DE19910878A1 - Clear, moderately foaming toilet freshener composition comprises an amphoteric surfactant, fragrance compounds and other additives - Google Patents
Clear, moderately foaming toilet freshener composition comprises an amphoteric surfactant, fragrance compounds and other additivesInfo
- Publication number
- DE19910878A1 DE19910878A1 DE1999110878 DE19910878A DE19910878A1 DE 19910878 A1 DE19910878 A1 DE 19910878A1 DE 1999110878 DE1999110878 DE 1999110878 DE 19910878 A DE19910878 A DE 19910878A DE 19910878 A1 DE19910878 A1 DE 19910878A1
- Authority
- DE
- Germany
- Prior art keywords
- preparation
- preparation according
- amphoteric surfactant
- surfactant
- surfactants
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000002280 amphoteric surfactant Substances 0.000 title claims abstract description 13
- 239000000203 mixture Substances 0.000 title claims abstract description 8
- 239000003205 fragrance Substances 0.000 title claims abstract description 5
- 150000001875 compounds Chemical class 0.000 title abstract description 3
- 238000005187 foaming Methods 0.000 title description 2
- 239000000654 additive Substances 0.000 title 1
- 238000002360 preparation method Methods 0.000 claims description 42
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 10
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 10
- 229960003237 betaine Drugs 0.000 claims description 10
- 239000002736 nonionic surfactant Substances 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- 239000002304 perfume Substances 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 claims description 4
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 4
- 244000060011 Cocos nucifera Species 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000003093 cationic surfactant Substances 0.000 claims description 3
- 150000004985 diamines Chemical class 0.000 claims description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 2
- 150000001408 amides Chemical group 0.000 claims description 2
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 238000007046 ethoxylation reaction Methods 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000003868 ammonium compounds Chemical class 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 230000007935 neutral effect Effects 0.000 abstract 2
- 239000006260 foam Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/05—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating specially adapted to be released by contact with a liquid, e.g. for toilets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Die Erfindung betrifft eine Zubereitung, insbesondere für WC- Erfrischer.The invention relates to a preparation, in particular for toilet Freshener.
Bekannte WC-Erfrischer umfassen beispielsweise WC-Steine, die in Körbchen unter den Beckenrand gehängt bzw. direkt in das Spül becken eingebracht werden, um beim Spülvorgang die Inhaltsstoffe der WC-Erfrischer in das Becken der Toilette zu spülen. Andere bekannte WC-Erfrischer bestehen aus Gelen oder umfassen Einhän gesysteme, die mit einem Nachfüllbehältnis für eine flüssige Zubereitung versehen sind.Known toilet fresheners include, for example, toilet stones that are in Basket hung under the edge of the basin or directly in the sink basins are introduced to remove the ingredients during the rinsing process Flush the toilet freshener into the basin of the toilet. Other known toilet fresheners consist of gels or include hangers systems that come with a refill for a liquid Preparation are provided.
Die bekannten Zubereitungen für WC-Erfrischer können Hilfs- und Duftstoffe sowie antibakterielle Mittel ebenso wie Mittel zur Verhinderung von Kalkablagerungen enthalten.The known preparations for toilet fresheners can be auxiliary and Fragrances as well as antibacterial agents as well as agents for Contain prevention of limescale deposits.
Aus der EP 0 775 741 A1 sind flüssige Zubereitungen für WC-Er frischer bekannt, welche anionische und/oder nichtionische Ten side enthalten.EP 0 775 741 A1 discloses liquid preparations for toilet bowls More recently known which anionic and / or nonionic Ten side included.
Die Verwendung anionischer Zubereitungen ist jedoch einerseits mit dem Nachteil verbunden, daß je nach Typ der Toilette beim Spülvorgang eine hohe Schaumentwicklung entstehen kann und des weiteren dürfen solche anionischen Zubereitungen keine kationi schen Tenside als bakterizide und fungizide Mittel enthalten. Bei Zubereitungen, die aus nichtionischen Tensiden bzw. aus einer Mischung aus nichtionischen und anionischen Tensiden be stehen, tritt weiterhin ein Problem der Lagerbeständigkeit auf, da eine längere Lagerzeit zu einem Viskositätsanstieg führen kann, wodurch sich Dosierprobleme und auch Schaumprobleme erge ben können. However, the use of anionic preparations is on the one hand associated with the disadvantage that depending on the type of toilet at Rinsing process can cause a high level of foam and des Furthermore, such anionic preparations must not be cationic usually contain surfactants as bactericidal and fungicidal agents. For preparations made from nonionic surfactants or from a mixture of nonionic and anionic surfactants there is still a problem of storage stability, since a longer storage time leads to an increase in viscosity can, resulting in dosing problems and foam problems can practice.
Der Erfindung liegt daher die Aufgabe zugrunde, eine klare Zube reitung, insbesondere für WC-Erfrischer zu schaffen, deren Vis kosität auch bei längerer Lagerung weitgehend unverändert bleibt und bei deren Anwendung sich keine größeren Mengen stabiler Schäume bilden und die in der Lage ist größere Mengen Parfümöl aufzunehmen.The invention is therefore based on the object of providing a clear concept preparation, especially for toilet fresheners, whose vis The viscosity remains largely unchanged even after prolonged storage and when they are used, no larger amounts are more stable Forms foams and is capable of large quantities of perfume oil to record.
Diese Aufgabe wird durch die im Anspruch 1 angegebene Zuberei tung gelöst. Die Unteransprüche 1 bis 13 geben vorteilhafte Aus gestaltungen der Zubereitung nach Anspruch 1 an.This task is achieved by the preparation specified in claim 1 solution solved. The subclaims 1 to 13 give advantageous from designs of the preparation according to claim 1.
Anspruch 14 beschreibt eine besonders wirkungsvolle und günstige Zubereitung für WC-Erfrischer.Claim 14 describes a particularly effective and inexpensive one Preparation for toilet freshener.
Gegenstand der Erfindung ist daher eine Zubereitung, insbesonde re für WC-Erfrischer, die neben an sich bekannten Hilfs- und Duftstoffen wenigstens ein amphoteres Tensid vom Betain-Typ enthält.The invention therefore relates to a preparation, in particular re for toilet fresheners, in addition to known auxiliary and Fragrances at least one amphoteric surfactant of the betaine type contains.
Besonders günstige Ergebnisse liefern amphotere Tenside vom Betain-Typ, die auf Basis von Kokosfettsäure aufgebaut sind. Ein bevorzugtes Beispiel ist Kokosalkyldimethylammoniumbetain.Amphoteric surfactants vom Betaine type, which are based on coconut fatty acid. A preferred example is cocoalkyldimethylammonium betaine.
Bei einer bevorzugten Ausführungsform kann die Zubereitung auch Mischungen verschiedener amphoterer Tenside vom Betain-Typ ent halten. Für den Fall, daß die erfindungsgemäße Zubereitung, ins besondere zur Verhinderung von Kalkablagerungen im Toiletten becken, auf einen sauren Bereich eingestellt wird, werden bevor zugt solche Betaine verwendet, die keinen Amidrest im Molekül aufweisen.In a preferred embodiment, the preparation can also Mixtures of various amphoteric surfactants of the betaine type ent keep. In the event that the preparation according to the invention ins especially to prevent limescale deposits in toilets basin, set to an acidic area, should be done before Appropriate betaines are used that do not have an amide residue in the molecule exhibit.
Überraschenderweise wurde gefunden, daß die erfindungsgemäßen Zubereitungen, insbesondere für WC-Erfrischer auch im niedrigen pH-Bereich zu klaren Lösungen führt und beim Spülvorgang keine hohe Schaumentwicklung bzw. Bildung stabiler Schäume auftritt. Surprisingly, it has been found that the invention Preparations, especially for toilet fresheners, even at low levels pH range leads to clear solutions and none during the rinsing process high foam development or formation of stable foams occurs.
Diese erfindungsgemäßen Zubereitungen sind lagerstabil mit gutem Netz- und Dispergierverhalten, so daß sie bei ihrer Anwendung eine gute Reinigungswirkung entfalten.These preparations according to the invention are storage-stable with good Wetting and dispersing behavior, so that they are useful in their application develop a good cleaning effect.
Zur Geruchsverbesserung können die erfindungsgemäßen Zubereitun gen beispielsweise Parfümöle enthalten, wobei sich als zusätzli che Emulgatoren für die lipophilen Bestandteile und zum Aufbau eines Teiles der Strukturviskosität nichtionische Tenside vor teilhaft einsetzen lassen. Durch die Verwendung nichtionischer Tenside läßt sich das Anschäumverhalten verbessern, ohne daß sich ein unerwünschter stabiler Schaum aufbaut.The preparations according to the invention can be used to improve the odor gen, for example, contain perfume oils, and as additional Che emulsifiers for the lipophilic components and for the structure some of the intrinsic viscosity are nonionic surfactants let use part. By using non-ionic Surfactants can improve the foaming behavior without an undesirable stable foam builds up.
Als nichtionische Tenside werden vorzugsweise Fettsäureglyceri de, Sorbitanester oder auch Fettalkoholethoxylate basierend auf Fettsäuren, Fettalkoholen oder Fettsäurederivaten mit 11 bis 18 Kohlenstoffatomen und einem Oxethylierungsgrad von 2-20 Mol EO, ebenso wie Fettsäurealkanolamide auf Basis von Kokosfettsäure mit Diethanolamin verwendet werden.Fatty acid glyceri are preferred as nonionic surfactants de, sorbitan esters or fatty alcohol ethoxylates based on Fatty acids, fatty alcohols or fatty acid derivatives with 11 to 18 Carbon atoms and a degree of ethoxylation of 2-20 mol EO, as well as fatty acid alkanolamides based on coconut fatty acid be used with diethanolamine.
Insbesondere wird als nichtionisches Tensid der erfindungsgemä ßen Zubereitung Isotridecylalkoholpolyglykolether, vorzugsweise mit 5-8 Mol EO zugesetzt, wodurch sich eine gewünschte Struktur viskosität ausbildet und die Schaumbildung auf ein gewünschtes Maß eingestellt werden kann. Die gemeinsame Verwendung eines amphoteren Tensids vom Betain-Typ mit Isotridecylalkoholpolygly kolether als nichtionischem Tensid führt überraschenderweise zu dem Ergebnis, daß sich dadurch große Parfummengen klar lösen lassen ohne daß die übrigen Produkteigenschaften der flüssigen Zubereitung beeinflußt wird.In particular, the nonionic surfactant according to the invention ßen preparation isotridecyl alcohol polyglycol ether, preferably with 5-8 moles of EO added, creating a desired structure viscosity develops and the foam formation to a desired Dimension can be adjusted. The common use of a betaine-type amphoteric surfactant with isotridecyl alcohol polygly Kolether as a nonionic surfactant surprisingly leads to the result that large quantities of perfume are clearly dissolved leave without affecting the other product properties of the liquid Preparation is influenced.
Im allgemeinen ist das amphotere Tensid vom Betain-Typ in der Zubereitung in einer Menge von 5-40 Gew.-% enthalten.In general, the betaine-type amphoteric surfactant is disclosed in US Pat Preparation contained in an amount of 5-40% by weight.
Bei einer weiteren bevorzugten Ausführungsform enthält die er findungsgemäße Zubereitung Mittel mit bakteriziden und fungizi den Eigenschaften, wie kationische Tenside z. B. quarternäre Am moniumverbindungen oder Amine bzw. Diamine. Diese Verbindungen entfalten je nach Typ ihre Wirksamkeit schon bei sehr geringen Einsatzmengen.In a further preferred embodiment it contains inventive preparation means with bactericidal and fungicidal the properties of how cationic surfactants z. B. Quaternary Am monium compounds or amines or diamines. These connections Depending on the type, they develop their effectiveness at very low levels Application quantities.
Überraschenderweise wurde festgestellt, daß die kationischen Tenside vom vorgenannten Typ mit den amphoteren Tensiden vom Betain-Typ kompatibel sind und sich daher die hohen bakteriziden und fungiziden Eigenschaften der quarternären Ammoniumverbin dungen bzw. Amine oder Diamine bei der Herstellung der erfin dungsgemäßen Zubereitungen nutzen lassen, so daß damit WC-Er frischer herstellbar sind, die bakteriostatische bis desinfizie rende Wirkungen aufweisen.Surprisingly, it was found that the cationic Surfactants of the aforementioned type with the amphoteric surfactants from Betaine type are compatible and are therefore highly bactericidal and fungicidal properties of the quaternary ammonium compounds applications or amines or diamines in the production of the inven Appropriate preparations can be used, so that WC-Er Fresher can be produced, bacteriostatic to disinfectant have beneficial effects.
Im folgenden wird die Erfindung anhand eines Beispiels erläu
tert, wobei sich die angegebenen Prozentzahlen auf das Gewicht
beziehen, wobei der Fachmann weiß, daß diese Rezeptur im Rahmen
des fachmännischen Könnens modifiziert werden kann.
In the following, the invention is explained by means of an example, the percentages given being based on weight, the person skilled in the art knowing that this formulation can be modified within the scope of the skilled person.
Dehyton AB 30 r: Kokosalkyldimethylammoniumbetain (30%),
Genapol X-080 r: Isotridecylalkoholpolyglykolether 8 EO und
Rhodopol T r: Xanthan.Dehyton AB 30 r: coconut alkyldimethylammonium betaine (30%),
Genapol X-080 r: isotridecyl alcohol polyglycol ether 8 EO and
Rhodopol T r: xanthan gum.
Die erfindungsgemäße Zubereitung wird wie folgt hergestellt:The preparation according to the invention is produced as follows:
Zunächst werden Dehyton, Genapol und Dipropylenglykol und Wasser gemischt und vorgemischtes Parfüm und Rhodopol werden unter Rüh ren zu dem Tensid-Wassergemisch zugegeben. Dabei wird kalt so lange gerührt, bis sich das Rhodopol vollständig gelöst hat. Abschließend werden zur Einstellung des pH-Wertes Zitronensäure sowie Konservierung und Farbe nach Belieben zugegeben.First are Dehyton, Genapol and Dipropylene Glycol and Water mixed and premixed perfume and Rhodopol are mixed with stirring Ren added to the surfactant-water mixture. It gets cold like that stirred for a long time until the rhodopole has completely dissolved. Finally, citric acid is used to adjust the pH as well as preservation and color added at will.
Die erfindungsgemäße flüssige Zubereitung läßt sich in beliebige Dosiersysteme einfüllen und läßt sich vielseitig beispielsweise zur Lufterfrischung bis hin zum antimikrobiellen WC-Erfrischer bzw. Reiniger verwenden.The liquid preparation according to the invention can be used in any Filling in dosing systems and can be versatile, for example for air freshening up to the antimicrobial toilet freshener or use cleaner.
Claims (14)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1999110878 DE19910878A1 (en) | 1999-03-11 | 1999-03-11 | Clear, moderately foaming toilet freshener composition comprises an amphoteric surfactant, fragrance compounds and other additives |
| DE1999122040 DE19922040A1 (en) | 1999-03-11 | 1999-05-12 | Preparation, especially for toilet fresheners |
| EP99121586A EP1035195A1 (en) | 1999-03-11 | 1999-10-29 | Fragrant composition, especially suitable as toilet freshener |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1999110878 DE19910878A1 (en) | 1999-03-11 | 1999-03-11 | Clear, moderately foaming toilet freshener composition comprises an amphoteric surfactant, fragrance compounds and other additives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE19910878A1 true DE19910878A1 (en) | 2000-09-21 |
Family
ID=7900618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1999110878 Withdrawn DE19910878A1 (en) | 1999-03-11 | 1999-03-11 | Clear, moderately foaming toilet freshener composition comprises an amphoteric surfactant, fragrance compounds and other additives |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE19910878A1 (en) |
-
1999
- 1999-03-11 DE DE1999110878 patent/DE19910878A1/en not_active Withdrawn
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