DE215664C - - Google Patents
Info
- Publication number
- DE215664C DE215664C DENDAT215664D DE215664DA DE215664C DE 215664 C DE215664 C DE 215664C DE NDAT215664 D DENDAT215664 D DE NDAT215664D DE 215664D A DE215664D A DE 215664DA DE 215664 C DE215664 C DE 215664C
- Authority
- DE
- Germany
- Prior art keywords
- acid
- iodine
- mercury
- fatty acids
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011630 iodine Substances 0.000 claims description 9
- 229910052740 iodine Inorganic materials 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 5
- 239000002023 wood Substances 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229910000474 mercury oxide Inorganic materials 0.000 claims description 4
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 2
- 229910052753 mercury Inorganic materials 0.000 claims description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- SRPSOCQMBCNWFR-UHFFFAOYSA-N iodous acid Chemical compound OI=O SRPSOCQMBCNWFR-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- -1 Iodine fatty acids Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- QKEOZZYXWAIQFO-UHFFFAOYSA-M mercury(1+);iodide Chemical compound [Hg]I QKEOZZYXWAIQFO-UHFFFAOYSA-M 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
- C07F3/103—Mercury compounds without C-Mercury linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- JVl 215664 -KLASSE 12o. GRUPPE - JVl 215664 - CLASS 12o. GROUP
J.D.RIEDEL AKT-GES. in BERLIN.J.D.RIEDEL AKT-GES. in Berlin.
Patentiert im Deutschen Reiche vom 1. Mai 1908 ab.Patented in the German Empire on May 1, 1908.
Nach dem Verfahren des Patents 202790 werden chlorfreie Ester und Salze hochmolekularer Jodfettsäuren dadurch erhalten, daß man Fette oder andere Ester hochmolekularer ungesättigter Säuren oder die entsprechenden Salze in Gegenwart von Jod und Wasser mit solchen Mitteln behandelt, welche, wie Quecksilberoxyd, mit Jod und Wasser unterjodige Säure liefern.According to the process of patent 202790, chlorine-free esters and salts become higher molecular weight Iodine fatty acids obtained by using fats or other esters of high molecular weight unsaturated acids or the corresponding salts in the presence of iodine and water with such agents which, like mercury oxide, sub-iodine with iodine and water Provide acid.
Es hat sich nun gezeigt, daß, wenn man Elaeomargarinsäure oder die diese Säure enthaltenden verseiften Holzöle bzw. die Holzölfettsäuren mit unterjodiger Säure in Gegenwart von Quecksilberoxyd behandelt, nicht nur Anlagerung von unterjodiger Säure erfolgt, vielmehr die Jodfettverbindung weiter mit dem gebildeten Quecksilber] odid zu einer Doppelverbindung zusammentritt.It has now been shown that if you use elaeomargaric acid or those containing this acid saponify wood oils or the wood oil fatty acids with hypoiodic acid in the presence treated with mercury oxide, not only deposition of hypoiodic acid takes place, Rather, the iodine fat compound continues with the formed mercury to form an odide Double connection comes together.
Beispielsweise werden 5 g Holzölfettsäuren in 50 ecm mit Wasser gesättigten Äthers gelöst, worauf man 2 g Jod zufügt und bis zu dessen Lösung schüttelt. Sodann gibt man ι g Quecksilberoxyd hinzu und läßt unter öfterem Schütteln 12 bis 24 Stunden stehen, worauf das anfänglich ausgeschiedene Quecksilber j odid sich in dem Jodfett gelöst hat. Das Produkt wird mit etwa der doppelten Menge Äther versetzt, getrocknet, der Äther abdestilliert und dann auf dem Wasserbade erwärmt, bis keine Joddämpfe mehr auftreten.For example, 5 g of wood oil fatty acids are dissolved in 50 ecm of ether saturated with water, whereupon 2 g of iodine are added and shaken until it dissolves. Then you give ι g of mercury oxide are added and left to stand for 12 to 24 hours with frequent shaking, whereupon the initially excreted mercury iodide has dissolved in the iodine fat. The product is mixed with about twice the amount of ether, dried, the ether distilled off and then heated on the water bath until no more iodine vapors appear.
Das erhaltene Produkt bildet eine salbenartige, dunkel gefärbte Masse, welche in Wasser unlöslich ist, sich dagegen in Alkohol, Benzol und Aceton auflöst. Es soll therapeutische Verwendung finden.The product obtained forms an ointment-like, dark-colored mass, which in water is insoluble, but dissolves in alcohol, benzene and acetone. It's supposed to be therapeutic Find use.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE215664C true DE215664C (en) |
Family
ID=477138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT215664D Active DE215664C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE215664C (en) |
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0
- DE DENDAT215664D patent/DE215664C/de active Active
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