more organic foam-forming detergents, c) 1 to 10 percent by weight of an emulsifying agent, d) 0.5 to 5.0 percent by weight of an organic agent; to stabilize foam, e) 0 to 20 percent by weight of a softening substance, but not petrolatum, f) 10 to 80 percent by weight .V / water, the amount of component b) not being more than double the amount of component a), characterized in that one 1) the mixture of ingredients a), c) and e) is heated to a temperature which is sufficient to produce this mixture melt, 2) mixes the components b), d) and f) together, 3) this mixture is heated to the temperature of the melt of components a), c) and e), 4) the mixture and the melt combined with stirring to form an oil-in-water emulsion, 5) this emulsion step by step with constant stirring cools to 30 °; and 6) the stirring of the emulsion continues at a temperature between 25 ^° C. and 30 ^° C. until 95 to 98 percent of the particles are one particle size in the oily phase of the emulsion 409823/1106 smaller than 5μ, 2 to 5 percent a particle size between 5 and 10μ, 0.2 to 1.0 percent a particle size between 10 and ΙΟΟμ and practically none of the particles has a particle size have more than ΙΟΟμ. 11. The method according to claim 10, characterized in that that the amount of component a) 10 to 55 percent by weight, the amount of component b) 10 "to 30 percent by weight, the Amount of component c) 3 to 8 percent by weight and the amount of component d) is 1 to 3 percent by weight. 12. The method according to claim 10 or 11, characterized in that that the amount of component e) is 3 to 15 percent by weight. 13. The method according to any one of claims 10 to 12, characterized characterized in that component b) is a mixture of one part by weight of sodium lauryl sulfate and from 0.5 to 10 parts by weight one or more aniphoteric cleaning agents of the general formula . ^. * - (SSL- fr- 0 - CH ^ - COONa IC 'X-' where R is an alkyl radical with 9 to 11 carbon atoms and X is a hydroxyl or lauryl sulfate radical, contains. 14 «The method according to claim 13, characterized in that that component b) is a component of sodium lauryl sulfate and 1 to 5 GevJchtr. parts of one or more amphoteric journeys 409823/110 6 cleaning agent of formula I contains. 15. The method according to any one of claims 10 to 14, characterized in that the component, c) sorbitan sesquioleate is. 16. The method according to any one of claims 11 to 15, characterized in that component b) caprylic acid diethanolamide, StearyltrihydroxymethylammoniiiEichlorid or a mixture of 70 percent by weight of lauric acid monoethanolamide and 30 percent by weight of myristic acid monoethanol amide is, 17. The method according to any one of claims 10 to 16, characterized in that there is an additional 0.5 to 1.5 percent by weight Contains polyvinylpyrrolidone. 18. The method according to any one of claims 10 to 17, characterized in that the HLB ~ value of component b) is between 1 and 6. 19. Method of cleaning the hair and at the same time Applying a palpable softening film, characterized in that the hair is treated with a preparation shampooed according to one of claims 1 to 9. 20. A method for cleaning the skin and for the simultaneous application of a palpable emollient film, characterized in that that the skin is washed with a preparation according to one of claims 1 to 9. 21. Use of a preparation according to one of claims 1 to 9 for cleaning the hair and for simultaneous 409 8 2 3/110 6 Applying a tactile emollient film. 22. Use of a preparation according to one of the claims 1 to 9 for cleaning the skin and applying a tactile emollient film at the same time. 409823/1106