DE202012006359U1 - Demarkierungsmittel - Google Patents

Abstract

Composition for removing markings, in particular road markings and hall floor markings, containing 5-50% by weight of at least one aromatic alcohol, 2-70% by weight of one or more dibasic esters, at least one of which is an ester of the formula (i), where R1, R2 and R3 are independently linear or branched alkyl radicals having 1 to 10 carbon atoms.

Description

The invention relates to a composition of an aromatic alcohol and at least one dibasic ester.

Markers are often used to regulate processes. For example, lane lines, stripes and arrows are applied to the traffic on the road. In warehouses and production halls are marks that z. B. limit storage areas or should mark restricted areas.

For the marking, it is preferred to use solvent-borne 1K paints (one-component paints) based on pure acrylate resins, 2K paints (two-component paints) based on epoxy-modified acrylic resins or water-dilutable 1K paints based on pure acrylate dispersions.

The colors used usually have good adhesion to the substrate and durability due to the stresses to which pavement or hall floor markings are exposed. However, there is often the need to remove existing lane or hall markings again. For example, removal of road markings may be required when repairing the roadway, changing the lane guidance, or establishing a detour or bypass.

• – Abdecken der Markierungen mit grauer oder schwarzer Farbe je nach Untergrund;
• – Abfräsen der Markierungen;
• – Ausfräsen der Markierungen und Verfüllen der Fräsflächen mit bituminöser Masse;
• – Entfernung von Markierungen mittels Kugel- oder Sandstrahlverfahren;
• – Entfernung von Markierungen unter Einwirkung von Wärme.

Various methods are known for removing markings, in particular those on floors. Roadway or hall markings are usually removed by one of the following methods:

• - covering the markings with gray or black color depending on the substrate;
• - milling the markings;
• - milling the markings and filling the milling surfaces with bituminous mass;
• - Removal of markings by means of ball or sandblasting method;
• - Removal of marks under the action of heat.

A common disadvantage of these methods is that a so-called phantom or ghost mark remains on the ground. While this is a rather aesthetic problem in halls, the phantom or ghost markings on the road pose a life-threatening risk. Especially in rainy weather, but also in certain lighting conditions or darkness is not always clear which is the correct lane marking. This seriously jeopardizes traffic safety.

The typically used methods such as the milling of old markings are often associated with a high energy consumption. In the high-pressure water process, in which old markings are removed under high pressure from the substrate, water is usually directed at a pressure of 2500 to 3000 bar on the markings. Another disadvantage of this very frequently used method is that very large amounts of contaminated water are incurred, which must be disposed of expensively. In times of heightened environmental awareness, this process also turns out to be wasteful of water.

The sandblasting process, which is a very effective method of removing marks, often results in damage to the adjacent vegetation and / or damage to the paint on the construction site of passing vehicles when used.

It is also known from the prior art to use demarcating agents in combination with a pressurized water treatment in order to detach markings from substrates such as roadways.

DE 29 27 968 A1 For example, a demarcating agent containing 50-70% by weight of chlorohydrocarbon, 3-10% by weight of aromatic hydrocarbon, 2-9% by weight of ketones, 2-10% by weight of lower alcohol, 5-11% by weight. % higher alcohol, 0.5-3 wt .-% swelling agent, 0.5-1.5 wt .-% wetting agent and 1-3 wt .-% alkaline raw materials. Such an agent is extremely harmful to health and environmentally hazardous.

Also, such a means is not suitable for every surface. In particular, hall floors are damaged by such aggressive compositions.

The object was therefore to provide a demarcating agent with which markings of different substrates with good material compatibility can be effectively and as far as possible without residue and avoid damage to adjacent areas, and which is possible not environmentally hazardous and harmful to health.

ist,
wobei R1, R2 und R3 unabhängig voneinander lineare oder verzweigte Alkylreste mit 1 bis 10 Kohlenstoffatomen sind.The object is achieved by a composition comprising 5-50% by weight of at least one aromatic alcohol and 2-70% by weight of one or more dibasic esters, of which at least one is an ester of the formula (i)

is
wherein R1, R2 and R3 are independently linear or branched alkyl radicals having 1 to 10 carbon atoms.

According to the invention, a dibasic ester is understood as meaning those esters of dicarboxylic acids in which both carboxyl functions are esterified. Examples of suitable dibasic esters are the diisopropyl or diisobutyl esters of glutaric acid, succinic acid, adipic acid or dimethyl 2-methylpentanedioate (dimethyl 2-methylpentanedioate) or a mixture of these esters. Particularly preferred is an ester of the formula (i) of the dibasic ester 2-Methylpentandisäuredimethylester (R1, R2 = CH _3; R 3 = CH _3).

Glutarsäuredimethylester (Dimethylglutarat):

Bernsteinsäuredimethylester (Dimethylsuccinat):

Malonsäurediethylester (Diethylmalonat):

Malonsäuredimethylester (Dimethylmalonat):

Methylmalonsäurediethylester (Diethylmethylmalonat):

Oxalsäurediethylester (Diethyloxalat):

Oxalsäuredimethylester (Dimethyloxalat):

Weinsäurediethylester (Diethyltartrat):

Below are listed by way of example a few other dibasic esters which, in addition to the at least one dibasic ester of the formula (i), can be present in compositions according to the invention: dimethyl adipate (dimethyl adipate):

Glutaric acid dimethyl ester (dimethyl glutarate):

Succinic acid dimethyl ester (dimethylsuccinate):

Diethyl malonate (diethyl malonate):

Dimethyl malonate (dimethyl malonate):

Methyl malonate diethyl (diethylmethylmalonate):

Diethyl oxalate (diethyl oxalate):

Oxalic acid dimethyl ester (dimethyl oxalate):

Diethyl tartrate (diethyl tartrate):

wobei n = 0 bis 10 ist und R4 und R5 unabhängig voneinander lineare oder verzweigte Alkylreste mit 1 bis 10 Kohlenstoffatomen sind, oder Carbonsäureester, die gegenüber dem Ester der Formel (ii) eine oder mehrere Substitution/en durch einen linearen oder verzweigten Alkylrest mit 1 bis 10 Kohlenstoffatomen oder durch eine Hydroxyfunktion in der Kette aufweisen.Preferred further dibasic esters are therefore carboxylic acid esters of the formula (ii)

wherein n = 0 to 10 and R4 and R5 independently of one another are linear or branched alkyl radicals having 1 to 10 carbon atoms, or carboxylic acid esters which, compared with the ester of the formula (ii), have one or more substitutions by a linear or branched alkyl radical with 1 to 10 carbon atoms or by a hydroxy function in the chain.

Preferably, the dibasic ester is used in amounts of 30-50 wt .-%, particularly preferably in amounts of 20-30 wt .-%. If more than one dibasic ester is included in the composition, the proportion of dibasic esters of formula (i) is at least 2% by weight.

Preferred compositions according to the invention contain 20-45% by weight of aromatic alcohol, more preferably even only 5-30% by weight. Benzyl alcohol-containing compositions, for example, are only subject to labeling above a content of 24 wt .-% benzyl alcohol, so that at appropriate choice of the other components and their amount of compositions according to the invention can be obtained, which are free of labeling.

Preferred embodiments of compositions according to the invention which are suitable for removing markings are described below or are the subject matter of the subclaims.

In principle, all aromatic alcohols can be used as aromatic alcohols for compositions according to the invention. The skilled person will, however, preferably use those whose health and environmental hazard potential is minimized. Such aromatic alcohols include, for example, benzyl alcohol, 2-benzylheptanol, 2-benzyloxyethanol, 4-benzyloxybenzyl alcohol, 3,4-dimethoxybenzyl alcohol, 3,5-dimethylbenzyl alcohol, 4-ethylbenzyl alcohol, 4-isopropylbenzyl alcohol, 2-methylbenzyl alcohol, 4-methoxybenzyl alcohol, 2-phenoxy 1-ethanol, 4-phenyl-1-butanol, 1-phenyl-1-propanol, 3-phenyl-1-propanol, 4-tert-butylbenzyl alcohol or trans-3-phenylallyl alcohol and mixtures thereof. Particularly preferred is the use of benzyl alcohol.

In addition to the active compounds mentioned, compositions according to the invention preferably contain further constituents which, in particular, improve their application properties and in some cases even enhance the action as a demarcating agent.

Optional additional ingredients include thickeners, for example. With thickeners, the viscosity of agents according to the invention can be adjusted to the particular application. For example, by sufficiently thickened compositions, the demarcating agent may be prevented from running off the area of the substrate with the mark to be removed following application to inclined surfaces. It can be guaranteed as a sufficient exposure time. Suitable thickeners are usually selected from the group consisting of agar-agar, carrageenan, tragacanth, gum arabic, guar flour, locust bean gum, starch, gelatin, casein, alginates, pectins, polyoses, dextrins, carboxymethylcellulose, cellulose ethers, polyacrylic and polymethacrylic compounds, vinyl polymers, Polycarboxylic acids, polyethers, polyimines, polyamides, titanium dioxides, silicas or mixtures thereof, although other thickeners can be used.

Thickeners are preferably used in compositions according to the invention in amounts of 0.5-10% by weight, more preferably in an amount of 1-5% by weight.

Compositions according to the invention preferably also contain surfactants which may be selected from the group of anionic, cationic, amphoteric and / or nonionic surfactants. Suitable anionic surfactants are, for example, those from the group of the sulfonates, such as sodium toluene xylene sulfonate, sodium toluene sulfonate, sodium cumene sulfonate, sodium decyl diphenyl ether sulfonate, sodium dodecylbenzenesulfonate, sodium dodecyldiphenyl ether sulfonate, sodium 1-octanesulfonate, sodium tetradecanesulfonate, sodium pentadecanesulfonate, sodium heptadecane sulfonate and potassium toluenesulfonate. Likewise, anionic surfactants are suitable, for example from the group of alkyl carboxylates. Suitable amphoteric surfactants are, for example, N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycine, N-alkyltaurine, N-alkylsacosine, 2-alkylaminopropionic acids and N-alkylaminoacetic acids having 8 to 24 carbon atoms in the alkyl group. Suitable nonionic surfactants are, for. B. alkylpolyglycosides. For compositions according to the invention, biodegradable but above all low-foaming surfactants are preferred because of the preferred use of the demarcating agent in combination with water as surfactants. These surfactants include, for example, the surfactants of the Plurafac® LF group and the Pluronic® group of BASF.

The amount of surfactants in compositions according to the invention is preferably 1-5% by weight, more preferably 2-4% by weight.

In order to improve the odor of compositions according to the invention and in particular to convey the impression of a relatively harmless agent, it is preferred to add compositions according to the invention to fragrance oils or natural, nature-identical or synthetic fragrances. Suitable fragrant fragrances are, for example, orange or lemon terpene or ethyl 2-naphthyl ether. A pleasant scent also causes wintergreen oil (salicylic acid methyl ester).

Preferably, only those amounts of fragrances or fragrance oils are used, which do not lead to a labeling requirement. For example, therefore, only up to 0.25 wt .-% of orange terpenes are used.

Further suitable auxiliaries, which may be constituents of compositions according to the invention if required, are solubilizers based on glycols or glycol ethers such as dipropylene glycol, tripropylene glycol n-butyl ester, dipropylene glycol n-propyl ether, dipropylene glycol n-butyl ether, dipropylene glycol dimethyl ether, dipropylene glycol monomethyl ether, propylene glycol isopropyl ether, tributylphenol polyglycol ether Propylene glycol tertiary butyl ether, hexylene glycol, 1,2-propylene glycol, dipropylene glycol, monoethylene glycol, butyl glycol, dibutyl glycol and / or methyl diglycol. Solubilizers are preferably used in amounts of 1-10 wt .-%, particularly preferably in amounts of 2-5 wt .-%. Solubilizers serve to keep the peeled paint in solution and to prevent "bleeding" of the paint.

• – 5–50 Gew.% mindestens eines aromatischen Alkohols,
• – 2–70 Gew.% eines oder mehrerer dibasischen/r Ester/s, von denen mindestens einer ein Ester der Formel (i)
  
  ist, wobei R1, R2 und R3 unabhängig voneinander lineare oder verzweigte Alkylreste mit 1 bis 10 Kohlenstoffatomen sind,
• – mindestens ein Tensid,
• – mindestens ein Duftöl oder einen natürlichen, naturidentischen oder synthetischen Duftstoff,
• – einen Verdicker und
• – ggf. sonstige Hilfsstoffe, beispielsweise ausgewählt aus der Gruppe der Lösungsvermittler auf Basis von Glykolen oder Glykolethern.

A general formula for a composition according to the invention which, in addition to the synergistic combination of active ingredients, contains further constituents, is, for example:

• 5-50% by weight of at least one aromatic alcohol,
• 2-70% by weight of one or more dibasic esters, of which at least one is an ester of the formula (i)
  
  where R 1, R 2 and R 3, independently of one another, are linear or branched alkyl radicals having 1 to 10 carbon atoms,
• At least one surfactant,
• At least one fragrance oil or a natural, nature-identical or synthetic fragrance,
• - a thickener and
• - If necessary, other auxiliaries, for example selected from the group of solubilizers based on glycols or glycol ethers.

Compositions according to the invention can be prepared simply by successively adding solvents, ie. H. aromatic alcohol, dibasic ester and optionally dicarboxylic monoester, auxiliaries and then the thickener are combined. After brief stirring, a clear, viscous liquid forms, which can be used directly as a demarcating agent.

The composition according to the invention makes it possible to remove markings from any desired substrates, in particular from roadways or hall floors.

Compositions according to the invention are therefore used as a demarcating agent, in particular for the removal of road and lane markings, ground markings, surface markings, cycle path markings, storage and production hall markings, ie. H. of markings of carriageways and hall floors.

A particularly gentle method for removing markings from the substrate and the environment comprises applying the composition according to the invention, the demarcating agent, using an airless spraying method, brushes, brushes, rollers, rolls or aerosol application. After a short reaction time, usually 5-25 min, depending on the layer thickness of the applied paint, the resulting mixture is removed with a jet of water. It is understood that the exposure time can be longer.

The use of demarcating agents according to the invention results in the softening of the structure caused by the binders contained in the marking ink. The dissolved color can then be removed by using water.

The detached paint residues are usually found again in the water used and form with this a heterogeneous mixture in the form of a suspension or an unstable emulsion. In suspensions, a strong tendency of the paint residues to sedimentation is often observed.

The paint residues can be separated from the water by known equipment. This allows recycling the water for another cleaning cycle. In addition to this additional aspect regarding the comparative environmental friendliness of inventive compositions over known compositions, the cost of disposing of the water used is significantly reduced. After separation of color can be discharged directly into the sewer system using demarcating agents according to the invention, whose biodegradability has been tested, the water content.

The separated, compacted paint can be dried in air for subsequent environmentally friendly disposal.

For removal by means of water jet so-called demarcation heads can be used, which suck in a single operation the dissolved mark, dirt particles, which are located on the ground, and the water used in a dirt container of the working machine. The use of a demarcation head also has the advantage that the surface is immediately almost dry after being released from the paint.

Even conventional high-pressure cleaners, such as those found in conventional street cleaning vehicles, can be used together with the demarcation agent according to the invention for the effective removal of markings. When using a demarcating agent according to the invention, the brush cleaning vehicles can drive off the road surface at a higher speed in order to remove the marking residues than is possible when the markers are removed by means of a mere high-pressure method.

When using demarcation agents according to the invention, no interfering phantom marks remain.

A further advantage of compositions according to the invention is, in addition, their good biodegradability. The biodegradability was tested according to OECD 302 B test.

In addition, the compositions according to the invention usually have a flash point> 120 ° C (determination according to DIN EN 22719 , Pensky-Martens method in a closed crucible). The compositions are therefore not considered flammable.

Examples

Example 1: Comparative Experiments

Comparative solutions V1 to V7 and inventive compositions B1 to B6 were prepared according to the formulations according to Table 1.

60 mL polypropylene screw caps (Sarstedt) were filled with 5 g of labeling dye (Signalin M11, Stramat). The marking ink was completely dried in the oven. Subsequently, the weight of the screw cans was determined with dried paint.

5 ml of the comparative solutions or the solutions according to the invention were in each case added to the screw-type containers. All samples were treated in the same way:
After standing at 22 ° C for 10 minutes, it was stirred at 22 ° C for 10 minutes. A PTFE-jacketed cylindrical magnetic stir bar (3.8 cm in length, diameter: 0.8 cm) was used. Then, each of the screw cans was held down with the opening so that the color mixed solution could leak out for a period of 30 seconds. It was rinsed once each with 10 ml of isopropanol. After renewed leakage of the screw cans over a period of 30 seconds, the screw cans were dried to constant weight at room temperature. The cans with the color residues were then weighed again. The loss weight was determined from the difference between the two weighing measurements. The higher the weight loss, the better the agents are as a demarcating agent. Table 1: Compositions of the comparative solutions and solutions according to the invention and their activity V1% by weight V2% by weight V3% by weight V4% by weight V5% by weight V6% by weight V7% by weight 2-Methylpentandisäuredimethylester 100 - 50 - - 50 10 dimethyl - - - - 11 - dimethyl - - - - - 30 - dimethyl - - - - - 9 - diethyl malonate - 100 - - - - 20 dimethyl - - 50 - - - 20 diethyl - - - - - - 10 diethyl - - - - - - 20 dimethyl - - - 100 - - 10 diethyl - - - - - - 10 aromatic alcohol - - - - 100 ¹⁾ - - Loss weight: 1.3 g 0.6 g 0.3 g 0.4 g 0.8 g 1.2 g 1.3 g ¹⁾ Benzyl alcohol continued Table 1 B1% by weight B2% by weight B3% by weight B4% by weight B5% by weight B6% by weight 2-Methylpentandisäuredimethylester 43 37 50 51 52 54 dimethyl 7 - - - - - dimethyl 6 - - - - - dimethyl 9 - - - - - diethyl malonate - 19 - - - - dimethyl - - - - - 16 diethyl - - 20 - - - diethyl - - - - - - dimethyl - - - 20 - - diethyl - - - - 18 - aromatic alcohol 35 ²⁾ 44 ³⁾ 30 ³⁾ 29 ¹⁾ 30 ⁴⁾ 30 ⁵⁾ Loss weight: 2.4 g 2.5 g 2.5 g 2.6 g 2.3 g 2.4 g ²⁾ trans-3-phenylallyl alcohol
³⁾ 4-methoxybenzyl alcohol
⁴⁾ 3-phenylpropyl alcohol
⁵⁾ 2-methylbenzyl alcohol

Agents containing only one aromatic alcohol, only one dibasic ester or only one carboxylic acid monoester have been found to be ineffective in experiments.

By contrast, compositions according to the invention have a synergistic effect.

Examples 2 to 8: Compositions according to the invention

Demarcating agents were prepared according to the formulations according to Examples 2 to 8. For this purpose, the individual components were combined. After brief stirring, each formed a clear or slightly cloudy, viscous solution, which is directly usable as a demarcating agent.

Example 2: a composition according to the invention

• 25% by weight of trans-3-phenylallyl alcohol
• 30% by weight of 2-methylpentanedioic acid dimethyl ester
• 5% by weight of adipic acid dimethyl ester
• 4% by weight of dimethyl glutarate
• 6% by weight of succinic acid dimethyl ester
• 4% by weight of fatty alcohol alkoxylate (Plurafac® LF 221, BASF; low foaming nonionic surfactant)
• 3% by weight of orange terpenes
• 2% by weight of silica (Aerosil® 200, Evonik, specific surface area: 200 m ² / g)
• 10% by weight of butylglycol
• 11% by weight of sodium cumene sulphonate

Example 3: a further composition according to the invention

• - 35 wt .-% 4-methoxybenzyl alcohol
• 30% by weight of 2-methylpentanedioic acid dimethyl ester
• 15% by weight of diethyl malonate
• 5% by weight of alkylpolyglycoside (Lutensol® GD 70, BASF)
• 4% by weight of D-limonene
• 2% by weight of silica (Aerosil® 200, Evonik, specific surface area: 200 m ² / g)
• 8% by weight of butyltriglycol
• 1% by weight of sodium cumene sulphonate

Example 4: a further composition according to the invention

• - 23 wt .-% 4-methoxybenzyl alcohol
• 40% by weight of 2-methylpentanedioic acid dimethyl ester
• - 15 wt .-% diethyl methylmalonate
• 5% by weight of alkylpolyglycoside (Lutensol® GD 70, BASF)
• 5% by weight of methyl salicylate
• 2% by weight of hydroxypropylcellulose (Methocel® 311 DOW)
• 10% by weight of dipropylene glycol methyl ether

Example 5: a further composition according to the invention

• 20% by weight of benzyl alcohol
• 35% by weight of 2-methylpentanedioic acid dimethyl ester
• 13% by weight of oxalic acid dimethyl ester
• 5% by weight of sodium lauryl ether sulfate
• 5% by weight of methyl salicylate
• 5% by weight of silica (Aerosil® 200, Evonik, specific surface area: 200 m ² / g)
• 10% by weight of ethylene glycol monophenyl ether
• 7% by weight of sodium cumene sulphonate

Example 6: a further composition according to the invention

• 21% by weight of 3-phenyl-1-propanol
• 37% by weight of 2-methylpentanedioic acid dimethyl ester
• 13% by weight of diethyl tartaric acid
• 5% by weight of lauryl alcohol 7-polyglycol ether
• 3% by weight of orange terpenes
• 4% by weight of silica (Aerosil® 200, Evonik, specific surface area: 200 m ² / g)
• - 11 wt .-% 1,2-propylene glycol
• 6% by weight of sodium / potassium cumene sulphonate

Example 7: a further composition according to the invention

• 21% by weight of 2-methoxybenzyl alcohol
• 37% by weight of 2-methylpentanedioic acid dimethyl ester
• 11% by weight of dimethyl malonate
• 2% by weight of anionic surfactant (HOSTAPUR® SAS 93, Clariant, secondary alkanesulfonate)
• 6% by weight of orange terpenes
• 4% by weight of silica (Aerosil® 200, Evonik, specific surface area: 200 m ² / g)
• - 13 wt .-% 1,2-propylene glycol
• 6% by weight of sodium / potassium cumene sulphonate

Example 8: a further composition according to the invention

• 25% by weight of trans-3-phenylallyl alcohol
• 45% by weight of 2-methylpentanedioic acid dimethyl ester
• 4% by weight low-foaming surfactant (Pluronic® PE3100 / PE4300, block copolymers of ethylene oxide and propylene oxide)
• 3% by weight of orange terpenes
• 2% by weight of silica (Aerosil® 300, Evonik, specific surface area: 300 m ² / g)
• 10% by weight of sodium cumene sulphonate
• 7% by weight of dibutylglycol
• 4% by weight of butylglycol

Example 9: Removal of lane markings

The compositions according to Examples 2 to 8 were used to remove a typical pavement marking. For this purpose, the agent was uniformly applied in a layer thickness of about 1-3 mm on the mark to be removed and removed after 5 min exposure time with a Kärcher® high pressure cleaner with a pressure of 100 bar. In another series of experiments, a demarcation head was used instead of the Kärcher® high-pressure cleaner. The applied water pressure was max. 250 bar.

The color was removed without residue. Even in the depressions of the road surface no paint residue remained. Phantom marks were also not recognizable. The road surface was not damaged by the demarcation agent.

Example 10: Removal of hall floor markings

The compositions of Examples 2-8 were used to remove four year old yellow security markings from a hall floor.

For this purpose, the agent was uniformly applied by means of a roller in a layer thickness of about 1 mm to the mark to be removed. After an exposure time of 10 minutes, the mark was removed using a high pressure washer using a water pressure of 150 bar.

The color was removed without residue. The hall floor was not attacked by the demarcation agent.

QUOTES INCLUDE IN THE DESCRIPTION

This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Cited patent literature

• DE 2927968 A1 [0010]

Cited non-patent literature

• DIN EN 22719 [0042]

Claims (10)

Composition for removing markings, in particular pavement markings and hall floor markings, containing 5-50% by weight of at least one aromatic alcohol, 2-70% by weight of one or more dibasic esters, of which at least one is an ester of the formula (i)

wherein R1, R2 and R3 are independently linear or branched alkyl radicals having 1 to 10 carbon atoms. A composition according to claim 1, characterized in that the dibasic ester of formula (i) is 2-methylpentanedioic acid dimethyl ester. Composition according to Claim 1 or 2, characterized in that the further dibasic ester used is a carboxylic acid ester of the formula (ii)

wherein n = 0 to 10 and R4 and R5 are independently linear or branched alkyl radicals having 1 to 10 carbon atoms, or a carboxylic acid ester which is one or more substitution (s) with a linear or branched chain radical over the ester of formula (ii) having branched alkyl having 1 to 10 carbon atoms or by a hydroxy function in the chain. Composition according to any one of the preceding claims, characterized in that the composition contains in total from 30 to 50% by weight of dibasic esters. Composition according to any one of the preceding claims, characterized in that the composition contains 20-30% by weight of aromatic alcohol. Composition according to one of the preceding claims, characterized in that the aromatic alcohol is selected from saturated or unsaturated, aromatic, substituted, unsubstituted, liquid or solid alcohols, preferably from benzyl alcohol, 2-benzylheptanol, 2-benzyloxyethanol, 4-benzyloxybenzyl alcohol, 3, 4-dimethoxybenzyl alcohol, 3,5-dimethylbenzyl alcohol, 4-ethylbenzyl alcohol, 4-isopropylbenzyl alcohol, 2-methylbenzyl alcohol, 4-methoxybenzyl alcohol, 2-phenoxy-1-ethanol, 4-phenyl-1-butanol, 1-phenyl-1-propanol, 3-phenyl-1-propanol, 4-tert-butylbenzyl alcohol or trans-3-phenylallyl alcohol and mixtures thereof, wherein the alcohol is particularly preferably benzyl alcohol. Composition according to one of the preceding claims, characterized in that the composition contains a thickener, preferably selected from the group of agar-agar, carrageenan, tragacanth, gum arabic, guar flour, locust bean gum, starch, gelatin, casein, alginates, pectins, Polyols, dextrins, carboxymethylcellulose, cellulose ethers, polyacrylic and polymethacrylic compounds, vinyl polymers, polycarboxylic acids, polyethers, polyimines, polyamides, titanium dioxides, silicas or mixtures thereof. Composition according to one of the preceding claims, characterized in that the composition contains at least one anionic, cationic, amphoteric or nonionic surfactant, wherein the anionic surfactants are preferably selected from the group of sulfonates such as sodium toluene xylene sulfonate, sodium toluenesulfonate, sodium cumenesulfonate, Natriumdecyldiphenylethersulfonat, Sodium dodecylbenzenesulfonate, sodium dodecyldiphenyl ether sulfonate, sodium 1-octanesulfonate, sodium tetradecanesulfonate, sodium pentadecanesulfonate, sodium heptadecane sulfonate and potassium toluenesulfonate and the amphoteric surfactants are preferably selected from the group consisting of N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N- Alkylamidopropylglycine, N-alkyltaurine, N-alkylsacosine, 2-alkylaminopropionic and N-alkylaminoacetic acids having 8 to 24 carbon atoms in the alkyl group and the nonionic surfactants are preferably selected from the group of alkylpolyglycosides. Composition according to one of the preceding claims, characterized in that the composition also contains fragrance oils or natural, nature-identical or synthetic fragrances. Composition according to one of the preceding claims, characterized in that the composition comprises at least one solubilizer based on a glycol or glycol ether, for example dipropylene glycol, tripropylene glycol n-butyl ester, dipropylene glycol n-propyl ether, dipropylene glycol n-butyl ether, dipropylene glycol dimethyl ether, dipropylene glycol monomethyl ether, propylene glycol isopropyl ether, Tributylphenolpolyglykolether, Propylenglykoltertiärbutylether, hexylene glycol, 1,2-propylene glycol, dipropylene glycol, monoethylene glycol, butyl glycol, dibutyl glycol, methyldigycol containing.