DE2344434A1 - METHOD FOR GALVANIZING STEEL PARTS - Google Patents

METHOD FOR GALVANIZING STEEL PARTS

Info

Publication number
DE2344434A1
DE2344434A1 DE19732344434 DE2344434A DE2344434A1 DE 2344434 A1 DE2344434 A1 DE 2344434A1 DE 19732344434 DE19732344434 DE 19732344434 DE 2344434 A DE2344434 A DE 2344434A DE 2344434 A1 DE2344434 A1 DE 2344434A1
Authority
DE
Germany
Prior art keywords
steel parts
galvanizing steel
galvanizing
zinc
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19732344434
Other languages
German (de)
Other versions
DE2344434B2 (en
DE2344434C3 (en
Inventor
Friedel Kaup
Heinrich Warnke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Miele und Cie KG
Original Assignee
Miele und Cie KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Miele und Cie KG filed Critical Miele und Cie KG
Priority to DE2344434A priority Critical patent/DE2344434C3/en
Priority to SE7409725A priority patent/SE443163B/en
Priority to IT25970/74A priority patent/IT1017897B/en
Priority to GB3528774A priority patent/GB1461181A/en
Priority to JP49097139A priority patent/JPS5949309B2/en
Priority to FR7429617A priority patent/FR2242485B1/fr
Publication of DE2344434A1 publication Critical patent/DE2344434A1/en
Priority to US05/636,456 priority patent/US4046646A/en
Publication of DE2344434B2 publication Critical patent/DE2344434B2/en
Application granted granted Critical
Publication of DE2344434C3 publication Critical patent/DE2344434C3/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D3/00Chemical treatment of the metal surfaces prior to coating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D5/00Coating with enamels or vitreous layers
    • C23D5/02Coating with enamels or vitreous layers by wet methods
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • C25D5/36Pretreatment of metallic surfaces to be electroplated of iron or steel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Chemically Coating (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Coating With Molten Metal (AREA)

Description

PatentabteilungPatent department

4830 Gfitersloh 1
Carl-Miste-Straße - Telefon 881
4830 Gfitersloh 1
Carl-Miste-Straße - Telephone 881

Verfahren zum Verzinken von StahlteilenProcess for galvanizing steel parts

Die Erfindung betrifft ein Verfahren zum Verzinken von Stahlteilen, insbesondere für eine anschließende elektrophoretisch« Emaillierung.The invention relates to a method for galvanizing Steel parts, especially for a subsequent electrophoretical « Enamelling.

Um eine einwandfreie elektrophoretische Emaillierung zu bekommen, ist es notwendig, die Stahlteile mit einer dünnen Zinkschicht zu versehen.In order to get a perfect electrophoretic enamelling, it is necessary to coat the steel parts with a to provide a thin zinc layer.

Nachteilig bei den bekannten Verzinkungsverfahren ist jedoch, daß die abgeschiedene Zinkschicht ungleichmäßig dick ist. Insbesondere bei bereits verformten Teilen tritt der Nachteil auf, daß an vorstehenden Kanten und Ecken der Zinkbelag größer ist als auf den abgeschirmten Innenflächen eines profilierten Teiles. Die Folge dieser ungleichmäßigen Zinkauflage ist, daß die nachfolgende elektrophoretische Emaillierung nicht einwandfrei wird, da an den strombegünstigten Stellen die Emailhaftung durch die zu starke Zinkauflage gestört wird.The disadvantage of the known galvanizing process, however, is that the deposited zinc layer is unevenly thick is. In particular with parts that are already deformed, the disadvantage arises that on protruding edges and corners of the Zinc coating is larger than on the shielded inner surfaces of a profiled part. The consequence of this uneven The zinc coating is that the subsequent electrophoretic enamelling is not flawless, because of the electricity-favored Make the enamel adhesion is disturbed by the excessive zinc coating.

Die Aufgabe der Erfindung ist, diese bekannten Nachteile zu vermeiden und ein Verfahren zum Verzinken von Stahlteilen zu offenbaren, bei welchem die Verzinkung in einer dünnen relativ gleichmäßigen Schicht aufgetragen wird. The object of the invention is to avoid these known disadvantages and to disclose a method for galvanizing steel parts in which the galvanizing is applied in a thin, relatively uniform layer.

Zu diesem Zweck ist die Erfindumg dadurch gekennzeichnet, daß der Aktivierungslösung Metall· in Form von Metallsalzen zugesetzt werden, welche potentialmäßig edler als Eisen For this purpose, the invention is characterized in that metal in the form of metal salts, which are potentially more noble than iron, are added to the activating solution

sind· 509816/0938 are · 509816/0938

Ein weiteres Merkmal der Erfindung ist, daß die der Aktivierungslösung zugesetzten Metallsalze aus Salzen des Kupfers oder des Silbers bestehen.Another feature of the invention is that the metal salts added to the activation solution are made from salts of copper or silver.

Das potentialmäßig edlere Metall setzt sich bei der Aktivierung in einer dünnen nicht geschlossenen Schicht auf der Oberfläche der Stahlteile ab.The potentially more noble metal settles in a thin, non-closed layer when activated on the surface of the steel parts.

Bei der anschließenden Verzinkung der Stahlteile wird die Metallverteilung des Zinks gleichmäßiger in der Stärke, weil in elektrochemischer Hinsicht durch das Vorhandensein von Kupfer oder Silber die Oberfläche aktiver ist.During the subsequent galvanizing of the steel parts the metal distribution of the zinc more evenly in strength, because in electrochemical terms by the Presence of copper or silver the surface is more active.

Auf abgeschirmten Innenflächen von profilierten Teilen, welche nur schlecht vom elektrischen Feld erreicht werden, erhält man noch einen Zinkniederschlag, ohne daß an den vorstehenden Kanten und Ecken der Zinkbelag zu dick wird.On shielded inner surfaces of profiled parts, which are difficult to reach by the electric field, a zinc deposit is obtained without the zinc coating becoming too thick on the protruding edges and corners.

Mit dieses Verfahren lassen sich deshalb besonders dünne und relativ gleichmäßig dicke Zinkauflagen herstellen.With this process, therefore, particularly thin and relatively evenly thick zinc coatings can be produced.

509816/0938509816/0938

Claims (2)

PatentansprücheClaims 1. Verfahren zum Verzinken von Stahlteilen, insbesondere für eine anschließende elektrophoretische Eaaillierung, dadurch gekennzeichnet, daß der Aktivierungslösung Metalle in Form von Metallsalzen zugesetzt werden, welche potentialmäßig edler als Eisen sind.1. Process for galvanizing steel parts, in particular for a subsequent electrophoretic Eaaillierung, characterized in that the activating solution Metals are added in the form of metal salts, which are potentially more noble than iron. 2. Verfahren zum Verzinken von Stahlteilen, dadurch gekennzeichnet, daß die der Aktivierungslösung zugesetzten Metallsalze aus Salzen des Kupfers oder des Silbers bestehen. 2. Process for galvanizing steel parts, characterized in that that the metal salts added to the activation solution consist of salts of copper or silver. 503816/0938503816/0938
DE2344434A 1973-09-04 1973-09-04 Process for galvanizing steel parts Expired DE2344434C3 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE2344434A DE2344434C3 (en) 1973-09-04 1973-09-04 Process for galvanizing steel parts
SE7409725A SE443163B (en) 1973-09-04 1974-07-26 PROCEDURE FOR ELECTROPHORETIC ENAMELING OF HOUSING DETAILS
IT25970/74A IT1017897B (en) 1973-09-04 1974-08-02 PROCEDURE FOR THE GALVANIZING OF STEEL PARTS
GB3528774A GB1461181A (en) 1973-09-04 1974-08-09 Electrophoretic enamelling
JP49097139A JPS5949309B2 (en) 1973-09-04 1974-08-26 Method of enameling steel parts by electrophoresis
FR7429617A FR2242485B1 (en) 1973-09-04 1974-08-30
US05/636,456 US4046646A (en) 1973-09-04 1975-12-01 Method of galvanizing steel parts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2344434A DE2344434C3 (en) 1973-09-04 1973-09-04 Process for galvanizing steel parts

Publications (3)

Publication Number Publication Date
DE2344434A1 true DE2344434A1 (en) 1975-04-17
DE2344434B2 DE2344434B2 (en) 1979-10-11
DE2344434C3 DE2344434C3 (en) 1980-06-19

Family

ID=5891534

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2344434A Expired DE2344434C3 (en) 1973-09-04 1973-09-04 Process for galvanizing steel parts

Country Status (6)

Country Link
JP (1) JPS5949309B2 (en)
DE (1) DE2344434C3 (en)
FR (1) FR2242485B1 (en)
GB (1) GB1461181A (en)
IT (1) IT1017897B (en)
SE (1) SE443163B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2947188A1 (en) * 1979-11-23 1981-05-27 Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt Electrophoretic enamel coating of steel parts - preceded by joint deposition of nickel and zinc
DE19745162A1 (en) * 1997-10-14 1999-04-15 Miele & Cie Pretreating workpiece in an electrophoretic dip enameling process activating bath

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52105921A (en) * 1976-03-02 1977-09-06 Nisshin Steel Co Ltd Enamelling method of oneeprocess type
DE2705770B2 (en) * 1977-02-11 1980-03-06 Bego Bremer Goldschlaegerei Wilh. Herbst, 2800 Bremen Method and device for applying a base material layer to a metallic base molding in dental technology
DE2710122A1 (en) * 1977-03-09 1978-09-14 Miele & Cie PROCESS FOR PRE-TREATMENT OF NON-FERROUS METALS BEFORE COATING WITH CERAMIC COMPOUNDS
JPS60169571A (en) * 1984-02-10 1985-09-03 Ig Tech Res Inc Enamel coated steel sheet

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2045265C2 (en) * 1970-09-12 1974-01-31 Miele & Cie, 4830 Guetersloh Process for the pretreatment of steel parts to be coated electrophoretically with enamel
US3751289A (en) * 1971-08-20 1973-08-07 M & T Chemicals Inc Method of preparing surfaces for electroplating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2947188A1 (en) * 1979-11-23 1981-05-27 Licentia Patent-Verwaltungs-Gmbh, 6000 Frankfurt Electrophoretic enamel coating of steel parts - preceded by joint deposition of nickel and zinc
DE19745162A1 (en) * 1997-10-14 1999-04-15 Miele & Cie Pretreating workpiece in an electrophoretic dip enameling process activating bath
DE19745162C2 (en) * 1997-10-14 2002-09-12 Miele & Cie Process for activating a material in an ETE coating process

Also Published As

Publication number Publication date
FR2242485B1 (en) 1978-08-11
SE443163B (en) 1986-02-17
FR2242485A1 (en) 1975-03-28
GB1461181A (en) 1977-01-13
DE2344434B2 (en) 1979-10-11
SE7409725L (en) 1975-03-05
JPS5081928A (en) 1975-07-03
JPS5949309B2 (en) 1984-12-01
IT1017897B (en) 1977-08-10
DE2344434C3 (en) 1980-06-19

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Legal Events

Date Code Title Description
OGA New person/name/address of the applicant
C3 Grant after two publication steps (3rd publication)
8320 Willingness to grant licences declared (paragraph 23)