DE202010001645U1 - Perfumes with spreading device - Google Patents

Abstract

Composition with a carrier, characterized in that the carrier is a silicone oil mixture.

Description

noble Perfumes are not only seductive, attractive or appear more sympathetic, they can also us quickly put in a good mood. So far, the perfumes were for example by means of a spray application mostly from the not always handy, heavy and very expensive glass bottles, taken.

Of the Location for these very unwieldy, heavy and big ones Packaging forms predominate in the "bathroom" at home.

Around but at any time of these amenities the perfumes use to be able to do this, this little, very noble and very handy product, as a "constant companion for on the way "to complement the example known spray application, developed.

• Komponente (a) Applikationsform
• Komponente (b) Silikonöl-Gemisch als Trägermaterial
• Komponente (c) Parfums in Silikonöl löslich (ohne Alkohol)

The invention consists of a combination of:

• Component (a) Application form
• Component (b) Silicone oil mixture as carrier material
• Component (c) Perfumes soluble in silicone oil (without alcohol)

Component (a)

The preferred application form (Example 1 and reference numerals to Example 1, Bottlemate GmbH, Taiwan), consisting of: Bottle PP, Roller ball housing PP material natural color with stainless steel ball 10 mm, Cap PP. Alternatively, the bottle of the application form can also made of other materials (such as glass or light metal), the sphere (such as plastic without cooling effect) getting produced.

The Steel ball may consist of a material or material mixtures and both solid, hollow or, for example, with a liquid, or a gel filled. Thought is also, instead of to choose a ball of any other shape such as a roll (for example cylindrical, oval or similar). The application form as well as the steel ball can also in any other size, shape and material Find application.

Component (b)

to Solution of the task that carries the carrier a silicone oil mixture is.

• (i) Cyclomethicon und/oder Dimethicon;
• (ii) mindestens einflüchtiges cyclisches organisches Polysiloxan mit einer Ringgrösse von 4 bis 12;
• (iii) mindestens ein zumindest teilweise vernetztes Organopolysiloxan: und
• (iv) mindestens einen verzweigten aliphatischen Kohlenwasserstoff mit 10 bis 18C-Atomen.

The silicone oil mixture preferably has the following constituents:

• (i) cyclomethicone and / or dimethicone;
• (ii) at least one volatile cyclic organic polysiloxane having a ring size of 4 to 12;
• (iii) at least one at least partially cross-linked organopolysiloxane: and
• (iv) at least one branched aliphatic hydrocarbon having 10 to 18C atoms.

• (i) Die Komponente (b) enthält (i) Cyclomethicon und/oder Dimethicon, vorzugsweise Coclomethicon. Die Gesamtmenge des Bestandteils (i) in der erfindungsgemässen Zusammensetzung liegt vorzugsweise im Bereich von 20 bis 80 Gew.-%, weiter bevorzugt im Bereich von 60 bis 70 Gew.-%, insbesondere bevorzugt im Bereich von 40 bis 50 Gew.-%.
• (ii) Die Komponente (b) enthält als Bestandteil (ii) mindestens ein flüchtiges Cyclisches organisches Polysiloxan mit einer Ringgrösse von 4 bis 12, das gegebenenfalls methyliert sein kann. Beispiele für diese cyclischen Polysiloxane umfassen Cyclotetrasiloxane und Cpclopentasiloxane, von denen Cyclopentasiloxane bevorzugt sind. Decamethylpentasiloxan, ein zehngliedriger Ring aus fünf Si(CH3)2-O-Einheiten ist ein Beispiel für die erfindungsgemäss verwendeten Cyclopentasiloxane.
• (iii) Die Komponente (b) enthält als Bestandteil (iii) mindestens ein zumindest teilweise vernetztes Organopolysiloxan. Das teilweise vernetzte Organopolysiloxan ist ein Elastomer mit einem Vernetzungsgrad, der ausreichend ist, um dem Siloxan gummiähnliche Eigenschaften zu verleihen. Dieses Organnopolysiloxan weist vorzugsweise eine dreidimensional vernetzte Struktur auf. Für die vorliegende Erfindung geeignete Organopolysiloxan-Elastomere werden beispielsweise in US-A-5,266,321 , US-A-4,980,167 und US-A-4,742,142 beschrieben. Repräsentative Beispiele sind Dimethicon-Netzpolymere.
• (iv) Als weiteren Bestandteil enthält die Komponente (b) der erfindungsgemässen Zusammensetzung mindestens einen verzweigten aliphatischen Kohlenwasserstoff mit 10 bis 18C-Atomen (Isoparaffine). Darunter sind Isododecan, ein mehrfach verzweigtkettiger aliphatischer Kohlenwasserstoff mit 12C-Atomen, und/oder Isohexadecan (CAS-Nr.4390-04-9) besonders bevorzugt.

The silicone components of component (b) are as follows:

• (i) Component (b) contains (i) cyclomethicone and / or dimethicone, preferably coclomethicone. The total amount of the component (i) in the composition of the present invention is preferably in the range of 20 to 80% by weight, more preferably in the range of 60 to 70% by weight, particularly preferably in the range of 40 to 50% by weight.
• (ii) Component (b) contains as component (ii) at least one volatile cyclic organic polysiloxane having a ring size of 4 to 12, which may optionally be methylated. Examples of these cyclic polysiloxanes include cyclotetrasiloxanes and cyclopentasiloxanes, of which cyclopentasiloxanes are preferred. Decamethylpentasiloxane, a ten-membered ring of five Si (CH 3) 2-O units, is an example of the cyclopentasiloxanes used in the present invention.
• (iii) Component (b) contains as component (iii) at least one at least partially cross-linked organopolysiloxane. The partially crosslinked organopolysiloxane is an elastomer having a degree of crosslinking sufficient to impart rubber-like properties to the siloxane. This organopolysiloxane preferably has a three-dimensionally crosslinked structure. Organopolysiloxane elastomers suitable for the present invention are described, for example, in US Pat US-A-5,266,321 . US-A-4,980,167 and US-A-4,742,142 described. Representative examples are dimethicone network polymers.
• (iv) As a further constituent, component (b) of the composition according to the invention contains at least one branched aliphatic hydrocarbon having 10 to 18 C atoms (isoparaffins). Of these, particular preference is given to isododecane, a multigrade-chain aliphatic hydrocarbon having 12 carbon atoms, and / or isohexadecane (CAS No. 4390-04-9).

The Ingredients (ii) and (iii) are preferably present in component (b) in a weight ratio of 450: 1 to 1: 4, more preferred from 350: 1 to 4: 1, especially from 140: 1 to 5: 1.

Component (b) of the composition according to the invention preferably contains a combination of components (ii) and (iii) as described in US Pat US-A-5,599,533 is described. Therein, the component (ii) is called "vehicle". In particular, in the present invention, a combination of the components (ii) and (iii) used, which is commercially available under the name DOW CORNING ^® 9040 and / or 9045 SILICONE ELASTOMER BLEND.

The Total amount of components (ii) and (iii) in the inventive Composition is preferably in the range of 0.5 to 75 wt .-%, further preferably in the range of 5 to 65 wt .-%, particularly preferably in the range of 10 to 55 wt .-%.

Of the Component (iv) is in the composition according to the invention preferably in an amount of 0.5 to 20% by weight, more preferably from 1 to 15 wt .-%, particularly preferably 2 to 10 wt .-%, before.

The Silicone oil / perfume oil mixture according to the invention, Component (b) and (c), when applied to the skin causes one physical cooling effect, d. H. it cools and refreshes the applied skin.

Of the occurring cooling effect is based on the interaction in particular two factors. On the one hand contains the silicone oil mixture as mentioned above, as a component at least a volatile cyclic organic polysiloxane having a Ring size from 4 to 12. This very thin liquid Silicone oil forms an ultrafine film on the skin that evaporated very quickly. The evaporation process needed while energy that is removed from the body. The body temperature is lowered, the process is perceived as cool. By irritation of the so-called cryogenic formulations arises a medium-term feeling of cooling.

To the Other is the silicone oil / perfume oil mixture over a device, component (a) applied to the skin for application, for this purpose in the device a ball, preferably a stainless steel ball provided is the silicone oil / perfume oil mixture in a very thin film on the skin. The preferred one Material of the ball, namely stainless steel, has a high thermal conductivity and is able to absorb body heat relatively quickly. By this effect at the moment of application also decreases the body repair at the applied site, resulting in as a feeling of cold directly on the skin noticeable power.

Besides However, other materials are suitable for use as a cooling Bullet. suitable are all metallic materials with a thermal conductivity (W / m · k) higher than 2.0. In addition, should also, for example. a plastic ball filled with liquid be preferred. This could be the liquid previously cooled / frozen, which is an advantage of a refrigeration Has.

The o. g. Stainless steel ball of the device for applying the silicone oil / perfume oil mixture is included in a receptacle of an insert of the device, wherein the ball is preferably stored floating in it, so that the liquid from a container interior one Container of the device between the inner wall of the recording and the ball can go outside.

Between the container and the insert is preferably still a threaded portion provided, the external thread with an internal thread of a cap is engageable, so that in particular the stainless steel ball and the liquid around it from the outside Influences is protected.

Component (c)

There Perfumes contain up to approx. 80% alcohol as carrier material, new perfume compositions had to be done (example 2a, 2b and 2c, LUZI AG, Switzerland) as special oil-soluble formulations for incorporation into silicone oils as a new carrier material become. They are free of alcohol, of polycyclic musk compounds and without the 7 allergens, Ökotest compliant. The rich Consistency is very productive and therefore causes a long-lasting Fragrance.

The Component (c) of the inventive composition are compatible perfumes (Example 3 and 3a, LUZI AG, Switzerland), which is preferably in an amount of 50 to 0.5 wt .-%, more preferably in an amount of up to 15 wt .-%, in particular in an amount of 16 to 8 wt .-%, are included.

1

contraption

2

container

3

threaded portion

4

external thread

5

cap

6

commitment with ball

7

admission

8th

liquid composition

9

Tank interior

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• - US 5266321 A [0009]
• - US 4980167 A [0009]
• - US 4742142 A [0009]
• US 5599533A [0011]

Claims (10)

Composition with a carrier, characterized in that the carrier is a silicone oil mixture. Composition according to Claim 1, characterized that the silicone oil mixture cyclomethicone and / or dimethicone having. Composition according to Claim 1, characterized that the silicone oil mixture at least one volatile Cyclic organic polysiloxane with one ring size from 4 to 12. Composition according to Claim 1, characterized that the silicone oil mixture at least one at least partially having crosslinked organopolysiloxane. Composition according to Claim 1, characterized that the silico-oil mixture at least one branched having aliphatic hydrocarbon having 10 to 18 atoms. Composition according to Claim 1, characterized that the silicone oil mixture cyclomethicone and / or dimethicone and at least one volatile cyclic organic Polysiloxane with a ring size of 4 to 12 and at least an at least partially cross-linked organopolysiloxane of at least a branched aliphatic hydrocarbon of 10 to 18 Has atoms. Composition according to at least one of the claims 1 to 6, characterized in that the silicone oil mixture enriched with oil-soluble perfume oils is. Device for dispensing the assembly according to claims 1 to 7 with a container (example 1, no. 2 ) and a ball associated therewith (Example 1, no. 6 ) which transfers the composition to the skin. Device according to claim 8, characterized in that that the ball has a high conductivity. Apparatus according to claim 8 or 9, characterized that the ball is made of steel.