DE202004012607U1 - Hair treatment composition includes fluorescent nanoparticles with a core consisting of a metal compound and a shell consisting of an organic polymer or a different metal compound - Google Patents

Abstract

Hair treatment composition includes fluorescent nanoparticles comprising a core consisting of a metal compound and a shell consisting of an organic polymer or a different metal compound.

Description

It are hair treatment agents containing certain fluorescent Nanocomposite particles described. The particles have a core on which is a combination of a metal and a non-metal exists and with a shell is coated from an organic polymer.

Achieving optical effects on the hair plays a special role for the user of hair treatment products. Typical optical effects are, for example, color and gloss effects of the hair. Hair treatment agents containing fluorescent substances can be used to produce optical effects on the hair. Appropriately treated hair can shine under black light (e.g. in a disco). But even in normal daylight, fluorescent dyes, especially in leave-in hair cosmetics, can improve the shine of the hair depending on the fluorescent color. Fluorescent substances can be insoluble compounds (pigments) or soluble fluorescent dyes dissolved in the hair treatment agent. So in the German utility models DE 203 08 712 . DE 203 09 463 and DE 203 08 748 Cosmetic preparations are described, inter alia, for dyeing hair, which contain at least one colorant (pigment) which is insoluble in the preparation and gives fluorescent effects under UV light. In the DE 196 46 804 describes a method for enhancing the shine of hair using certain organic fluorescent brighteners that are soluble in cosmetic solvents.

The Soluble fluorescent dyes previously proposed for hair treatment and pigments have the disadvantage that they have chemical interactions can enter into with other cosmetic active ingredients or additives and therefore only compatible to a limited extent and can only be used to a limited extent are. The interactions with other substances can reduce the Product performance, especially the desired optical effects. organic The disadvantage of fluorescent dyes is that their stability is often sensitive to light are what causes them to age over time and become part of their effectiveness to lose. insoluble, particulate Pigments have the disadvantage that they are often due to either too strong surface effects tend to coagulate or with less strong surface effects the substantivity is not sufficient for human hair. Pigments can also improve the optical Appearance of the product due to cloudiness impair and the production of optically clear or transparent products difficult. The gloss and color effects, especially their extent and durability as well as the application properties and compatibility of the previously proposed hair treatment agents with fluorescent Ingredients are not yet completely satisfactory. It there is therefore a need for products with at least using any of the above disadvantages of improved effectiveness of non-toxic and cosmetically and dermatologically acceptable active ingredients.

It it has now been found that the task is solved by the use of fluorescent composite particles consisting of a core and an envelope. The invention relates to the use of nanocomposite particles with fluorescent properties for hair treatment, in particular to create or intensify color or gloss effects human hair, the particles having a core, which is a combination of a metal and a non-metal exists and the particles are a shell has, the wrapping material selected is made of organic polymers and different from the core material Connections of a metal and a non-metal.

object of the invention are hair treatment compositions containing nanocomposite particles, wherein

• - the Particles have a core, which consists of a connection of a Metal and a non-metal,
• - the Particles a shell have selected is made of organic polymers and different from the core material Compounds of a metal and a nonmetal and
• - the Particles have fluorescent properties.

The core of the particles is preferably formed from an oxide ceramic material. Oxide ceramics are materials made of high-melting metal oxides with a glass phase-free structure and are characterized by their high temperature resistance, strength, corrosion resistance and usually by special electrical or magnetic properties. Oxide-ceramic materials include, for example, aluminum oxides, zirconium oxides, beryllium oxides, magnesium oxides, uranium oxides, titanates and ferrites. The core consists of a compound of a metal with a preferably multivalent non-metal. Aluminum, zirconium, hafnium, zinc, titanium, iron and chromium are particularly suitable as metals. The nonme tall can be, for example, oxygen, nitrogen, sulfur, selenium or carbon, so that the core consists of the compound classes of the oxides, nitrides, sulfides, sulfonitrides, selenides or carbides, with the oxides being preferred. Preferred core materials are oxide ceramics made of hafnium dioxide, zirconium dioxide, aluminum oxide, zinc dioxide and / or iron oxides, for example iron (III) oxide.

The Envelope around the core on the one hand reduces undesirable interactions and Agglomeration of the particles with each other, with other ingredients of the hair treatment agent and with the hair surface and on the other hand ensures but still sufficient adhesion of the particles to the hair, whereby the adhesion to the hair through functional groups on the particle surface and / or through suitable additives, especially the hair-setting agents mentioned below and hair-care polymers can be reinforced. The shell can e.g. from an oxide ceramic different from the oxide ceramic of the core exist (ceramic-ceramic composite). Alumina is considered a shell material well usable oxide ceramics.

Preferably is used as a material for the case a polymer is used (ceramic-polymer composite). Polymers can be homo- or from two or copolymers composed of several different monomers. Prefers are organic polymers, e.g. from ethylenically unsaturated, polymers, polyethers composed of free-radically polymerizable monomers, Polyesters, polyamides, polyolefins, polyurethanes. Radical fish polymerizable Monomers that can also be used in a mixture are e.g.

• (a) monoethylenically unsaturated C3 to C12 carboxylic acids or their salts,
• (b) monoethylenically unsaturated Esters of C3 to C12 carboxylic acids and C1 to C14 alcohols,
• (c) acrylic acid or dialkylaminoalkyl methacrylic acid with a total of up to 30 carbon atoms in the dialkylaminoalkyl radical, which can be in N-quaternized form or in salt form,
• (d) amides of the unsaturated carboxylic acids mentioned under (a), e.g. acrylamide, Methacrylic acid amide, N, N-dialkylacrylic acid or -methacrylsäureamid,
• (e) five- to eight-membered N-vinyl lactams, which on the ring by up to three C1 to C12 alkyl radicals can be substituted,
• (f) maleic acid, fumaric and itaconic acid dialkyl esters with up to 12 carbon atoms per alkyl radical,
• (g) monoethylenically unsaturated C3 to C12 alkyl vinyl ether,
• (h) vinylaromatics, which on the aromatic ring by one to three C1 to C12 alkyl radicals or functional groups substituted could be,
• (i) mono- or polyunsaturated hydrocarbons,
• (j) vinyl halides,
• (k) acrylonitrile or methacrylonitrile.

suitable Monomers are in particular:

• (a) acrylic acid, methacrylic acid, dimethylacrylic ethyl acrylic, Vinyl acetic acid, allylacetic vinyl propionic acid, fumaric acid, maleic acid, Itaconic acid. From this group, preference is given to using acrylic acid, methacrylic acid and itaconic acid Mixtures as well as the sodium, potassium, calcium or ammonium salts or their mixtures.
• (b) alkyl, hydroxyalkyl and vinyl esters such as methyl acrylate, Ethyl acrylate, n-propyl acrylate, isopropyl acrylate, n-butyl acrylate, tert-butyl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, ethyl methacrylate, Isopropyl methacrylate, n-butyl methacrylate, Isobutyl methacrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, Hydroxybutyl acrylate, hydroxyethyl methacrylate, 2-ethylhexyl methacrylate and vinyl formate, vinyl acetate, isopropenylacetate, vinyl propionate, Vinyl 2-ethylhexanoate, vinyl laurate and mixtures of these monomers.
• (c) dimethylaminoethyl acrylate, diethylaminoethyl acrylate, methylethylaminoethyl acrylate, Di-tert-butylaminoethyl acrylate, dimethylamino-methyl (or butyl, hexyl, octyl, stearyl) acrylate, dimethyl (or diethyl, methyl ethyl) Di-tert-butyl) aminoethyl methacrylate, dimethylaminomethyl (or butyl, amyl, hexyl, octyl, stearyl) methacrylate.
• (d) acrylic acid amide, methacrylamide, N, N-Dimethylacrylsäureamid, N, N-dimethyl methacrylamide.
• (e) N-vinyl lactams, e.g. 1-vinylpyrrolidone, 1-vinylcaprolactam, 1-vinylpiperidone, 4-methyl-1-vinylpyrrolidone, 3,5-dimethyl-1-vinylcaprolactam
• (f) diethyl fumarate, dimethyl fumarate, Fumarsäuredicyclohexylester, maleate, dimethyl maleate, Itakonsäuredimethylester, Itakonsäurediethylester.
• (g) alkyl and hydroxyalkyl vinyl ethers such as methyl, ethyl, propyl, Isopropyl, butyl vinyl ether, hydroxyethyl vinyl ether, hydroxypropyl vinyl ether, Hydroxybutyl.
• (h) styrene and styrene derivatives such as methylstyrene, vinyltoluene, Vinylbenzyl chloride and derivatives and vinylnaphthalene and derivatives.
• (i) mono- or polyunsaturated Hydrocarbons such as ethylene, propylene, isoprene, 1,3-butadiene,
• (j) vinyl chloride.

Besondes acrylic acid is preferred, methacrylic acid, acrylate, Metharylsäureester, Acrylamides and methacrylamides.

A more Fluorescence emission, which is the fluorescence emission of the nuclei in significantly exceeds the particles described, if the envelope additionally contains a fluorescent material. Such nanoparticles can be found in two different embodiments getting produced. Firstly, the fluorescent material installed as an intermediate layer between the oxide ceramic core and the polymer shell become. Ideally, it is a monomolecular intermediate layer. Without significant loss of quality however it is for the invention completely sufficient if the intermediate layer e.g. Is 0.25 to 2 nm thick. As material for the intermediate layer is particularly suitable for polyaromatic compounds such as. Anthracene, perylene or pyrene. The polymer is preferred selected so that the fluorescence is as little as possible impaired becomes. Polymethyl methacrylate (PMMA) or polymethacrylate are particularly suitable (PMA), mixtures of PMMA and PMA and MA / MMA copolymer. The usage of fluorinated carbon compounds is in individual cases of Advantage. Aluminum oxide is suitable as the core in all embodiments particularly good; it can however, other ceramics can also be used.

In a second embodiment Polymers are used which themselves and without further addition or fluoresce without an additional layer. Such polymers or copolymers Examples are poly (p-phenylene), poly (p-phenylene vinylene), poly (2-vinylquinoline), Poly (9-anthrylmethyl) methacrylate or poly (b-naphthyl methacrylate).

The Nanocomposite particles have a core of preferably 3 to 100 nm, in particular 3 to 50 nm diameter and an envelope with a thickness of preferably 1 to 20 nm, in particular 1 to 5 nm. The fluorescent nanocomposite particles are emitted by light in the wavelength range excited preferably from 200 to 400 nm and emit after excitation Light in the wavelength range preferably less than 800nm. Especially in the range of 200 to 800 nm, particularly preferably in the range from 400 to less than 800 nm. Those to be used according to the invention Nanoparticles can be found in the usual cosmetic solvents, especially in water and C1-C4 alcohols. They are not or hardly toxic. So far toxic fluorescent Connections are used, these connections are non-toxic Polymer or copolymer layer covered. A special advantage is that the fluorescence spectrum through the choice of material for the core can be varied. The wavelength of the fluorescence lines can be therefore within certain limits as desired by using others Oxide ceramics for set the core. The adhesive properties on the hair can be chosen of material for the case can be varied, especially polymers with cationic groups advantageous.

The above-mentioned fluorescent nanocomposite particles can be produced by a so-called plasma process, in particular a microwave plasma process. The basic steps for manufacturing are in the pamphlets DE 196 38 601 C1 . DE 94 03 581 U1 , WO 03/040727 and WO 03/064557 explained. The production processes and nanocomposite particles described there are suitable according to the invention and form part of the present invention. In principle, in all embodiments of the nanoparticles, the core is first produced from the oxide ceramic. An intermediate layer made of a fluorescent compound can then be applied to the core in a further reaction zone. In addition, the nanoparticles can be produced by condensing on a hydrocarbon or a fluorinated carbon compound having 10 to 30 carbon atoms on a ceramic core or on the intermediate layer with which the ceramic core is coated. The fluorescent properties can be enhanced or changed by doping the core or the shell with foreign atoms.

at the hair treatment compositions according to the invention can be funds for the care or cleaning of the hair, e.g. Shampoos, hair treatments, Hair rinses, Top fluids, hair oils, Brilliantine that is used in a wide variety of applications, e.g. as leave on or as rinse off products, can be applied; permanent, semi permanent or temporary hair dye, e.g. oxidative hair dye or non-oxidative hair tinting agents or hair bleach; permanent hair styling agents, e.g. in the form of mildly alkaline or acidic permanent waving agents, hair removal agents or permanent wave fixatives; as well as means for temporary deformation and / or stabilization of the hairstyle (styling agent), e.g. Hair sprays, Hair lacquers, setting lotions, setting foams, hair gels, hair waxes, Act hairstyle creams etc.

The cosmetic according to the invention Contains funds the nanocomposite particles preferably in an amount of 0.01 to 20 % By weight, in particular from 0.2 to 15% by weight or from 0.3 to 10% by weight in a cosmetically acceptable Carrier medium.

A embodiment The invention relates to a hair treatment agent that it Content shows

• (A) fluorescent nanocomposite particles and
• (B) at least one active ingredient or additive selected from hair-care substances, hair-setting substances, silicone compounds, Light stabilizers, oils, Grow, viscosity modifying Substances, preservatives, non-fluorescent pigments, direct hair dyes, non-fluorescent particulate substances, Surfactants, oxidizing agents, reducing agents and oxidation hair dye precursors.

The other active ingredients and additives are depending on the type and purpose preferably in an amount of 0.01 to 20% by weight, in particular from 0.05 to 10 or from 0.1 to 5% by weight.

In one embodiment contains the inventive means as a hair-care or hair-fixing additive (B) at least a polymer with anionic or anionizable groups in one Amount of preferably 0.01 to 20% by weight or from 0.05 to 10% by weight, particularly preferably from 0.1 to 5% by weight. Among anionizable groups become acid groups such as. carboxylic acid, sulfonic acid or phosphoric acid groups understood which by means of usual Bases such as organic amines or alkali or alkaline earth hydroxides can be deprotonated.

The Polymers of component (B) can partially or completely be neutralized with a basic neutralizing agent. Prefers are those agents in which in the polymer of component (B) acidic groups neutralized to 50 to 100%, particularly preferably to 70-100% are. Organic or inorganic can be used as neutralizing agents Bases are used. Examples of bases are in particular aminoalkanols such as. Aminomethylpropanol (AMP), triethanolamine or monoethanolamine, but also ammonia, NaOH, KOH etc.

The Polymer (B) can be a homo- or copolymer with monomer units containing acid groups naturally or be synthetic based, which may be combined with comonomers, which have no acid groups contain, is copolymerized. The acid groups are sulfonic acid, phosphoric acid and carboxylic acid groups into consideration, of which the carboxylic acid groups are preferred. Suitable acid groups Monomers containing are, for example, acrylic acid, methacrylic acid, crotonic acid, maleic acid or maleic anhydride, maleic, in particular the mono-C1-C7-alkyl esters of maleic acid as well aldehydocarboxylic or ketocarboxylic acids. Not with acid groups substituted comonomers are, for example, acrylamide, methacrylamide, Alkyl and dialkyl acrylamide, alkyl and dialkyl methacrylamide, alkyl acrylate, Alkyl methacrylate, vinyl caprolactone, vinyl pyrrolidone, vinyl ester, Vinyl alcohol, propylene glycol or ethylene glycol, amine-substituted Vinyl monomers such as Dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, Monoalkylaminoalkyl acrylate and monoalkylaminoalkyl methacrylate, wherein the alkyl groups of these monomers are preferably C1 to C7 alkyl groups, C1 to C3 alkyl groups are particularly preferred.

suitable Polymers with acid groups are especially uncrosslinked or with polyfunctional agents cross-linked homopolymers of acrylic acid or methacrylic acid, copolymers of acrylic acid or methacrylic acid selected with monomers from acrylic acid or methacrylic acid esters, Acrylamides, methacrylamides and vinyl pyrrolidone, homopolymers of crotonic and copolymers of crotonic acid selected with monomers from vinyl esters, acrylic acid or methacrylic acid esters, Acrylamides and methacrylamides. A suitable natural Polymer is, for example, shellac.

Preferred polymers with acid groups are: terpolymers made from acrylic acid, alkyl acrylate and N-alkylacrylamide (INCI name: acrylates / acrylamide copolymer), in particular terpolymers made from acrylic acid, ethyl acrylate and n-butyl acrylamide; crosslinked or uncrosslinked vinyl acetate / crotonic acid copolymers (INCI name: VA / crotonates copolymer); Copolymers of one or more C1-C5-alkyl acrylates, in particular C2-C4-alkyl acrylates and at least one monomer selected from acrylic acid or methacrylic acid (INCI name: acrylate copolymer), for example terpolymers from tert-butyl acrylate, ethyl acrylate and methacrylic acid; sodium polystyrene sulfonate; Vinyl acetate / crotonic acid / vinyl alkanoate copolymers, for example copolymers of vinyl acetate, crotonic acid and vinyl propionate; Copolymers of vinyl acetate, crotonic acid and vinyl neodecanoate (INCI names: VA / Crotonates / Vinyl Propionate Copolymer, VA / Crotonates / Vinyl Neodecanoate Copolymer); Aminomethylpropanol-acrylate copolymers; Copolymers of vinyl pyrrolidone and at least one further monomer selected from acrylic acid and methacrylic acid and optionally acrylic acid esters and methacrylic acid esters; Copolymers of methyl vinyl ether and maleic acid monoalkyl esters (INCI names: ethyl ester of PVM / MA copolymer, butyl ester of PVM / MA copolymer); Aminomethylpropanol salts of copolymers of allyl methacrylate and at least one further monomer selected from acrylic acid, and methacrylic acid and optionally acrylic acid esters and methacrylic acid esters; cross-linked copolymers of ethyl acrylate and methacrylic acid; Copolymers of vinyl acetate, mono-n-butyl maleate and isobornyl acrylate; Copolymers of two or more monomers selected from acrylic acid and methacrylic acid and optionally acrylic acid esters and methacrylic acid esters; Copolymers of octylacrylamide and at least one monomer selected from acrylic acid and methacrylic acid and optionally acrylic acid esters and methacrylic acid esters; Polyesters from diglycol, cyclohexanedimethanol, isophthalic acid and sulfoisophthalic acid, the alkyl groups of the abovementioned polymers generally preferably having 1, 2, 3 or 4 carbon atoms.

In one embodiment contains the inventive means as a hair care or hair-fixing additive at least one zwitterionic and / or amphoteric polymer in an amount of preferably 0.01 to 20% by weight or from 0.05 to 10% by weight, particularly preferably from 0.1 to 5% by weight. Zwitterionic polymers show at the same time at least one anionic and at least one cationic charge on. Amphoteric polymers have at least one acidic group (e.g. carboxylic acid or sulfonic acid group) and at least one basic group (e.g. amino group). acid groups can by means of usual Bases such as organic amines or alkali or alkaline earth hydroxides be deprotonated.

preferred zwitterionic or amphoteric polymers are: copolymers formed from alkyl acrylamide, alkyl amino alkyl methacrylate and two or more Acrylic acid monomers and methacrylic acid and optionally their esters, in particular copolymers of octylacrylamide, Acrylic acid, Butylaminoethyl methacrylate, methyl methacrylate and hydroxypropyl methacrylate (INCI name: Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer); Copolymers which are formed from at least one first type of monomer which has quaternary amine groups and at least one second type of monomer which has acid groups; copolymers from fatty alcohol acrylates, alkylamine oxide methacrylate and at least a monomer selected from acrylic acid and methacrylic acid and possibly acrylic acid esters and methacrylic acid esters, in particular copolymers of lauryl acrylate, stearyl acrylate, ethylamine oxide methacrylate and at least one monomer selected from acrylic acid and methacrylic acid and possibly their esters; Copolymers of methacryloyl ethyl betaine and at least one monomer selected from methacrylic acid and methacrylic acid esters; Copolymers of acrylic acid, Methyl acrylate and methacrylamidopropyltrimethylammonium chloride (TNCI name: Folyquaternium-47); Copolymers of acrylamidopropyltrimethylammonium chloride and acrylates or copolymers of acrylamide, acrylamidopropyltrimethylammonium chloride, 2-amidopropylacrylamide sulfonate and dimethylaminopropylamine (INCI name: Polyquaternium-43); Oligomers or polymers that can be produced from quaternary croton betaines or quaternary Crotonbetainestern.

In one embodiment contains the inventive means as a hair care or hair-fixing additive at least one cationic polymer, i.e. a polymer with cationic or cationizable groups, especially primary, secondary tertiary or quaternary Amine groups in an amount of preferably 0.01 to 20% by weight or from 0.05 to 10% by weight, particularly preferably from 0.1 to 5% by weight. The cationic charge density is preferably 1 to 7 meq / g.

at the suitable cationic polymers are preferably about hair-fixing or hair-conditioning polymers. suitable Polymers of component (B) preferably contain quaternary amine groups. The cationic polymers can Homopolymers or copolymers, the quaternary nitrogen groups being either in the polymer chain or preferably as a substituent on one or several of the monomers are contained. The containing ammonium groups Monomers can be copolymerized with non-cationic monomers. suitable cationic monomers are unsaturated, Radically polymerizable compounds which have at least one carry cationic group, especially ammonium substituted vinyl monomers such as. Trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary Vinylammoniummonomere with cyclic, containing cationic nitrogen Groups such as pyridinium, imidazolium or quaternary pyrrolidones, e.g. alkylvinylimidizolium, Alkyl vinyl pyridinium, or alkyl vinyl pyrrolidone salts. The alkyl groups these monomers are preferably lower alkyl groups such as e.g. C1 to C7 alkyl groups, particularly preferably C1 to C3 alkyl groups.

The monomers containing ammonium groups can be copolymerized with non-cationic monomers. Suitable comonomers are, for example, acrylamide, methacrylamide, alkyl and dialkyl acrylamide, alkyl and dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, vinyl caprolactam, Vi nylpyrrolidone, vinyl esters, for example vinyl acetate, vinyl alcohol, propylene glycol or ethylene glycol, the alkyl groups of these monomers preferably being C1 to C7 alkyl groups, particularly preferably C1 to C3 alkyl groups.

suitable Polymers with quaternary Amine groups are e.g. those in the CTFA Cosmetic Ingredient Dictionary Polymers described under the names Polyquaternium such as Methyl vinylimidazolium chloride / vinyl pyrrolidone copolymer (Polyquaternium-16) or quaternized vinyl pyrrolidone / dimethylaminoethyl methacrylate Copolymer (polyquaternium-11) and quaternary silicone polymers or oligomers such as silicone polymers with quaternary end groups (Quaternium-80).

Preferred synthetic synthetic cationic polymers: poly (dimethyldiallylammonium chloride); Copolymers of acrylamide and dimethyldiallylammonium chloride; quaternary ammonium polymers formed by the reaction of diethyl sulfate and a copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate, especially vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer (such as Gafquat ^® 755 N, Gafquat ^® 734); quaternary ammonium polymers made from methyl vinyl imidazolium chloride and vinyl pyrrolidone (eg LUVIQUAT ^® HM 550); Polyquaternium-35; Polyquaternium-57; Trimethylammonium ethyl methacrylate chloride polymer; Terpolymers of dimethyldiallylammonium chloride, sodium acrylate and acrylamide (eg Merquat ^® Plus 3300); Copolymers of vinyl pyrrolidone, dimethylaminopropyl methacrylamide and methacryloylaminopropyllauryldimethylammonium chloride; Terpolymers of vinyl pyrrolidone, dimethylaminoethyl methacrylate and vinyl caprolactam (eg Gaffix ^® VC 713); Vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymers (eg Gafquat ^® HS 100); Copolymers of vinyl pyrrolidone and dimethylaminoethyl methacrylate; Copolymers of vinyl pyrrolidone, vinyl caprolactam and dimethylaminopropylacrylamide; Polyesters or oligoesters composed of at least one first type of monomer which is selected from hydroxy acid substituted with at least one quaternary ammonium group; Dimethylpolysiloxanes which are terminally substituted with quaternary ammonium groups.

Suitable cationic polymers derived from natural polymers are, in particular, cationic derivatives of polysaccharides, for example cationic derivatives of cellulose, starch or guar. Chitosan and chitosan derivatives are also suitable. For example, cationic polysaccharides have the general formula GOBN ⁺ R ^a R ^b R ^c X ^-

G is an anhydroglucose residue, for example starch or cellulose anhydroglucose;

B is a divalent linking group, for example alkylene, oxyalkylene, polyoxyalkylene or hydroxyalkylene; R ^a , R ^b and R ^c are independently alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl, each with up to 18 C atoms, the total number of C atoms in R ^a , R ^b and R ^c preferably being a maximum of 20 is;

X is a common one Counter anion, for example a halogen, acetate, phosphate, nitrate or alkyl sulfate, preferably a chloride. Cationic celluloses are e.g. those with the INCI names Polyquaternium-10 or Polyquaternium-24th A suitable cationic guar derivative has e.g. the INCI name Guar hydroxypropyltrimonium chloride.

Especially preferred cationic substances are chitosan, chitosan salts and Chitosan derivatives. In the chitosans to be used according to the invention it is complete or partially deacetylated chitins. The molecular weight can be about one broad spectrum, for example from 20,000 to approx. 5 million g / mol, e.g. from 30,000 to 70,000 g / mol. Preferably however, the molecular weight is above 100,000 g / mol, particularly preferably from 200,000 to 700,000 g / mol. The degree of deacetylation is preferably 10 to 99%, particularly preferably 60 to 99%. A favorite Chitosan salt is chitosonium pyrrolidone carboxylate, e.g.

Kytamer ^® PC with a molecular weight of approx. 200,000 to 300,000 g / mol and deacetylation of 70 to 85%. Quaternized, alkylated or hydroxyalkylated derivatives, for example hydroxyethyl, hydroxypropyl or hydroxybutyl chitosan, are suitable as chitosan derivatives. The chitosans or chitosan derivatives are preferably in neutralized or partially neutralized form. The degree of neutralization is preferably at least 50%, particularly preferably between 70 and 100, based on the number of free base groups. In principle, all cosmetically compatible inorganic or organic acids can be used as neutralizing agents, for example formic acid, tartaric acid, malic acid, lactic acid, citrus Nenoic acid, pyrrolidone carboxylic acid, hydrochloric acid and others, of which pyrrolidone carboxylic acid is particularly preferred.

preferred cationic polymers on natural Basis: cationic cellulose derivatives from hydroxyethyl cellulose and diallyl dimethyl ammonium chloride; cationic cellulose derivatives Hydroxyethyl cellulose and trimethyl ammonium substituted epoxy; Chitosan and its salts; Hydroxyalkylchitosans and their salts; Alkyl-hydroxyalkylchitosans and their salts; N-Hydroxyalkylchitosanalkylether.

In a further preferred embodiment contains the agent according to the invention 0.01 to 15% by weight, preferably 0.5 to 10% by weight, of at least one synthetic or natural nonionic film-forming polymer. Among natural polymers are also understood chemically modified polymers of natural origin. Film-forming polymers are understood to mean those polymers which when used in 0.01 to 5% aqueous, alcoholic or aqueous-alcoholic solution are able to deposit a polymer film on the hair.

suitable synthetic, non-ionic film-forming, hair-fixing polymers are homo- or copolymers which consist of at least one of the following Monomers are built up: vinyl pyrrolidone, vinyl caprolactam, vinyl ester such as. Vinyl acetate, vinyl alcohol, acrylamide, methacrylamide, alkyl and dialkylacrylamide, Alkyl and dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, Propylene glycol or ethylene glycol, the alkyl groups of these Monomers preferably C1 to C7 alkyl groups, particularly preferred C1 to C3 alkyl groups are. Suitable are e.g. Homopolymers of vinyl caprolactam, Vinyl pyrrolidone or N-vinyl formamide. other suitable synthetic Film-forming, non-ionic, hair-fixing polymers are e.g. Copolymers of vinyl pyrrolidone and vinyl acetate, terpolymers from vinyl pyrrolidone, vinyl acetate and vinyl propionate, polyacrylamides; Polyvinyl alcohols as well as polyethylene glycol / polypropylene glycol copolymers. Suitable natural film-forming polymers are e.g. Cellulose derivatives, e.g. Hydroxyalkylcellulose.

preferred nonionic polymers are: polyvinylpyrrolidone, polyvinylcaprolactam, Vinyl pyrrolidone / vinyl acetate copolymers, polyvinyl alcohol, isobutylene / ethyl maleimide / hydroxyethyl maleimide copolymer; Copolymers of vinyl pyrrolidone, vinyl acetate and vinyl propionate.

In one embodiment contains the inventive means as a hair care additive, at least one silicone compound in an amount of preferably 0.01 to 15% by weight, particularly preferably from 0.1 to 5% by weight. The silicone compounds include volatile and nonvolatile Silicones and soluble in the agent and insoluble Silicones. In one embodiment are high-molecular silicones with a viscosity of 1,000 up to 2,000,000 cSt at 25 ° C, preferably 10,000 to 1,800,000 or 100,000 to 1,500,000. The Silicone compounds include polyalkyl and polyarylsiloxanes, in particular with methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl groups. Polydimethylsiloxanes, polydiethylsiloxanes, polymethylphenylsiloxanes are preferred. Glossy, arylated silicones with a refractive index are also preferred of at least 1.46, or at least 1.52. The silicone compounds include in particular the substances with the INCI names Cyclomethicone, Dimethicone, Dimethiconol, Dimethicone Copolyol, Phenyl Trimethicone, Amodimethicones, trimethylsilylamodimethicones, stearyl siloxysilicates, Polymethylsilsesquioxane, Dimethicone Crosspolymer. Are suitable also silicone resins and silicone elastomers, which are highly cross-linked Siloxanes.

preferred Silicones are:

cyclic Dimethylsiloxanes, linear polydimethylsiloxanes, block polymers Polydimethylsiloxane and polyethylene oxide and / or polypropylene oxide, Polydimethylsiloxanes with end or pendant Polyethylene oxide or polypropylene oxide residues, polydimethylsiloxanes with terminal Hydroxyl groups, phenyl-substituted polydimethylsiloxanes, silicone emulsions, Silicone elastomers, silicone waxes, silicone gums, amino-substituted Silicones and with quaternary Silicones substituted with ammonium groups.

In one embodiment, the agent according to the invention contains a light stabilizer in an amount of preferably from 0.01 to 10% by weight or from 0.1 to 5% by weight, particularly preferably from 0.2 to 2% by weight. The light stabilizers in particular include all in the EP 1 084 696 called light stabilizers. Preferred are: 2-ethylhexyl 4-methoxycinnamate, methyl methoxycinnamate, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and polyethoxylated p-aminobenzoates.

In one embodiment, the agent according to the invention contains at least one hydrophobic oil or wax in an amount of preferably 0.01 to 20, particularly preferably 0.05 to 10, very particularly preferably from 0.1 to 5% by weight.

The liquid, hydrophobic oils have a melting point of less than or equal to 25 ° C and a boiling point from preferably about 250 ° C, especially about 300 ° C. Therefor can in principle use any oil which is generally known to the person skilled in the art become. Vegetable or animal oils, mineral oils (paraffinum liquidum), silicone oils or their mixtures. Hydrocarbon oils, e.g. Paraffin or isoparaffin oils, Squalane, oils from fatty acids and polyols, especially triglycerides. Suitable vegetable oils are e.g. Sunflower oil, Coconut oil, Castor oil, lanolin, jojoba oil, Corn oil, Soybean oil.

As In principle, any wax or waxy substance can be found in the state of the art Technology known wax can be used. These include animal, vegetable, mineral and synthetic waxes, microcrystalline waxes, macrocrystalline waxes, solid paraffins, petrolatum, petroleum jelly, Ozokerite, Montan wax, Fischer-Tropsch waxes, polyolefin waxes e.g. Polybutene, beeswax, wool wax and its derivatives such as Wool wax alcohols, candelilla wax, olive wax, carnauba wax, Japanese wax, apple wax, hardened Fats, fatty acid esters and fatty acid glycerides with a solidification point of above 40 ° C, polyethylene waxes and silicone waxes. The waxes or wax-like substances have one Solidification point above 40 ° C, preferably above 55 ° C. The needle penetration number (0.1 mm, 100 g, 5 s, 25 ° C; according to DIN 51 579) is preferably in the range from 2 to 70, in particular from 3 to 40.

In one embodiment contains the inventive means 0.01 to 20, particularly preferably from 0.05 to 10, very particularly preferably from 0.1 to 5% by weight of at least one hair conditioning agent Additive selected from betaine; panthenol; panthenyl; sorbitol; protein hydrolysates; Plant extracts; A-B block copolymers of alkyl acrylates and Alkylmethacryaten; A-B block copolymers of alkyl methacrylates and acrylonitrile; A-B-A block copolymers of lactide and ethylene oxide; A-B-A block copolymers of caprolactone and ethylene oxide; A-B-C block copolymers from alkylene or alkadiene compounds, styrene and alkyl methacrylates; A-B-C block copolymers of acrylic acid, styrene and alkyl methacrylates; star-shaped block copolymers; hyperbranched polymers; dendrimers; intrinsically electrical conductive 3,4-polyethylene dioxythiophenes and intrinsically electrically conductive polyanilines.

In one embodiment contains the inventive means at least one viscosity modifier Substance in an amount of preferably 0.01 to 20% by weight or 0.05 up to 10% by weight or particularly preferably from 0.1 to 5% by weight. The viscosity modifier Fabric is preferably a thickening polymer selected from Copolymers from at least one first type of monomer selected from acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of acrylic acid and ethoxylated fatty alcohol; cross-linked polyacrylic acid; networked Copolymers of at least one first type of monomer that is selected from acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of acrylic acid with C10 to C30 alcohols; Copolymers of at least one first Monomer type selected is made of acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of itaconic acid and ethoxylated fatty alcohol; Copolymers of at least one first type of monomer selected is made of acrylic acid and methacrylic acid, at least one second type of monomer, which is selected from esters of itaconic acid and ethoxylated C10 to C30 alcohol and a third type of monomer, selected from C1 to C4 amino alkyl acrylates; Copolymers of two or more Monomers selected from acrylic acid, methacrylic acid, Acrylsäureestern and methacrylic acid esters; Copolymers of vinyl pyrrolidone and ammonium acryloyldimethyl taurate; Copolymers of ammonium acryloyldimethyl taurate and monomers selected from Esters of methacrylic acid and ethoxylated fatty alcohols; hydroxyethyl cellulose; hydroxypropyl cellulose; hydroxypropyl; Glycerylpolyacrylat; glyceryl; Copolymers of at least one C2, C3 or C4 alkylene and styrene; polyurethanes; hydroxypropyl starch; polyacrylamide; copolymer of maleic anhydride crosslinked with decadiene and methyl vinyl ether; Locust bean gum; Guar gum; xanthan; Dehydroxanthan; carrageenan; Karaya gum; hydrolyzed corn starch; copolymers made of polyethylene oxide, fatty alcohols and saturated methylene diphenyl diisocyanate (e.g. PEG-150 / stearyl alcohol / -SMDI Copolymer).

In one embodiment contains the inventive means 0.01 to 20, particularly preferably from 0.05 to 10, very particularly preferably from 0.1 to 5% by weight of at least one surfactant. The surfactant can be non-ionic, anionic, cationic or zwitterionic.

suitable nonionic surfactants are e.g.

• - Ethoxylated fatty alcohols, fatty acids, fatty acid glycerides or alkylphenols, in particular addition products of 2 to 30 mol of ethylene oxide and / or 1 to 5 mol of propylene oxide with C8 to C22 fatty alcohols C12 to C22 fatty acids or to alkylphenols with 8 to 15 carbon atoms in the alkyl group
• - C12- up to C22 fatty acid mono- and diesters of adducts of 1 to 30 moles of ethylene oxide on glycerin
• - Addition products from 5 to 60 mol ethylene oxide on castor oil or on hardened (hydrogenated) Castor oil.
• - fatty acid sugar esters, in particular esters of sucrose and one or two C8 to C22 fatty acids, INCI: Sucrose Cocoate, Sucrose Dilaurate, Sucrose Distearate, Sucrose Laurate, sucrose myristate, sucrose oleate, sucrose palmitate, sucrose Ricinoleate, sucrose stearate
• - esters from sorbitan and one, two or three C8 to C22 fatty acids and a degree of ethoxylation from 4 to 20
• - polyglyceryl fatty acid esters, in particular from one, two or more C8 to C22 fatty acids and Polyglycerol with preferably 2 to 20 glyceryl units
• - alkyl glucosides, Alkyl oligoglucosides and alkyl polyglucosides with C8 to C22 alkyl groups, e.g. Decyl glucoside or lauryl glucoside,

suitable anionic surfactants are e.g. Salts and esters of carboxylic acids, alkyl ether sulfates and alkyl sulfates, fatty alcohol ether sulfates, sulfonic acid and their salts (e.g. sulfosuccinates or fatty acid isethienates), phosphoric acid esters and their salts, acylamino acids and their salts. A detailed one Description of these anionic surfactants is the publication "FIEDLER Lexicon of auxiliary substances ", Volume 1, fifth Edition (2002), pages 97 to 102, on the hereby expressly Reference is made. Preferred surfactants are mono-, di- and / or Triester of phosphoric acid with adducts of 2 to 30 mol ethylene oxide with C8 to C22 fatty alcohols.

wobei R1 eine geradkettige oder verzweigtkettige Alkyl-, Alkenyl- oder Hydroxyalkylgruppe mit 8 bis 18 C-Atomen und 0 bis etwa 10 Ethylenoxideinheiten und 0 bis 1 Glycerineinheit darstellt; Y eine N-, P- oder S-haltige Gruppe ist; R2 eine Alkyl- oder Monohydroxyalkylgruppe mit 1 bis 3 C-Atomen ist; X gleich 1 ist, falls Y ein Schwefelatom ist und X gleich 2 ist, wenn Y ein Stickstoffatom oder ein Phosphoratom ist; R3 eine Alkylen- oder Hydroxyalkylengruppe mit 1 bis 4 C-Atomen ist und Z^(–) eine Carboxylat-, Sulfat-, Phosphonat- oder Phosphatgruppe darstellt.Suitable amphoteric surfactants are, for example, derivatives of aliphatic quaternary ammonium, phosphonium and sulfonium compounds of the formula

wherein R1 represents a straight-chain or branched-chain alkyl, alkenyl or hydroxyalkyl group with 8 to 18 C atoms and 0 to about 10 ethylene oxide units and 0 to 1 glycerol unit; Y is a group containing N, P or S; R2 is an alkyl or monohydroxyalkyl group with 1 to 3 C atoms; X is 1 if Y is a sulfur atom and X is 2 if Y is a nitrogen atom or a phosphorus atom; R3 is an alkylene or hydroxyalkylene group with 1 to 4 carbon atoms and Z ^{(-) represents} a carboxylate, sulfate, phosphonate or phosphate group.

Other Amphoteric surfactants such as betaines are also suitable. Examples of betaines include C8 to C18 alkyl betaines such as cocodimethylcarboxymethyl betaine, Lauryldimethylcarboxymethylbetaine, lauryldimethylalphacarboxyethylbetaine, Cetyldimethylcarboxymethylbetaine, oleyldimethylgammacarboxypropylbetaine and lauryl-bis (2-hydroxypropyl) alphacarboxyethyl betaine; C8 to C18 sulfobetaines such as cocodimethylsulfopropylbetaine, stearyldimethylsulfopropylbetaine, Lauryldimethylsulfoethylbetaine, laurylbis- (2-hydroxyethyl) sulfopropylbetaine; the carboxyl derivatives of imidazole, the C8 to C18 alkyldimethylammonium acetates, the C8 to C18 alkyldimethylcarbonylmethylammonium salts and the C8 to C18 fatty acid alkylamido betaines such as coconut fatty acid amidopropyl betaine and N-coconut fatty acid amidoethyl-N- [2- (carboxymethoxy) ethyl] glycerol (CTFA name: Cocoamphocarboxyglycinate).

Suitable cationic surfactants contain amino groups or quaternized hydrophilic ammonium groups, which carry a positive charge in solution and by the general formula N ⁽⁺⁾ R ¹ R ² R ³ R ⁴ X ^(-) can be represented, wherein R1 to R4 independently of one another denote aliphatic groups, aromatic groups, alkoxy groups, polyoxyalkylene groups, alkylamido groups, hydroxyalkyl groups, aryl groups or alkaryl groups with 1 to 22 carbon atoms, at least one radical having at least 6, preferably at least 8 carbon atoms and X ^{- represents} an anion, for example a halogen, acetate, phosphate, nitrate or alkyl sulfate, preferably a chloride. In addition to the carbon atoms and the hydrogen atoms, the aliphatic groups can also contain cross-links or other groups such as, for example, further amino groups.

Examples of suitable cationic surfactants are the chlorides or bromides of alkyldimethylbenzyl ammonium salts, alkyltrimethylammonium salts, for example cetyltrimethylammonium chloride or bromide, tetradecyltrimethylammonium chloride or bromide, alkyldimethylhydroxyethylammonium chlorides or bromides, dialkyldimethylammonium chlorides or bromides, alkylpyridinium salts, for example lauryl- or cetylpyridinium chloride, alkylamidoethyltrimethylammonium ether sulfates as well as compounds with cationic character such as amine oxides, for example alkylmethylamine or alkylaminoethyldimethylamine oxides. C8-22-alkyldimethylbenzylammonium compounds, C8-22-alkyltrimethylammonium compounds, in particular cetyltrimethylammonium chloride, C8-22-alkyldimethylhydroxyethylammonium compounds, di- (C8-22-alkyl) -dimethylammonium compounds, C8-22-alkylpyridinium sulfate ammonium, C8-22-alkylpyridinium sulfate salts, C8-22-alkylpyridinium sulfate salts, C8-22-alkylpyridinium sulfate salts, C8-22-alkylpyridinium sulfate ammonium salts, 22-alkylmethylamine oxides, C8-22-alkylaminoethyldimethylamine oxides.

In one embodiment contains the agent according to the invention 0.01 to 5, particularly preferably from 0.05 to 1% by weight of at least a preservative. Suitable preservatives are in the International Cosmetic Ingredient Dictionary and Handbook, 9th edition with the function "Preservatives" listed substances, e.g. Phenoxyethanol, benzyl paraben, butyl paraben, ethyl paraben, Isobutyl paraben, isopropyl paraben, methyl paraben, propyl paraben, Iodopropynyl butyl carbamate, methyl dibromoglutaronitrile, DMDM hydantoin.

A special embodiment the invention relates to a hair care product. Hair care products are e.g. Conditioners, treatments, hair treatments, conditioners or the like. The Contains hair care products at least one hair care active ingredient selected from the above Silicone compounds, cationic or amine-substituted surfactants and cationic or amine substituted polymers. The hair care ingredient can be present in amounts between 0.01 and 10.0% by weight, in particular between 0.01 and 5.0 wt.%, Based on the finished product, used become. The hair care product according to the invention can be applied to dry, damp or wet hair either remain in the hair or it can after a suitable exposure time rinsed out again become. The exposure times depend depends on the type of hair. As a general guideline, exposure times between 0.5 and 30 minutes, especially 0.5 and 10 minutes, preferably between 1 and 5 minutes.

In addition to the cationic surfactants mentioned above, other suitable cationic or amine-substituted surfactants are such
of the formula R1-NH- (CH ₂ ) n-NR2R3
or the formula R1-NH- (CH ₂ ) nN ⁺ R2R3R4 X ^-
wherein R1 is an acyl or an alkyl radical having 8 to 24 carbon atoms, which can be branched or unbranched, saturated or unsaturated, wherein the acyl and / or the alkyl radical can contain one or more OH groups, R2, R3 and R4 are independently hydrogen, alkyl or alkoxy alkyl radicals having 1 to 6 carbon atoms, which may be the same or different, saturated or unsaturated and substituted by one or more hydroxyl groups, X ^{- is} an anion, in particular a halide ion or a compound of general formula RSO ₃ ^- , in which R has the meaning of saturated or unsaturated alkyl radicals having 1 to 4 carbon atoms, and n is an integer between 1 and 10, preferably from 2 to 5.

The hair care active ingredient is preferably an amidoamine and / or a quaternized amidoamine of the formulas mentioned above, in which R1 is a branched or unbranched, saturated or unsaturated acyl radical having 8 to 24 carbon atoms, which may contain at least one OH group. Also preferred are those amines and / or quaternized amines in which at least one of the radicals R2, R3 and R4 is a radical of the general formula CH ₂ CH ₂ OR5, in which R5 is alkyl radicals having 1 to 4 carbon atoms, hydroxyethyl or can have H. Suitable amines or amidoamines, which may or may not be quaternized, are in particular those with the INCI names ricinoleamidopropyl betaine, ricinoleamidopropyl dimethylamine, ricinoleamidopropyl dimethyl lactate, ricinoleamidopropyl ethyldimonium ethosulfate, ricinoleamidopropyltrimonium chloride, ricinolamide amide sulfate, ricinolamide amidopropyl Chloride, Behenamidopropyl Dimethylamine, Isostearylamidopropyl Dimethylamine, Stearylamidopropyl Dimethylamine, Quaternium-33, Undecyleneamidopropyltrimonium Methosulfate.

In a preferred embodiment, the agent according to the invention contains at least one pigment. These can be colored pigments which give color effects to the product composition or the hair or it can be glossy effect pigments which give the product composition or the hair gloss effects. The color or gloss effects on the hair are preferably temporary, ie they last until the next hair wash and can be removed by washing the hair with conventional shampoos. The pigments are present in the product composition in undissolved form and can be contained in an amount of 0.01 to 25% by weight, particularly preferably 5 to 15% by weight. The preferred particle size is 1 to 200 μm, in particular 3 to 150 μm, particularly preferably 10 to 100 μm. The pigments are practically insoluble colorants in the application medium and can be inorganic or organic. Inorganic-organic mixed pigments are also possible. Inorganic pigments are preferred. The advantage of inorganic pigments is their excellent light, weather and temperature resistance. The inorganic pigments can be of natural origin, for example made from chalk, ocher, umber, green earth, burnt terra di Siena or graphite. The pigments can be white pigments such as titanium dioxide or zinc oxide, black pigments such as iron oxide black, colored pigments such as ultramarine or iron oxide red, gloss pigments, metallic effect pigments, pearlescent pigments and fluorescent or phosphorescent pigments, preferably at least one pigment , non-white pigment. Metal oxides, hydroxides and oxide hydrates, mixed phase pigments, sulfur-containing silicates, metal sulfides, complex metal cyanides, metal sulfates, chromates and molybdates as well as the metals themselves (bronze pigments) are suitable. Titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), ultramarine (sodium aluminum sulfosilicate, CI 77007, pigment blue 29 ), Chromium Oxide Hydrate (CI77289), Iron Blue (Ferric Ferrocyanide, CI77510), Carmine (Cochineal).

Pearlescent and color pigments based on mica or mica are particularly preferred, which are coated with a metal oxide or a metal oxychloride such as titanium dioxide or bismuth oxychloride and, if appropriate, other colorants such as iron oxides, iron blue, ultramarine, carmine, etc., and the color is determined by varying the layer thickness can be. Such pigments are marketed under the trade names Rona ^®, Colorona® ^{®, ®} and Dichrona® Timiron ^® from Merck, Germany.

organic Pigments are, for example, the natural pigments sepia, gummy Bone charcoal, Kasseler brown, indigo, chlorophyll and other plant pigments. Synthetic organic pigments are, for example, azo pigments, Anthraquinones, indigoids, dioxazine, quinacridone, phthalocyanine, Isoindolinone, perylene and perinone, metal complex, alkali blue and diketopyrrolopyrrole pigments.

In one embodiment contains the inventive means 0.01 to 10, particularly preferably from 0.05 to 5% by weight of at least another particulate substance different from component (A). suitable Fabrics are e.g. Substances that are solid at room temperature (25 ° C) and are in the form of particles. Silica, Silicates, aluminates, clays, mica, salts, especially inorganic Metal salts, metal oxides, e.g. Titanium dioxide, minerals and polymer particles. The particles lie in the medium in undissolved, preferably stably dispersed Form before and can after application to the hair and evaporation of the solvent deposit on the hair in a solid form. A stable dispersion can be achieved by the composition with a yield point that is big enough is to prevent the solid particles from sinking. Adequate yield can be used by using suitable gelling agents in suitable amounts can be set. Preferred particulate substances are silica (silica gel, Silicon dioxide) and metal salts, especially inorganic metal salts, silica being particularly preferred. Metal salts are e.g. Alkali- or alkaline earth halides such as sodium chloride or potassium chloride; Alkali or alkaline earth metal sulfates such as sodium sulfate or magnesium sulfate.

Another embodiment relates to a means for permanently deforming the hair. In addition to preferably 0.05 to 5% by weight of the nanocomposite particles, it contains at least one reducing agent, in particular a keratin-reducing mercapto compound in an amount of preferably 0.5 to 15% by weight. The permanent waving agent is preferably in the form of an aqueous, alkaline (pH = 5 to 10) preparation which is used as a keratin-reducing mercapto compound, for example cysteine, cysteamine, N-acetyl-L-cysteine, mercaptocarboxylic acids, such as thioglycolic acid or thiolactic acid, or salts of mercaptocarboxylic acids, such as ammonium and guanidine salts of thioglycolic acid or thio lactic acid. The required alkalinity is adjusted by adding ammonia, organic amines, ammonium and alkali carbonates or bicarbonates. However, it is also possible to use a neutral or acidic (pH = 4.5 to 7) hair styling agent which has an effective content of sulfites or mercaptocarboxylic acid esters in the aqueous medium. In the former case, sodium or ammonium sulfite or the sulfurous acid salt with an organic amine, such as monoethanolamine and guanidine, are preferably used in a concentration of about 2 to 12% by weight (calculated as SO2). In the latter case, thioglycolic acid monoglycol esters or glycerol esters in particular are used in a concentration of about 5 to 50% by weight (corresponding to a free thioglycolic acid content of 2 to 16% by weight). The agent for permanent hair shaping according to the invention can also contain a mixture of the keratin-reducing compounds mentioned above. After a sufficient time for the hair to be permanently deformed, the hair is rinsed with water and then oxidatively treated (fixed). For the oxidative aftertreatment, a fixing agent according to the invention containing at least one oxidizing agent or any fixing agent previously used for such a treatment can be used. Examples of oxidizing agents which can be used in such a fixing agent are sodium and potassium bromate, sodium perborate, urea peroxide and hydrogen peroxide. The concentration of the oxidizing agent can be from about 0.5 to 10% by weight, a fixing agent according to the invention preferably containing 0.05 to 5% by weight of the nanocomposite particles. Both the agent for permanent hair shaping according to the invention and the fixing agent according to the invention can be in the form of an aqueous solution or emulsion and in thickened form on an aqueous basis, in particular as a cream, gel or paste. It is also possible to fill this agent under pressure in aerosol cans and remove it as foam. The above-described process for permanent hair shaping enables a gentle and uniform shaping from the hairline to the hair tips, the hair shows excellent wet and dry combability, a pleasant handle and an appealing shine in the dried state, as well as a loose, erratic and even permanent wave, in particular in the area of the hair tips.

A further embodiment relates to a hair dye. Hair tints. It contains preferably 0.05 to 5% by weight of the nanocomposite particles and can both in the form of an oxidative as well as non-oxidative colorant based on the oxidative and / or substantive mentioned below Dyes are present. The total amount of the agent in the invention contained oxidation dye precursors is preferably about 0.01 to 12% by weight, in particular approximately 0.2 to 6% by weight. As suitable oxidation dye precursors can for example, the following developer substances and coupler substances and called self-coupling connections.

Developer:

1,4-diamino-benzene (p-phenylenediamine), 1,4-diamino-2-methylbenzene (p-toluenediamine), 1,4-diamino-2,6-dimethyl-benzene, 1,4-diamino-3,5-diethyl-benzene, 1,4-diamino-2,5-dimethylbenzene, 1,4-diamino-2,3-dimethyl-benzene, 2-chloro-1,4-diaminobenzene, 1,4-diamino-2- (thiophene-2-yl) benzene, 1,4-diamino-2- (thiophen-3-yl) benzene, 1,4-diamino-2- (pyridin-3-yl) benzene, 2,5-diaminobiphenyl, 1,4-diamino-2-methoxymethyl-benzene, 1,4-diamino-2-aminomethyl-benzene, 1,4-diamino-2-hydroxymethyl-benzene, 1,4-diamino-2- (2-hydroxyethoxy) benzene, 2- (2- (acetylamino) ethoxy) -1,4-diamino-benzene, 4-phenylamino-aniline, 4-dimethylamino-aniline, 4-diethylamino-aniline, 4-dipropylamino aniline, 4- [ethyl (2-hydroxyethyl) amino] aniline, 4- [di (2-hydroxyethyl) amino] aniline, 4- [di (2-hydroxyethyl) amino] -2-methyl-aniline, 4 - [(2-methoxyethyl) amino] aniline, 4 - [(3-hydroxypropyl) amino] aniline, 4 - [(2,3-dihydroxypropyl) amino] aniline, 1,4-diamino-2- (2-hydroxyethyl) benzene, 1,4-diamino-2- (1-methylethyl) benzene, 1,3-bis [(4-aminophenyl) (2-hydroxyethyl) amino] -2-propanol, 1,4-bis [(4-aminophenyl) amino] butane, 1,8-bis (2,5-diaminophenoxy) -3,6-dioxaoctane, 4-aminophenol, 4-amino-3-methylphenol, 4-amino-3- (hydroxymethyl) phenol, 4-amino-3-fluoro-phenol, 4-methylamino-phenol, 4-amino-2- (aminomethyl) phenol, 4-amino-2- (hydroxymethyl) phenol, 4-Amino-2-fluoro-phenol, 4-amino-2 - [(2-hydroxyethyl) amino] methylphenol, 4-amino-2-methylphenol, 4-amino-2- (methoxymethyl) phenol, 4-amino-2- (2-hydroxyethyl) phenol, 5-amino-salicylic acid, 2,5-diamino-pyridine, 2,4,5,6-tetraamino-pyrimidine, 2,5,6-triamino-4- (1H) -pyrimidone, 5-diamino-1- (2-hydroxyethyl) -1H-pyrazole, 4,5-diamino- 1- (1-methylethyl) -1H-pyrazole, 4,5-diamino-1 - [(4-methylphenyl) methyl] -1H-pyrazole, 1 - [(4-chloro-phenyl) methyl] -4,5-diamino-1H-pyrazol, 4,5-diamino-1-methyl-1H-pyrazol, 2-amino-phenol, 2-amino-6-methylphenol, 2-amino-5-methylphenol, 2,4-dihydroxyphenol

coupler:

N- (3-Dimethylaminophenyl) urea, 2,6-diamino-pyridine, 2-amino-4 - [(2-hydroxyethyl) amino] anisole, 2,4-diamino-1-fluoro-5-methyl -benzene, 2,4-diamino-1-methoxy-5-methyl-benzene, 2,4-diamino-1-ethoxy-5-methyl-benzene, 2,4-diamino-1- (2-hydroxyethoxy) -5 -methyl-benzene, 2,4-di [(2-hydroxyethyl) amino] -1,5-dimethoxy-benzene, 2,3-diamino-6-methoxy-pyridine, 3-amino-6-methoxy-2- ( methylamino) pyridine, 2,6-diamino-3,5-dimethoxy-pyridine, 3,5-diamino-2,6-dimethoxy-pyridine, 1,3-diamino-benzene, 2,4-diamino-1- ( 2-hydroxyethoxy) benzene, 1,3-diamino-4- (2,3-dihydroxypropoxy) benzene, 1,3-diamino-4- (3-hydroxypropoxy) benzene, 1,3-diamino-4- ( 2-methoxyethoxy) benzene, 2,4-diamino-1,5-di (2-hydroxyethoxy) benzene, 1- (2-aminoethoxy) -2,4-diamino-benzene, 2-amino-1- (2nd -hydroxyethoxy) -4-methylamino-benzene, 2,4-diaminophenoxy-acetic acid, 3- [di (2-hydroxyethyl) amino] aniline, 4-amino-2-di [(2-hydroxyethyl) amino] -1 -ethoxy-benzene, 5-methyl-2- (1-methylethyl) phenol, 3 - [(2-hydroxyethyl) amino] aniline, 3 - [(2-aminoethyl) amino] aniline, 1,3-di (2,4-diaminophenoxy) propane, di (2,4-diaminophenoxy) methane, 1,3-diamino-2,4-dimethoxy-benzene, 2,6-bis (2-hydroxyethyl ) amino-toluene, 4-hydroxyindole, 3-dimethylamino-phenol, 3-diethylamino-phenol, 5-amino-2-methyl-phenol, 5-amino-4-fluoro-2-methyl-phenol, 5-amino-4 -methoxy-2-methylphenol, 5-amino-4-ethoxy-2-methylphenol, 3-amino-2,4-dichlorophenol, 5-amino-2,4-dichlorophenol, 3-amino -2-methylphenol, 3-ami no-2-chloro-6-methylphenol, 3-aminophenol, 2 - [(3-hydroxyphenyl) amino] acetamide, 5 - [(2-hydroxyethyl) amino] -4-methoxy-2-methyl- phenol, 5 - [(2-hydroxyethyl) amino] -2-methylphenol, 3 - [(2-hydroxyethyl) amino] phenol, 3 - [(2-methoxyethyl) amino] phenol, 5-amino- 2-ethylphenol, 5-amino-2-methoxyphenol, 2- (4-amino-2-hydroxyphenoxy) ethanol, 5 - [(3-hydroxypropyl) amino] -2-methylphenol, 3- [ (2,3-dihydroxypropyl) amino] -2-methylphenol, 3 - [(2-hydroxyethyl) amino] -2-methylphenol, 2-amino-3-hydroxy-pyridine, 2,6-dihydroy-3 , 4-dimethylpyridine, 5-amino-4-chloro-2-methylphenol, 1-naphthol, 2-methyl-1-naphthol, 1,5-dihydroxy-naphthalene, 1,7-dihydroxy-naphthalene, 2,3 -Dihydroxy-naphthalene, 2,7-dihydroxy-naphthalene, 2-methyl-1-naphthol acetate, 1,3-dihydroxy-benzene, 1-chloro-2,4-dihydroxy-benzene, 2-chloro-1,3 -dihydroxy-benzene, 1,2-dichloro-3,5-dihydroxy-4-methyl-benzene, 1,5-dichloro-2,4-dihydroxy-benzene, 1,3-dihydroxy-2-methyl-benzene, 3 , 4-methylenedioxy-phenol, 3,4-methylenedioxy-aniline, 5 - [(2-hydroxyethyl) amino] -1.3 -benzodioxol, 6-bromo-1-hydroxy-3,4-methylenedioxy-benzene, 3,4-diamino-benzoic acid, 3,4-dihydro-6-hydroxy-1,4 (2H) -benzoxazine, 6-amino- 3,4-dihydro-1,4 (2H) -benzoxazine, 3-methyl-1-phenyl-5-pyrazolone, 5,6-dihydroxy-indole, 5,6-dihydroxy-indoline, 5-hydroxy-indole, 6 -Hydroxy-indole, 7-hydroxy-indole, 2,3-indolinedione.

The The total amount of direct dyes in the agent according to the invention about 0.01 to 7% by weight, preferably about 0.2 to 4% by weight. Geignete direct dyes are e.g. Triphenylmethane dyes, aromatic Nitro dyes, azo dyes, quinone dyes, cationic or anionic dyes, especially:

Nitro dyes (blue)

1,4-bis [(2-hydroxyethyl) amino] -2-nitrobenzene, 1- (2-hydroxyethyl) amino-2-nitro-4- [di (2-hydroxyethyl) amino] benzene (HC Blue No. 2), 1-amino-3-methyl-4 - [(2-hydroxyethyl) amino] -6-nitrobenzene (HC Violet No. 1), 4- [ethyl- (2-hydroxyethyl) amino] -1 - [(2-hydroxyethyl) amino] -2-nitrobenzene hydrochloride (HC Blue No. 12), 4- [di (2-hydroxyethyl) amino] -1 - [(2-methoxyethyl) amino] -2-nitrobenzene (HC Blue No. 11), 1 - [(2,3-dihydroxypropyl) amino] -4- [methyl- (2-hydroxyethyl amino] -2-nitrobenzene (HC Blue No. 10), 1 - [(2,3-dihydroxypropyl) amino] -4- [ethyl- (2-hydroxyethyl) amino] -2-nitrobenzene hydrochloride (HC Blue No. 9), 1- (3-hydroxypropylamino) -4- [di (2-hydroxyethyl) amino] -2-nitrobenzene (HC Violet No. 2), 1-methylamino-4- [methyl- (2,3-dihydroxypropyl) amino] -2-nitrobenzene (HC Blue No. 6), 2 - ((4-amino-2-nitrophenyl) amino) -5-dimethylamino-benzoic acid (HC Blue No. 13), 1- (2-aminoethylamino) -4- [di (2-hydroxyethyl) amino] -2-nitrobenzene, 4- (di (2-hydroxyethyl) amino) -2-nitro-1-phenylamino-benzene.

Nitro dyes (red):

1-amino-4 - [(2-hydroxyethyl) amino] -2-nitrobenzene (HC Red No. 7), 2-amino-4,6-dinitro-phenol, 1,4-diamino-2-nitrobenzene (CI76070), 4-amino-2-nitro-diphenylamine (HC Red No. 1), 1-amino-4- [di (2-hydroxyethyl) amino] -2-nitrobenzene hydrochloride (HC Red No. 13), 1-amino-5-chloro-4 - [(2-hydroxyethyl) amino] -2-nitrobenzene, 4-amino-1 - [(2-hydroxyethyl) amino] -2-nitro- benzene (HC Red No. 3), 4 - ((2-hydroxyethyl) methylamino) -1- (methylamino) -2-nitrobenzene, 1-amino-4 - ((2,3-dihydroxypropyl) amino) -5-methyl-2-nitrobenzene, 1-amino-4- (methylamino) -2-nitrobenzene, 4-amino-2-vitro-1 - ((prop-2-en-1-yl) -amino) -benzene, 4-amino-3-nitrophenol, 4 - [(2-hydroxyethyl) amino] -3-nitrophenol, 4 - [(2-nitrophenyl) amino] phenol (HC Orange No. 1), 1 - [(2-aminoethyl) amino] -4- (2-hydroxyethoxy) -2-nitrobenzene (HC Orange No. 2), 4- (2,3-Dihydroxypropoxy) -1 - [(2-hydroxyethyl) amino] -2-nitrobenzene (HC Orange No. 3), 1-amino-5-chloro-4 - [(2,3-dihydroxypropyl) amino] -2-nitrobenzene (HC Red No. 10), 5-chloro-1,4- [di (2,3-dihydroxypropyl) amino] -2-nitrobenzene (HC Red No. 11), 2 - [(2-hydroxyethyl) amino] -4,6-dinitro-phenol, 4-ethylamino-3-nitrobenzoic acid, 2 - [(4-amino-2-nitrophenyl) amino] - benzoic acid, 2-chloro-6-ethylamino-4-nitrophenol, 2-amino-6-chloro-4-nitrophenol, 4 - [(3-hydroxypropyl) amino] -3-nitrophenol, 2,5-diamino-6-nitropyridine, 6-amino-3 - ((2-hydroxyethyl) amino) -2-nitropyridine, 3-amino-6 - ((2-hydroxyethyl) amino) -2-nitropyridine, 3-amino-6- (ethylamino) -2-nitropyridine, 3 - ((2-hydroxyethyl) amino) -6- (methylamino) -2-nitropyridine, 3-Amino-6- (methylamino) -2-nitropyridine, 6- (ethylamino) -3 - ((2-hydroxyethyl) amino) -2-nitropyridine, 1,2,3,4-tetrahydro-6-nitroquinoxaline, 7-amino-3,4-dihydro-6-nitro-2H-1,4-benzoxazine (HC Red No. 14).

Nitro dyes (yellow):

1,2-diamino-4-nitrobenzene (CI76020), 1-amino-2 - [(2-hydroxyethyl) amino] -5-nitrobenzene (HC Yellow No. 5), 1- (2-hydroxyethoxy) -2- [ (2-hydroxyethyl) amino] -5-nitrobenzene (HC Yellow No. 4), 1 - [(2-hydroxyethyl) amino] -2-nitrobenzene (HC Yellow No. 2), 2- (di (2-hydroxyethyl) amino) -5-nitrophenol, 2 - [(2-hydroxyethyl) amino] -1-methoxy-5-nitrobenzene, 2-amino-3-nitrophenol, 1-amino-2-methyl-6-nitrobenzene, 1- (2nd -Hydroxyethoxy) -3-methylamino-4-nitrobenzene, 2,3- (dihydroxypropoxy) -3-methylamino-4-nitrobenzene, 2 - [(2-hydroxyethyl) amino] -5-nitrophenol (HC Yellow No. 11), 3 - [(2-aminoethyl) amino] -1-methoxy-4-nitrobenzene hydrochloride (HC Yellow No.9), 1 - [(2-ureidoethyl) amino] -4-nitrobenzene, 4 - [(2,3-dihydroxypropyl) amino] -3-vitro-1-trifluoromethyl-benzene (HC Yellow No 6), 1-chloro-2,4-bis [(2-hydroxyethyl) amino] -5-nitrobenzene (HC Yellow No. 10), 1-amino-4 - ((2-aminoethyl) amino) -5- methyl-2-nitrobenzene, 4 - [(2-hydroxyethyl) amino] -3-vitro-1-methylbenzene, 1-chloro-4 - [(2-hydroxyethyl) amino] -3-nitrobenzene (HC Yellow No. 12), 4 - [(2-hydroxyethyl) amino] -3-nitro-1-trifluoromethyl-benzene (HC Yellow No. 13), 4 - [(2-hydroxyethyl) amino] -3-nitro-benzonitrile (HC Yellow No. 14), 4 - [(2-Hydroxyethyl) amino] -3-nitro-benzamide (HC Yellow No. 15) 3 - ((2-Hydroxyethyl) amino) -4-methyl-1-nitrobenzene, 4- chloro-3 - ((2-hydroxyethyl) amino) -1-nitrobenzene.

Quinone dyes:

1,4-di [(2,3-dihydroxypropyl) amino] -9,10-anthraquinone, 1,4-di [(2-hydroxyethyl) amino] -9,10-anthraquinone (CI61545, Disperse Blue 23), 1 - [(2-hydroxyethyl) amino] -4-methylamino-9,10-anthraquinone (CI61505, Disperse Blue No. 3), 2 - [(2-aminoethyl) amino] -9,10-anthraquinone (HC Orange No. 5), 1-amino-4-hydroxy-9,10-anthraquinone (CI60710, Disperse Red 15), 1-hydroxy-4 - [(4-methyl-2-sulfophenyl) amino] -9,10-anthraquinone, 7-beta-D-glucopyranosyl-9,10-dihydro-1-methyl -9,10-dioxo-3,5,6,8-tetrahydroxy-2-anthracenecarboxylic acid (CI75470, Natural Red 4), 1 - [(3-aminopropyl) amino] -4-methylamino-9,10-anthraquinone (HC Blue No. 8), 1 - [(3-aminopropyl) amino] -9,10-anthraquinone (HC Red No. 8), 1,4-diamino-2-methoxy-9,10-anthraquinone (CI62015, Disperse Red No. 11, Solvent Violet No. 26), 1,4-Dihydroxy-5,8-bis [(2-hydroxyethyl) amino] -9,10-anthraquinone (CI62500, Disperse Blue No. 7, Solvent Blue No. 69), 1,4-diamino-9,10-anthraquinone (CI61100, Disperse Violet No. 1), 1-amino-4- (methylamino) -9,10-anthraquinone (CI61105, Disperse Violet No. 4, Solvent Violet No. 12), 2-hydroxy-3-methoxy-1,4-naphthoquinone, 2,5-dihydroxy-1,4-naphthoquinone, 2-Hydroxy-3-methyl-1,4-naphthoquinone, N- (6 - ((3-chloro-4- (methylamino) phenyl) imino) -4-methyl-3-oxo-1,4-cyclohexadiene-1 yl) urea (HC Red No. 9), 2 - ((4- (di (2-hydroxyethyl) amino) phenyl) amino) -5 - ((2-hydroxyethyl) amino) -2,5-cyclohexadiene-1,4-dione (HC Green No. 1), 5-hydroxy-1,4-naphthoquinone (CI75500, Natural Brown No. 7), 2-Hydroxy-1,4-naphthoquinone (CI75480, Natural Orange No. 6), 1,2-dihydro-2- (1,3-dihydro-3-oxo-2H-indol-2-ylidene) -3H-indol-3-one (CI73000), 4 - ((5 - (( 2-hydroxyethyl) amino-1-methyl-1H-pyrazol-4-yl) imino) -4,5-dihydro-5 - ((2-hydroxyethyl) imino) -1-methyl-1H-pyrazole sulphate (1 : 1) hydrate (1: 1).

Basic dyes:

9- (dimethylamino) benzo [a] phenoxazin-7-ium chloride (CI51175; Basic Blue No. 6), Di [4- (diethylamino) phenyl] [4- (ethylamino) naphthyl] carbenium chloride (CI42595; Basic Blue No. 7), di- (4- (dimethylamino) phenyl) - (4- (methyl-phenylamino) naphthalin-1-yl) carbenium chloride (CI42563; Basic Blue No. 8), 3,7-di (dimethylamino) phenothiazin-5-ium chloride (CI52015; Basic Blue No. 9), Di [4- (dimethylamino) phenyl] [4- (phenylamino) naphthyl] carbenium chloride (CI44045; Basic Blue No. 26), 2 - [(4- (ethyl (2-hydroxyethyl) amino) phenyl) azo] -6-methoxy-3-methylbenzothiazolium methyl sulfate (CI11154; Basic Blue No. 41), 8-amino-2-bromo-5-hydroxy-4-imino-6 - [(3- (trimethylammonio) phenyl) amino] -1 (4H) -naphthalenone chloride (CI56059; Basic Blue No. 99), bis [4- (dimethylamino) phenyl] - (4- (methylamino) phenyl] carbenium chloride (CI42535; Basic Violet No. 1), tri (4-amino-3-methylphenyl) carbenium chloride (CI42520; Basic Violet No. 2), tris [4- (dimethylamino) phenyl] carbenium chloride (CI42555; Basic Violet No. 3), 2- [3,6- (diethylamino) dibenzopyranium-9-yl] benzoic acid chloride (CI45170; Basic Violet No. 10), di (4-aminophenyl) (4-amino-3-methylphenyl) carbenium chloride (CI42510; Basic Violet No. 14), 1,3-bis [(2,4-diamino-5-methylphenyl) azo] -3-methylbenzene (CI21010; Basic Brown No. 4), 1 - [(4-aminophenyl) azo] -7- (trimethylammonio) -2-naphthol chloride (CI12250; Basic Brown No. 16), 3 - [(4-Amino-2,5-dimethoxyphenyl) azo] -N, N, N-trimethylbenzolaminium chloride (CI112605, Basic Orange No. 69), 1 - [(4-amino-2-nitrophenyl) azo] -7- (trimethylammonio) -2-naphthol chloride, 1 - [(4-amino-3-nitrophenyl) azo] -7- (trimethylammonio) -2-naphthol chloride (CI12251; Basic Brown No. 17), 3,7-diamino-2,8-dimethyl-5-phenylphenazinium chloride (CI50240; Basic Red No. 2), 1,4-dimethyl-5 - [(4- (dimethylamino) phenyl) azo] -1,2,4-triazolium chloride (CI11055; Basic Red No. 22), 2-Hydroxy-1 - [(2-methoxyphenyl) azo] -7- (trimethylammonio) naphthalene chloride (CI12245; Basic Red No. 76), 2- [2 - ((2,4-Dimethoxyphenyl) amino) ethenyl] -1,3,3-trimethyl-3H-indole-1-ium chloride (CI48055; Basic Yellow No. 11), 3-methyl-1-phenyl-4 - [(3- (trimethylammonio) phenyl) azo] pyrazole-5-one chloride (CI12719; Basic Yellow No. 57), Di [4- (dimethylamino) phenyl] iminomethane hydrochloride (CI41000; Basic Yellow No. 2), bis [4- (diethylamino) phenyl] phenylcarbenium hydrogen sulfate (1: 1) (CI42040; Basic Green No. 1), di (4- (dimethylamino) phenyl) phenylmethanol (CI42000; Basic Green No. 4), 1- (2-morpholiniumpropylamino) -4-hydroxy-9,10-anthraquinone methyl sulfate, 1 - [(3- (dimethylpropylaminium) propyl) amino] -4- (methylamino) -9.10- anthrachinonchlorid.

Neutral azo dyes:

1- [di (.2-hydroxyethyl) amino] -3-methyl-4 - [(4-nitrophenyl) azo] benzene (CI11210, Disperse Red No. 17), 1- [Di (2-hydroxyethyl) amino] -4 - [(4-nitrophenyl) azo] benzene (Disperse Black No. 9), 4 - [(4-aminophenyl) azo] -1- [di (2- hydroxyethyl) amino] -3-methylbenzene (HC Yellow No. 7), 2,6-diamino-3 - [(pyridin-3-yl) azo] pyridine, 2 - ((4- (acetylamino) phenyl) azo) -4-methylphenol (CI11855; Disperse Yellow No. 3).

Acid dyes:

6-hydroxy-5 - [(4-sulfophenyl) azo] -2-naphthalinsulfonsäuredinatriumsalz (CI15985; Food Yellow No. 3; FD&C Yellow No. 6), 2,4-Dinitro-1-naphthol-7-sulfonic acid disodium salt (CI10316; Acid Yellow No. 1; Food Yellow No. 1), 2- (Indan-1,3-dion-2-yl) quinolin-x, x-sulfonic acid (mixture from mono- and disulfonic acid) (CI47005; D&C Yellow No. 10; Food Yellow No. 13; Acid Yellow No. 3), 5-Hydroxy-1- (4-sulfophenyl) -4 - [(4-sulfophenyl) azo] pyrazole-3-carboxylic acid, trisodium salt (CI19140; Food Yellow No. 4; Acid Yellow No. 23), 9- (2-carboxyphenyl) -6-hydroxy-3H-xanthen-3-one (CI45350; Acid Yellow No. 73; D&C Yellow No. 8), 4 - ((4-Amino-3-sulfophenyl) azo) benzenesulfonic acid disodium salt (CI13015, Acid Yellow No. 9), 5 - [(2,4-dinitrophenyl) amino] -2-phenylamino-benzenesulfonic acid sodium salt (CI10385; Acid Orange No. 3), 4 - [(2,4-Dihydroxyphenyl) azo] benzenesulfonic acid monosodium salt (CI14270; Acid Orange No. 6), 4 - [(2-hydroxynaphth-1-yl) azo] benzenesulfonic acid sodium salt (CI15510; Acid Orange No. 7), 4 - [(2,4-Dihydroxy-3 - [(2,4-dimethylphenyl) azo] phenyl) azo] benzenesulfonic acid sodium salt (CI20170; Acid Orange No. 24), 4-Hydroxy-3 - [(4-sulfonaphth-1-yl) azo] -1-naphthalenesulfonic acid disodium salt (CI14720; Acid Red No. 14), 4-hydroxy-3 - [(2-methoxyphenyl) azo] -1-naphthalenesulfonic acid monosodium salt (CI14710; Acid Red No. 4), 6-Hydroxy-5- [i4-sulfonaphth-1-yl) azo] -2,4-naphthalene-disulfonic acid trisodium salt (CI16255; Ponceau 4R; Acid Red No. 18), 3-Hydroxy-4 - [(4-sulfonaphth-1-yl) azo] -2,7-naphthalenedisulfonic acid trisodium salt (CI16185; Acid Red No. 27), 8-amino-1-hydroxy-2- (phenylazo) -3,6-naphthalene disulfonic acid disodium salt (CI17200; Acid Red No. 33), 5- (acetylamino) -4-hydroxy-3 - [(2-methylphenyl) azo] -2,7-naphthalenedisulfonic acid disodium salt (CI18065; Acid Red No. 35), 2- (3-Hydroxy-2,4,5,7-tetraiododibenzopyran-6-one-9-yl) benzoic acid disodium salt (CI45430; Acid Red No. 51), N- [6- (diethylamino) -9- (2,4-disulfophenyl) -3H-xanthen-3-ylidene] -N-ethylethanammonium hydroxide, inner salt, sodium salt (CI45100; Acid Red No. 52), 8 - [(4- (phenylazo) phenyl) azo] -7-naphthol-1,3-disulfonic acid disodium salt (CI27290; Acid Red No. 73), 2 ', 4', 5 ', 7'-tetrabromo-3', 6'-dihydroxyspiro [isobenzofuran-1 (, 3H), 9 '- [9H] xanthene] -3 -one disodium salt (CI45380; Acid Red No. 87), 2 ', 4', 5 ', 7'-tetrabromo-4,5,6,7-tetrachlor-3', 6'-dihydroxyspiro [isobenzofuran-1 (3H), 9 '[9H] xanthene] -3-one disodium salt (CI45410; Acid Red No. 92), 3 ', 6'-dihydroxy-4', 5'-diiodospiro [isobenzofuran-1 (3H), 9 '- (9H) -xanthene] -3-one disodium salt (CI45425 ; Acid Red No. 95), 2-Hydroxy-3 - ((2-hydroxynaphth-1-yl) azo) -5-nitrobenzenesulfonic acid monosodium salt (CI15685; Acid Red No. 184), (2-sulfophenyl) di [4- (ethyl ((4-sulfophenyl) methyl) amino) phenyl] carbenium disodium salt Betaine (CI42090; Acid Blue No. 9; FD&C Blue No. 1), 1,4-bis [(2-sulfo-4-methylphenyl) amino] -9,10-anthraquinone disodium salt (CI 61570; Acid Green No. 25), bis [4- (dimethylamino) phenyl] -f3,7-disulfo-2-hydroxynaphth-1-yl) carbenium interior Salt monosodium salt (CI44090; Food Green No. 4; Acid Green No. 50), bis [4- (diethylamino) phenyl] (2,4-disulfophenyl) carbenium interior salt, sodium salt (2: 1) (CI42045; Food Blue No. 3; Acid Blue No. 1), Bis [4- (diethylamino) phenyl] (5-hydroxy-2,4-disulfophenyl) carbenium inside salt, calcium salt (2: 1) (CI42051; Acid Blue No. 3), 1-amino-4- (cyclohexylamino) -9,10-anthraquinone-2-sulfonic acid sodium salt (CI62045; Acid Blue No. 62), 1-amino-4- (phenylamino) -9,10-anthraquinone-2-sulfonic acid (CI62055; Acid Blue No. 25), 2- (1,3-Dihydro-3-oxo-5-sulfo-2H-indol-2-ylidene) -2,3-dihydro-3-oxo-1H-indole-5-sulfonic acid disodium salt (CI73015 ; Acid Blue No. 74), 9- (2-Carboxyphenyl) -3 - [(2-methylphenyl) amino] -6 - [(2-methyl-4-sulfophenyl) amino] xanthylium interior Salt, monosodium salt (CI45190; Acid Violet No. 9), 1-hydroxy-4 - [(4-methyl-2-sulfophenyl) amino] -9,10-anthraquinone sodium salt (CI60730; D&C Violet No. 2; Acid Violet No. 43), bis [3-nitro-4 - [(4-phenylamino) -3-sulfophenylamino] phenyl] sulfone (CI10410; Acid Brown No. 13), 5-amino-4-hydroxy-6 - [(4-nitrophenyl) -azo] -3- (phenylazo) -2,7-naphthalenedisulfonic acid disodium salt (CI20470; Acid Black No. 1), 3-hydroxy-4 - [(2-hydroxynaphth-1-yl) azo] -7-nitro-1-naphthalene-sulfonic acid-chromium complex (3: 2) (CI15711; Acid Black No. 52), 3 - [(2,4-Dimethyl-5-sulfophenyl) azo] -4-hydroxy-1-naphthalenesulfonic acid disodium salt (CI14700; Food Red No. 1; Ponceau SX; FD&C Red No. 4), 4- (acetylamino) -5-hydroxy-6 - [(7-sulfo-4 - [(4-sulfophenyl) azo] naphth-1 yl) azo] -1,7-naphthalene disulfonic acid tetrasodium salt (CI28440; Food Black No. 1), 3-hydroxy-4- (3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylazo) -naphthalene-1-sulfonic acid- sodium salt, chromium complex (Acid Red No. 195).

Further for hair coloring known and usual Dyes that can be contained in the colorant according to the invention are among others in E. Sagarin, "Cosmetics, Science and Technology ", Interscience Publishers Inc., New York (1957), pages 503 ff. And H. Janistyn, "Handbook of cosmetics and fragrances ", volume 3 (1973), pages 388 ff. And K.

Schrader "Basics and Recipes the cosmetics ", 2nd edition (1989), pages 782-815 described.

For the application for oxidative coloring a colorant according to the invention is mixed immediately before use with an oxidizer composition and carries one for the coloring sufficient amount of the ready-to-use preparation on the hair on. If the colorant according to the invention contains no oxidation dye precursors or such oxidation dye precursors contains which are easily oxidized with atmospheric oxygen, it can be done without prior Mix directly with an oxidizing agent on the keratin fiber be applied. As the oxidizing agent composition, a according to the invention, at least a composition containing an oxidizing agent and nanocomposite particles or any so far for such a treatment used composition, wherein a fixative according to the invention preferably contains 0.05 to 5% by weight of the nanocomposite particles. As Oxidizing agents to develop the color come mainly from hydrogen peroxide or its addition compounds to urea, melamine or sodium borate in the form of a 1 to 12%, preferably a 1.5 to 6% aqueous solution into consideration. The mixing ratio of colorant depends on oxidizing agent of the concentration of the oxidizing agent and is in the Rule about 5: 1 to 1: 2, preferably 1: 1, with the oxidizing agent content in the ready-to-use preparation, preferably about 0.5 to 8 % By weight, in particular 1 to 4% by weight.

The agents according to the invention can about it further, for Hair treatment products usual Contain additional components, e.g. Perfume oils; Opacifiers such as ethylene glycol, Styrene / PVP copolymers or polystyrenes; Humectants; Luster-imparting agents; Produktanfärbestoffe; antioxidants; in amounts of preferably 0.01 to 10% by weight, the total amount preferably not exceeding 10% by weight.

The agents according to the invention can be in any for Hair treatment agent suitable preparation form, for example in the form of a solution, an emulsion, a dispersion, a cream or a gel. The agent can also be mixed with a propellant gas or by means of a mechanically operated spraying device sprayed or foamed become. The agent according to the invention is preferred in an aqueous, an alcoholic or in an aqueous-alcoholic medium made up with preferably at least 10% by weight of water. As Alcohols can especially those for cosmetic purposes usually used lower alcohols with 1 to 4 carbon atoms, e.g. ethanol and isopropanol may be included. The agent according to the invention can be in a pH range of 2.0 to 9.5. Particularly preferred is the pH range between 4 and 8, unless special forms of application require different pH values. As additional co-solvents, organic solvent or a mixture of solvents with a boiling point below 400 ° C in an amount of 0.1 to 15% by weight, preferably 1 to 10% by weight be included. Are particularly suitable as additional co-solvents unbranched or branched hydrocarbons such as pentane, hexane, Isopentane and cyclic hydrocarbons such as cyclopentane and cyclohexane. Other particularly preferred water-soluble solvents are glycerol, Ethylene glycol and propylene glycol in an amount up to 30% by weight.

The agents according to the invention can be used in various forms of application, e.g. in the form of hair care, hair fixation, hair cleaning, hair coloring or Tints, as a bleaching agent or as a permanent waving agent. The remedy can be used as Lotion, aerosol foam, non-aerosol foam, hair milk, hair gel, liquid gel, spray gel, Hair cream, gel foam, aerosol or non-aerosol spray, hair wax or in the form of an emulsion Hair care products (hair conditioner, Conditioner) can be applied. The remedy can also be used as a shampoo in combination with preferably anionic, amphoteric and nonionic Surfactants or as colorants in combination with direct or oxidative hair colors, e.g. are present as a color fixer.

In one embodiment, the agent according to the invention is in the form of a gel, in the form of a viscous lotion or in the form of a spray gel which is sprayed with a mechanical device and contains at least one of the above-mentioned thickening polymers in an amount of preferably 0.05 to 10, particularly preferably from 0.1 to 2% by weight and has a viscosity of at least 250 mPa s (measured using a Bohlin rheometer CS, measuring body C25 at 25 ° C. and a shear rate of 50 s ⁻¹ ). The viscosity of the gel is preferably from 500 to 50,000 mPa s, particularly preferably from 1,000 to 15,000 mPa s at 25 ° C.

In one embodiment is the agent according to the invention in the form of an O / W emulsion, a W / O emulsion or a microemulsion before and contains at least one of the abovementioned oils emulsified in water or Waxes and at least one of the surfactants mentioned above.

In one embodiment, the agent according to the invention is in the form of a spray product, either in combination with a mechanical pump spray device or in combination with at least one egg A blowing agent selected from propane, butane, dimethyl ether and fluorinated hydrocarbons. An aerosol spray additionally preferably contains 15 to 85% by weight, particularly preferably 25 to 75% by weight, of a propellant and is filled in a pressure container. As blowing agents are, for example, lower alkanes, such as n-butane, i-butane and propane, or also their mixtures, and also dimethyl ether or fluorocarbons such as F 152a (1,1-difluoroethane) or F 134 (tetrafluoroethane) and also those which come into consideration Pressures of gaseous blowing agents, such as N ₂ , N ₂ O and CO _2, as well as mixtures of the blowing agents mentioned above, are suitable.

On Non-aerosol hair sprays are made using a suitable mechanical operated spraying device sprayed. Under mechanical spray devices are to be understood as devices that spray a Allow composition without using a blowing agent. As a suitable mechanical spray device can, for example, a spray pump or one with a spray valve provided elastic container, in which the cosmetic according to the invention Bottled agent under pressure is, the elastic container expands and from which the Means due to the contraction of the elastic container when opening the spray valve continuously released, can be used.

In one embodiment is the agent according to the invention in the form of a foamable Product (mousse) in combination with a device for foaming, contains at least one common, known for this foaming substance, e.g. at least one foam-forming surfactant or at least one foam-forming polymer. Under fixtures for foaming are to be understood as devices that prevent foaming liquid enable with or without the use of a propellant. As a suitable mechanical frothing can, for example, a commercially available foam pump or an aerosol foam head can be used. The product lies either in combination with a mechanical pump foam device (pump foam) or in combination with at least one propellant (aerosol foam) in an amount of preferably 1 to 20, in particular 2 to 10% by weight. Blowing agents are e.g. selected from propane, butane, dimethyl ether and fluorinated hydrocarbons. The remedy becomes immediate foamed before use and worked into the hair as a foam and can then be rinsed out or without rinsing to be left in the hair.

In one embodiment is the agent according to the invention in the form of a hair wax, i.e. it has waxy consistency on and contains at least one of the above waxes in an amount of preferably 0.5 to 30% by weight and optionally other water-insoluble substances. The waxy consistency is preferably characterized by that the needle penetration number (unit of measurement 0.1 mm, test weight 100 g, test duration 5 s, test temperature 25 ° C; to DIN 51 579) larger or is equal to 10, particularly preferably greater than or equal to 20 and that the solidification point of the product is preferably greater than or equal to 30 ° C and less than or equal to 70 ° C is, particularly preferably in the range from 40 to 55 ° C. Suitable waxes and water-insoluble Substances are especially emulsifiers with an HLB value below of 7, silicone oils, Silicone waxes, waxes (e.g. wax alcohols, wax acids, wax esters, as well as especially natural ones Waxes such as beeswax, carnauba wax, etc.), fatty alcohols, fatty acids, fatty acid esters or hydrophilic waxes such as high molecular weight polyethylene glycols with a molecular weight of 800 to 20,000, preferably of 2,000 to 10,000 g / mol.

If the hair treatment composition according to the invention is in the form of a hair lotion, it is considered essentially non-viscous or slightly viscous, flowable solution, dispersion or emulsion containing at least 10% by weight, preferably 20 to 95 % By weight of a cosmetically acceptable Alcohol. As alcohols can especially those for cosmetic purposes usually used lower alcohols with 1 to 4 carbon atoms, e.g. ethanol and isopropanol can be used.

If the hair treatment composition according to the invention is in the form of a hair cream, it is preferably an emulsion before and contains either additionally viscosity-imparting Ingredients in an amount of 0.1 to 10 wt.% Or the required viscosity and creamy consistency is obtained by micelle formation with the help of suitable Emulsifiers, fatty acids, Fatty alcohols, waxes etc. in the usual way Built up way.

wobei R2 eine gerad- oder verzweigtkettige Alkyl-, Alkenyl- oder Hydroxyalkylgruppe mit 8 bis 18 C-Atomen und 0 bis 10 Ethylenoxideinheiten und 0 bis 1 Glycerineinheit darstellt; Y ein N-, P- oder S-Atom ist; R3 eine Alkyl- oder Monohydroxyalkylgruppe mit 1 bis 3 C-Atomen ist; x gleich 1 ist, falls Y ein Schwefelatom ist und x gleich 2 ist, wenn Y ein Stickstoff- oder Phosphoratom ist; R4 eine Alkylen- oder Hydroxyalkylengruppe mit 1 bis 4 C-Atomen ist und Z eine Carboxylat-, Sulfat-, Phosphonat- oder Phosphatgruppe darstellt.If the hair treatment composition according to the invention is in the form of a hair cleaning composition, it additionally contains at least one wash-active surfactant, preferably 0.01 to 25% by weight, in particular 5 to 20% by weight, of at least one anionic, amphoteric and / or non-ionic surfactant and 50 up to 90% by weight of water. The hair cleansing agent according to the invention has a pH of preferably 3 to 8, in particular 4 to 7. Suitable surfactants are, for example, those mentioned above. Preferred surfactants for a hair cleanser according to the invention are selected from alkali or alkaline earth metal salts of the C10 to C18 alkyl sulfates, the C10 to C18 alkyl sulfonates, the C10 to C18 alkylbenzenesulfonates, the C10 to C18 xylene sulfonates and the C10 to C18 alkyl ether sulfates ethoxylated with 1 to 10 ethylene oxide units; the ethoxylated sulfosuccinic acid half-esters of the general formula R ¹ (OCH ₂ CH ₂ ) _m -O _Z C-CH ₂ CH (SO ₃ M) -CO ₂ M, where R1 is a C10- to C18-alkyl radical, M is an alkali or alkaline earth metalation represents and m represents an integer from 1 to 10; the alkyl ether carboxylates of the formula R ² (OCH ₂ CH ₂ ) n-OCH ₂ COOM, where R2 is a C10 to C18 alkyl radical, M is an alkali or alkaline earth metal cation and n is an integer from 1 to 20; ethoxylated fatty alcohols with 12 to 18 carbon atoms; Polyglyceryl ethers of saturated or unsaturated fatty alcohols and alkylphenols with 8 to 30 carbon atoms in the alkyl radical and 1 to 10 glyceryl units in the molecule; fatty acid alkanolamides; ethoxylated sorbitan fatty acid esters, C8-C18 alkyl polyglucosides, C8 to C18 alkyl betaines and amphoteric surfactants of the formula

wherein R2 represents a straight or branched chain alkyl, alkenyl or hydroxyalkyl group with 8 to 18 carbon atoms and 0 to 10 ethylene oxide units and 0 to 1 glycerol unit; Y is an N, P or S atom; R3 is an alkyl or monohydroxyalkyl group with 1 to 3 C atoms; x is 1 if Y is a sulfur atom and x is 2 if Y is a nitrogen or phosphorus atom; R4 is an alkylene or hydroxyalkylene group with 1 to 4 carbon atoms and Z represents a carboxylate, sulfate, phosphonate or phosphate group.

object The invention is also a method for hair treatment, wherein

• - on hair treatment composition according to the invention provided,
• - the Hair treatment agent is applied to the hair and
• - the Hair treatment agents either after exposure to the hair rinsed or left in the hair.

Becomes the cosmetic according to the invention Hair care or fixative is used as follows: After shampooing are in the towel-dried hair, depending on the fullness, 5 to Spread 30 g of the agent. Then the hair is combed and shaped and dried for hairstyle.

The The following examples are intended to explain the subject matter of the invention in more detail.

The fluorescent nanocomposite particles mentioned in the examples below are iron (III) particles coated with polymethyl methacrylate, which can be produced using a microwave plasma process in accordance with DE 196 38 601 from vaporized FeCl ₃ to produce the core and methyl methacrylate to polymerize the shell. The particles are referred to as PMMA-Fe ₂ O ₃ . Quantities in grams, percentages mean percentages by weight, unless stated otherwise.

Example 1: Hair styling cream

Example 2: Hair styling foam

Claims (36)

Hair treatment products containing nanocomposite particles, in which - the Particles have a core, which consists of a connection of a Metal and a non-metal The particles have a shell, the selected is made of organic polymers and different from the core material Compounds of a metal and a nonmetal and - the particles have fluorescent properties. Agent according to claim 1, characterized in that the core of the particles consists of an oxide ceramic material. Agent according to one of the preceding claims, characterized characterized in that the core of the particles is at least one metal oxide contains selected from iron (III) oxide, aluminum oxide, hafnium oxide, zirconium oxide, zinc oxide. Agent according to one of the preceding claims, characterized characterized in that the polymer of the shell from ethylenically unsaturated, is built up by radically polymerizable monomers. Agent according to claim 4, characterized in that the radically polymerizable monomers are selected from acrylic acid, methacrylic acid, Acrylsäureestern, Metharylsäureestern, Acrylamides and methacrylamides. Agent according to claim 4 or 5, characterized in that the polymeric shell the particles have at least one organic fluorescent substance contains or consists of it. Agent according to claim 6, characterized in that the polymeric shell consists of polymers that fluoresce without further addition. Agent according to one of the preceding claims, characterized characterized in that the nanocomposite particles between the core and the outer shell a Have intermediate layer which have at least one organic fluorescent Contains fabric or consists of it. Means according to claim 8, characterized in that the intermediate layer made of fluorescent polyaromatic compounds consists. Agent according to one of the preceding claims, characterized characterized in that the nanocomposite particles in an amount of 0.01 to 20 wt.% Are contained in a cosmetically acceptable carrier medium. Agent according to one of the preceding claims, characterized characterized in that the average diameter of the nanoparticles in the Range from 3 to 100 nm and the thickness of the shell in the range from 1 to 20 nm lies. Agent according to one of the preceding claims, characterized characterized that the nanocomposite particles of light in the wavelength range from 200 to 400 nm and after excitation light in the wavelength range emit from 200 to 800 nm. Agent according to one of the preceding claims, characterized characterized in that the nanocomposite particles are produced by a plasma process. Agent according to one of the preceding claims, characterized characterized that it has a content of (A) fluorescent Nanocomposite particles and (B) at least one active ingredient or additive, selected from hair care substances, hair-setting substances, silicone compounds, Light stabilizers, oils, Grow, viscosity modifying Substances, preservatives, non-fluorescent pigments, direct hair dyes, non-fluorescent particulate substances, Surfactants, oxidizing agents, reducing agents and oxidation hair dye precursors. Agent according to claim 14, characterized in that the active ingredients and additives (B) in an amount of 0.01 to 20% by weight are included. Agent according to claim 14 or 15, characterized in that as a hair-care or hair-fixing substance, a polymer with anionic or anionizable groups is selected from Terpolymers of acrylic acid, Ethyl acrylate and N-tert-butyl acrylamide; networked or non-networked Vinyl acetate / crotonic acid copolymers; Terpolymers of tert-butyl acrylate, ethyl acrylate and methacrylic acid; sodium polystyrene sulfonate; Copolymers of vinyl acetate, crotonic acid and propionate; Copolymers of vinyl acetate, crotonic acid and neodecanoate; Aminomethylpropanol-acrylate copolymers; copolymers selected from vinyl pyrrolidone and at least one further monomer Acrylic acid, methacrylic acid, Acrylic acid esters and methacrylic acid esters; Copolymers of methyl vinyl ether and maleic acid monoalkyl esters; aminomethylpropanol salts of copolymers of allyl methacrylate and at least one other Monomer selected from acrylic acid, methacrylic acid, Acrylsäureestern and methacrylic acid esters; cross-linked copolymers of ethyl acrylate and methacrylic acid; copolymers from vinyl acetate, mono-n-butyl maleate and isobornyl acrylate; copolymers from two or more monomers selected from acrylic acid, methacrylic acid, acrylic acid esters and methacrylic esters, Copolymers of octylacrylamide and at least one monomer selected from Acrylic acid, methacrylic acid, Acrylsäureestern and methacrylic acid esters; Polyesters from diglycol, cyclohexanedimethanol, isophthalic acid and Sulfoisophthalic. Agent according to claim 14 or 15, characterized in that a polymer with cationic or cationizable groups is contained as hair care or hair-setting substance, selected from cationic cellulose derivatives of hydroxyethyl cellulose and diallyldimethyl ammonium chloride; cationic cellulose derivatives of hydroxyethyl cellulose and epoxy substituted with trimethylammonium; Poly (dimethyldiallylammonium chloride); Copolymers of acrylamide and dimethyldiallylammonium chloride; quaternary ammonium polymers formed by the reaction of diethyl sulfate and a copolymer of vinyl pyrrolidone and dimethylaminoethyl methacrylate; quaternary ammonium polymers of methyl vinyl imidazolium chloride and vinyl pyrrolidone; Polyquaternium-35; Trimethylammonium ethyl methacrylate chloride polymer; Polyquaternium-57; dimethylpolysiloxanes terminally substituted with quaternary ammonium groups; copolymer from vinyl pyrrolidone, dimethylaminopropyl methacrylamide and methacryloylaminopropyllauryldimethylammonium chloride; Chitosan and its salts; Hydroxyalkylchitosans and their salts; Alkyl-hydroxyalkylchitosans and their salts; N-Hydroxyalkylchitosanalkylether; Copolymer of vinyl caprolactam, vinyl pyrrolidone and dimethylaminoethyl methacrylate; Copolymers of vinyl pyrrolidone and dimethylaminoethyl methacrylate, copolymers of vinyl pyrrolidone, vinyl caprolactam and dimethylaminopropylacrylamide; Poly- or oligoesters, built up from at least one first type of monomer, which is selected from hydroxy acid substituted with at least one quaternary ammonium group. Agent according to claim 14 or 15, characterized in that as a hair care or hair-setting substance, a zwitterionic and / or an amphoteric polymer is selected from Copolymers of octylacrylamide, acrylic acid, butylaminoethyl methacrylate, methyl methacrylate and hydroxypropyl methacrylate; Copolymers of lauryl acrylate, stearyl acrylate, Ethylamine oxide methacrylate and at least one monomer selected from Acrylic acid, methacrylic acid, Acrylsäureestern and methacrylic acid esters; Copolymers of methacryloylethyl betaine and at least one monomer selected from methacrylic acid and methacrylic acid esters; Copolymers of acrylic acid, Methyl acrylate and methacrylamidopropyltrimethylammonium chloride; Oligomers or polymers that can be produced from quaternary croton betaines or quaternary Crotonbetainestern. Agent according to claim 14 or 15, characterized in that as a hair care or hair-setting substance is a non-ionic Polymer is selected from polyvinylpyrrolidone, polyvinylcaprolactam, vinylpyrrolidone / vinyl acetate Copolymers, polyvinyl alcohol, isobutylene / ethyl maleimide / hydroxyethyl maleimide copolymer; Copolymers of vinyl pyrrolidone, vinyl acetate and vinyl propionate. Agent according to claim 14 or 15, characterized in that the viscosity modifier Substance is a thickening polymer selected from copolymers of at least one a first type of monomer selected from acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of acrylic acid and ethoxylated fatty alcohol; cross-linked polyacrylic acid; networked Copolymers of at least one first type of monomer that is selected from acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of acrylic acid with C10 to C30 alcohols; Copolymers of at least one first Monomer type selected is made of acrylic acid and methacrylic acid and at least one second type of monomer selected from esters of itaconic acid and ethoxylated fatty alcohol; Copolymers of at least one first type of monomer selected is made of acrylic acid and methacrylic acid, at least one second type of monomer, which is selected from esters of itaconic acid and ethoxylated C10 to C30 alcohol and a third type of monomer, selected from C1 to C4 amino alkyl acrylates; copolymers from two or more monomers selected from acrylic acid, methacrylic acid, acrylic acid esters and methacrylic acid esters; Copolymers of vinyl pyrrolidone and ammonium acryloyldimethyl taurate; Copolymers of ammonium acryloyldimethyl taurate and monomers selected from Esters of methacrylic acid and ethoxylated fatty alcohols; hydroxyethyl cellulose; hydroxypropyl cellulose; hydroxypropyl; Glycerylpolyacrylat; glyceryl; Copolymers of at least one C2, C3 or C4 alkylene and styrene; polyurethanes; hydroxypropyl starch; polyacrylamide; copolymer of maleic anhydride crosslinked with decadiene and methyl vinyl ether; Locust bean gum; Guar gum; xanthan; Dehydroxanthan; carrageenan; Karaya gum; hydrolyzed corn starch; copolymers made of polyethylene oxide, fatty alcohols and saturated methylene diphenyl diisocyanate. Agent according to one of the preceding claims, characterized characterized that contain at least one silicone compound is selected from cyclic dimethylsiloxanes, linear polydimethylsiloxanes, block polymers from polydimethylsiloxane and polyethylene oxide and / or polypropylene oxide, Polydimethylsiloxanes with end or pendant Polyethylene oxide or polypropylene oxide residues, polydimethylsiloxanes with terminal Hydroxyl groups, phenyl-substituted polydimethylsiloxanes, silicone emulsions, Silicone elastomers, silicone waxes, silicone gums, amine-substituted Silicones and substituted with one or more quaternary ammonium groups Silicones. Agent according to one of the preceding claims, characterized marked that at least one light protection substance is contained, selected from 4-methoxy-cinnamic acid-2-ethylhexyl ester, Methyl methoxycinnamate, 2-hydroxy-4-methoxy-benzophenone-5-sulfonic acid and polyethoxylated p-aminobenzoates. Agent according to one of the preceding claims, characterized in that at least one oil or wax is contained, selected from paraffin waxes, polyolefin waxes, wool wax, wool wax alcohols, candelilla wax, olive wax, carnauba wax, Japanese wax, apple wax, hardened fats, fatty acid esters, fatty acid glycerides, fatty acid triglycerides, polyethylene glycol waxes, Silicone waxes, silicone oils, Mineral oils, isoparaffin oils, paraffin oils, squalane, sunflower oil, coconut oil, castor oil, lanolin oil, jojoba oil, corn oil, soybean oil. Agent according to one of the preceding claims, characterized characterized in that an active ingredient and additive (B) is contained, the selected is from betaine; panthenol; panthenyl; sorbitol; protein hydrolysates; Plant extracts; A-B block copolymers of alkyl acrylates and methacrylates; A-B block copolymers from alkyl methacrylates and acrylonitrile; A-B-A block copolymers of lactide and ethylene oxide; A-B-A block copolymers from caprolactone and ethylene oxide; A-B-C block copolymers of alkylene or Alkadiene compounds, styrene and alkyl methacrylates; A-B-C block copolymers of acrylic acid, styrene and alkyl methacrylates; stellate Block copolymers; hyperbranched polymers, dendrimers, intrinsic electrically conductive 3,4-polyethylene dioxythiophenes and intrinsically electrically conductive polyanilines. Agent according to one of the preceding claims, characterized characterized in that at least one surfactant is selected from Addition products of 2 to 30 mol ethylene oxide and / or 1 to 5 mol propylene oxide on C8 to C22 fatty alcohols, add-on products from 2 to 30 mol of ethylene oxide and / or 1 to 5 mol of propylene oxide C12 to C22 fatty acids, Addition products of 2 to 30 mol ethylene oxide and / or 1 to 5 mol of propylene oxide on alkylphenols with 8 to 15 carbon atoms in the Alkyl group, C12 to C22 fatty acid mono- and diesters of adducts of 1 to 30 moles of ethylene oxide on glycerol, adducts of 5 to 60 mol of ethylene oxide castor oil or hardened (hydrogenated) castor oil, Mono-, di- or triesters of phosphoric acid with addition products from 2 to 30 mol of ethylene oxide with C8 to C22 fatty alcohols, esters Sucrose and one or two C8 to C22 fatty acids, esters of sorbitan and one, two or three C8 to C22 fatty acids and a degree of ethoxylation from 4 to 20, polyglyceryl fatty acid esters from one, two or more C8 to C22 fatty acids and polyglycerol with 2 up to 20 glyceryl units, alkyl glycosides, C8-22-alkyldimethylbenzylammonium compounds, C8-22-alkyltrimethylammonium compounds, C8-22-alkyldimethylhydroxyethylammonium compounds, Di- (C8-22-alkyl) -dimethylammonium compounds, C8-22-alkylpyridinium salts, C8-22- alkylamidoethyltrimethylammonium ether sulfates, C8-22- alkylmethylamine oxides, C8-22-alkylaminoethyldimethylamine oxides, amidoamines and quaternized Amidoamines. Agent according to one of the preceding claims, characterized characterized in that at least one non-fluorescent pigment is selected from titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow Iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), Ultramarine (CI 77007), Chromium Oxide Hydrate (CI77289), Iron Blue (CI77510), bismuth oxychloride (CI77163), carmine (cochineal), pearlescent and color pigments based on micas which are coated with a metal oxide or a metal oxychloride such as titanium dioxide or bismuth oxychloride and optionally other coloring substances such as iron oxides, iron blue, Ultramarine or Carmine are coated and the color is through Variation of the layer thickness is determined. Agent according to one of the preceding claims, characterized characterized in that at least one non-fluorescent particulate is selected from silica, silicates, aluminates, clays, mica, insoluble Metal salts, metal oxides, minerals and different from component (A), insoluble Polymer particles. Agent according to one of claims 1 to 27, characterized in that it is in the form of a hair gel, in the form of a viscous hair lotion or in the form of a hair spray gel which is sprayed with a mechanical device, contains at least one thickening polymer according to claim 20 and one Viscosity of at least 250 mPa s (measured with a Bohlin Rheometer CS, measuring body C25 at 25 ° C and a shear rate of 50 s ^-1 ). Agent according to one of claims 1 to 27, characterized in that that it is in the form of an O / W emulsion, a W / O emulsion or a Microemulsion is present and at least one oil or wax according to claim 23 and at least one surfactant according to claim 25. Agent according to one of claims 1 to 27 in the form of a Hair sprays, characterized in that it is either in combination with a mechanical pump spray device or in combination with at least one blowing agent selected from Propane, butane, dimethyl ether and fluorinated hydrocarbons is present. Agent according to one of claims 1 to 27, characterized in that it is in the form of a foamable product in combination with a device for foaming, at least one foamable contains surfactant or at least one foam-forming polymer and is present either in combination with a mechanical pump foam device or in combination with at least one blowing agent selected from propane, butane, dimethyl ether and fluorinated hydrocarbons. Agent according to one of claims 1 to 27, characterized in that that it is in the form of a solid hair wax and at least contains one of the waxes mentioned in claim 23. Agent according to one of claims 1 to 27, characterized in that that it is in the form of a hair cleanser and 0.01 to 40% by weight of at least one anionic, amphoteric or non-ionic detergent Contains surfactants and 50 to 90 wt.% Water. Agent according to one of claims 1 to 27, characterized in that that it is a permanent set with an additional one Content of at least one keratin-reducing mercapto compound. Agent according to one of claims 1 to 27, characterized in that that it's a hair bleach, an oxidation hair dye or a permanent wave fixative is containing at least an oxidizing agent. Agent according to one of claims 1 to 27, characterized in that that it is a hair tint and at least one synthetic directly on the hair and / or natural Contains hair dye.