DE2007893B2 - METHOD FOR FORMING THE ELECTRODES OF LEAD ACCUMULATORS - Google Patents
METHOD FOR FORMING THE ELECTRODES OF LEAD ACCUMULATORSInfo
- Publication number
- DE2007893B2 DE2007893B2 DE19702007893 DE2007893A DE2007893B2 DE 2007893 B2 DE2007893 B2 DE 2007893B2 DE 19702007893 DE19702007893 DE 19702007893 DE 2007893 A DE2007893 A DE 2007893A DE 2007893 B2 DE2007893 B2 DE 2007893B2
- Authority
- DE
- Germany
- Prior art keywords
- electrodes
- lead
- gas
- forming
- current
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/14—Electrodes for lead-acid accumulators
- H01M4/16—Processes of manufacture
- H01M4/22—Forming of electrodes
- H01M4/23—Drying or preserving electrodes after forming
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/14—Electrodes for lead-acid accumulators
- H01M4/16—Processes of manufacture
- H01M4/22—Forming of electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Hybrid Cells (AREA)
- Connection Of Batteries Or Terminals (AREA)
Claims (3)
dieser Behandlung ist es, eine bestimmte Struktur bei io Die Erfindung stellt ein Verfahren dar, welches den genannten Bleiverbindungen aufzubauen. Die Be- verhindert, daß. Elektrolyt die Kontaktstelle erreicht handlung beeinflußt das Ergebnis des nachfolgenden und daß sich ein Elektrolytfilm bildet, der Kriech-Formierprozesses, welcher eine elektrochemische ströme ermöglicht. Ein besonderes Verfahren der ErUmwandlung der vorgenannten Verbindungen mit findung besteht darin, daß ein Luft- oder Gasstrom den Valenzen 0 und^2 in Bleiverbindungen, mit der 15 mit einer bestimmten Geschwindigkeit entlang der Valenz +4 in den positiven Elektroden und der Kontaktstelle zwischen Elektroden und Stromzu-Valenz 0 in den negativen Elektroden bedeutet. leitern während des Fonnierens vorbeiströmt.Lead accumulator electrodes are predominantly in direct contact with the grid in which there is a metal grid as a mass carrier made of lead is contained, the predominantly lead surface of the grid itself will be converted into lead oxide with the valences 0 and + 2. 5 transforms. The lead oxide that forms on the grid from the gas bubbles rising up after the active material enters the plate grid. Once it has been released, the electrodes are then subjected to a persistence between the positive and the negative action, which is to some extent of the tive electrode type, so-called leakage currents, which is dependent on the electrode in question. Purpose lead to formation of lead dioxide,
This treatment is to create a certain structure in the case of io. The invention represents a method for building up the lead compounds mentioned. The loading prevents that. The electrolyte reaches the contact point and affects the result of the subsequent action and the formation of an electrolyte film, the creep-forming process, which enables electrochemical currents. A special method of converting the aforementioned compounds with invention is that a stream of air or gas with valences 0 and ^ 2 in lead compounds, with 15 at a certain speed along valence +4 in the positive electrodes and the contact point between electrodes and Means current to valence 0 in the negative electrodes. ladders flow by while the building is being made.
liegen können. Dagegen ist es üblich, daß die posi- Durch das Verfahren gemäß der Erfindung erhält tiven Elektroden durch Schweißung an den positiven man einen weiteren formierungstechnischen Vorteil Stromleiter angeschlossen werden, damit der Kontakt in bezug auf das spätere Verschweißen mehrerer zwischen diesem und,, den Elektroden mit Sicherheit 50 Elektroden gleicher Polarität zu Plattensätzen,
während der ganzen Dauer des Formierens aufrecht- Die Kontaktstelle der Elektroden, die sogenannte erhalten werden kann. Bei den positiven Anschlüssen Stromfahne, ist vorzugsweise die Kontaktstelle bei der bildet sich nämlich Bleisulfat, welches nichtleitend ist Formierung. Auf Grund der vorher erwähnten Ver- und also allen Kontakt zunichte machen würde. Sulfat hältnisse war diese Stelle bei den bisher angewenbildet sich zum großen Teil dadurch^ daß Schwefel- 55 deten Formiermethoden nach dem Formieren mit säure beim Zerplatzen der Gasblasen, die sich beim einer Dioxydschicht überzogen, die mit einer Metall-Formieren bilden, hochgeschleudert wird. Eine we- bürste vor dem Verschweißen abgebürstet oder durch sentliche Vereinfachung beim Formieren dieser Elek- anderweitiges Abkratzen entfernt werden mußte. Da troden würde man erzielen können, wenn man diese bei dem Verfahren gemäß der Erfindung keine Oxy-Schweißung vermeiden könnte. 60 dation der Kontaktstelle stattfindet, erspart man sichA common process used in shaping a shaping vessel. In the cover there are channels for tive and negative electrodes, so that air or gas is attached directly, which are denoted by the supply channel 4 after one of the treatments described. The gas is passed through the supply trodes either individually or several together into channels 4, which are provided in the cover 3 with guide grooves in a forming container. In . extend along the forming vessel, and of the forming vessel alternately one around the 30 supply channels 4, via branched air or other guide grooves either with electrodes, the gas channels 5, to the contact points. The channels are intended to be negative, or with electrodes which can, of course, be made positive in many ways. Mistake. After electrolyte. as shown in FIG. 2 shows. The final acid and sulfuric acid of a suitable concentration in lid 3, which covers the entire forming vessel, can fill the container and then the electrodes can of course only be connected to the outer shell for the DC power source, channels 4, 5 or a part thereof represent. Fig. 3 is started with the formation. Usually represents a variant of the channels, and in this the electrodes are connected by welding to the figure, an electrode section is connected in view of the current conductor of the power source. That shows. The electrode is also referred to here as 1. Current conductors for their part expediently consist of 40 and the current supply conductor with 2. The channel, which is made of lead rods. The electrodes, in which the two contact points surround the electrode 1, are transformed into anaovalent lead compounds by forming them into metallic to F i g. 1 and 2 are to be reduced with air or gas duct 5 'and lischem lead, nor need a gas line that supplies air or gas, especially not to be soldered, but one called guide line 4'. The top of the gets enough. Contact with the conductor, 45 forming vessel is denoted by 6 and the electrolyte level when these electrodes against the conductor are marked with a dash-dotted line with 7,
can lie. On the other hand, it is customary that the positive electrodes are connected by welding to the positive one another formation-technical advantage current conductors, so that the contact with respect to the later welding of several between this and ,, the electrodes with Safety 50 electrodes of the same polarity to plate sets,
Maintained during the entire duration of the formation- The contact point of the electrodes, which can be so-called preserved. In the case of the positive connections, the current vane is preferably the contact point where lead sulphate is formed, which is non-conductive. Because of the aforementioned connection and would destroy all contact. Sulphate content was this point in the hitherto used form largely due to the fact that sulphurous forming methods are thrown up after forming with acid when the gas bubbles burst, which are covered by a layer of dioxide that is formed with metal forming. A woven brush had to be brushed off before welding or, due to a considerable simplification when forming this electrical element, had to be removed by other scraping. One would be able to achieve this if one could not avoid oxy welding in the method according to the invention. 60 dation of the contact point takes place, you save yourself
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE02938/69A SE334427B (en) | 1969-03-04 | 1969-03-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE2007893A1 DE2007893A1 (en) | 1970-09-10 |
DE2007893B2 true DE2007893B2 (en) | 1971-04-01 |
Family
ID=20261045
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19702007893 Pending DE2007893B2 (en) | 1969-03-04 | 1970-02-20 | METHOD FOR FORMING THE ELECTRODES OF LEAD ACCUMULATORS |
Country Status (11)
Country | Link |
---|---|
AU (1) | AU1044570A (en) |
BE (1) | BE745087A (en) |
CA (1) | CA935875A (en) |
CH (1) | CH495636A (en) |
DE (1) | DE2007893B2 (en) |
ES (1) | ES376499A1 (en) |
FR (1) | FR2037555A5 (en) |
GB (1) | GB1246233A (en) |
NL (1) | NL7003112A (en) |
SE (1) | SE334427B (en) |
ZA (1) | ZA701106B (en) |
-
1969
- 1969-03-04 SE SE02938/69A patent/SE334427B/xx unknown
-
1970
- 1970-01-20 AU AU10445/70A patent/AU1044570A/en not_active Expired
- 1970-01-28 BE BE745087D patent/BE745087A/en unknown
- 1970-02-12 ES ES376499A patent/ES376499A1/en not_active Expired
- 1970-02-13 GB GB6981/70A patent/GB1246233A/en not_active Expired
- 1970-02-19 ZA ZA701106A patent/ZA701106B/en unknown
- 1970-02-20 DE DE19702007893 patent/DE2007893B2/en active Pending
- 1970-03-02 CA CA076209A patent/CA935875A/en not_active Expired
- 1970-03-03 FR FR7007585A patent/FR2037555A5/fr not_active Expired
- 1970-03-04 NL NL7003112A patent/NL7003112A/xx unknown
- 1970-03-04 CH CH317870A patent/CH495636A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
SE334427B (en) | 1971-04-26 |
ES376499A1 (en) | 1972-08-16 |
GB1246233A (en) | 1971-09-15 |
AU1044570A (en) | 1971-07-22 |
FR2037555A5 (en) | 1970-12-31 |
CH495636A (en) | 1970-08-31 |
CA935875A (en) | 1973-10-23 |
ZA701106B (en) | 1971-06-30 |
NL7003112A (en) | 1970-09-08 |
BE745087A (en) | 1970-07-01 |
DE2007893A1 (en) | 1970-09-10 |
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