DE19527926A1 - Double-sided pressure-sensitive adhesive material with high load bearing capacity - has film base contg. microballoons, useful in furniture industry - Google Patents

Double-sided pressure-sensitive adhesive material with high load bearing capacity - has film base contg. microballoons, useful in furniture industry

Info

Publication number
DE19527926A1
DE19527926A1 DE19527926A DE19527926A DE19527926A1 DE 19527926 A1 DE19527926 A1 DE 19527926A1 DE 19527926 A DE19527926 A DE 19527926A DE 19527926 A DE19527926 A DE 19527926A DE 19527926 A1 DE19527926 A1 DE 19527926A1
Authority
DE
Germany
Prior art keywords
sensitive adhesive
pressure
adhesive material
material according
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19527926A
Other languages
German (de)
Inventor
Edgar Lindner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lohmann GmbH and Co KG
Original Assignee
Lohmann GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lohmann GmbH and Co KG filed Critical Lohmann GmbH and Co KG
Priority to DE19527926A priority Critical patent/DE19527926A1/en
Publication of DE19527926A1 publication Critical patent/DE19527926A1/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/26—Porous or cellular plastics

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

In double-sided pressure-sensitive adhesive material with a film base, the film contains microballoons (I).

Description

1. Die Erfindung betrifft ein doppelseitig haftklebend aus­ gerüstetes Haftklebematerial mit einem Träger auf Filmba­ sis.1. The invention relates to a double-sided pressure-sensitive adhesive scaffolded PSA material with a support on film base sis.

Zur dauerhaften Verklebung beispielsweise von Spiegeln auf Schränken in der Möbelindustrie werden bislang doppelseitig haftklebend ausgerüstete Haftklebematerialien mit Trägern auf Schaumstoffbasis eingesetzt, die aufgrund des oftmals hohen Gewichtes der Spiegel besonders scherfest sein müs­ sen, damit auch geringfügiges Rutschen des angeklebten Spiegels verhindert wird. Desweiteren muß der Träger eines solchen Haftklebematerials in der Lage sein, auftretende Unebenheiten auf der Substratseite zu kompensieren, damit es aufgrund schlechter Verklebung nicht zu einem Abrutschen des angebrachten Spiegels kommt.For permanent bonding of mirrors, for example Cabinets in the furniture industry are currently double-sided Pressure-sensitive adhesive pressure-sensitive adhesive materials with carriers used on foam basis, due to the often high weight of the mirror must be particularly shear resistant sen, so that even slight gliding of the glued Mirror is prevented. Furthermore, the carrier of a such pressure-sensitive adhesive material to be able to occur To compensate for unevenness on the substrate side, so it does not slip due to poor adhesion the attached mirror comes.

Derartige Anforderungen weisen bislang Haftklebematerialien mit Schaumstoffträgern auf Basis von Polyethylen, Polyuret­ han oder Polyacrylat auf. Als Haftklebstoffe kommen solche auf Basis von Acrylat-, Silikon-, Polyurethan- oder Kautschukklebern zum Einsatz. Die so aufgebauten Haftklebe­ materialien verfügen über eine ausreichende Dicke und Kom­ pressibilität, um eventuell auftretende Unebenheiten zu kompensieren. Nachteilig erweist sich jedoch die zu geringe Scherbelastbarkeit des Schaumträgers, was bei hoher Bela­ stung zu Problemen führt.Such requirements have hitherto been pressure-sensitive adhesive materials with foam carriers based on polyethylene, Polyuret han or polyacrylate. As pressure-sensitive adhesives come such based on acrylate, silicone, polyurethane or Rubber adhesives used. The adhesive thus constructed Materials have sufficient thickness and grain pressibility to prevent any unevenness compensate. The disadvantage, however, proves to be too low Shear resilience of the foam carrier, which at high Bela equipment leads to problems.

Aufgabe der Erfindung ist es daher, die Scherbelastbarkeit des Trägersystems der nach dem heutigen Stand der Technik hergestellten Haftklebematerialien zu verbessern.The object of the invention is, therefore, the shear capacity the carrier system of the state of the art improved pressure-sensitive adhesive materials.

Gelöst wird diese Aufgabe überraschenderweise durch ein doppelseitig haftklebend ausgerüstetes Haftklebematerial mit einem Träger auf Filmbasis, der Mikrohohlkugeln ent­ hält.This problem is solved surprisingly by a Pressure-sensitive adhesive material with double-sided pressure-sensitive adhesive properties  with a film-based carrier ent the hollow microspheres ent holds.

Besonders geeignet sind Filme auf Polyurethanbasis. Die Mikrohohlkugeln enthalten vorzugsweise organische Materia­ lien. Der max. Durchmesser der Mikrokugeln liegt bei 5 bis 350 µm, vorzugsweise bei 10 bis 150 µm. Der Anteil der Mi­ krokugeln in den Filmen beträgt bis zu 50 Vol.-%. Als be­ sonders geeignet haben sich Mikrokugeln auf Polymerbasis erwiesen.Particularly suitable are polyurethane-based films. The Hollow microspheres preferably contain organic matter lien. The max. Diameter of the microspheres is 5 to 350 μm, preferably at 10 to 150 μm. The share of Mi Crocs in the films is up to 50 vol .-%. As be especially suitable are microspheres based on polymers proved.

Der zur ein- oder beidseitigen Ausrüstung des Trägermateri­ als einzusetzende Haftkleber kann aus der Gruppe der Acry­ lat-, Silikon-, Polyurethan- oder Kautschukkleber ausge­ wählt werden. Die haftklebenden Flächen können vor Gebrauch durch Abdeckungen geschützt werden. Das Haftklebematerial kann noch weitere Schichten umfassen, wie z. B. solche zum Dickenausgleich oder zur Wärmeaktivierbarkeit. Besondere Bedeutung haben erfindungsgemäße Haftklebemate­ rialien in der Möbelindustrie. Hier werden sie beispiels­ weise in Form von Bändern zur Befestigung von Spiegeln auf Schränken eingesetzt. Die dabei an das Haftklebematerial zu stellenden Anforderungen bezüglich der Scherbelastbarkeit werden von der herkömmlichen Materialien nicht erfüllt. Aufgrund des Schaumstoffträgers ist die Scherbelastbarkeit dieser Materialien nicht ausreichend so hoch und es kommt zu einem Versatz infolge Abrutschens des aufgeklebten Spie­ gels.The one- or two-sided equipment of the Trägermateri as to be used pressure-sensitive adhesive can from the group of Acry lat, silicone, polyurethane or rubber adhesive out be chosen. The pressure-sensitive adhesive surfaces can be used before use protected by covers. The pressure-sensitive adhesive material may include other layers, such as. B. such Thickness compensation or for heat activation. Particular importance is attached to pressure-sensitive adhesives according to the invention rials in the furniture industry. Here you will for example wise in the form of bands for attaching mirrors Cabinets used. The case of the pressure-sensitive adhesive material requirements with regard to shear resilience are not fulfilled by the conventional materials. Due to the foam carrier is the shear load capacity these materials are not high enough and it comes to an offset due to slipping of the glued Spie gels.

Mit dem Haftklebematerial nach der Erfindung wird dieser Nachteil behoben. Durch den Einsatz eines Trägers auf Film­ basis, der Mikrohohlkugeln enthält, wird das Haftklebemate­ rial wesentlich stabiler und es kommt zu keinem Verrutschen des Spiegels. With the pressure-sensitive adhesive material according to the invention this becomes Disadvantage solved. By using a carrier on film base, which contains hollow microspheres, becomes the pressure-sensitive adhesive rial much more stable and there is no slippage of the mirror.  

Beispielexample

Zur Herstellung des erfindungsgemäßen PUR-Klebebandes wird ein Gemisch hergestellt aus:For the preparation of the polyurethane adhesive tape according to the invention a mixture made of:

Gew.-TeileParts by weight ®Impranil HS-62 (Aromatisches PUR-Prepolymer der Fa. Bayer)®Impranil HS-62 (Aromatic PUR prepolymer from Bayer) 10001000 ®Imprafix HS-C (Vernetzungskomponente auf Aminbasis der Fa. Bayer)®Imprafix HS-C (amine-based crosslinking component from Bayer) 6262 ®Bayderm B-T0 schwarz (ketonhaltige Pigmentpräparation der Fa. Bayer)®Bayderm B-T0 black (ketone-containing pigment preparation from Bayer) 4040 ®Levacast Fluid SN (Zurichtmittel auf PUR-Basis der Fa. Bayer)®Levacast Fluid SN (Bayer PUR-based dressing) 1010 ®Acronal L 700 (Polyacrylsäureester der Fa. BASF)®Acronal L 700 (polyacrylic ester from BASF) 55 ®Tinuvin 765 (UV-Absorber der Fa. Ciba-Geigy)®Tinuvin 765 (UV absorber from Ciba-Geigy) 55 ®Dualite M 6017 AE (Hohlkugeln der Fa. UCB auf Acrylnitrilpolymerbasis)®Dualite M 6017 AE (hollow spheres of the company UCB based on acrylonitrile polymer) 6060

®Impranil HS-62 wird in einem Behälter vorgelegt und unter Rühren werden ®Imprafix HS-C und das ®Bayderm B-T0 schwarz zugegeben. Diese Mischung wird 10 Minuten gerührt. Anschließend werden ®Levacast Fluid SN, ®Acronal L 700, ®Tinuvin 765 und ®Dualite M 6017 AE zugegeben und nochmals 30 Minuten gerührt, bis eine beschichtbare Masse erhalten wird. Diese Masse wird mit Hilfe einer Streichrakel auf ein dehäsiv ausgerüstetes Papier ausgestrichen und bei einer Temperatur von ca. 160°C 2 Minuten getrocknet, so daß man eine Schicht mit einer Dicke von ca. 800 µm erhält. Die so hergestellte Schicht wird anschließend beidseitig nach Ent­ fernung des dehäsiv ausgerüsteten Papiers mit ca. 70 g/m² eines Polyacrylathaftklebers beschichtet. Zum Schutz der Klebstoffschicht wird das Klebeband mit einem dehäsiv aus­ gerüsteten Schutzpapier oder einer Schutzfolie abgedeckt.®Impranil HS-62 is placed in a container and placed under Stirring will be ®Imprafix HS-C and ®Bayderm B-T0 black added. This mixture is stirred for 10 minutes. Subsequently, ®Levacast Fluid SN, ®Acronal L 700, ®Tinuvin 765 and ®Dualite M 6017 AE added and again  Stirred for 30 minutes until a coatable mass was obtained becomes. This mass is put on with the help of a squeegee dehäsiv equipped paper struck and in a Temperature of about 160 ° C dried for 2 minutes, so that one receives a layer with a thickness of about 800 microns. The way produced layer is then on both sides after Ent Distance of the dehäsiv equipped paper with approx. 70 g / m² coated with a polyacrylate adhesive. To protect the Adhesive layer makes the tape with a dehäsiv protected protective paper or a protective film.

Claims (10)

1. Doppelseitig haftklebend ausgerüstetes Haftklebematerial mit Träger auf Filmbasis, dadurch gekennzeichnet, daß der Film Mikrohohlkugeln enthält.1. Double-sided pressure-sensitive adhesive pressure-sensitive adhesive material with a film-based carrier, characterized in that the film contains hollow microspheres. 2. Haftklebematerial nach Anspruch 1, dadurch gekennzeich­ net, daß der Film ein Polyurethanfilm ist.2. Pressure-sensitive adhesive material according to claim 1, characterized gekennzeich net, that the film is a polyurethane film. 3. Haftklebematerial nach Anspruch 1, dadurch gekennzeich­ net, daß der Anteil der Mikrokugeln am Material des Films zwischen 1 und 50 Vol-% beträgt.3. pressure-sensitive adhesive material according to claim 1, characterized gekennzeich net, that the proportion of microspheres on the material of the film between 1 and 50% by volume. 4. Haftklebematerial nach einem oder mehreren der vorange­ henden Ansprüche, dadurch gekennzeichnet, daß die Mikroku­ geln organisches oder anorganisches Material enthalten.4. pressure-sensitive adhesive material according to one or more of the preceding existing claims, characterized in that the Mikroku contain organic or inorganic material. 5. Haftklebematerial nach einem oder mehreren der vorange­ henden Ansprüche, dadurch gekennzeichnet, daß der maximale Durchmesser der Mikrokugeln zwischen 5 und 350 µm, vorzugs­ weise zwischen 10 und 150 µm beträgt.5. pressure-sensitive adhesive material according to one or more of the preceding existing claims, characterized in that the maximum Diameter of the microspheres between 5 and 350 microns, preferably wise between 10 and 150 microns. 6. Haftklebematerial nach einem oder mehreren der vorange­ henden Ansprüche, dadurch gekennzeichnet, daß die Mikroku­ geln Polymer-Hohlkugeln sind.6. pressure-sensitive adhesive material according to one or more of the preceding existing claims, characterized in that the Mikroku are polymer hollow spheres. 7. Haftklebematerial nach einem oder mehreren der vorange­ henden Ansprüche, dadurch gekennzeichnet, daß der Haftkleb­ stoff aus der Gruppe bestehend aus Acrylatklebern, Silikon­ klebern, Polyurethanklebern und Kautschukklebern ausgewählt ist.7. pressure-sensitive adhesive material according to one or more of the preceding existing claims, characterized in that the pressure-sensitive adhesive fabric from the group consisting of acrylate adhesives, silicone selected from adhesives, polyurethane adhesives and rubber adhesives is. 8. Haftklebematerial nach einem oder mehreren der vorange­ henden Ansprüche, dadurch gekennzeichnet, daß der Film ein­ seitig mit Haftkleber beschichtet ist. 8. pressure-sensitive adhesive material according to one or more of the preceding Henden claims, characterized in that the film a coated on the side with pressure-sensitive adhesive.   9. Haftklebematerial nach einem oder mehreren der vorange­ henden Ansprüche, dadurch gekennzeichnet, daß das Haftkle­ bematerial noch zusätzlich mindestens eine Schicht enthält.9. pressure-sensitive adhesive material according to one or more of the preceding existing claims, characterized in that the pressure sensitive adhesive bematerial additionally contains at least one layer. 10. Verwendung des Haftklebematerials nach einem der An­ sprüche 1 bis 9 zur Herstellung von Klebeverbindungen an Teilen.10. Use of the pressure-sensitive adhesive material according to one of the Proverbs 1 to 9 for the production of adhesive bonds Divide.
DE19527926A 1995-07-29 1995-07-29 Double-sided pressure-sensitive adhesive material with high load bearing capacity - has film base contg. microballoons, useful in furniture industry Withdrawn DE19527926A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19527926A DE19527926A1 (en) 1995-07-29 1995-07-29 Double-sided pressure-sensitive adhesive material with high load bearing capacity - has film base contg. microballoons, useful in furniture industry

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19527926A DE19527926A1 (en) 1995-07-29 1995-07-29 Double-sided pressure-sensitive adhesive material with high load bearing capacity - has film base contg. microballoons, useful in furniture industry

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DE19527926A1 true DE19527926A1 (en) 1997-01-30

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19730854A1 (en) * 1997-07-18 1999-01-21 Beiersdorf Ag Self-adhesive tape containing microballoons in the carrier layer
DE19733014A1 (en) * 1997-07-31 1999-02-04 Beiersdorf Ag Self-adhesive tape
US6103152A (en) * 1998-07-31 2000-08-15 3M Innovative Properties Co. Articles that include a polymer foam and method for preparing same
US6630531B1 (en) 2000-02-02 2003-10-07 3M Innovative Properties Company Adhesive for bonding to low surface energy surfaces
DE102004047913A1 (en) * 2004-09-29 2006-03-30 Tesa Ag Production of self-adhesive tape with expanded hollow microspheres in the base layer, for use e.g. in furniture production, involves expanding the microspheres after mixing with the components of the base tape
US7491434B2 (en) 2000-02-02 2009-02-17 3M Innovative Properties Company Adhesive for bonding to low surface energy surfaces

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4303736A (en) * 1979-07-20 1981-12-01 Leonard Torobin Hollow plastic microspheres
US5100728A (en) * 1987-07-01 1992-03-31 Avery Dennison Corporation High performance pressure sensitive adhesive tapes and process for making the same
DE9016999U1 (en) * 1990-12-17 1992-04-16 Beiersdorf Ag, 20253 Hamburg Cliché mounting tape

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4303736A (en) * 1979-07-20 1981-12-01 Leonard Torobin Hollow plastic microspheres
US5100728A (en) * 1987-07-01 1992-03-31 Avery Dennison Corporation High performance pressure sensitive adhesive tapes and process for making the same
DE9016999U1 (en) * 1990-12-17 1992-04-16 Beiersdorf Ag, 20253 Hamburg Cliché mounting tape

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999003943A1 (en) * 1997-07-18 1999-01-28 Beiersdorf Ag Self-adhesive tape with microbeads in the support layer
DE19730854A1 (en) * 1997-07-18 1999-01-21 Beiersdorf Ag Self-adhesive tape containing microballoons in the carrier layer
US6129983A (en) * 1997-07-31 2000-10-10 Beiersdorf Ag Self-adhesive tape
DE19733014A1 (en) * 1997-07-31 1999-02-04 Beiersdorf Ag Self-adhesive tape
US6797371B1 (en) 1998-07-31 2004-09-28 3M Innovative Properties Company Articles that include a polymer foam and method for preparing same
US6103152A (en) * 1998-07-31 2000-08-15 3M Innovative Properties Co. Articles that include a polymer foam and method for preparing same
US7879441B2 (en) 1998-07-31 2011-02-01 3M Innovative Properties Company Articles that include a polymer foam and method for preparing same
USRE45747E1 (en) 1998-07-31 2015-10-13 3M Innovative Properties Company Articles that include a polymer foam and method for preparing same
US6630531B1 (en) 2000-02-02 2003-10-07 3M Innovative Properties Company Adhesive for bonding to low surface energy surfaces
US7163741B2 (en) 2000-02-02 2007-01-16 3M Innovative Properties Company Adhesive for bonding to low surface energy surfaces
US7491434B2 (en) 2000-02-02 2009-02-17 3M Innovative Properties Company Adhesive for bonding to low surface energy surfaces
DE102004047913A1 (en) * 2004-09-29 2006-03-30 Tesa Ag Production of self-adhesive tape with expanded hollow microspheres in the base layer, for use e.g. in furniture production, involves expanding the microspheres after mixing with the components of the base tape
EP1642950A3 (en) * 2004-09-29 2006-06-07 tesa AG Process for producing self-adhesive tapes containing expanded micro-balloons in their support layer

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