DE200613C - - Google Patents
Info
- Publication number
- DE200613C DE200613C DENDAT200613D DE200613DA DE200613C DE 200613 C DE200613 C DE 200613C DE NDAT200613 D DENDAT200613 D DE NDAT200613D DE 200613D A DE200613D A DE 200613DA DE 200613 C DE200613 C DE 200613C
- Authority
- DE
- Germany
- Prior art keywords
- zinc
- sulphate
- sulfate
- solution
- ferric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011701 zinc Substances 0.000 claims description 10
- RUTXIHLAWFEWGM-UHFFFAOYSA-H Iron(III) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 9
- 229940091251 Zinc Supplements Drugs 0.000 claims description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- NWONKYPBYAMBJT-UHFFFAOYSA-L Zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- BAUYGSIQEAFULO-UHFFFAOYSA-L Iron(II) sulfate Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 5
- 229940032950 ferric sulfate Drugs 0.000 claims description 5
- 239000011790 ferrous sulphate Substances 0.000 claims description 5
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 5
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 5
- 229960001763 zinc sulfate Drugs 0.000 claims description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 3
- 239000011686 zinc sulphate Substances 0.000 claims description 3
- 235000009529 zinc sulphate Nutrition 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 230000002378 acidificating Effects 0.000 claims 2
- NSUBOZSRZQKZOW-UHFFFAOYSA-J [Fe+2].[Zn+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O Chemical compound [Fe+2].[Zn+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O NSUBOZSRZQKZOW-UHFFFAOYSA-J 0.000 claims 1
- 238000002425 crystallisation Methods 0.000 claims 1
- 230000005712 crystallization Effects 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 21
- 239000000243 solution Substances 0.000 description 12
- 229910052742 iron Inorganic materials 0.000 description 10
- 229910052748 manganese Inorganic materials 0.000 description 6
- 239000011572 manganese Substances 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 239000011702 manganese sulphate Substances 0.000 description 5
- 235000007079 manganese sulphate Nutrition 0.000 description 5
- SQQMAOCOWKFBNP-UHFFFAOYSA-L Manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- VWDWKYIASSYTQR-UHFFFAOYSA-N Sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229940099596 manganese sulfate Drugs 0.000 description 2
- ISPYRSDWRDQNSW-UHFFFAOYSA-L manganese(II) sulfate monohydrate Chemical compound O.[Mn+2].[O-]S([O-])(=O)=O ISPYRSDWRDQNSW-UHFFFAOYSA-L 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- -1 B. copper Chemical class 0.000 description 1
- 230000036826 Excretion Effects 0.000 description 1
- 241000530268 Lycaena heteronea Species 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N Manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- WKPSFPXMYGFAQW-UHFFFAOYSA-N iron;hydrate Chemical compound O.[Fe] WKPSFPXMYGFAQW-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- 229910000468 manganese oxide Inorganic materials 0.000 description 1
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese(II,III) oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 229910052950 sphalerite Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
- C22B19/22—Obtaining zinc otherwise than by distilling with leaching with acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
.iMiiiyL'r'iH'ji \.-C-Z OiCJIHisi-iliK'.!{.iMiiiyL'r'iH'ji \ .- CZ OiCJIHisi-iliK '.! {
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- M 200613 ~ KLASSE 40«. GRUPPE- M 200613 ~ CLASS 40 «. GROUP
in LONDON.in London.
Gegenstand der Erfindung ist ein Verfahren zur Trennung der Bestandteile gemischter, insbesondere bleihaltiger, sulfidischer Zinkerze auf nassem Wege und zur Gewinnung der einzelnen Bestandteile, derart, daß der ganze Prozeß unter Verwertung sämtlicher Nebenprodukte einen geschlossenen Kreislauf darstellt.The invention relates to a method for separating the components of mixed, in particular lead-containing, sulphidic zinc ores on the wet route and for extraction of the individual components, in such a way that the whole process utilizes all of them By-products represents a closed cycle.
Bei den bisher bekannten Verfahren zur ίο Verarbeitung gemischter sulfidischer Zinkerze auf nassem Wege war es nötig, die Erze zunächst zu rösten, worauf dieselben mit verdünnter Ferrisulfatlösung behandelt wurdenIn the previously known processes for processing mixed sulphidic zinc ores on the wet road it was necessary to first roast the ores, after which they were diluted with Ferric sulfate solution were treated
(D. R. P. 78159)·(D. R. P. 78159)
Vorliegendes Verfahren ermöglicht es hingegen, unmittelbar von Roherzen auszugehen, wodurch eine Verbesserung des Verfahrens und eine zweckmäßigere Gewinnung der einzelnen Bestandteile erzielt wird.The present method, however, makes it possible to start directly from raw ore, whereby an improvement of the process and a more expedient recovery of the individual Components is achieved.
Die Ausführung des Verfahrens gestaltet sich wie folgt:The procedure is carried out as follows:
Zunächst wird das Roherz pulverisiert, und zwar nicht nur fein im gewöhnlichen Sinne, sondern bis zu einem unfühlbaren Pulver gemahlen und hierauf bei Siedehitze oder unter Druck mit einer konzentrierten Lösung von Ferrisulfat, dessen Lösefähigkeit für Zinksulfid an sich bekannt ist, behandelt. Diese Lösung hat zweckmäßig einen Gehalt von IOO g Eisen und IOO g freier Schwefelsäure pro Liter. Durch das Ferrisulfat werden die Sulfide nach der bekannten Reaktion:First, the raw ore is pulverized, and not just fine in the ordinary Senses, but ground to an impalpable powder and then at the boiling point or under pressure with a concentrated solution of ferric sulphate, its solubility for zinc sulfide is known per se. This solution expediently has a content of 100 g iron and 100 g free sulfuric acid per liter. Be by the ferric sulfate the sulphides according to the well-known reaction:
ZnS + Fe2 (S OJS
= Zn S O4 + 2 Fe S O4 + 5 ZnS + Fe 2 (S OJ S
= Zn S O 4 + 2 Fe S O 4 + 5
in Sulfate unter Abscheidung freien Schwefels verwandelt, welcher auf diese Weise in bequemer und wirtschaftlich vorteilhafter Form gewonnen werden kann. Die Reaktion verläuft quantitativ nur, wenn das Roherz außerordentlich fein pulverisiert war. In diesem 'Falle geht alles Zink als Sulfat in Lösung, welche durch Filtrieren von den unlöslichen bleihaltigen Rückständen getrennt wird. Das aus einem Gemisch von Ferrosulfat und Zinksulfat bestehende Filtrat wird nun, um die Ausscheidung eines Doppelsalzes von Zink und Eisen zu vermeiden, in heißem Zustand der Oxydation unterworfen, welche in Anbetracht der konzentrierten Ferrosulfatlösung zweckmäßig mit Salpetersäure unter Regeneration der nitrosen Dämpfe in üblicher Weise erfolgt. Nach erfolgtet Oxydierung des Eisens wird' die Lösung abgekühlt, wobei bei genügendem Zinkgehalt dieses als. Sulfat auskristallisiert, während das Eisen als leicht lösliches Ferrisulfat in der Mutterlauge zurückbleibt. Das Zinksulfat wird von dieser getrennt und nach dem Trocknen in einem Muffelofen zur Über-converted into sulphates with deposition of free sulfur, which in this way is more convenient and economically advantageous form can be obtained. The reaction proceeds quantitatively only if the raw ore was extremely finely pulverized. In this case all zinc goes in as sulphate Solution, which is separated from the insoluble lead-containing residues by filtration will. The filtrate, which consists of a mixture of ferrous sulfate and zinc sulfate, is now, in order to avoid the excretion of a double salt of zinc and iron subject to oxidation in the hot state, which given the concentrated Ferrous sulphate solution is advisable with nitric acid with regeneration of the nitrous vapors takes place in the usual way. After the iron has been oxidized, the solution is cooled with sufficient zinc content this as. Sulphate crystallizes out, while the iron as easily soluble ferric sulphate in the mother liquor remains. The zinc sulphate is separated from this and after drying in a muffle furnace for over-
führung in Zinkoxyd in bekannter Weise kalziniert, wobei die entweichenden sauren Gase zur Gewinnung der Eisenlösung Verwendung finden.Lead in zinc oxide calcined in a known manner, with the escaping acids Find gases to obtain the iron solution use.
Das so erhaltene Zinkoxyd ist frei von Blei und anderen Metallen und ergibt nach der Reduktion mit Kohle reines Zink.The zinc oxide thus obtained is free from lead and other metals and yields the reduction with coal is pure zinc.
Der bei der Filtration erhaltene unlösliche Rückstand enthält das Blei, die Gangart undThe insoluble residue obtained in the filtration contains the lead, gangue and
ίο den gebildeten Schwefel. Letzterer wird durch Destillation gewonnen und der Bleirückstand nach bekannten Methoden zu Blei verarbeitet. Das gesamte Verfahren erfordert daher zur Gewinnung sämtlicher in dem Erz enthaltenen Bestandteile nur rohes, ungeröstetes Erz als Ausgangsstoff sowie Kohle und eine kleine Menge Natriumnitrat zur Oxydation der Eisenlösung.ίο the sulfur formed. The latter will obtained by distillation and the lead residue converted to lead by known methods processed. The entire process therefore requires recovering all of the ore Contains only raw, unroasted ore as a starting material and coal and a small amount of sodium nitrate to oxidize the iron solution.
Enthält das sulfidische Zinkerz noch andere Metalle, wie z. B. Kupfer, Silber, Gold, Eisen und Mangan, so wird die Behandlung dementsprechend abgeändert. Kupfer, Gold und Silber bleiben zum großen Teil mit dem unlöslichen Bleirückstand zurück, wobei das Kupfer auf der Bleiverhüttung als Kupferstein gewonnen wird und die Edelmetalle sich mit dem Blei legieren.Does the sulfidic zinc ore contain other metals, such as B. copper, silver, gold, iron and manganese, the treatment is modified accordingly. Copper, gold and silver for the most part remain with the insoluble Lead residue back, whereby the copper is extracted from the lead smelting as copper stone and the precious metals alloy with the lead.
Mangan und ein Teil des Eisens werden bei der Behandlung des Erzes mit Ferrisulfat in lösliche Sulfate übergeführt; da die Lösung immer reicher an Eisen wird, muß dessen Gehalt von Zeit zu Zeit entsprechend reduziert werden. Dies kann beispielsweise durch Niederschlagen des überschüssigen Eisens mit selbsterzeugtem Zinkoxyd erfolgen, welches als Eisenhydrat oder basisches unlösliches Ferrisulfat abfiltriert, während die Zinklösung zu dem Verfahren zurückgeführt wird.Manganese and some of the iron are used in the treatment of the ore with ferric sulfate converted into soluble sulfates; as the solution becomes richer and richer in iron, its content must correspond from time to time be reduced. This can be done, for example, by knocking down the excess Iron made with self-produced zinc oxide, which as iron hydrate or basic insoluble ferric sulfate is filtered off while the zinc solution is returned to the process will.
Mangan löst sich als Mangansulfat so lange auf,, bis eine heißgesättigte Lösung entsteht. Da Mangansulfat jedoch in der Kälte leichter löslich ist als in der Wärme, so kristallisiert mit dem Zinksulfat kein Mangansulfat aus. Sobald jedoch die Lösung mit Mangan gesättigt ist, bleibt der Rest des Mangans zusammen . mit'!dem Bleirückstand. Diesen Mangangehalt; kann man aus dem unlöslichen Rückstand nach erfolgter Befreiung von anhaftender Mutterlauge durch Waschen mit Mangansulfatlösung und durch Auslaugen des gewaschenen Rückstandes mit reinem Wasser gewinnen, um es entweder auszukristallisieren oder durch Kalzination des Mangansulfats Manganoxyd darzustellen.Manganese dissolves as manganese sulphate until a hot, saturated solution is formed. However, since manganese sulphate is more soluble in the cold than in the warm, no manganese sulphate crystallizes out with the zinc sulphate. However, once the solution is saturated with manganese, the rest of the manganese stays together. with ' ! the lead residue. This manganese content ; can be obtained from the insoluble residue after it has been freed from adhering mother liquor by washing with manganese sulfate solution and by leaching the washed residue with pure water in order to either crystallize it out or to produce manganese oxide by calcination of the manganese sulfate.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE200613C true DE200613C (en) | 1900-01-01 |
Family
ID=463238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT200613D Expired DE200613C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE200613C (en) |
-
0
- DE DENDAT200613D patent/DE200613C/de not_active Expired
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