DE196112C - - Google Patents
Info
- Publication number
- DE196112C DE196112C DENDAT196112D DE196112DC DE196112C DE 196112 C DE196112 C DE 196112C DE NDAT196112 D DENDAT196112 D DE NDAT196112D DE 196112D C DE196112D C DE 196112DC DE 196112 C DE196112 C DE 196112C
- Authority
- DE
- Germany
- Prior art keywords
- gases
- nitric acid
- nitrous gases
- electrical discharges
- marketable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007789 gas Substances 0.000 claims description 10
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 230000036826 Excretion Effects 0.000 claims 1
- 230000029142 excretion Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229910052813 nitrogen oxide Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- 229910052572 stoneware Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
- C01B21/24—Nitric oxide (NO)
- C01B21/26—Preparation by catalytic or non-catalytic oxidation of ammonia
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
KLASSE 12«. GRUPPECLASS 12 «. GROUP
in GELSENKIRCHEN.in GELSENKIRCHEN.
aus nitrosen Gasen.from nitrous gases.
Patentiert im Deutschen Reiche vom 4. Februar 1906 ab. Patented in the German Empire on February 4, 1906.
Die vorliegende Erfindung betrifft die Kondensation sogenannter nitroser Gase, wie sie beispielsweise bei der Behandlung von atmosphärischer Luft mit elektrischen Entladungen erhalten werden, zu Salpetersäure von handelsfähiger Konzentration.The present invention relates to the condensation of so-called nitrous gases, such as them for example in the treatment of atmospheric air with electrical discharges obtained, to nitric acid of marketable concentration.
Das neue Verfahren besteht darin, daß man den Reaktionsgasen nach Verlassen der elektrischen Entladungen Wasser oder Wasser dampf in solcher Menge zusetzt, daß sich bei einer Abkühlung bis auf ioo° noch keine Säure aus den Gasen ausscheiden kann, weil man damit die Möglichkeit gewinnt, bis zur Abkühlung der Gase bis auf etwa ioo° metallene Kühleinrichtungen zu verwenden, welche sehr viel wirksamer und billiger sind· als Kühleinrichtungen aus Steinzeug.The new process consists in that one of the reaction gases after leaving the electrical Discharges Water or water vapor is added in such an amount that, when it cools down to 100 °, none Acid can be eliminated from the gases because it gives you the opportunity to up to Cooling of the gases down to about ioo ° to use metal cooling devices, which are much more effective and cheaper than cooling devices made of stoneware.
Dies ist wegen der geringen Haltbarkeit von Steinzeugapparaten bei TemperaturenThis is because of the low durability of stoneware appliances at temperatures
ao. über ioo° ein ganz wesentlicher Fortschritt, der noch dadurch an Bedeutung gewinnt, daß man bei dieser Arbeitsweise natürlich auch keiner Reaktionsgase von hohem Stickoxydgehalt bedarf. Letzteres hat den doppelten Vorteil, daß erstens diese dünneren Gase bei der elektrischen Luftverbrennung mit bedeutend besserer Wattausbeute hergestellt werden können als höherprozentige, daß aber auch zweitens die Gase bei ihrer Kondensation nur noch so wenig Stickstoffoxyde enthalten, daß die ausgeschiedene Säure kein Stickstoffdioxyd mehr löst, so daß die so gewonnene Säure auch praktisch frei von gelösten Stickstoffoxyden ist.ao. a very significant advance via ioo °, which becomes even more important as a result, that one of course also no reaction gases with a high nitrogen oxide content with this method of operation requirement. The latter has the double advantage that, firstly, these thinner gases are used in electrical air combustion can be produced with significantly better wattage than higher percentage that but also, secondly, the gases condense only so little nitrogen oxides contain that the precipitated acid no longer dissolves nitrogen dioxide, so that the so obtained Acid is also practically free of dissolved nitrogen oxides.
Claims (1)
Publications (1)
Publication Number | Publication Date |
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DE196112C true DE196112C (en) |
Family
ID=459120
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT196112D Active DE196112C (en) |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE196112C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE753538C (en) * | 1937-11-28 | 1953-05-26 | Ig Farbenindustrie Ag | Process for cooling ammonia oxidizing gases |
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0
- DE DENDAT196112D patent/DE196112C/de active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE753538C (en) * | 1937-11-28 | 1953-05-26 | Ig Farbenindustrie Ag | Process for cooling ammonia oxidizing gases |
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