DE2045408A1 - Improving souring ability of milk - by addition of a thiocyanate or isothiocyanate - Google Patents
Improving souring ability of milk - by addition of a thiocyanate or isothiocyanateInfo
- Publication number
- DE2045408A1 DE2045408A1 DE19702045408 DE2045408A DE2045408A1 DE 2045408 A1 DE2045408 A1 DE 2045408A1 DE 19702045408 DE19702045408 DE 19702045408 DE 2045408 A DE2045408 A DE 2045408A DE 2045408 A1 DE2045408 A1 DE 2045408A1
- Authority
- DE
- Germany
- Prior art keywords
- milk
- isothiocyanate
- thiocyanate
- addition
- improving
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/12—Fermented milk preparations; Treatment using microorganisms or enzymes
- A23C9/13—Fermented milk preparations; Treatment using microorganisms or enzymes using additives
- A23C9/1322—Inorganic compounds; Minerals, including organic salts thereof, oligo-elements; Amino-acids, peptides, protein-hydrolysates or derivatives; Nucleic acids or derivatives; Yeast extract or autolysate; Vitamins; Antibiotics; Bacteriocins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
- A23C9/1522—Inorganic additives, e.g. minerals, trace elements; Chlorination or fluoridation of milk; Organic salts or complexes of metals other than natrium or kalium; Calcium enrichment of milk
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Nutrition Science (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Microbiology (AREA)
- Fodder In General (AREA)
Abstract
Description
Patentanmeldung von Thi<ncyanat- bzw. Isothiocyanstzustatz zu schlecht säuernder Milch vor der Erhitzung für die Herstellung von Joghurt und anderen fermentierten Milcherzeugnissen.Patent application for thi <ncyanate or isothiocyanate additive too bad Sour milk before heating for making yogurt and other fermented Dairy products.
Gewisse Beobachtungen von Molkereien häufen sich, daß nicht nur antibiotikahaltige Arzneimittel in der Milch, Herbizide, Insektizide und Rückstände von Reinigungs- und DesinfeRtionsmitteln Hemmwirkungen auf die technologischen Bakterienkulturen der Milcherzeugnisbetriebe ausüben, sondern daß die Fütterung einen nicht zu unterschätzenden Einfluß auf die Säuerungsfähigkeit der Milch hat. Forss (1951) und Limmer (1969) stellten fest, daß extrem stark senfölhaltige Pflanzen im Futter der Kühe die Herstellung von Milchfertigprodukten erschweren. Andererseits bewirkt die Weideumstellung, bei der man durch den Cruciferenanteileinen relativ hohen Thiocyanatgehalt annehmen darf, eine ausgezeichnete Säuerung der Milch. Frank (1963, 1969) weist darauf hin, daß nicht so sehr Hemmstoffe die jewiligen Säuerungseigenschaften der Milch beeinflussen, sondern daß vor allem Stimulatoren für die technologischen Streptokokkenkulturen in der Milch anwesend sein müssen, die je nach vorhandener Menge den Ablauf der Säuerung negativ (zu wenig) oder positiv steuern können.Certain observations from dairies are accumulating, and not only those containing antibiotics Medicines in milk, herbicides, insecticides and residues from cleaning agents and disinfectants inhibit the technological bacterial cultures of dairy farms, but that feeding should not be underestimated Has an influence on the acidity of milk. Forss (1951) and Limmer (1969) found that extremely high mustard oil-containing plants in the cows' feed were responsible for the production of ready-to-use dairy products. On the other hand, the change of pasture causes which is assumed to have a relatively high thiocyanate content due to the crucifera content may, an excellent acidification of the milk. Frank (1963, 1969) points out that not so much inhibitors influence the acidification properties of the milk, but that above all stimulators for the technological streptococcal cultures must be present in the milk, which, depending on the amount present, the expiry of the Can control acidification negatively (too little) or positively.
Anhand von Versuchen kann ich zeigen, daß die in jeder Milch vorhandenen Senföle (Thiocyanate und Isothiocyanate) diese Rolle als Stimulatoren spielen; sie können in größerer Menge jedoch auch als Hemmstoffe auftreten. Ein Zusatz von 5 - 10 an Natriumisothiocanat z.B. zu schlecht säuernder Milch (vorkommend vor allem nach Futterumstellungen und während der Stallperiode) vor der üblichen Erhitzung, gewährleistet eine gute Säuerung und damit einwandfreie Produktion von milcherzeugnissen. On the basis of experiments I can show that the Mustard oils (thiocyanates and isothiocyanates) play this role as stimulators; she however, they can also act as inhibitors in larger quantities. An addition of 5 - 10 sodium isothiocanate e.g. milk that is too poorly acidic (occurs above all after feed changes and during the stall period) before the usual heating, ensures good acidification and thus flawless production of milk products.
Die Isothiocyanate, die in der rohen Milch zum Teil frei, zum Teil an Fette und Eiweiße gebunden vorliegen, gehen bei hohen Erhitzungsgraden einheitlich Verbindungen mit den Milcheiweißen ein und sind als inaktive Thioharnstoffe thermisch sehr stabil.The isothiocyanates, some of which are free in raw milk and some of which are bound to fats and proteins, form uniform compounds with the milk proteins when they are heated to a high level and, as inactive thioureas, are very thermally active stable.
Im verlaufe der Säuerung werden unterhalb pH 5 die Bindungen mit Eiweißen kontinuierlich wieder gelöst (Appelquist und Josefseon 1965) und die freie aktive Porm liegt vor, die zu Anfang als Stumulans, später hemmend auf die Streptokokken wirkt (Abschluß der Säuerung).In the course of acidification, the bonds with proteins are below pH 5 continuously resolved again (Appelquist and Josefseon 1965) and the free active Porm is present, initially as a stumulant, later inhibiting the streptococci acts (completion of the acidification).
Boulangé(1959) demonstriert, daß das ganze Jahr hindurch in Abhangigkeit von Fütterung wechselnde Mengen an Thiocyanat ausgeschieden werden. in den Monaten Januar, Bebruar, März, April ist die Ausscheidung besonders gering (Ende der Stallfütterung-Silagefütterung) und ein Zusatz von Thiocyanat, der nach meiner Feststellung die Säuerungsfähigkeit erheblich verbessert, würde als eine echte Substituion der natürlichum vorkommenden Stoffe bezeichnet werden können. Es können demnach das Milchgesetz betreffend keine Bedenken geäußert werden, da es sich nicht um Zusatz eines fremden Stoffes handelt. thiocyanate und Isothiocyanate kommen weitverbreitet in unseren Nahrungsmitteln vor und sind vom diäthetischen Standpunkt aus als gesundheitsfördernd zu bezeichnen (Winter 1953).Boulangé (1959) demonstrates that year-round dependence varying amounts of thiocyanate are excreted from feeding. in the months January, February, March, April, the excretion is particularly low (end of stable feeding - silage feeding) and an addition of thiocyanate, which, according to my findings, has the ability to acidify greatly improved, would be considered a true substitution of naturally occurring Substances can be designated. Accordingly, there can be none with regard to the Milk Act Concerns are raised as it is not an addition of a foreign substance. thiocyanates and isothiocyanates are widespread in our foods and are to be described as health-promoting from a dietetic point of view (Winter 1953).
Autoren: Appelquist, L.A. und E. Josefsson : Acta chem. scand. 2i, 1242 (1965) - Boulange, M.: Compt. rend. soc. biol. 43, 2019 (1959) - Forss, D.A.: Austr. J. of Äppl. Sci. 2, 396 (1951)-Frank, H.K. : Milchwiss. 24, 269 (1969) - Limmer, H.D.: Arch.Authors: Appelquist, L.A. and E. Josefsson: Acta chem. scand. 2i, 1242 (1965) - Boulange, M .: Compt. rend. soc. biol. 43, 2019 (1959) - Forss, D.A .: Austr. J. of Äppl. Sci. 2, 396 (1951) - Frank, H.K. : Milk science 24, 269 (1969) - Limmer, H.D .: Arch.
Lebenmittelhyg. 20, 227 (1969) - Winter,A.G.: Madaus Jahresbericht VII. 7, (1953).Food hyg. 20, 227 (1969) - Winter, A.G .: Madaus annual report VII. 7, (1953).
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19702045408 DE2045408A1 (en) | 1970-09-15 | 1970-09-15 | Improving souring ability of milk - by addition of a thiocyanate or isothiocyanate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19702045408 DE2045408A1 (en) | 1970-09-15 | 1970-09-15 | Improving souring ability of milk - by addition of a thiocyanate or isothiocyanate |
Publications (1)
Publication Number | Publication Date |
---|---|
DE2045408A1 true DE2045408A1 (en) | 1972-04-13 |
Family
ID=5782397
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19702045408 Pending DE2045408A1 (en) | 1970-09-15 | 1970-09-15 | Improving souring ability of milk - by addition of a thiocyanate or isothiocyanate |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE2045408A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010102937A1 (en) | 2009-03-12 | 2010-09-16 | Nestec S.A. | Covalent milk protein/isothiocyanate complexes |
WO2010102936A1 (en) * | 2009-03-12 | 2010-09-16 | Nestec S.A. | Electrostatic protein/glucosinolate complexes |
-
1970
- 1970-09-15 DE DE19702045408 patent/DE2045408A1/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010102937A1 (en) | 2009-03-12 | 2010-09-16 | Nestec S.A. | Covalent milk protein/isothiocyanate complexes |
WO2010102936A1 (en) * | 2009-03-12 | 2010-09-16 | Nestec S.A. | Electrostatic protein/glucosinolate complexes |
EP2229824A1 (en) | 2009-03-12 | 2010-09-22 | Nestec S.A. | Covalent milk protein/isothiocyanate complexes |
EP2229823A1 (en) * | 2009-03-12 | 2010-09-22 | Nestec S.A. | Electrostatic protein/glucosinolate complexes |
CN102333456A (en) * | 2009-03-12 | 2012-01-25 | 雀巢产品技术援助有限公司 | Electrostatic protein/glucosinolate complexes |
CN102341008A (en) * | 2009-03-12 | 2012-02-01 | 雀巢产品技术援助有限公司 | Covalent milk protein/isothiocyanate complexes |
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