DE19910355A1 - Textiles useful in germ-critical environments e.g. hospitals, operating theaters and clean rooms are rendered largely germ-free by treatment with food preservative(s) and non-toxic acid(s) - Google Patents

Textiles useful in germ-critical environments e.g. hospitals, operating theaters and clean rooms are rendered largely germ-free by treatment with food preservative(s) and non-toxic acid(s)

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Publication number
DE19910355A1
DE19910355A1 DE19910355A DE19910355A DE19910355A1 DE 19910355 A1 DE19910355 A1 DE 19910355A1 DE 19910355 A DE19910355 A DE 19910355A DE 19910355 A DE19910355 A DE 19910355A DE 19910355 A1 DE19910355 A1 DE 19910355A1
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Prior art keywords
acid
germ
composition according
textiles
agent
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DE19910355A
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German (de)
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Arconia Chur GmbH
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Arconia Chur GmbH
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Priority to DE19910355A priority Critical patent/DE19910355A1/en
Priority to EP00105006A priority patent/EP1034701A1/en
Publication of DE19910355A1 publication Critical patent/DE19910355A1/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/047—Arrangements specially adapted for dry cleaning or laundry dryer related applications
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
    • A61L2/186—Peroxide solutions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/046—Insoluble free body dispenser
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/1845—Aromatic mono- or polycarboxylic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/20—Targets to be treated
    • A61L2202/26—Textiles, e.g. towels, beds, cloths

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Organic Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dentistry (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Emergency Medicine (AREA)
  • Microbiology (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Textiles are rendered germ-free or germ-reduced, without a separate disinfection treatment, by use of food preservative(s) and non-toxic acid(s) Independent claims are also included for the following: (1) A process for producing highly disinfected textiles, comprising adding a non-toxic, purely organic disinfectant composition during a washing, rinsing and/or drying operation. (2) A deodorizing and germ-reducing composition for use in this process comprising one or more food preservatives (I) and one or more non-toxic acids (II).

Description

Die Erfindung betrifft keimreduzierte bzw. entkeimte Textilien bzw. Wäsche sowie Verfahren und Mittel zu deren Herstellung.The invention relates to reduced or sterilized Textiles or laundry as well as processes and agents for their Manufacturing.

Auch bei modernen Reinigungsanlagen besteht das Problem, dass die in Lösungsmitteln gereinigten und anschließend getrockneten Textilien, insbesondere auch Kleidungsstücke und notwendigerweise keimfreie Wäsche wie OP-Kleidung nur mit stark umweltschädigenden Mitteln behandelt werden können. Aber auch nach anderen Verfahren z. B. nur auf Wasserbasis mit z. B. normaler Waschmaschine gereinigte Textilien sind im fertigen Zustand unzulässig stark verkeimt und auch geruchsbelastet.Even with modern cleaning systems, there is the problem that the cleaned in solvents and then dried textiles, especially clothing and necessarily germ-free laundry such as surgical clothing only are treated with highly environmentally harmful agents can. But also by other methods such. B. only on Water based with e.g. B. normal washing machine cleaned Textiles are inadmissibly strong when finished germs and also smells.

Aufgabe der Erfindung ist es, diese Nachteile auszuschalten und keimreduzierte bzw. entkeimte Textilien mit einem völlig untoxischen (Trinkwasserklasse 0) und vollständig biologisch abbaubaren und hautfreundlichen Mittel zu erreichen.The object of the invention is to overcome these disadvantages switch off and germ-reduced or sterilized textiles with a completely non-toxic (drinking water class 0) and fully biodegradable and skin-friendly Means to achieve.

Dies wird überraschenderweise mit einem Mittel erreicht, das gemäß den Ansprüchen in vergleichsweise schwach konzentrierter Mischungskonzentration zusammengesetzt ist, bei dem die Mischungskomponenten in synergistisch zusammenwirkender Form wirksam sind. Surprisingly, this is achieved with a means that according to the claims in comparatively weak concentrated mixture concentration composed is where the blend components are synergistic interacting form are effective.  

Die mit dem erfindungsgemäßen Mittel gereinigten Textilien gemäß Anspruch 1 bis 4 weisen alle Vorteile einer mindestens weitgehenden Entkeimung auf.Those cleaned with the agent according to the invention Textiles according to claims 1 to 4 have all advantages an at least extensive disinfection.

Überraschenderweise hat sich die Zugabe eines Mittels mit im wesentlichen folgenden Zusammensetzungs-Komponenten als kurzfristig intensiv desodorierend und keim­ reduzierend und damit als vorteilhafte Lösung bei der Behandlung mit einer Mittelkombination gemäß Patentansprüchen 5 bis 13 erwiesen.Surprisingly, the addition of an agent essentially following composition components as short-term intensive deodorant and germ reducing and thus as an advantageous solution for Treatment with a combination of agents according to Claims 5 to 13 proved.

Besonders überraschend für die Wirksamkeit des Mittels ist, dass die zu reinigenden bzw. zu waschenden Textilien im hochkontaminierten Zustand pH-Werte von 6,0 bis z. T. 7 und noch darüber aufweisen können und das Mittel selbst bei rein biologischer Zusammensetzung gemäß Patentansprüchen 5 bis 13 mit z. T. alkalischen Komponenten eine gründlichen Entkeimung und vollständige Geruchseliminierung bewirkt.Particularly surprising for the effectiveness of the agent is that the textiles to be cleaned or washed in the highly contaminated state pH values from 6.0 to z. T. 7 and can still have and the agent itself with a purely biological composition Claims 5 to 13 with z. T. alkaline Components a thorough disinfection and complete Odor elimination causes.

Das Lebensmittelkonservierungsmittel kann gemäß Anspruch 6 vorteilhafterweise ausgewählt sein aus der Gruppe bestehend aus Citronensäure, Natriumbenzoat, Weinsäure, Milchsäure, Apfelsäure, Essigsäure, Bernsteinsäure, Acetylsalicylsäure und L-Ascorbinsäure, Sorbinsäure, Benzoesäure, p-Hydroxybenzoesäure, Ameisensäure und Propionsäure sowie deren Abkömmlingen, eingeschlossen Salze und Estern derselben.The food preservative can according to claim 6 can advantageously be selected from the group consisting of citric acid, sodium benzoate, tartaric acid, Lactic acid, malic acid, acetic acid, succinic acid, Acetylsalicylic acid and L-ascorbic acid, sorbic acid, Benzoic acid, p-hydroxybenzoic acid, formic acid and Propionic acid and its derivatives, included Salts and esters thereof.

Die mit dem Mittel insbesondere nach den Ansprüchen 5 und 6 erzielte synergistische Wirkung wird durch die Zumischung von sauerstoffabgebenden Stoffen gemäß Anspruch 7 und 12 verstärkt. The with the agent in particular according to claims 5 and 6 achieved synergistic effect is through the Addition of oxygen-releasing substances according to Claim 7 and 12 reinforced.  

Die Erfindung erfasst die in den Ansprüchen 5 bis 8 enthaltenen speziellen Ausführungsformen, wobei die in Wasser gelöste Mischungskombination bei einem pH-Wert zwischen etwa 2 bis 7 liegt.The invention covers that in claims 5 to 8 contained special embodiments, the in Mixture of water dissolved in a pH value is between about 2 to 7.

Zwecks wirkungsverstärkender Durchdringung und verbesserter Benetzung können der Mischung gemäß den Ansprüchen 5 bis 13.For effect-enhancing penetration and improved wetting can the mixture according to the Claims 5 to 13.

1,0 bis 5% eines oder mehrerer Tenside ausgewählt aus der Gruppe bestehend aus in der verwendeten Menge untoxischen anionischen und nichtionischen Tensiden, Seifen, Fettsäure-Aminocarbonsäurekondensate, Alkyl­ benzolsulfonate, Ligninsulfonate, Alkylsulfonate, Fettsäureestern, sulfatierten Fettsäureglyceriden, Betaine, Sulfobetaine, Saponine, Fettsäureester von Polyalkoholen, Oxyäthylierte Fettsäuren, etc., von denen Natriumdodecylsulfonat und Natriumlaurylsulfat besonders bevorzugt sind, beigefügt sein.1.0 to 5% of one or more surfactants selected from the group consisting of in the amount used non-toxic anionic and nonionic surfactants, Soaps, fatty acid aminocarboxylic acid condensates, alkyl benzenesulfonates, ligninsulfonates, alkylsulfonates, Fatty acid esters, sulfated fatty acid glycerides, Betaines, sulfobetaines, saponins, fatty acid esters from Polyalcohols, oxyethylated fatty acids, etc., of which Sodium dodecyl sulfonate and sodium lauryl sulfate in particular are preferred to be attached.

Es kann erfindungsgemäß sinnvoll sein, dass das Behandlungs-Mittel zusätzlich ein oder mehrere von Materialien ausgewählt aus der Gruppe bestehend aus lebensmittelrechtlich unbedenklichen Stabilisatoren, Trocknungsmittel, Säuerungsmittel, Korrosionsinhibitoren, Emulgatoren, Sprengmittel und/oder Tenside enthält.It can make sense according to the invention that the Treatment agents additionally one or more of Materials selected from the group consisting of stabilizers that are safe under food law, Desiccants, acidifiers, corrosion inhibitors, Contains emulsifiers, disintegrants and / or surfactants.

Ein entscheidender Vorteil der erfindungsgemäß gereinigten bzw. gewaschenen Wäsche liegt darin, dass man das Mittel nicht nur bis zur Entkeimung der Wäsche selbst dosieren kann, sondern in einem Überschuß davon, so dass von der fertig gereinigten Wäsche selbst eine länger andauernde, zusätzliche entkeimende Wirkung ausgeht, die nicht nur in keimempfindlichen Situationen (z. B. im OP- Saal oder Binden, Wundtücher) zusätzlich entkeimend wirkt. Dabei ist das Mittel selbst absolut hautfreundlich und die gereinigte Wäsche wirkt selbst als Medium der Entkeimung.A decisive advantage of the invention cleaned or washed laundry lies in the fact that one not only until the laundry itself has been sterilized can dose, but in an excess of it, so that of the finished laundry itself a longer one ongoing, additional disinfecting effect that not only in germ-sensitive situations (e.g. in the OR  Hall or bandages, wound cloths) additionally sterilizing works. The product itself is absolutely skin-friendly and the cleaned laundry itself acts as the medium of Disinfection.

Insbesondere zur Vermeidung einer Nachverkeimung hat es sich als vorteilhaft herausgestellt, wenn die Wasch- oder Spülflüssigkeit mindestens ein wasserlösliches Silbersalz aufweist, das eine Nachverkeimung verhindert bzw. die Wirkungsdauer erheblich verlängert. Der Gehalt an Silbersalzen beträgt vorteilhafterweise zwischen weniger als 0,2 bis 0,5 Gew.-% des Mittels als Trockenmasse.It has in particular to avoid re-contamination turned out to be advantageous if the washing or Flushing liquid at least one water-soluble silver salt has, which prevents re-contamination or the Effectiveness extended considerably. The content of Silver salts are advantageously between less than 0.2 to 0.5% by weight of the composition as dry matter.

Um das Lösungsverhalten weiter günstig zu beeinflussen, kann es sinnvoll sein, MgCl2 einzusetzen, das durch Ionenaustausch mit anderen zweiwertigen Salzen die Lösung der Ablagerungen zweiwertiger Ionen fördert.In order to influence the dissolution behavior further favorably, it can make sense to use MgCl 2 , which promotes the dissolution of the deposits of divalent ions by ion exchange with other divalent salts.

Dadurch, dass nun Citronensäure mit ihren günstigen Lösungseigenschaften gemeinsam mit Silberverbindungen, wie -salzen, die gegen ein Wachstum von Keimen eingesetzt werden, kann bei einer überraschend guten unabhängigen Entkeimungswirkung auch die Nachverkeimung herabgesetzt werden.Because now citric acid with its cheap Solution properties together with silver compounds, such as salts used against the growth of germs can be at a surprisingly good independent Disinfection effect also reduced the subsequent germination become.

Die Wirkung des erfindungsgemäßen Mittels ist vor allem deshalb überraschend, weil es den Wasch- und Spülflüssigkeiten nur in wenigen Prozent oder auch nur in Bruchteilen von Prozenten zum Desodorieren und Entkeimen zugesetzt zu werden braucht, obwohl es aus nachweislich völlig untoxischen, biologisch verträglichen und biologisch völlig abbaubaren Bestandteilen ohne jegliche Chlor- und Halogenbestandteile und auch ohne jegliche Antibiotika, Pestizide, Fungizide und Insektizide zusammengesetzt ist und in vergleichsweise kurzer Zeit und zeitlich lang anhalten wirksam ist.The effect of the agent according to the invention is above all surprising because it is the washing and Rinsing liquids only in a few percent or only in Fractions of percent for deodorization and sterilization needs to be added, although it is proven to be completely non-toxic, biologically compatible and fully biodegradable ingredients without any Chlorine and halogen components and also without any Antibiotics, pesticides, fungicides and insecticides  is composed and in a comparatively short time and is effective for a long time.

Das Mittel ist sowohl völlig untoxisch als auch vollständig biologisch abbaubar und hautschonend. Es baut sogar aufgrund seiner fungiziden Wirkung Antibiotika ab und löst keinerlei Resistenzerscheinungen aus.The remedy is both completely non-toxic as well completely biodegradable and gentle on the skin. It builds even antibiotics due to its fungicidal effects and does not trigger any signs of resistance.

Das Mittel wirkt gegen Keime wie Bakterien (bakterizid), Pilze wie Schimmelpilze (fungizid), Pilzsporen und Blütenstaub, Hefen, Protozoen, Eukaryoten, Eiweißmoleküle, Enzyme, Makrophagen und auch molekular­ biologische Schädlinge oder dergleichen, Parasiten durch Zerstörung deren Nachwuchs und Eier, sowie Biofouling und Epelithionbildung.The agent acts against germs like bacteria (bactericidal), Fungi such as mold (fungicidal), fungal spores and Pollen, yeast, protozoa, eukaryotes, Protein molecules, enzymes, macrophages and also molecular biological pests or the like, parasites by Destruction of their offspring and eggs, as well as biofouling and Epelithione formation.

Konkret ist das erfindungsgemäße Mittel auch gegen sämtliche Arten von Aspergillus, Legionellen und Salmonellen, sowie
Escherichia coli,
Klebstelle pneumoniae,
Staphylococcus aureus,
Pseudomonas aeruginosa,
Streptococcus faecalis,
Proteus mirabilis,
Mycobacterium tuberculosis,
Clostridium sporogenes,
Candida albicans
mit bis zu völliger Entkeimung erprobt.Specifically, the agent according to the invention is also effective against all types of Aspergillus, Legionella and Salmonella, as well
Escherichia coli,
Glue joint pneumoniae,
Staphylococcus aureus,
Pseudomonas aeruginosa,
Streptococcus faecalis,
Proteus mirabilis,
Mycobacterium tuberculosis,
Clostridium sporogenes,
Candida albicans
tested with up to complete disinfection.

Bei dem erfindungsgemäßen Reinigungs- bzw. Waschverfahren mit Lösungsmittel kann das Mittel der Reinigungs­ flüssigkeit sowohl in gelöster flüssiger Form, als auch in fester Konsistenz zugesetzt werden, bevorzugt aber aus z. B. wirtschaftlichen Gründen in der Spül- und Trockenstufe. Die Entkeimungswirkung ist dabei stark genug, um die fertig gereinigten Textilien zumindest ausreichend keimfrei bzw. keimarm zu machen und darüberhinaus noch mit eigener Entkeimungswirkung auszustatten.In the cleaning or washing process according to the invention with solvent can be the means of cleaning  liquid both in dissolved liquid form, as well be added in a firm consistency, but preferably from e.g. B. economic reasons in the dishwashing and Drying level. The disinfection effect is strong enough to clean the finished textiles at least to make sufficiently germ-free or low-germ and furthermore with its own disinfection effect equip.

Diese Kondition der Textilien wird auch durch ein anschließendes Bügeln oder Pressen nicht beeinträchtigt. Im Gegenteil kann dabei der Bügelfeuchtigkeit das entkeimende Mittel zugegeben werden. Dabei können die Umgebungsbedingungen durch diese Vorgänge mit dem mit dem Enkeimungsmittel behandelten Textilien merklich verbesserte, arbeitsbegünstigende Keimverarmung erfahren.This condition of the textiles is also confirmed by a subsequent ironing or pressing is not affected. On the contrary, the iron moisture can do that sterilizing agents are added. The Environmental conditions through these processes with that with the Textile treated with disinfectant noticeably experienced improved, work-promoting germ depletion.

Diese Wirkung kann noch länger anhaltend gestaltet werden, wenn die Textilien mit einer Imprägnierung gemäß Anspruch 18 versehen werden.This effect can last longer if the textiles are impregnated in accordance with Claim 18 are provided.

Mit dem erfindungsgemäßen Verfahren kann jede Art von Textilien, vor allem aber keimkritische Textilien (Krankenhaus-, OP- und Reinstraumtextilien) erfindungsgemäß mindestens stark keimreduzierend gereinigt werden.With the method according to the invention, any type of Textiles, but above all germ-critical textiles (Hospital, operating room and clean room textiles) according to the invention at least strongly reducing bacteria getting cleaned.

Claims (18)

1. Textilien, wie z. B. Wäsche, dadurch gekennzeichnet, dass sie ohne gesonderten Entkeimungsvorgang weitgehend keimfrei bzw. keimreduziert sind.1. Textiles, such as B. laundry, characterized in that they are largely germ-free or germ-reduced without separate disinfection process. 2. Verfahren zur Herstellung mindestens stark entkeimter Textilien, dadurch gekennzeichnet, dass während mindestens einem der Wasch- bzw. Spül- oder Trocknervorgänge ein untoxisches rein biologisches Entkeimungsmittel zugesetzt wird.2. Process for producing at least heavily disinfected Textiles, characterized in that during at least one of the washing or rinsing or Drying operations are a non-toxic, purely biological Sterilizer is added. 3. Verfahren nach Anspruch 2, dadurch gekennzeichnet, dass das Mittel in der Spül- und/oder Trocknerphase dem Reinigungsvorgang beigefügt wird.3. The method according to claim 2, characterized in that that the agent in the rinsing and / or drying phase is added to the cleaning process. 4. Verfahren nach Anspruch 2 oder 3, dadurch gekennzeichnet, dass das Mittel vor und während des Bügelvorgangs verwendet wird.4. The method according to claim 2 or 3, characterized characterized that the means before and during the Ironing process is used. 5. Mittel zur Herstellung der weitgehend entkeimten Textilien nach Anspruch 1 und zur Durchführung der Verfahren nach einem der Ansprüche 2 bis 4, dadurch gekennzeichnet, dass ein desodorierendes und stark keimreduzierendes Mittel zur Behandlung der Textilien mit einem oder mehreren Lebensmittel- Konservierungsstoffen sowie mindestens einer nicht­ toxischen, insbesondere organischen Säure eingesetzt wird.5. Means for producing the largely sterilized Textiles according to claim 1 and for carrying out the Method according to one of claims 2 to 4, characterized characterized that a deodorant and strong germ-reducing agent for treating textiles with one or more food Preservatives and at least one not toxic, especially organic acid used becomes. 6. Mittel nach Anspruch 5, welches mindestens eine Kombination einer oder mehrerer Verbindungen aus der Gruppe der Verbindungen Citronensäure, Sorbinsäure, L-Ascorbinsäure und/oder Acetylsalicylsäure oder deren Derivate aufweist
mit mindestens einem Lebensmittelkonservierungsstoff wie beispielsweise Benzoesäure und deren Derivate wie
Sorbinsäure, Citronensäure, Weinsäure, Milchsäure, Apfelsäure, Essigsäure, Bernsteinsäure, Acetysalicyl- und L-Ascorbinsäure sowie
Natriumbenzoat, p-Hydroxybenzoesäure, Ameisensäure, Propionsäure und Abkömmlinge sowie Salze, Ester und/oder Mischungen derselben.6. Composition according to claim 5, which has at least one combination of one or more compounds from the group of the compounds citric acid, sorbic acid, L-ascorbic acid and / or acetylsalicylic acid or their derivatives
with at least one food preservative such as benzoic acid and its derivatives such as
Sorbic acid, citric acid, tartaric acid, lactic acid, malic acid, acetic acid, succinic acid, acetysalicylic and L-ascorbic acid as well
Sodium benzoate, p-hydroxybenzoic acid, formic acid, propionic acid and derivatives as well as salts, esters and / or mixtures thereof. 7. Mittel nach Anspruch 5, dadurch gekennzeichnet, dass es einen Anteil eines Oxidationsmittels wie eine Perverbindung aus z. B. einem Peroxid, wie Natrium-, Kalium-, Calcium- oder Wasserstoffperoxid oder einen Abkömmling einer Persäure wie Perborat, Perphosphat, Percarbonat oder eine stark oxidierende Verbindung wie ein Permanganat aufweist.7. Composition according to claim 5, characterized in that there is a proportion of an oxidizing agent like one Per connection from z. B. a peroxide, such as sodium, Potassium, calcium or hydrogen peroxide or one Descendant of a peracid such as perborate, perphosphate, Percarbonate or a strong oxidizing compound like a permanganate. 8. Mittel nach einem der Ansprüche 5 bis 7, dadurch gekennzeichnet, dass die Kombination von 50 bis 80 Gew.-%, bevorzugt 55 bis 70 Gew.%, insbesondere 60 bis 65 Gew.-% Citronensäure, 20 bis 50 Gew.-%, bevorzugt 30 bis 45 Gew.-%, insbesondere 35 bis 40 Gew.-% einer festen Peroxoverbindung, sowie 0,3 bis 1 Gew.-% eines Lebensmittelkonservierungsstoffes aufweist, wobei die Summe aller Prozentsätze jeweils 100 ist.8. Agent according to one of claims 5 to 7, characterized characterized that the combination of 50 to 80 % By weight, preferably 55 to 70% by weight, in particular 60 to 65% by weight citric acid, 20 to 50% by weight, preferably 30 up to 45% by weight, in particular 35 to 40% by weight of a solid peroxo compound, and 0.3 to 1 wt .-% of a Has food preservative, the Sum of all percentages is 100 each. 9. Mittel nach Anspruch 8, dadurch gekennzeichnet, dass die Citronensäure bis zu 1 bis 25 Gew.-% der Gesamtmenge durch L-Ascorbinsäure und/oder Acetyl­ salicylsäure ersetzt ist.9. Composition according to claim 8, characterized in that the citric acid up to 1 to 25 wt .-% of  Total amount due to L-ascorbic acid and / or acetyl salicylic acid is replaced. 10. Mittel nach einem der Ansprüche 5 bis 7 in wässriger Lösung von 15-0,03 g Mittel, bevorzugt 10-0,1 g, insbesondere 8-0,1 g Mittel pro Liter Wasser.10. Composition according to one of claims 5 to 7 in aqueous Solution of 15-0.03 g of agent, preferably 10-0.1 g, in particular 8-0.1 g of agent per liter of water. 11. Mittel nach einem der Ansprüche 5 bis 7, gekennzeichnet durch 0,05-10 g, bevorzugt 0,2-6 g und besonders bevorzugt 0,3-4 g Natriumbenzoat und 0,1-10 g, bevorzugt 0,2-5 g und besonders bevorzugt 0,3-3 g Sorbinsäure.11. Agent according to one of claims 5 to 7, characterized by 0.05-10 g, preferably 0.2-6 g and particularly preferably 0.3-4 g of sodium benzoate and 0.1-10 g, preferably 0.2-5 g and particularly preferably 0.3-3 g sorbic acid. 12. Mittel nach einem der Ansprüche 5 bis 7 mit zusätzlich 0,001-16, vorzugsweise 12, insbesondere 10 Vol.-% H2O2 pro Liter Wasser sowie gegebenenfalls Stabilisatoren für die Peroxidverbindung.12. Composition according to one of claims 5 to 7 with an additional 0.001-16, preferably 12, in particular 10 vol .-% H 2 O 2 per liter of water and optionally stabilizers for the peroxide compound. 13. Mittel nach einem der vorhergehenden Ansprüche 5 bis 12, dadurch gekennzeichnet, dass die Lösung einen sauren PH-Wert zwischen etwa 2 und 7 aufweist.13. Composition according to one of the preceding claims 5 to 12, characterized in that the solution is one has acidic pH between about 2 and 7. 14. Mittel, insbesondere nach einem der vorhergehenden Ansprüche, gekennzeichnet durch 0,1 bis 5% eines oder mehrerer Tenside ausgewählt aus der Gruppe bestehend aus in der verwendeten Menge untoxischen anionischen und nichtionischen Tensiden, Seifen, Fettsäure-Aminocarbonsäurekondensate, Alkylbenzol­ sulfonate, Ligninsulfonate, Alkylsulfonate, Fett­ säureestern, sulfatierten Fettsäureglyceriden, Betaine, Sulfobetaine, Saponine, Fettsäureester von Polyalkoholen, Oxyäthylierte Fettsäuren, etc., und insbesondere Natriumdodecylsulfonat und Natrium­ laurylsulfat. 14. Means, in particular according to one of the preceding Claims, characterized by 0.1 to 5% of one or several surfactants selected from the group consisting of non-toxic in the amount used anionic and nonionic surfactants, soaps, Fatty acid aminocarboxylic acid condensates, alkylbenzene sulfonates, lignin sulfonates, alkyl sulfonates, fat acid esters, sulfated fatty acid glycerides, Betaines, sulfobetaines, saponins, fatty acid esters from Polyalcohols, oxyethylated fatty acids, etc., and especially sodium dodecyl sulfonate and sodium lauryl sulfate.   15. Mittel nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die organischen Säuren gesättigte oder ungesättigte Carbonsäuren mit 1-14 C- Atomen, bevorzugt 1-12 C-Atomen sind.15. Composition according to one of the preceding claims, characterized in that the organic acids saturated or unsaturated carboxylic acids with 1-14 C- Atoms, preferably 1-12 carbon atoms. 16. Mittel nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass ihm ein Korrosions­ schutzmittel vorzugsweise in 0,1 bis 1 Gew.-% in der bei der Behandlung verwendeten Konzentration der Lösung zugesetzt ist.16. Composition according to one of the preceding claims, characterized by giving it a corrosion protective agent preferably in 0.1 to 1 wt .-% in the concentration of the used in the treatment Solution is added. 17. Mittel nach einem der vorhergehenden Ansprüche 5 bis 16, dadurch gekennzeichnet, dass ihm ein wasserlösliches Silbersalz in einem Anteil von vorzugsweise weniger als 0,2 bis 0,5% der Trockenmasse zugesetzt ist.17. Composition according to one of the preceding claims 5 to 16, characterized in that it is a water soluble silver salt in a proportion of preferably less than 0.2 to 0.5% of the Dry matter is added. 18. Mittel nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass ihm eine imprägnierende faserumhüllende Komponente, z. B. Wachs beigefügt ist.18. Composition according to one of the preceding claims, characterized in that it has an impregnating fiber covering component, e.g. B. wax is added.
DE19910355A 1999-03-01 1999-03-09 Textiles useful in germ-critical environments e.g. hospitals, operating theaters and clean rooms are rendered largely germ-free by treatment with food preservative(s) and non-toxic acid(s) Withdrawn DE19910355A1 (en)

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EP00105006A EP1034701A1 (en) 1999-03-09 2000-03-09 Flat article, process and means for manufacturing

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10105345A1 (en) * 2000-07-14 2002-01-24 Arconia Gmbh Chur Composition for cleaning and disinfecting animal hair products, e.g. wool, pelts and furs, comprises a food preservative and a nontoxic acid
DE10312617A1 (en) * 2003-03-21 2004-10-07 Henkel Kgaa Germ-reducing detergent or cleaning agent and process for its production
DE10346387A1 (en) * 2003-10-07 2005-06-09 Henkel Kgaa Antimicrobial equipment of bathroom and toilet articles
WO2010078883A3 (en) * 2008-12-18 2010-12-29 Bode Chemie Gmbh Combined disinfection and decontamination agent having increased effectivity
CN114606063A (en) * 2022-03-18 2022-06-10 秦皇岛正大有限公司 Composition for digesting chloramphenicol residues and application thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10105345A1 (en) * 2000-07-14 2002-01-24 Arconia Gmbh Chur Composition for cleaning and disinfecting animal hair products, e.g. wool, pelts and furs, comprises a food preservative and a nontoxic acid
DE10312617A1 (en) * 2003-03-21 2004-10-07 Henkel Kgaa Germ-reducing detergent or cleaning agent and process for its production
DE10346387A1 (en) * 2003-10-07 2005-06-09 Henkel Kgaa Antimicrobial equipment of bathroom and toilet articles
WO2010078883A3 (en) * 2008-12-18 2010-12-29 Bode Chemie Gmbh Combined disinfection and decontamination agent having increased effectivity
US8999399B2 (en) 2008-12-18 2015-04-07 Bose Chemie GmbH Combined disinfection and decontamination agent having increased effectiveness
CN114606063A (en) * 2022-03-18 2022-06-10 秦皇岛正大有限公司 Composition for digesting chloramphenicol residues and application thereof

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