DE19740053A1 - Reactor for removing unpleasant smells and germs from (in)organic gases - Google Patents

Reactor for removing unpleasant smells and germs from (in)organic gases

Info

Publication number
DE19740053A1
DE19740053A1 DE1997140053 DE19740053A DE19740053A1 DE 19740053 A1 DE19740053 A1 DE 19740053A1 DE 1997140053 DE1997140053 DE 1997140053 DE 19740053 A DE19740053 A DE 19740053A DE 19740053 A1 DE19740053 A1 DE 19740053A1
Authority
DE
Germany
Prior art keywords
reactor
catalyst
ozone
titanium dioxide
tubes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE1997140053
Other languages
German (de)
Inventor
Kurt W Dipl Ing Hofmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HOFMANN KURT W DIPL ING FH
Original Assignee
HOFMANN KURT W DIPL ING FH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HOFMANN KURT W DIPL ING FH filed Critical HOFMANN KURT W DIPL ING FH
Priority to DE1997140053 priority Critical patent/DE19740053A1/en
Publication of DE19740053A1 publication Critical patent/DE19740053A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/88Handling or mounting catalysts
    • B01D53/885Devices in general for catalytic purification of waste gases
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/18Radiation
    • A61L9/20Ultra-violet radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light

Abstract

A reactor removes the unpleasant smells and germs present in organic and/or inorganic gases. The gases are passed through tubes in which they are brought into contact with ozone generating or ozone-free ultra violet light (UV) lamps (172-280 nm) and a catalyst (preferably titanium dioxide, especially in anatase modification, or TiO2 with silica gel). The gas passes at a uniform rate past the UV-source. Incoming gas first passes through a filter removing solid particles to prevent particle deposit on the UV-lamp surface. Liquid drops and/or aerosol droplets are collected by a separator/demister at the inlet.

Description

Reaktor zur Geruchs- und Keimminderung mittels UV-Katalysator-Technologie wird in Betrieben, in denen vorgebrauchte, recycelbare Wertstoffe angeliefert, zwischengelagert bzw. sortiert sowie an Produktionsstätten, in denen Gase organischer Zusammensetzung emittiert werden, eingesetzt. Desweiteren wird der Reaktor in Betrieben/Lebensmittelindustrie eingesetzt, die keimfreie Zuluft als Produktionsluft benötigen. Bei Recyclingbetrieben oder Betrieben in denen Geruchsstoffe organischer Zusammensetzung emittiert werden, wird der Reaktor zur Umluft- und/oder Abluftreinigung der organischen und anorganischen Geruchsstoffe sowie zur Abtötung der Viren, Pilze und Mikroorganismen verwendet.Reactor for odor and germ reduction using UV catalyst technology is delivered to companies where pre-used, recyclable materials are delivered, temporarily stored or sorted as well as at production sites in which gases organic composition are used. Furthermore, the Reactor used in companies / food industry, the aseptic supply air as Need production air. At recycling companies or companies in which Odor substances of organic composition are emitted, the reactor for air and / or exhaust air purification of organic and inorganic Odorants as well as to kill viruses, fungi and microorganisms used.

In der Massentierhaltung kann der Reaktor ebenfalls zur Abluftreinigung sowie zur Bekämpfung der in der Tierhaltung vorkommenden Mikroorganismen eingesetzt werden.In factory farming, the reactor can also be used for exhaust air purification and Combating the microorganisms occurring in animal husbandry become.

Das bedeutet, daß der Reaktor sowohl für die Zuluftaufbereitung, um keimfreie sowie geruchsneutrale Luft zu erzeugen, als auch zur Abluftreinigung, um Gase organischer und/oder anorganischer Zusammensetzung sowie mikrobiell belastete Abluft zu behandeln, großtechnisch eingesetzt werden kann.This means that the reactor for both the supply air treatment to aseptic as well as generating odorless air, as well as for exhaust air purification to gases organic and / or inorganic composition as well as microbially contaminated Treat exhaust air, can be used on an industrial scale.

Die zu reinigende Luft wird mittels eines Saugzugventilators angesaugt und dem UV-Reaktor zugeführt. In dem Reaktor befinden sich UV-Strahlenquellen spezieller Wellenlänge sowie ein Katalysator, der im Reaktorinnenraum angebracht ist. Der Prozeß der Geruchsminderung richtet sich nach der Reaktorgröße bzw. Verweilzeit des Gases in dem Reaktor, der Anzahl der UV-Strahlenquellen, der Reaktionsfläche an dem der Katalysator angebracht ist sowie der organischen Zusammensetzung des geruchsintensiven, keimbelasteten Gases.The air to be cleaned is sucked in by a suction fan and the UV reactor supplied. There are UV radiation sources in the reactor special wavelength as well as a catalyst in the interior of the reactor is appropriate. The process of odor reduction depends on the Reactor size or residence time of the gas in the reactor, the number of UV radiation sources, the reaction surface to which the catalyst is attached and the organic composition of the odor-intensive, germ-laden gas.

Um eine intensive Wechselwirkung zwischen den Geruchskomponenten, der UV Strahlung sowie dem Katalysator (Titandioxid, anatase Modifikation) zu erzielen, ist eine angemessene Verweilzeit notwendig, die durch Umlenk- und/oder Lochbleche erzielt wird.To an intensive interaction between the odor components, the UV To achieve radiation and the catalyst (titanium dioxide, anatase modification), a reasonable dwell time is necessary, which is due to deflection and / or Perforated sheets is achieved.

Folgende grundlegende Reaktionen treten in dem Reaktionsraum auf: The following basic reactions occur in the reaction space:  

Wasser (feuchte Luft) bildet unter UV-Einwirkung in Verbindung mit Titandioxid Hydroxylradikale.Water (moist air) forms under the influence of UV in conjunction with Titanium dioxide hydroxyl radicals.

Hydroxylradikale besitzen ein großes Oxidationspotential und oxidieren die meisten Geruchsstoffe auf.Hydroxyl radicals have a large oxidation potential and oxidize them most odorants.

Einige C-H-Verbindungen bilden unter UV-Einwirkung Radikale, die wiederum mit dem Sauerstoff aus der Luft weiter reagieren und somit die Geruchs­ komponente zerstört wird.Some C-H compounds form radicals under the action of UV, which in turn continue to react with the oxygen from the air and thus the smell component is destroyed.

Der Vorteil liegt darin, daß der durch das UV-Licht aktivierte Katalysator (Titandioxid TiO2) mit dem Wasser aus der Luft Hydroxylradikale bildet, die auf die Geruchskomponenten (organische Zusammensetzung) oxidierend wirken. Dadurch entstehen geruchsneutrale Komponenten.The advantage is that the catalyst activated by the UV light (titanium dioxide TiO 2 ) forms with the water from the air hydroxyl radicals, which have an oxidizing effect on the odor components (organic composition). This creates odorless components.

Die Mikroorganismen werden unter Einwirkung von UV-Licht abgetötet bzw. inaktiviert. Die Strahlung der UV-Röhren liegt im Wellenlängenbereich zwischen 172-280 nm und entspricht der Absorptionswellenlänge der Desoxyribo­ nucleinsäure, dem Baustein, der die genetische Erbinformation der Mikroorganismenzelle beinhaltet. Durch die Absorption energiereichen Lichtes werden die DNS-Moleküle in einen angeregten Zustand versetzt, wobei die aufgenommene Energie ausreicht, die Zelle so stark zu schädigen, daß sie abstirbt bzw. inaktiviert wird.The microorganisms are killed under the action of UV light or deactivated. The radiation from the UV tubes lies in the wavelength range between 172-280 nm and corresponds to the absorption wavelength of the deoxyribo nucleic acid, the building block that the genetic information of the Microorganism cell contains. High energy through absorption In light, the DNA molecules are put into an excited state, whereby the absorbed energy is sufficient to damage the cell so much that it dies or is inactivated.

Nachdem die Luft durch den Reaktor geführt wurde ist sie soweit von Geruchsemittienten und Mikroorganismen befreit, daß sie ohne weitere Nachbehandlung in die Atmosphäre abgeleitet werden kann.After the air has been led through the reactor, it is as far from Odor emitters and microorganisms exempted them without further Aftertreatment can be derived into the atmosphere.

Um den Reaktorinnenraum vor Staubpartikeln und Aerosolen zu schützen, ist am Reaktoreingang ein Partikel- bzw. Aerosolfilter plaziert. Da Staubablagerungen auf den UV-Strahlenquellen bzw. dem Katalysator die Leistung mindern. In order to protect the reactor interior from dust particles and aerosols, is on Placed a particle or aerosol filter. Because dust deposits on reduce the power of the UV radiation sources or the catalytic converter.  

Der Vorteil dieser UV-Technologie liegt im geringen Druckverlust des Reaktors, die Katalysator unterstützte Oxidation der Geruchskomponenten, dem apparativ gleich aufgebauten und kostengünstigen Reaktor sowie im niedrigen Energieverbrauch der eingesetzten UV-Strahlenquellen.The advantage of this UV technology is the low pressure drop in the reactor, the catalyst supported oxidation of the odor components, the apparatus identically constructed and inexpensive reactor as well as in the low Energy consumption of the UV radiation sources used.

Desweiteren entstehen keine Reststoffe, die zu entsorgen wären.Furthermore, there are no residues to be disposed of.

Claims (5)

1. Reaktor zur Geruchs- und Keimminderung von organischen und anorganischen Gasen, dadurch gekennzeichnet, daß das zu behandelnde Gas in diesem Reaktor mit ozonerzeugenden und/oder ozonfreien UV-Röhren der Wellenlänge 172-280 nm und einem Katalysator in Kontakt gebracht wird.1. Reactor for odor and germ reduction of organic and inorganic gases, characterized in that the gas to be treated is brought into contact with ozone-generating and / or ozone-free UV tubes of the wavelength 172-280 nm and a catalyst in this reactor. 2. Reaktor nach Anspruch 1, dadurch gekennzeichnet, daß das zu behandelnde Gas gleichmäßig um die UV-Strahlenquellen geleitet und mit dem Katalysator in Kontakt gebracht wird.2. Reactor according to claim 1, characterized in that the treating gas evenly directed around the UV radiation sources and is brought into contact with the catalyst. 3. Reaktor nach Anspruch 2, dadurch gekennzeichnet, daß Feststoff­ partikel am Reaktoreingang mittels eines Staubfilters abgeschieden werden, um die UV-Röhren vor Verschmutzung zu schützen.3. Reactor according to claim 2, characterized in that solid particles separated at the reactor inlet using a dust filter to protect the UV tubes from contamination. 4. Reaktor nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß Flüssigkeitströpfchen/Aerosole am Reaktoreingang mittels eines Tropfenabscheiders/Demisters abgeschieden werden.4. Reactor according to one of claims 1 to 3, characterized in that that liquid droplets / aerosols at the reactor inlet by means of a Droplet separators / demisters are separated. 5. Reaktor nach einem oder mehreren Ansprüchen 1 bis 4, dadurch ge­ kennzeichnet, daß zur schnellen Oxidation der Geruchskomponenten ein UV-aktivierter Katalysator, vorzugsweise Titandioxid (vorzugs­ weise anatase Modikation) und/oder Titandioxid sowie Kieselgel eingesetzt wird.5. Reactor according to one or more claims 1 to 4, characterized ge indicates that for the rapid oxidation of the odor components a UV activated catalyst, preferably titanium dioxide (preferred wise anatase modification) and / or titanium dioxide and silica gel is used.
DE1997140053 1997-09-12 1997-09-12 Reactor for removing unpleasant smells and germs from (in)organic gases Withdrawn DE19740053A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE1997140053 DE19740053A1 (en) 1997-09-12 1997-09-12 Reactor for removing unpleasant smells and germs from (in)organic gases

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1997140053 DE19740053A1 (en) 1997-09-12 1997-09-12 Reactor for removing unpleasant smells and germs from (in)organic gases

Publications (1)

Publication Number Publication Date
DE19740053A1 true DE19740053A1 (en) 1999-03-18

Family

ID=7842089

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
DE (1) DE19740053A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000039025A1 (en) * 1998-12-28 2000-07-06 Daewoo Electronics Co., Ltd. Radical generating system
WO2006128383A1 (en) * 2005-06-01 2006-12-07 72G Group Limited A processor of eliminating inside organic volatile
WO2012101406A1 (en) * 2011-01-25 2012-08-02 Sirius Products Limited An odour control unit
CN109499356A (en) * 2018-12-10 2019-03-22 绍兴上虞复旦协创绿色照明研究院有限公司 A kind of ultraviolet ray deodorization device and its deodorizing methods

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000039025A1 (en) * 1998-12-28 2000-07-06 Daewoo Electronics Co., Ltd. Radical generating system
US6303085B1 (en) 1998-12-28 2001-10-16 Daewoo Electronics Co., Ltd. Radical generating system
AU764349B2 (en) * 1998-12-28 2003-08-14 Daewoo Electronics Corporation Radical generating system
WO2006128383A1 (en) * 2005-06-01 2006-12-07 72G Group Limited A processor of eliminating inside organic volatile
WO2012101406A1 (en) * 2011-01-25 2012-08-02 Sirius Products Limited An odour control unit
CN109499356A (en) * 2018-12-10 2019-03-22 绍兴上虞复旦协创绿色照明研究院有限公司 A kind of ultraviolet ray deodorization device and its deodorizing methods

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8139 Disposal/non-payment of the annual fee